1. Relationship between Tc and hole concentration in Bi2Sr2CaCu2O8 + δ
- Author
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Seiichiro Noguchi, Norikazu Tahata, Satoshi Kanno, and Kuniyuki Koyama
- Subjects
Superconductivity ,Quenching ,Materials science ,Condensed matter physics ,Analytical chemistry ,Liquid nitrogen ,Condensed Matter Physics ,Chemical formula ,Electronic, Optical and Magnetic Materials ,law.invention ,Magazine ,law ,Limiting oxygen concentration ,Electrical and Electronic Engineering ,Single phase - Abstract
Structure and electrical property are studied in the quenched Bi 2 Sr 2 Ca 1-x Nd x Cu 2 O 8 + δ system. The quenched samples with 0≦x≦1 have a single phase of the Bi 2 Sr 2 CaCu 2 O 8 + δ structure, as do the furnace-cooled samples. The oxygen concentration decreases slightly by about 0.05 in the chemical formula upon quenching from 800°C into liquid nitrogen. The T c remains a constant (∼90K) for x≦0.15, and decreases linearly with x in the range of 0.15≦x≦0.45, and superconductivity disappears for x≧0.45. The result for the quenched systems, if x is shifted by +0.1 in it, agrees very well with that for the furnace-cooled Bi 2 Sr 2 Ca 1-x Nd x Cu 2 O 8 + δ and Bi 2 Sr 2-x Nd x CaCu 2 O 8 + δ systems. The relationship between the T c and the hole concentration in [Cu-O] is confirmed to be universal in both the quenched and the furnace-cooled Bi 2 Sr 2 CaCu 2 O 8 + δ systems.
- Published
- 1991
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