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1. Hyperfine fields at the Li site in LiFePO (sub)4 -type olivine materials for lithium rechargeable batteries: a (super)7 Li MAS NMR and SQUID study

Author

Tucker, Michael C., Doeff, Marca M., Richardson, Thomas J., Finones, Rita, Cairns, Elton J., and Reimer, Jeffrey A.

Subjects
Chemical research -- Analysis, Lithium -- Physiological aspects, Iron -- Physiological aspects, Phosphorus -- Physiological aspects, Oxygen -- Physiological aspects, Olivine -- Physiological aspects, Nuclear magnetic resonance spectroscopy -- Usage, Metal ions -- Physiological aspects, Chemistry
Abstract

Research has been conducted on the olivines in the solid solution Li(Fe,Mn)PO (sub)4. The nature of (super)7 Li NMR shift in LiMPO (sub)4 (M= Mn, Fe, Co, Ni) has been investigated and the results indicate that all compositions contain paramagnetic metal ions.

Published
2002

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