1. Emission factors and chemical characterization of particulate emissions from garden green waste burning
- Author
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Nicolas Karoski, Camille Noblet, Olivier Favez, Pascal Dubois, Mathieu Pin, François Lestremau, Robin Aujay-Plouzeau, Jean-Luc Jaffrezo, Adrien Dermigny, Jean-Luc Besombes, Alexandre Albinet, Denis Van Elsuve, Marie Lemire, Serge Collet, Institut National de l'Environnement Industriel et des Risques (INERIS), Environnements, Dynamiques et Territoires de la Montagne (EDYTEM), Centre National de la Recherche Scientifique (CNRS)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry]), Institut des Géosciences de l’Environnement (IGE), Université Grenoble Alpes (UGA)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Institut de Recherche pour le Développement (IRD)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA), Environnements, Dynamiques et Territoires de Montagne (EDYTEM), Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS), and Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )
- Subjects
Environmental Engineering ,010504 meteorology & atmospheric sciences ,chemistry.chemical_element ,Backyard burning ,010501 environmental sciences ,Combustion ,01 natural sciences ,7. Clean energy ,chemistry.chemical_compound ,Organic aerosol ,11. Sustainability ,Environmental Chemistry ,[CHIM]Chemical Sciences ,Polycyclic Aromatic Hydrocarbons ,Waste Management and Disposal ,Water content ,Aerosol ,0105 earth and related environmental sciences ,Air Pollutants ,Levoglucosan ,Particulates ,Pollution ,Wood ,Green waste ,Fireplace ,Coal ,chemistry ,13. Climate action ,Emissions ,Environmental chemistry ,MESH: GEOF ,[SDE]Environmental Sciences ,Environmental science ,Pyrene ,Particulate Matter ,Open burning ,Carbon ,Gardens ,Biomass burning - Abstract
International audience; This work provides an evaluation of the emission factors (EFs) of typical garden waste burning (fallen leaves and hedge trimming) in terms of particulate matter (PM), elemental and organic carbon (EC-OC) together with a detailed chemical characterization of 88 particle-bound organic species including polycyclic aromatic hydrocarbons (PAHs), levoglucosan and its isomers, lignin breakdown products (methoxyphenols), cholesterol, alkanes, polyols and sugars. Furthermore, wood-log based burning experiments have been performed to highlight key indicators or chemical patterns of both, green waste and wood burning (residential heating) sources, that may be used for PM source apportionment purposes. Two residential log wood combustion appliances, wood stove (RWS) and fireplace, under different output conditions (nominal and reduced) and wood log moisture content (mix of beech, oak and hornbeam), have been tested. Open wood burning experiments using wood logs were also performed. Green waste burning EFs obtained were comparable to the available literature data for open-air biomass burning. For PM and for most of the organic species studied, they were about 2 to 30 times higher than those observed for wood log combustion experiments. Though, poor performance wood combustions (open-air wood log burning, fireplace and RWS in reduced output) showed comparable EFs for levoglucosan and its isomers, methoxyphenols, polyols, PAHs and sugars. Toxic PAH equivalent benzo[a]pyrene EFs were even 3–10 times higher for the fireplace and open-air wood log burning. These results highlighted the impact of the nature of the fuel burnt and the combustion performances on the emissions. Different chemical fingerprints between both biomass burning sources were highlighted with notably a predominance of odd high-molecular weight n-alkanes (higher carbon preference index, CPI), lower levoglucosan/mannosan ratio and lower sinapylaldehyde abundance for green waste burning. However, the use of such indicators seems limited, especially if applied alone, for a clear discrimination of both sources in ambient air.
- Published
- 2021
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