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White teeth can give confidence and tend to be associated with a healthier lifestyle in modern society. Therefore, tooth-bleaching strategies have been developed, including the use of hydrogen peroxide. Recently, peroxymonosulfate has been introduced as an alternative bleaching method to hydrogen peroxide. Although both chemicals are oxidizing agents, their effects on the molecular composition of the stained teeth are yet unknown. In this study, the molecular profiles of teeth bleached with hydrogen peroxide and peroxymonosulfate were compared using Liquid Chromatography-Tandem Mass Spectrometry. Statistical analyses were used to assess the samples. In addition, reference spectral libraries and in silico tools were used to perform metabolite annotation. Overall, principal component analysis showed a strong separation between control and hydrogen peroxide and peroxymonosulfate samples (p

In this study, we report the synthesis of a new type of chiral crystalline organic porous salt CF2 derived from the ionic reaction between tetrakis(4‐sulfophenyl)methane (TSPM) and the tetra‐(S)‐prolylamide of tetrakis(4‐aminophenyl)methane, (S)‐TPPM, and its ability to stabilize 2 nm palladium nanoparticles to give a novel, nonpyrophoric, chiral, catalytic material Pd@CF2. The preparation of the catalyst was very simple and conducted in water. The heterogeneous catalytic performance of Pd@CF2 was tested in hydrogen reductions of olefins and substituted nitroaromatic compounds using Pd/C as a comparison to determine the specific features of the novel catalyst. Although both types of catalysts exhibited similar catalytic activity in case of reductions of diphenylacetylene and nitrobenzene, Pd@CF2 predominantly promoted the reduction of p‐nitrobenzaldehyde to p‐aminobenzyl alcohol whereas Pd/C gave p‐toluidine. The reduction of p‐dinitrobenzene led to predominant formation of p‐nitrophenylhydroxylamine if promoted by the novel catalyst and to a mixture of products if promoted by Pd/C. In addition, the introduction of p‐alkoxy groups onto nitrobenzenes slowed down the reduction with Pd@CF2 but had no influence on Pd/C activity. A hypothesis ascribing these observations to dissimilar equilibrium distributions of nitro and polar groups within the organic framework and the palladium metal surface is proposed to rationalize the selectivity of the novel catalytic material. [ABSTRACT FROM AUTHOR]

The aim of the work was to achieve the Italian validation of the Succession, Identity, and Consumption Scale of Prescriptive Ageism (SIC) developed by North and Fiske. SIC is a measure of prescriptive ageism, which incorporates intergenerational tensions over practical and symbolic resources. To evaluate the psychometric properties of the Italian version of the scale, two studies were conducted. Study 1 included 931 Italian participants (mean age: 30.94; range: 18–67 years; 50.5% female) and was conducted to test the scale's structure and construct validity. Study 2 comprised 1015 Italian participants (mean age: 30.73 years; age range: 18–67; 53.5% female) and investigated the scale's structure, construct validity, and invariance by gender and age. Confirmatory factorial analyses confirmed the three-factor solution to be invariant across sex and age groups. The scale also demonstrated high internal reliability. SIC scores correlated positively with traditional measures for detecting prejudice and stereotypes towards older people. The results of the present work show that the SIC scale of Prescriptive Ageism is a valid tool for measuring prescriptive beliefs about older adults that are the basis of intergenerational tensions. [ABSTRACT FROM AUTHOR]

Intergenerational conflict appears frequently in American public discourse, often framed as clashes between Millennials and Baby Boomers. Building on intergroup threat theory in an exploratory survey, a preregistered correlational study, and a preregistered intervention (N = 1,714), we find that (a) Millennials and Baby Boomers do express more animosity toward each other than toward other generations (Studies 1–3); (b) their animosity reflects asymmetric generational concerns: Baby Boomers primarily fear that Millennials threaten traditional American values (symbolic threat) while Millennials primarily fear that Baby Boomers's delayed transmission of power hampers their life prospects (realistic threat; Studies 2–3); (c) finally, an intervention challenging the entitativity of generational categories alleviates perceived threats and hostility for both generations (Study 3). These findings inform research on intergroup threat, provide a theoretically grounded framework to understand intergenerational relations, and put forward a strategy to increase harmony in aging societies. [ABSTRACT FROM AUTHOR]

Fundamental questions in bud dormancy remain, including what temperatures fulfill dormancy requirements (i.e. chill accumulation). Recent studies demonstrate freezing temperatures promote chill accumulation and cold hardiness influences time to budbreak—the phenotype used for dormancy evaluations. Here we evaluated bud cold hardiness and budbreak responses of grapevines (Vitis hybrids) throughout chill accumulation under three treatments: constant (5 °C), fluctuating (−3.5 to 6.5 °C daily), and field conditions (Madison, WI, USA). Chill treatments experiencing lower temperatures promoted greater gains in cold hardiness (field>fluctuating>constant). All treatments decreased observed time to budbreak with increased chill accumulation. However, perceived treatment effectiveness changed when time to budbreak was adjusted to remove cold acclimation effects. Among three classic chill models (North Carolina, Utah, and Dynamic), none was able to correctly describe adjusted time to budbreak responses to chill accumulation. Thus, a new model is proposed that expands the range of chill accumulation temperatures to include freezing temperatures and enhances chill accumulation under fluctuating temperature conditions. Most importantly, our analysis demonstrates that adjustments for uneven acclimation change the perceived effectiveness of chill treatments. Therefore, future work in bud dormancy would benefit from simultaneously evaluating cold hardiness. [ABSTRACT FROM AUTHOR]