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The level structure of Er158 has been studied using the Gammasphere spectrometer via the Cd114(Ca48,4n) reaction at 215 MeV with both thin (self-supporting) and thick (backed) targets. The level scheme has been considerably extended with more than 200 new transitions and six new rotational structures, including two strongly coupled high-K bands. Configuration assignments for the new structures are based on their observed alignments, B(M1)/B(E2) ratios of reduced transition probabilities, excitation energies, and comparisons with neighboring nuclei and theoretical calculations. With increasing angular momentum, this nucleus exhibits Coriolis-induced alignments of both neutrons and protons before it then undergoes a rotation-induced transition from near-prolate collective rotation to a noncollective oblate configuration. This transition occurs via the mechanism of band termination around spin 45ħ in three rotational structures. Two distinct lifetime branches, consistent with the crossing of a collective "fast"rotational structure by an energetically favored "slow"terminating sequence, are confirmed for the positive-parity states, and similar behavior is established in the negative-parity states. Weak-intensity, high-energy transitions are observed to feed into the terminating states. At the highest spins, three collective bands with high dynamic moments of inertia and large quadrupole moments were identified. These bands are interpreted as triaxial strongly deformed structures and mark a return to collectivity at ultrahigh spin.

The Be9(BeF25(5/2+),BeO24)X proton-removal reaction was studied at the NSCL using the S800 spectrometer. The experimental spectroscopic factor for the ground-state to ground-state transition indicates a substantial depletion of the proton d5/2 strength compared to shell-model expectations, similar to the findings of an inverse-kinematics (p,2p) measurement performed at RIBF. The BeF25 to BeO24 ground-states overlap is considerably less than anticipated if the core nucleons behaved as rigid, doubly-magic BeO24 within BeF25. We interpret the new results within the framework of the Particle-Vibration Coupling (PVC) model, of a d5/2 proton coupled to a quadrupole phonon of an effective core. This approach provides a good description of the experimental data, requiring an effective BeO∗24 core with a phonon energy of ħω2= 3.2 MeV and a B(E2)≈2.7 W.u. - softer and more collective than a bare BeO24. Both the Nilsson deformed mean field and the PVC models appear to capture the properties of the effective core of BeF25, suggesting that the additional proton polarizes BeO24 in such a way that it becomes either slightly deformed or a quadrupole vibrator.

Hauke Horstmann, Roman Karkosch, Jochen Plagge, Tomas Smith, Maximilian Petri Department of Orthopedic Surgery, Hannover Medical School, Hannover, GermanyCorrespondence: Hauke Horstmann, Anna-von-Borries-Straße 1-7, Hannover, 30625, Germany, Tel +49 511 5354 568, Fax +49 511 5354 685, Email hauke.horstmann@diakovere.dePurpose: Torn anterior cruciate ligaments in children are rare injuries. The incidence of concomitant avulsion fracture in the skeletally immature patient is high. Reports of arthroscopic reconstruction in the literature are sparse.Case Presentation: We present the case of a femoral avulsion fracture of the anterior cruciate ligament in a seven-year-old girl. The patient underwent arthroscopic refixation with DynacordTM Suture and Suture Button. At a follow-up of 8 weeks, the patient had free range of motion and a stable knee, with a negative Lachman- and Pivot-Shift-test in particular.Conclusion: Refixation of femoral avulsion fracture can lead to good results. Open physes and size of the knee should be taken into account. Anatomic reconstruction is compulsory to receive bone on bone healing.Keywords: anterior cruciate ligament, femoral avulsion, arthroscopy, refixation

Variations in the productivity of subnivean vegetation can substantially affect the ecology of regions more susceptible to increasing warming levels and lead to significant feedback effects on the global climate. Due to its importance, this topic is at the center of a broad scope of interdisciplinary studies supported by field and remote sensing observations. However, the current knowledge about environmental factors affecting the penetration of photosynthetically active radiation (PAR) through snow is still constrained by the paucity of transmittance data. In this work, we aim to further the understanding about these interconnected processes. We conduct a systematic investigation about the effects of independent and combined changes in key nivological characteristics, namely thickness, saturation, density and grain size, on snow transmittance in the photosynthetic spectral domain. Our investigation is carried out through controlled in silico (computational) experiments supported by measured radiometric data. Its outcomes unveil fundamental quantitative and qualitative trends related to the role played by these nivological characteristics on the spectral quality of transmitted PAR, which is quantified in terms of red to blue (R/B), red to far-red (R/FR) and blue to far-red (B/FR) ratios. These trends include increases in the R/B ratio as well as decreases in the R/FR and B/FR ratios following thickness reductions or grain size increases, with opposite variations in these ratios being observed for saturation or density increases. Accordingly, the pairing of our findings with in situ and remotely collected information contributes to cement the scientific foundation required for the effective assessment of cause-effect loops linking accentuated vegetation greening to accelerated rates of snow cover recession.

The evolution of the traditional nuclear magic numbers away from the valley of stability is an active field of research. Experimental efforts focus on providing key spectroscopic information that will shed light into the structure of exotic nuclei and understanding the driving mechanism behind the shell evolution. In this work, we investigate the Z=6 spin-orbit shell gap towards the neutron dripline. To do so, we employed NA(p,2p)CA−1 quasi-free scattering reactions to measure the proton component of the 21+ state of 16,18,20C. The experimental findings support the notion of a moderate reduction of the proton 1p1/2−1p3/2 spin-orbit splitting, at variance to recent claims for a prevalent Z=6 magic number towards the neutron dripline.

We propose a phenomenological approach to examine the role of short- and long-range nucleon-nucleon correlations in the quenching of single-particle strength in atomic nuclei and their evolution in asymmetric nuclei and neutron matter. These correlations are thought to be the reason for the quenching of spectroscopic factors observed in (e,e′p), (p,2p) and transfer reactions. We show that the recently observed increase of the high-momentum component of the protons in neutron-rich nuclei is consistent with the reduced proton spectroscopic factors. Our approach connects recent results on short-range correlations from high-energy electron scattering experiments with the quenching of spectroscopic factors and addresses for the first time quantitatively this intriguing question in nuclear physics, in particular regarding its isospin dependence. We also speculate about the nature of a quasi-proton (nuclear polaron) in neutron matter and its kinetic energy, an important quantity for the properties of neutron stars.

One of the most exotic light neutron-rich nuclei currently accessible for experimental study is ^{40}Mg, which lies at the intersection of the nucleon magic number N=28 and the neutron drip line. Low-lying excited states of ^{40}Mg have been studied for the first time following a one-proton removal reaction from ^{41}Al, performed at the Radioactive Isotope Beam Factory of RIKEN Nishina Center with the DALI2 γ-ray array and the ZeroDegree spectrometer. Two γ-ray transitions were observed, suggesting an excitation spectrum that shows unexpected properties as compared to both the systematics along the Z=12, N≥20  Mg isotopes and available state-of-the-art theoretical model predictions. A possible explanation for the observed structure involves weak-binding effects in the low-lying excitation spectrum.

One of the most exotic light neutron-rich nuclei currently accessible for experimental study is ^{40}Mg, which lies at the intersection of the nucleon magic number N=28 and the neutron drip line. Low-lying excited states of ^{40}Mg have been studied for the first time following a one-proton removal reaction from ^{41}Al, performed at the Radioactive Isotope Beam Factory of RIKEN Nishina Center with the DALI2 γ-ray array and the ZeroDegree spectrometer. Two γ-ray transitions were observed, suggesting an excitation spectrum that shows unexpected properties as compared to both the systematics along the Z=12, N≥20  Mg isotopes and available state-of-the-art theoretical model predictions. A possible explanation for the observed structure involves weak-binding effects in the low-lying excitation spectrum.

Fluorenones are suitable candidates for negolytes in flow batteries, as they demonstrate the ability to store 2 electrons, and can achieve reversibility, solubility, and stability with appropriate molecular design. However, limitations persist such as the use of alkaline media, high redox potentials, and a limited scope for optimization. Herein, azoniafluorenones is reported as a novel class of negolytes. They can be readily accessed in a highly modular fashion from inexpensive commercially available materials (e.g., boronic acids). Variations in the substitution patterns reveal the 3‐substituted N‐alkylated AZON3, which demonstrates excellent solubility at neutral pH (1.64 m) with two low reversible redox potentials (−0.31 and −0.58 V vs Ag/AgCl). AZON3 exhibits high stability when evaluated at high concentration in a neutral supporting electrolyte (1 m in 3 m KCl), paired with BTMAP‐Fc on the positive side. Capacity retentions of 99.95% and 99.91% per cycle (99.35% and 99.21% per day) are achieved when cycling with 1 and 2 electrons, respectively, coupled with high volumetric capacity of 46.4 Ah L−1 (87% of capacity utilization). [ABSTRACT FROM AUTHOR]

Early invasive skin melanoma (EISM) associated with partial tumor invasion to the thin and optically complex papillary dermis (PD) represents a critical stage before the onset of metastasis. EISM lesions may be accompanied by angiogenesis, which can alter the PD's blood and fibril contents. A comprehensive understanding about these interconnected processes is essential for enhancing the efficacy of EISM optical evaluation methodologies. Employing a first‐principles computational approach supported by measured data, we systematically assess the impact that angiogenesis can have on the EISM's spectral responses. Our findings indicate that these responses are discernibly affected by angiogenesis under distinct physiological conditions, with more substantial tissue alterations leading to accentuated spectral changes in the 550–600 nm region. Accordingly, we propose the use of a customized low‐cost spectral index to monitor these processes. Furthermore, our investigation provides a high‐fidelity in silico platform for interdisciplinary research on the photobiology of evolving skin melanomas. [ABSTRACT FROM AUTHOR]

After optimization for retention of catalytic activity, 4‐chlorobenzoic acid emerged as the optimal catalyst for the aliphatic ketone Claisen rearrangement. The optimal catalyst enables a one‐pot, metal‐free, catalytic protocol from allylic alcohols to γ,δ‐unsaturated ketones. The optimized process tolerates a range of substrates, including substituents with acid‐labile protecting groups. Reaction monitoring and DFT studies of the aliphatic ketone Claisen process agree that the ultimate rearrangement step typically has the highest activation barrier. [ABSTRACT FROM AUTHOR]

Excited states in the neutron-rich isotopes P33 and P34 were populated by the O18+O18 fusion-evaporation reaction at Elab=24 MeV. The Gammasphere array was used along with the Microball particle detector array to detect γ transitions in coincidence with the charged particles emitted from the compound nucleus S36. The use of Microball enabled the selection of the proton emission channel. It also helped in determining the exact position and energy of the emitted proton; this was later employed in kinematic Doppler corrections. 16 new transitions and 13 new states were observed in P33 and 21 γ rays and 20 energy levels were observed in P34 for the first time. The nearly 4π geometry of Gammasphere allowed the measurement of γ-ray angular distributions leading to spin assignments for many states. The experimental observations for both isotopes were interpreted with the help of shell-model calculations using the (0+1)ω PSDPF interaction. The calculations accounted for both the 0p-0h and 1p-1h states reasonably well and indicated that 2p-2h excitations might dominate the higher-spin configurations in both P33 and P34.

Excited states in the neutron-rich isotopes P33 and P34 were populated by the O18+O18 fusion-evaporation reaction at Elab=24 MeV. The Gammasphere array was used along with the Microball particle detector array to detect γ transitions in coincidence with the charged particles emitted from the compound nucleus S36. The use of Microball enabled the selection of the proton emission channel. It also helped in determining the exact position and energy of the emitted proton; this was later employed in kinematic Doppler corrections. 16 new transitions and 13 new states were observed in P33 and 21 γ rays and 20 energy levels were observed in P34 for the first time. The nearly 4π geometry of Gammasphere allowed the measurement of γ-ray angular distributions leading to spin assignments for many states. The experimental observations for both isotopes were interpreted with the help of shell-model calculations using the (0+1)ω PSDPF interaction. The calculations accounted for both the 0p-0h and 1p-1h states reasonably well and indicated that 2p-2h excitations might dominate the higher-spin configurations in both P33 and P34.

The Si31 nucleus was produced through the O18(O18, αn) fusion-evaporation reaction at Elab=24MeV. Evaporated α particles from the reaction were detected and identified in the Microball detector array for channel selection. Multiple γ-ray coincidence events were detected in Gammasphere. The energy and angle information for the α particles was used to determine the Si31 recoil kinematics on an event-by-event basis for a more accurate Doppler correction. A total of 22 new states and 52 new γ transitions were observed, including 14 from states above the neutron separation energy. The positive-parity states predicted by the shell-model calculations in the sd model space agree well with experiment. The negative-parity states were compared with shell-model calculations in the psdpf model space with some variations in the N=20 shell gap. The best agreement was found with a shell gap intermediate between that originally used for A≈20 nuclei and that previously adapted for P32,34. This variation suggests the need for a more universal cross-shell interaction.

One of the overarching goals in nuclear science is to understand how the nuclear chart emerges from the underlying fundamental interactions. The description of the structure of nuclei from first principles, using ab initio methods for the solution of the many-nucleon problem with inputs from chiral effective field theory, has advanced dramatically over the past two decades. We present an overview over the available ab initio tools with a specific emphasis on electromagnetic observables, such as multipole moments and transition strengths. These observables still pose a challenge for ab initio theory and are one of the most exciting domains to exploit synergies with modern experiments. Precise experimental data are vital for the validation of the theory predictions and the refinement of ab initio methods. We discuss some of the past and future experimental efforts highlighting these synergies. This article is part of the theme issue 'The liminal position of Nuclear Physics: from hadrons to neutron stars'. [ABSTRACT FROM AUTHOR]

Conformationally flexible tertiary amine – thiourea−urea catalysts 1 and 2 for the Mannich reaction between imines and malonate esters are efficiently inhibited by quaternary ammonium halides. NMR titrations, isothermal titration calorimetry (ITC) and NOE experiments showed that the catalysts bind chloride and bromide ions with relatively high affinities (K=103–105 M−1 in acetonitrile). The halide ions not only block the active site of the catalysts, but they also induce refolding into catalytically inactive conformations upon complexation in an allosteric‐like event. At substoichiometric inhibitor:catalyst ratios, the catalysts displayed hypersensitivity to the inhibitors, with overall rates that were lower than those expected from simple 1st order kinetics and 1 : 1 inhibitor:catalyst stoichiometry. To rationalize the observed hypersensitivity, different kinetic scenarios were examined. For catalyst 2 and the Takemoto catalyst (6), the data is consistent with 2nd order dependency on catalyst concentration, suggesting that a mechanism involving only a single catalyst in the catalytic cycle is not operative. For catalyst 1, an alternative scenario involving 1st order in catalyst and catalyst poisoning at low concentrations of 1 could also rationalize the hypersensitivity. Interestingly, inhibition of catalysts 1 and 2 by halide salts led to significant loss of enantioselectivity, in contrast to the Takemoto catalyst 6 which was inhibited but with essentially no change in enantioselectivity. [ABSTRACT FROM AUTHOR]

Pyridoxal hydrochloride, a vitamin B6 vitamer, was synthetically converted to a series of diverse redox‐active benzoyl pyridinium salts. Cyclic voltammetry studies demonstrated redox reversibility under basic conditions, and two of the most promising salts were subjected to laboratory‐scale flow battery tests involving galvanostatic cycling at 10 mM in 0.1 M NaOH. In these tests, the battery was charged completely, corresponding to the transfer of two electrons to the electrolyte, but no discharge was observed. Both CV analysis and electrochemical simulations confirmed that the redox wave observed in the experimental voltammograms corresponds to a two‐electron process. To explain the irreversibility in the battery tests, we conducted bulk electrolysis with the benzoyl pyridinium salts, affording the corresponding benzylic secondary alcohols. Computational studies suggest that the reduction proceeds in three consecutive steps: first electron transfer (ET), then proton‐coupled electron transfer (PCET) and finally proton transfer (PT) to give the secondary alcohol. 1H NMR deuterium exchange studies indicated that the last PT step is not reversible in 0.1 M NaOH, rendering the entire redox process irreversible. The apparent reversibility observed in CV at the basic media likely arises from the slow rate of the PT step at the timescale of the measurement. [ABSTRACT FROM AUTHOR]

ObjectiveTo describe the frequency of myocardial infarction (MI) prior to the diagnosis of systemic lupus erythematosus (SLE) and within the first 2 years of follow-up.MethodsThe systemic lupus international collaborating clinics (SLICC) atherosclerosis inception cohort enters patients within 15 months of SLE diagnosis. MIs were reported and attributed on a specialised vascular event form. MIs were confirmed by one or more of the following: abnormal ECG, typical or atypical symptoms with ECG abnormalities and elevated enzymes (≥2 times upper limit of normal), or abnormal stress test, echocardiogram, nuclear scan or angiogram. Descriptive statistics were used.Results31 of 1848 patients who entered the cohort had an MI. Of those, 23 patients had an MI prior to SLE diagnosis or within the first 2 years of disease. Of the 23 patients studied, 60.9% were female, 78.3% were Caucasian, 8.7% black, 8.7% Hispanic and 4.3% other. The mean age at SLE diagnosis was 52.5±15.0 years. Of the 23 MIs that occurred, 16 MIs occurred at a mean of 6.1±7.0 years prior to diagnosis and 7 occurred within the first 2 years of follow-up. Risk factors associated with early MI in univariate analysis are male sex, Caucasian, older age at diagnosis, hypertension, hypercholesterolaemia, family history of MI and smoking. In multivariate analysis only age (OR=1.06 95% CI 1.03 to 1.09), hypertension (OR=5.01, 95% CI 1.38 to 18.23), hypercholesterolaemia (OR=4.43, 95% CI 1.51 to 12.99) and smoking (OR=7.50, 95% CI 2.38 to 23.57) remained significant risk factors.ConclusionsIn some patients with lupus, MI may develop even before the diagnosis of SLE or shortly thereafter, suggesting that there may be a link between autoimmune inflammation and atherosclerosis.

The emission of γ rays from neutron-bound and neutron-unbound states in Mo95, populated in the Mo94(d,p) reaction, has been investigated. Charged particles and γ radiation were detected with arrays of annular silicon and Clover-type high-purity Germanium detectors, respectively. Utilizing p-γ and p-γ-γ coincidences, the Mo95 level scheme was greatly enhanced with 102 new transitions and 43 new states. It agrees well with shell model calculations for excitation energies below ≈2 MeV. From p-γ coincidence data, a new method for the determination of spins of discrete levels is proposed. The method exploits the suppression of high-angular momentum neutron emission from levels with high spins populated in the (d,p) reaction above the neutron separation energy. Spins for almost all Mo95 levels below 2 MeV (and for a few levels above) have been determined with this method.

The emission of γ rays from neutron-bound and neutron-unbound states in Mo95, populated in the Mo94(d,p) reaction, has been investigated. Charged particles and γ radiation were detected with arrays of annular silicon and Clover-type high-purity Germanium detectors, respectively. Utilizing p-γ and p-γ-γ coincidences, the Mo95 level scheme was greatly enhanced with 102 new transitions and 43 new states. It agrees well with shell model calculations for excitation energies below ≈2 MeV. From p-γ coincidence data, a new method for the determination of spins of discrete levels is proposed. The method exploits the suppression of high-angular momentum neutron emission from levels with high spins populated in the (d,p) reaction above the neutron separation energy. Spins for almost all Mo95 levels below 2 MeV (and for a few levels above) have been determined with this method.