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CuInS2 quantum dots have been studied in a broad range of applications, but despite this, the fine details of their charge carrier dynamics remain a subject of intense debate. Two of the most relevant points of discussion are the hole dynamics and the influence of Cu:In synthesis stoichiometry on them. It has been proposed that Cu-deficiency leads to the formation of Cu2+, affecting the localization of holes into Cu defects. Importantly, it is precisely these confined hole states which are used to explain the interesting photoluminescence properties of CuInS2 quantum dots. We use static X-ray spectroscopy to reveal no evidence for a measurable amount of native Cu2+ states in Cu-deficient samples. Instead, the improved properties of these samples are explained by an increase of crystallinity, reducing the concentration of mid gap states. Furthermore, to understand the charge carrier dynamics, herein we employ ultrafast optical transient absorption, and fluorescence up-conversion spectroscopies in combination with ultrafast X-ray absorption spectroscopy using a hard X-ray free electron laser. We demonstrate that in non-passivated samples, holes are transferred from Cu atoms in sub-picosecond timescales. We assign this transfer to occur towards the thiol-based ligands. Finally, we observe that Cu-deficient samples are more robust against the photothermal heating effects of using higher laser fluences. This is not the case for the stoichiometric sample, where heating effects on the structure are directly observed.

Long-distance communication is one of the main bottlenecks in the development of quantum communication networks. Free-space communication is a way to circumvent exponential fiber loss and to allow longer communication distances. Satellite nodes are the main devices currently studied for free-space communication, but they come with downsides such as high cost and low availability. In this work, we study an alternative to satellites, namely aerial platforms such as high-altitude balloons. We provide a loss model to simulate the channel efficiency of balloon-to-ground, ground-to-balloon, and balloon-to-balloon communication channels, considering a large set of hardware parameters. We perform a parameter exploration to exhibit important trade-offs in these channels, as well as simulations of different quantum key distribution network architectures including balloon nodes. We demonstrate that balloons are a realistic alternative to satellites for free-space communications in national network architectures.

Future quantum networks will be composed of both terrestrial links for metropolitan and continent-scale connections and space-based links for global coverage and infrastructure resilience. However, the propagation of quantum signals through the atmosphere is severely impacted by the effects of turbulence. This is even more the case for entanglement-based quantum communication protocols requiring two free-space channels to be considered simultaneously. In this work, we assess the advantage of turbulence mitigation by adaptive optics, in particular during daytime link operation, so as to increase the coupling of the received signal into an optical fiber. We show in particular that this improves the performance of entanglement-based quantum key distribution by up to a few hundred bits per second when compared with the uncorrected scenario

Unravelling galaxy formation theory requires understanding galaxies both at high and low redshifts. A possible way to connect both realms is by studying the oldest stars in the Milky Way (i.e., the proto-Galaxy). We use the $APOGEE$-$Gaia$ surveys to perform a purely chemical dissection of Milky Way (MW) stellar populations, and identify samples of stars likely belonging to proto-Galactic fragments. The metallicity dependence of the distribution of old MW stars in the [Mg/Mn]-[Al/Fe] enables the distinction of at least two populations in terms of their star formation histories: a rapidly evolved population likely associated with the main progenitor system of the proto-MW; and populations characterised by less efficient, slower, star formation. In the Solar neighbourhood these populations are dominated by the $Gaia-Enceladus/Sausage$ accretion debris. In the inner Galaxy, they are largely associated with the $Heracles$ structure. We model the density of chemically defined proto-Galaxy populations, finding that they are well represented by a Plummer model with a scale radius of $a$ ~3.5 kpc, and an oblate ellipsoid with flattening parameters [$p$ ~0.8; $q$ ~0.6]; this finding indicates that the MW plausibly hosts a low-mass, metal-poor, bulge component. We integrate this density for $chemically$ $unevolved$ stars between $-2$ < [Fe/H] < $-0.5$ to obtain a minimum stellar mass for the proto-Galaxy of $M_{*}$ ($r$ < 10 kpc) = $9.1\pm0.2\times10^{8}$ M$_{\odot}$. Our results suggest the proto-Milky Way is at least comprised of two significant fragments: the main $in$ $situ$ progenitor and the $Heracles$ structure., Comment: Under second review in MNRAS. 13 pages, 8 Figures. We thank the referee for their comments, and welcome more!

Symbolic neural networks, such as Kolmogorov-Arnold Networks (KAN), offer a promising approach for integrating prior knowledge with data-driven methods, making them valuable for addressing inverse problems in scientific and engineering domains. This study explores the application of KAN in building physics, focusing on predictive modeling, knowledge discovery, and continuous learning. Through four case studies, we demonstrate KAN's ability to rediscover fundamental equations, approximate complex formulas, and capture time-dependent dynamics in heat transfer. While there are challenges in extrapolation and interpretability, we highlight KAN's potential to combine advanced modeling methods for knowledge augmentation, which benefits energy efficiency, system optimization, and sustainability assessments beyond the personal knowledge constraints of the modelers. Additionally, we propose a model selection decision tree to guide practitioners in appropriate applications for building physics., Comment: 19 pages, 5 figures

Stars presently identified in the bulge spheroid are probably very old, and their abundances can be interpreted as due to the fast chemical enrichment of the early Galactic bulge. The abundances of the iron-peak elements are important tracers of nucleosynthesis processes, in particular oxygen burning, silicon burning, the weak s-process, and alpha-rich freeze-out. Aims. The aim of this work is to derive the abundances of V, Cr, Mn, Co, Ni, and Cu in 58 bulge spheroid stars and to compare them with the results of a previous analysis of data from APOGEE. We selected the best lines for V, Cr, Mn, Co, Ni, and Cu located within the H-band of the spectrum, identifying the most suitable ones for abundance determination, and discarding severe blends. Using the stellar physical parameters available for our sample from the DR17 release of the APOGEE project, we derived the individual abundances through spectrum synthesis. We then complemented these measurements with similar results from different bulge field and globular cluster stars, in order to define the trends of the individual elements and compare with the results of chemical-evolution models. We verify that the H-band has useful lines for the derivation of the elements V, Cr, Mn, Co, Ni, and Cu in moderately metal-poor stars. The resulting abundances indicate that: V, Cr, and Ni vary in lockstep with Fe; Co tends to vary in lockstep with Fe, but could be showing a slight decrease with decreasing metallicity; and Mn and Cu decrease with decreasing metallicity. These behaviours are well reproduced by chemical-evolution models except for Cu, which appears to drop faster than the models predict for moderate metallicities. Finally, abundance indicators combined with kinematical and dynamical criteria appear to show that our 58 sample stars are likely to have originated in situ., Comment: 12 pages, Astronomy & Astrophysics, accepted on 9/October/2024

Fluctuations are inherent to biological systems, arising from the stochastic nature of molecular interactions, and influence various aspects of system behavior, stability, and robustness. These fluctuations can be categorized as intrinsic, stemming from the system's inherent structure and dynamics, and extrinsic, arising from external factors, such as temperature variations. Understanding the interplay between these fluctuations is crucial for obtaining a comprehensive understanding of biological phenomena. However, studying these effects poses significant computational challenges. In this study, we used an underexplored methodology to analyze the effect of extrinsic fluctuations in stochastic systems using ordinary differential equations instead of solving the Master Equation with stochastic parameters. By incorporating temperature fluctuations into reaction rates, we explored the impact of extrinsic factors on system dynamics. We constructed a master equation and calculated the equations for the dynamics of the first two moments, offering computational efficiency compared with directly solving the chemical master equation. We applied this approach to analyze a biological oscillator, focusing on the p53 model and its response to temperature-induced extrinsic fluctuations. Our findings underscore the impact of extrinsic fluctuations on the nature of oscillations in biological systems, with alterations in oscillatory behavior depending on the characteristics of extrinsic fluctuations. We observed an increased oscillation amplitude and frequency of the p53 concentration cycle. This study provides valuable insights into the effects of extrinsic fluctuations on biological oscillations and highlights the importance of considering them in more complex systems to prevent unwanted scenarios related to health issues., Comment: 21 pages, 9 figures

Carbon abundances in first-ascent giant stars are usually lower than those of their main-sequence counterparts. At moderate metallicities, stellar evolution of single stars cannot account for the existence of red-giant branch stars with enhanced carbon abundances. The phenomenon is usually interpreted as resulting from past mass transfer from an evolved binary companion now in the white dwarf evolutionary stage. Aims: We aim to confirm the links between [C/O] enhancement, s-process element enhancement and binary fraction using large-scale catalogues of stellar abundances and probable binary stars. Methods: We use a large data set from the 17 data release of the SDSS-IV/APOGEE~2 survey to identify carbon-enhanced stars in the Galactic disk. We identify a continuum of carbon enrichment throughout three different sub-populations of disk stars and explore links between the degree of carbon enrichment and binary frequency, metallicity and chemical compositions. Results: We verify a clear correlation between binary frequency and enhancement in the abundances of both carbon and cerium, lending support to the scenario whereby carbon-enhanced stars are the result of mass transfer by an evolved binary companion. In addition, we identify clustering in the carbon abundances of high-$\alpha$ disk stars, suggesting that those on the high metallicity end are likely younger, in agreement with theoretical predictions for the presence of a starburst population following the gas-rich merger of the Gaia-Enceladus/Sausage system., Comment: 20 pages

The first generation of ELT instruments includes an optical-infrared high-resolution spectrograph, indicated as ELT-HIRES and recently christened ANDES (ArmazoNes high Dispersion Echelle Spectrograph). ANDES consists of three fibre-fed spectrographs ([U]BV, RIZ, YJH) providing a spectral resolution of $\sim$100,000 with a minimum simultaneous wavelength coverage of 0.4-1.8 $\mu$m with the goal of extending it to 0.35-2.4 $\mu$m with the addition of a U arm to the BV spectrograph and a separate K band spectrograph. It operates both in seeing- and diffraction-limited conditions and the fibre feeding allows several, interchangeable observing modes including a single conjugated adaptive optics module and a small diffraction-limited integral field unit in the NIR. Modularity and fibre-feeding allow ANDES to be placed partly on the ELT Nasmyth platform and partly in the Coud\'e room. ANDES has a wide range of groundbreaking science cases spanning nearly all areas of research in astrophysics and even fundamental physics. Among the top science cases, there are the detection of biosignatures from exoplanet atmospheres, finding the fingerprints of the first generation of stars, tests on the stability of Nature's fundamental couplings, and the direct detection of the cosmic acceleration. The ANDES project is carried forward by a large international consortium, composed of 35 Institutes from 13 countries, forming a team of almost 300 scientists and engineers which include the majority of the scientific and technical expertise in the field that can be found in ESO member states., Comment: SPIE astronomical telescope and instrumentation 2024, in press

In recent years, there has been a growing demand to discern clusters of subjects in datasets characterized by a large set of features. Often, these clusters may be highly variable in size and present partial hierarchical structures. In this context, model-based clustering approaches with nonparametric priors are gaining attention in the literature due to their flexibility and adaptability to new data. However, current approaches still face challenges in recognizing hierarchical cluster structures and in managing tiny clusters or singletons. To address these limitations, we propose a novel infinite mixture model with kernels organized within a multiscale structure. Leveraging a careful specification of the kernel parameters, our method allows the inclusion of additional information guiding possible hierarchies among clusters while maintaining flexibility. We provide theoretical support and an elegant, parsimonious formulation based on infinite factorization that allows efficient inference via Gibbs sampler.

Quantum Key Distribution (QKD) enables secret key exchange between two remote parties with information-theoretic security rooted in the laws of quantum physics. Encoding key information in continuous variables (CV), such as the values of quadrature components of coherent states of light, brings implementations much closer to standard optical communication systems, but this comes at the price of significant complexity in the digital signal processing techniques required for operation at low signal-to-noise ratios. In this work, we wish to lower the barriers to entry for CV-QKD experiments associated to this difficulty by providing a highly modular, open source software that is in principle hardware agnostic and can be used in multiple configurations. We benchmarked this software, called QOSST, using an experimental setup with a locally generated local oscillator, frequency multiplexed pilots and RF-heterodyne detection, and obtained state-of-the-art secret key rates of the order of Mbit/s over metropolitan distances at the asymptotic limit. We hope that QOSST can be used to stimulate further experimental advances in CV-QKD and be improved and extended by the community to achieve high performance in a wide variety of configurations., Comment: 15 pages, 8 figures; Corrected names in metadata and file; Added acceptance date in quantum

Stellar halos of galaxies retain crucial clues to their mass assembly history. It is in these galactic components that the remains of cannibalised galactic building blocks are deposited. For the case of the Milky Way, the opportunity to analyse the stellar halo's structure on a star-by-star basis in a multi-faceted approach provides a basis from which to infer its past and assembly history in unrivalled detail. Moreover, the insights that can be gained about the formation of the Galaxy not only help constrain the evolution of our Milky Way, but may also help place constraints on the formation of other disc galaxies in the Universe. This paper includes a summary of work undertaken during a PhD thesis aiming to make progress toward answering the most fundamental question in the field of Galactic archaeology: "How did the Milky Way form?" Through the effort to answer this question, we summarise new insights into aspects of the history of assembly and evolution of our Galaxy and measurements of the structure of various of its Galactic components., Comment: This paper was written after invitation from the initiative "2023 edition of the Astronomy Prize Awardees Collection", part of the Astronomy Prize Awardees Collection in the Astrophysics and Space Science Journal. It is 17 pages long and contains nine figures

The past years have presented a surge in (AI) development, fueled by breakthroughs in deep learning, increased computational power, and substantial investments in the field. Given the generative capabilities of more recent AI systems, the era of large-scale AI models has transformed various domains that intersect our daily lives. However, this progress raises concerns about the balance between technological advancement, ethical considerations, safety measures, and financial interests. Moreover, using such systems in sensitive areas amplifies our general ethical awareness, prompting a reemergence of debates on governance, regulation, and human values. However, amidst this landscape, how to bridge the principle-practice gap separating ethical discourse from the technical side of AI development remains an open problem. In response to this challenge, the present work proposes a framework to help shorten this gap: ethical problem-solving (EPS). EPS is a methodology promoting responsible, human-centric, and value-oriented AI development. The framework's core resides in translating principles into practical implementations using impact assessment surveys and a differential recommendation methodology. We utilize EPS as a blueprint to propose the implementation of Ethics as a Service Platform, which is currently available as a simple demonstration. We released all framework components openly and with a permissive license, hoping the community would adopt and extend our efforts into other contexts. Available in https://github.com/Nkluge\-correa/ethical\-problem\-solving

Context. Traditionally, Globular Clusters (GCs) have been assumed to be quasi-relaxed non-rotating systems, characterized by spherical symmetry and orbital isotropy. However, in recent years, a growing set of observational evidence is unveiling an unexpected dynamical complexity in Galactic GCs. Indeed, kinematic studies show that a measurable amount of internal rotation is present in many present-day GCs. Aims. The objective of this work is to analyse the APOGEE-2 Value-Added Catalogs (VACs) DR17 data of a sample of 21 GCs to extend the sample showing signatures of systemic rotation, in order to better understand the kinematic properties of GCs in general. Also, we aim to identify the fastest rotating GC from the sample of objects with suitable measurements. Methods. From the sample of 23 GCs included in this work, the presence of systemic rotation was detected in 21 of the GCs, using three different methods. All these methods use the radial velocity referred to the cluster systemic velocity. Using the first method, it was possible to visually verify the clear-cut signature of systemic rotation. Whereas, using the second and third methods, it was possible to determine the amplitude of the rotation curve and the position angle of the rotation axis. Results. This study shows that 21 GCs have a signature of systemic rotation. For these clusters, the rotation amplitude and the position angle of the rotation axis have been calculated. The clusters cover a remarkable range of rotational amplitudes, from 0.77 km/s to 13.85 km/s.

In several countries, including Italy, a prominent approach to population health surveillance involves conducting repeated cross-sectional surveys at short intervals of time. These surveys gather information on the health status of individual respondents, including details on their behaviours, risk factors, and relevant socio-demographic information. While the collected data undoubtedly provides valuable information, modelling such data presents several challenges. For instance, in health risk models, it is essential to consider behavioural information, local and temporal dynamics, and disease co-occurrence. In response to these challenges, our work proposes a multivariate temporal logistic model for chronic disease diagnoses at local level. Linear predictors are modelled using individual risk factor covariates and a latent individual propensity to diseases. Leveraging a state space formulation of the model, we construct a framework in which temporal heterogeneity in regression coefficients is informed by exogenous information at local level, correspond ing to different contextual risk factors that may affect the occurrence of chronic diseases in different ways. To explore the utility and the effectiveness of our method, we analyse behavioural and risk factor surveillance data collected in Italy (PASSI), which is well-known as a country characterised by high peculiar administrative, social and territorial diversities reflected on high variability in morbidity among population subgroups., Comment: revised

This study probes the chemical abundances of the neutron-capture elements cerium and neodymium in the inner Milky Way from an analysis of a sample of $\sim$2000 stars in the Galactic Bulge/bar spatially contained within $|X_{Gal}|<$5 kpc, $|Y_{Gal}|<$3.5 kpc, and $|Z_{Gal}|<$1 kpc, and spanning metallicities between $-$2.0$\lesssim$[Fe/H]$\lesssim$+0.5. We classify the sample stars into low- or high-[Mg/Fe] populations and find that, in general, values of [Ce/Fe] and [Nd/Fe] increase as the metallicity decreases for the low- and high-[Mg/Fe] populations. Ce abundances show a more complex variation across the metallicity range of our Bulge-bar sample when compared to Nd, with the r-process dominating the production of neutron-capture elements in the high-[Mg/Fe] population ([Ce/Nd]$<$0.0). We find a spatial chemical dependence of Ce and Nd abundances for our sample of Bulge-bar stars, with low- and high-[Mg/Fe] populations displaying a distinct abundance distribution. In the region close to the center of the MW, the low-[Mg/Fe] population is dominated by stars with low [Ce/Fe], [Ce/Mg], [Nd/Mg], [Nd/Fe], and [Ce/Nd] ratios. The low [Ce/Nd] ratio indicates a significant contribution in this central region from r-process yields for the low-[Mg/Fe] population. The chemical pattern of the most metal-poor stars in our sample suggests an early chemical enrichment of the Bulge dominated by yields from core-collapse supernovae and r-process astrophysical sites, such as magneto-rotational supernovae., Comment: 21 pages, 10 figures, 1 table

Quantum Key Distribution (QKD) is a prominent application in the field of quantum cryptography providing information-theoretic security for secret key exchange. The implementation of QKD systems on photonic integrated circuits (PICs) can reduce the size and cost of such systems and facilitate their deployment in practical infrastructures. To this end, continuous-variable (CV) QKD systems are particularly well-suited as they do not require single-photon detectors, whose integration is presently challenging. Here we present a CV-QKD receiver based on a silicon PIC capable of performing balanced detection. We characterize its performance in a laboratory QKD setup using a frequency multiplexed pilot scheme with specifically designed data processing allowing for high modulation and secret key rates. The obtained excess noise values are compatible with asymptotic secret key rates of 2.4 Mbit/s and 220 kbit/s at an emulated distance of 10 km and 23 km, respectively. These results demonstrate the potential of this technology towards fully integrated devices suitable for high-speed, metropolitan-distance secure communication., Comment: 11 pages, 13 figures; Changed figure 8, acknowledgments updated