Search

Prevention and management of water pollution are becoming a great challenge in the present scenario. Different conventional methods like carbon adsorption, ion exchange, chemical precipitation, evaporation, and biological treatments remove water pollutants. Nowadays, the requirement for effective, non-toxic and safe waste management strategies is very high. Nanomaterials have been explored in various fields due to their unique characteristics. Green synthesis of nanomaterial is becoming more popular due to their safety, non-toxicity, and ease of scale-up technology. Metal nanoparticles can be synthesized using a green synthesis method using biological sources provided by eco-friendly, non-hazardous nanomaterials with superior properties to bulk metals. Hence, this study has designed a green synthesis of magnetic (cobalt oxide) and noble (gold) nanoparticles from the fresh flowers of Clitoria ternatea. The flavonoids and polyphenols in the extract decreased the energy band gap of cobalt oxide and gold nanoparticles; hence, the capping of the natural constituents in Clitoria ternatea helped form stable metal nanoparticles. The cobalt oxide and gold nanoparticles are evaluated for their potential for eliminating organic pollutants from industrial effluent. The novelty of this present work represents the application of cobalt oxide nanoparticles in the removal of organic pollutants and a comparative study of the catalytic behaviour of both metal nanoparticles. The degradation of bromophenol blue, bromocresol green, and 4–nitrophenol in the presence of gold nanoparticles was completed in 120, 45, and 20 min with rate constants of 3.7 × 10−3/min, 6.9 × 10−3/min, and 16.5 × 10−3/min, respectively. Similarly, the photocatalysis of bromophenol blue, bromocresol green, and 4–nitrophenol in the presence of cobalt oxide nanoparticles was achieved in 60, 90, and 40 min with rate constants of 2.3 × 10−3/min, 1.8 × 10−3/min, and 1.7 × 10−3/min, respectively. The coefficient of correlation (R2) values justify that the degradation of organic pollutants follows first-order kinetics. The significance of the study is to develop green nanomaterials that can be used efficiently to remove organic pollutants in wastewater using a cost-effective method with minimal toxicity to aquatic animals. It has proved to be useful in environmental pollution management.

Conventional cold storage systems increase the risk of damage and are no longer used for the long-term storage of agricultural products. Thus, newer affordable and energy-efficient storage systems are required for enhancing the shelf life of farm produce. We investigated the coefficient of performance (COP) of an earthen clay pot refrigerator with a thermoelectric cooler (TEC) and explored cooling strategies to enhance cooling and electrical performance for increasing the shelf life of farm produce. We used MATLAB Simulink to analyze Peltier TEC module efficiency. The intrinsic characteristics, including the Seebeck coefficient (α), thermal conductivity (K), and electrical resistance (R), were determined, forming the basis of the Peltier module in MATLAB Simulink. Thermal characteristics such as COP and cooling capacity were studied as a function of system voltage (Vin) and current (Iin). The model was equipped with a 12 V/6 A, 60 W TEC and was verified by simulation investigation. We also used psychrometric measures (e.g., wet bulb, dry bulb, and dew point temperatures and relative humidity) to determine the extent of wetness or dryness of an object and monitor other temperatures of the clay pot refrigerator. The results revealed that the ambient temperature and cold and hot side temperatures fundamentally affected TEC performance. The TEC extended the shelf life of tomatoes, potatoes, and spinach by 60% compared to those stored under ambient conditions, thereby reducing their wastage. In conclusion, earthen refrigeration using TEC doubled the shelf life of farm produce compared to storage under ambient conditions, saving money, resources, labor, and supplies and enabling the development of efficient and environmentally friendly refrigeration systems.

Henoch-Schonlein Purpura (HSP) is an IgA mediated vasculitis predominantly affecting the pediatric population. This disease may leave a lifelong residual effect on renal system with a propensity for a relapse during pregnancy leading to hypertensive and hemorrhagic complications. We present a case of a patient who had HSP in adulthood and had uncomplicated caesarean delivery under regional anesthesia.