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Hyperbolic metasurfaces with unique dispersion properties can manipulate light–matter interactions according to the demands. However, due to their inherent physical properties, topological transitions (flat bands) exist only in the orthogonal directions, which greatly limit their application. Here, we unveil rich dispersion engineering and topological transitions in hyperbolic metasurfaces. Based on the effective medium theory, the rotation matrix is introduced into the dispersion relation to explain the distorted energy band diagrams, iso-frequency contours and higher-order multi-dipoles of the novel twisted metasurfaces, thereby forming multi-directional topological transitions and surface plasmon polariton propagation. Furthermore, we develop an integrated model to realize new dual-channel negative refraction and nondiffraction negative refraction. The phenomena observed in the experiments match well with the simulations, which proves that the designed metasurfaces make new types of negative refraction possible and will help to overcome the diffraction limit. The hyperbolic metasurfaces presented here exhibit exceptional capabilities for designing microscopes with a super lens at the molecular level, concealment of military aircraft, invisibility cloaks and other photonic devices with higher transmission efficiency.

Polarization conversion dichroism is of particular interest in manipulating the polarization state of light, whereas high-performance asymmetric transmission (AT) of linearly polarized waves is still inaccessible in the terahertz range. Here, a bilayer chiral metamaterial consisting of orthogonally chained S-shaped patterns with broken symmetry along the light propagation direction is proposed and demonstrated experimentally to realize a dual-band dichroic AT effect for linearly polarized terahertz waves. The AT effects are robust across a wide range of incident angles. The observed strong AT can be theoretically explained by a multiple reflection and transmission interference model and the transfer matrix method. The proposed bilayer chiral metamaterial may have broad applications in polarization manipulation, chiral biosensing and direction-dependent information processing.

Ion hydration plays a crucial role in numerous fundamental processes. Various spectroscopic methods are employed to investigate the slowing down of hydration bond dynamics in the proximity of both anions and cations. To date, most of these studies have primarily focused on the properties of binary systems. However, in comparison to ion–water binary systems, ternary systems that involve ions, water, and organic matter are more prevalent in nature and provide more realistic insights into biological processes. This study focuses on ion hydration in water and alcohol mixture using terahertz spectroscopy and x-ray diffraction (XRD). The results reveal a distinct behavior depending on the type of alcohol used. Specifically, the presence of both methanol and ethanol results in the disappearance of absorption peaks associated with NaCl hydrate at low temperatures. In contrast, tert-butanol does not exhibit such an effect, and isopropanol demonstrates a more complex response. By combining these terahertz spectroscopic findings with low-temperature XRD data, we gain insights into the formation, or lack thereof, of NaCl · 2H2O hydrate crystals. Crucially, our observations suggest a dominant correlation between the polarity of the alcohol molecules and its impact on the Na+ hydration. Strongly polar alcohols preferentially solvating the Na+ ion lead to the failure of hydrate formation, while weakly polar alcohols do not have this effect. [ABSTRACT FROM AUTHOR]

In this work, GHz and THz complex dielectric spectra of a polyethylene glycol dimethyl ether (2000 g/mol) aqueous solution were studied. The reorientation relaxation of water in this kind of macro-amphiphilic molecule solution can be well described by three Debye models, including under-coordinated water, bulk-like water [water molecules in a tetrahedral hydrogen bond network (bulk water) and bulk water molecules affected by hydrophobic groups], and slow hydrating water (water molecules donating hydrogen bonds to hydrophilic ether groups). The reorientation relaxation timescales of bulk-like water and slow hydration water both show increases with concentration from 9.8 to 26.7 ps and from 46.9 to 100.1 ps, respectively. By estimating the ratios of the dipole moment of slow hydration water to the dipole moment of bulk-like water, we calculated the experimental Kirkwood factors of bulk-like and slow hydrating water. The experimental Kirkwood factor of bulk-like water increased from 3.17 to 3.44 with concentrations, while the experimental Kirkwood factor of slow hydrating water roughly remained constant at 4.13 from concentrations of 15%–60%. The estimated water molecule numbers of three water components around monomers also confirm our sorting for water components. [ABSTRACT FROM AUTHOR]

Metasurfaces have been continuously garnering attention in both scientific and industrial fields owing to their unprecedented wavefront manipulation capabilities using arranged subwavelength artificial structures. Terahertz vortex beams have become a focus of research in recent years due to their prominent role in many cutting-edge applications. However, traditional terahertz vortex beam plates are often faced with challenges including large size, low efficiency, and limited working bandwidth. Here, we propose and experimentally demonstrate highly efficient and broadband vortex beam plates based on metasurface in the terahertz region. The experimental results well verify that the designed metasurfaces can efficiently generate terahertz vortex beams with different orbital angular momentum topological charges in the range of 0.5–1 THz. Notably, the maximum efficiency can reach about 65% at 0.5 THz. The proposed devices may play a vital role in developing vortex beams-related terahertz applications. [ABSTRACT FROM AUTHOR]