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Abstract Most fine ambient particulate matter (PM2.5)-based epidemiological models use globalized concentration-response (CR) functions assuming that the toxicity of PM2.5 is solely mass-dependent without considering its chemical composition. Although oxidative potential (OP) has emerged as an alternate metric of PM2.5 toxicity, the association between PM2.5 mass and OP on a large spatial extent has not been investigated. In this study, we evaluate this relationship using 385 PM2.5 samples collected from 14 different sites across 4 different continents and using 5 different OP (and cytotoxicity) endpoints. Our results show that the relationship between PM2.5 mass vs. OP (and cytotoxicity) is largely non-linear due to significant differences in the intrinsic toxicity, resulting from a spatially heterogeneous chemical composition of PM2.5. These results emphasize the need to develop localized CR functions incorporating other measures of PM2.5 properties (e.g., OP) to better predict the PM2.5-attributed health burdens.

Abstract The geopolitical conflict between Russia and Ukraine has disrupted Europe’s natural gas supplies, driving up gas prices and leading to a shift towards biomass for residential heating during colder months. This study assessed the consequent air quality and toxicological impacts in Milan, Italy, focusing on fine particulate matter (PM2.5, dp

Successful application of plasma-activated water (PAW) as an alternate source of nitrogen for agricultural application requires low specific energy consumption. This work reports on a dielectric barrier discharge (DBD) plasma reactor for the generation of PAW having low specific energy (SE) consumption. The SE to produce N in PAW was 3.26 GJ/kg of N, which is 68% lower than the lowest value reported to date for DBD-PAW systems. The PAW generated was characterized for its physico-chemical parameters, most of which showed a linear increase with activation time (ta). The concentration of hydrogen ion and that of the nitrate, which is the desired product for agricultural application, remained stable for four weeks in the PAW. The results indicate that minimal reactive oxygen species was formed in the plasma zone and only reactive nitrogen species (RNS) was formed confirming selectivity toward RNS. [ABSTRACT FROM AUTHOR]