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2. Perturbation of conjugation in allylic lithium compounds due to stereochemical control of internal lithium coordination: crystallography, NMR, and calculational studies

Author

Fraenkel, Gideon, Chow, Albert, Fleischer, Roland, and Liu, Hua

Subjects
Organolithium compounds -- Analysis, Organolithium compounds -- Spectra, Nuclear magnetic resonance spectroscopy -- Analysis, Crystals -- Structure, Crystals -- Analysis, Chemistry
Abstract

The crystal structures for various internally solvated allylic lithium compounds, together with some new NMR data which provide unusual insight into dynamic behavior, is presented. Changes among the structural parameters is associated with the trends among the NMR data.

Published
2004

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