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Atom interferometry is proving to be one of the most precise technique in gravimetry and gravity gradiometry, measurements of gravitational acceleration and gravitation gradient, respectively, in addition to magnetometry, inertial sensing and many other fields. The high precision of these instruments has attracted applications in fundamental physics research. The potential of employing this technique for the searches in dark-sector physics initiated the building of an atom interferometer at the University of Liverpool. The interferometer is in an atomic drop configuration. It employs ultra-cold Rb-85 as the atomic medium and a two-laser optical system. The atom source loads about a hundred million Rb-85 atoms and cools them down to 15 ��K. The interferometric beams are generated with a high-frequency acoustic-optical modulator. The coherent control of atomic states was achieved via Raby oscillations, and atom interferometry has been demonstrated via Ramsey fringes with velocity-insensitive interferometric beams. This success provided an opportunity for building a new atom interferometer capable of velocity-sensitive measurements. The new interferometer will be able to operate in both atom launch and drop configurations and has the main vacuum chamber with 23 viewports, compared to 10 previously. This allowed for the incorporation of a low-velocity atom source. Two prototypes, 2D MOT and Axicon MOT, are being developed. A high power laser generating 8 W of 780 nm light via frequency doubling was built to increase the number of atoms. Such high powers necessitated a reconstruction of the optical control circuit, also allowing for atomic launch, improved state selection, and spurious light reduction. An effective vibration isolation system was constructed. Combining passive isolation and active cancellation technology in a working device was a significant step towards high sensitivity measurements. A new interferometry beam system was prospected, employing an injection-locked modulated laser diode. The prototype of such a system was built. The system proved to be capable of generating phase-locked light separated by 3 GHz. Later, due to concerns of stability and power limitations, a previous interferometry beam system was redesigned and improved instead. It employs additional tampered amplifiers to increase the power and a separate laser with an electro-optical modulator for the higher single-photon detuning, both required for velocity-sensitive measurements.

Cooling enhances the energy conversion efficiency and output of photovoltaic (PV) panels. In this work, the effects of natural convection, forced convection, and evaporative cooling on the performance of polycrystalline PV panels were investigated. The output and efficiency of a cooled PV panel were monitored and compared to those of an uncooled PV panel under the same conditions. The cooling was conducted using an insulated channel installed below a PV panel. Natural convection cooling was investigated for various channel air gaps (H = 30, 60, 90, and 120 mm). Natural convection currents in the cooling channels were capable of cooling the panel with wide air gaps. In forced convection cooling, the air was introduced by fans installed at the bottom opening of the cooling channel with various air velocities (ua = 1, 2, and 3 m/s). Evaporative natural convection cooling was performed by a wetted fabric along the lower surface of the cooling channel, whereas evaporative forced convection cooling by pushing air along the wetted lower surface of the channel. The experimental data showed that the panel efficiency and output increased due to cooling. The experimental results of natural convection cooling revealed that the use of an air gap of 120 mm to cool the solar panel contributed to an increase in the panel daily energy production and efficiency by 1.7% and 1.2%, respectively. For forced convection cooling, using air at a speed of 3 m/s increased the daily energy production by 4.4% and the efficiency by 4%. Natural convection evaporative cooling increased the daily energy production and the efficiency by 3.6% and 2.7%, respectively. Forced convection evaporative cooling contributed, at a speed of 2 m/s, to an increase in the daily energy production by 3.8% and an increase in efficiency of 3.8%.

In this manuscript, the chemi-ionization (CI) processes in atom - Rydberg atom collisions are examined. We obtained the cross-sections, as well as rate coefficients for CI processes in potassium and sodium collisions for principal quantum numbers 5⩽n⩽25 in the 500 K ⩽T⩽1500 K temperature region. The presented data could be useful for the improvement of analysis and modelling of weakly ionized layers of different atmospheres and cosmic objects where these and other CI processes could change excited state populations and the free electron density, consequently affecting the optical characteristics.

For any distinct two primes $p_1\equiv p_2\equiv 3$ $(\text{mod }4)$, let $h(-p_1)$, $h(-p_2)$ and $h(p_1p_2)$ be the class numbers of the quadratic fields $\mathbb{Q}(\sqrt{-p_1})$, $\mathbb{Q}(\sqrt{-p_2})$ and $\mathbb{Q}(\sqrt{p_1p_2})$, respectively. Let $\omega_{p_1p_2}:=(1+\sqrt{p_1p_2})/2$ and let $\Psi(\omega_{p_1p_2})$ be the Hirzebruch sum of $\omega_{p_1p_2}$. We show that $h(-p_1)h(-p_2)\equiv h(p_1p_2)\Psi(\omega_{p_1p_2})/n$ $(\text{mod }8)$, where $n=6$ (respectively, $n=2$) if $\min\{p_1,p_2\}>3$ (respectively, otherwise). We also consider the real quadratic order with conductor $2$ in $\mathbb{Q}(\sqrt{p_1p_2})$., Comment: 19 pages

Hyperfine interactions between electron and nuclear spins have been widely used in material science, organic chemistry, and structural biology as a sensitive probe to the local chemical environment through spatial identification of nuclear spins. With the nuclear spins identified, the isotropic and anisotropic components of the hyperfine interactions in turn offer unique insight into the electronic ground-state properties of the paramagnetic centers. However, traditional ensemble measurements of hyperfine interactions average over a macroscopic number of spins with different geometrical locations and nuclear isotopes. Here, we use a scanning tunneling microscope (STM) combined with electron spin resonance (ESR) to measure hyperfine spectra of hydrogenated-titanium (Ti) atoms on MgO/Ag(100) and thereby determine the isotropic and anisotropic hyperfine interactions at the single-atom level. By combining vector-field ESR spectroscopy with STM-based atom manipulation, we characterize the full hyperfine tensor of individual Ti-47 and Ti-49 atoms and identify significant spatial anisotropy of hyperfine interaction for both isotopes when they are adsorbed at low-symmetry binding sites. Density functional theory calculations reveal that the large hyperfine anisotropy arises from a highly anisotropic distribution of the ground-state electron spin density. Our work highlights the power of ESR-STM-enabled single-atom hyperfine spectroscopy as a powerful tool in revealing ground-state electronic structures and atomic-scale chemical environments with nano-electronvolt resolution., 17 pages, 4 figures

The objective of the paper was to compare values of the muzzle brake efficiency coefficient for a rifle with active or inactive automatics systems. Special laboratory stand designed for investigating the recoil process was used. The motion of the rifle was detected by the use of the laser interferometer and the optical camera. The recoil velocity time courses were determined by smoothing and differentiation of experimental position records. The results of the experiments indicated that in the case of an active automatics system two values of the recoil velocity can be used for calculation of the energetic efficiency coefficient: the maximum recoil velocity and the final recoil velocity at the end of the automatics action cycle. The values of the coefficient, calculated using these two values of the recoil velocity, distinctly differ. However, it was shown that their values indicate the same relation between the efficiency of various muzzle brakes. The value of the efficiency coefficient, determined on the basis of the final recoil velocity value, is practically the same as that determined on the basis of the final recoil velocity value for the rifle with an inactive automatics system.

Ultralight scalar dark matter may induce apparent oscillations of the muon mass, which may be directly probed via temporal shifts in the spectra of muonium and muonic atoms. Existing datasets and ongoing spectroscopy measurements with muonium are capable of probing scalar-muon interactions that are up to 12 orders of magnitude more stringent than astrophysical bounds. Ongoing free-fall experiments with muonium can probe forces associated with the exchange of virtual ultralight scalar bosons between muons and standard-model particles, offering up to 5 orders of magnitude improvement in sensitivity over complementary laboratory and astrophysical bounds., Comment: 14 pages, 2 figures, version accepted for publication in PRL

By using corks we construct diffeomorphic ribbon disks $D\subset B^{4}$, which are non-isotopic rel boundary to each other., Comment: 5 pages, 9 figures

We introduce the concept of TRAP (Traces and Permutations), which can roughly be viewed as a wheeled PROP (Products and Permutations) without unit. TRAPs are equipped with a horizontal concatenation and partial trace maps. Continuous morphisms on an infinite dimensional topological space and smooth kernels (resp. smoothing operators) on a closed manifold form a TRAP but not a wheeled PROP. We build the free objects in the category of TRAPs as TRAPs of graphs and show that a TRAP can be completed to a unitary TRAP (or wheeled PROP). We further show that it can be equipped with a vertical concatenation, which on the TRAP of linear homomorphisms of a vector space, amounts to the usual composition. The vertical concatenation in the TRAP of smooth kernels gives rise to generalised convolutions. Graphs whose vertices are decorated by smooth kernels (resp. smoothing operators) on a closed manifold form a TRAP. From their universal properties we build smooth amplitudes associated with the graph., 52 pages, many figures. arXiv admin note: substantial text overlap with arXiv:2005.02115

Sympathetic cooling of a Fermi gas with a buffer gas of bosonic atoms is an efficient way to achieve quantum degeneracy in Fermi systems. However, all attempts to use this method for cooling ions until recently were ineffective because of the unremovable ion `"micromotion" in electromagnetic Paul traps, which prevents the realization of a number of hot projects with cold atom-ion systems. In this regard, we propose a new efficient method for sympathetic cooling of ions: the use for this purpose of cold buffer atoms in the region of atom-ion confinement-induced resonances (CIRs) [V.S. Melezhik, Phys. Rev. A103, 53109 (2021)]. We show that the destructive effect of "micromotion" on its sympathetic cooling can, however, be suppressed in the vicinity of the atom-ion CIR. Here, the resonant blocking of a close collision of an atom with an ion also resists its heating due to "micromotion". We investigate the effect of sympathetic cooling around CIRs in atom-ion, and atom-atom confined collisions within the quantum-quasiclassical approach using the Li-Yb$^+$ and Li-Yb confined systems as an example. In this approach, the Schr\"odinger equation for a cold light atom is integrated simultaneously with the classical Hamilton equations for a hotter heavy-ion or atom during a collision. We have found the region near the atom-ion CIR where the sympathetic cooling of the ion by cold atoms is possible in a hybrid atom-ion trap. We also show that it is possible to improve the efficiency of sympathetic cooling in atomic traps by using atomic CIRs., Comment: 8 pages, 4 figures, report on Int. Conf. on Pecision Physics and Fundamental Physical Constants (FFK2021) 4-8 October 2021, Stara Lesna, Slovakia. arXiv admin note: substantial text overlap with arXiv:2101.03565

The prospects of tests of CPT symmetry using precision spectroscopy of antihydrogen are discussed with special emphasis on the ground-state hyperfine structure, a measurement of which is the aim of the ASACUSA collaboration at the AD/ELENA facility of CERN. Ongoing parallel experiments using hyperfine spectroscopy of hydrogen and deuterium aiming at studying Lorentz invariance by determining coefficients of the Standard Model Extension framework are described., 8 pages 2 figures, Physics of Elementary Particles and Atomic Nuclei, in print, as part of the proceedings of the International Conference on Precision Physics and Fundamental Physical Constants, FFK2021

We consider the spectral gap of a uniformly chosen random $(d_1,d_2)$-biregular bipartite graph $G$ with $|V_1|=n, |V_2|=m$, where $d_1,d_2$ could possibly grow with $n$ and $m$. Let $A$ be the adjacency matrix of $G$. Under the assumption that $d_1\geq d_2$ and $d_2=O(n^{2/3}),$ we show that $\lambda_2(A)=O(\sqrt{d_1})$ with high probability. As a corollary, combining the results from Tikhomirov and Youssef (2019), we showed that the second singular value of a uniform random $d$-regular digraph is $O(\sqrt{d})$ for $1\leq d\leq n/2$ with high probability. Assuming $d_2$ is fixed and $d_1=O(n^2)$, we further prove that for a random $(d_1,d_2)$-biregular bipartite graph, $|\lambda_i^2(A)-d_1|=O(\sqrt{d_1})$ for all $2\leq i\leq n+m-1$ with high probability. The proofs of the two results are based on the size biased coupling method introduced in Cook, Goldstein, and Johnson (2018) for random $d$-regular graphs and several new switching operations we defined for random bipartite biregular graphs., Comment: 23 pages, 3 figures

We study the quantum interference between the excitation pathways in a three-level $\Lambda$-type atom interacting with two short laser pulse trains under the conditions of electromagnetically induced transparency. The probability amplitude equations which describe the interaction of a three-level $\Lambda$-type atom with two laser pulse trains are numerically solved. We derive analytical expressions for the population of the upper excited state for resonant laser pulse trains with a rectangular temporal profile. By varying the parameters of the laser pulse trains such as area of a single pulse, detuning, repetition period, and number of individual pulses, we analyze the quantum interference between the excitation pathways in terms of the upper excited state population.

Using the platform of a trapped-atom clock on a chip, we observe the time evolution of spin-squeezed hyperfine clock states in ultracold rubidium atoms on previously inaccessible timescales up to 1 s. The spin degree-of-freedom remains squeezed after 0.6 s, which is consistent with the limit imposed by particle loss and is compatible with typical Ramsey times in state-of-the-art microwave clocks. The results also reveal a surprising spin-exchange interaction effect that amplifies the cavity-based spin measurement via a correlation between spin and external degrees of freedom. These results open up perspectives for squeezing-enhanced atomic clocks in a metrologically relevant regime and highlight the importance of spin interactions in real-life applications of spin squeezing., 12 pages, 6 figures

Anomalous high-harmonic generation (HHG) arises in certain solids when irradiated by an intense laser field, as the result of a nonlinear perpendicular current akin to a Hall current. Here, we theoretically characterize the anomalous HHG mechanism, via development of an ab-initio methodology for strong-field laser-solid interaction that allows a rigorous decomposition of the total current. We identify two key characteristics of the anomalous harmonic yields: an overall increase with laser wavelength; and pronounced minima at certain intensities or wavelengths around which the emission time profiles drastically change. Such signatures can be exploited to disentangle the anomalous harmonics from the competing interband harmonics, and thus pave way for the experimental identification and time-domain control of pure anomalous harmonics., Comment: 7 pages, 4 figures

Alkali-metal atomic magnetometry is widely used due to its high sensitivity and cryogen-free operation. However, when operating in geomagnetic field, it suffers from heading errors originating from nonlinear Zeeman (NLZ) splittings and magnetic resonance asymmetries, which lead to difficulties in mobile-platform measurements. We demonstrate an alignment based $^{87}$Rb magnetometer, which, with only a single magnetic resonance peak and well-separated hyperfine transition frequencies, is insensitive or even immune to NLZ-related heading errors. It is shown that the magnetometer can be implemented for practical measurements in the geomagnetic environments and the photon-shot-noise-limited sensitivity reaches $9\,{\rm{fT}}/\sqrt{\rm{Hz}}$ at room temperature., 8 pages, 5 figures

International audience; The frequency chirping properties of silicon ring resonator modulators (RRMs) are experimentally investigated under sinusoidal modulation. The modulated electric field at the output of an RRM is measured in the time domain thanks to a coherent detection system. The power and phase waveforms are then analyzed in terms of their temporal phase and amplitude for different wavelength detunings between the optical source and the resonance and for different modulation frequencies. The evolution of the frequency chirp, described through a peak-to-peak chirp parameter, is quantified as a function of wavelength detuning and modulation frequency for the first time.

The Lamb dipole is a traveling wave solution to the two-dimensional Euler equations introduced by S. A. Chaplygin (1903) and H. Lamb (1906) at the early 20th century. We prove orbital stability of this solution based on a vorticity method initiated by V. I. Arnold. Our method is a minimization of a penalized energy with multiple constraints that deduces existence and orbital stability for a family of traveling waves. As a typical case, orbital stability of the Lamb dipole is deduced by characterizing a set of minimizers as an orbit of the dipole by a uniqueness theorem in the variational setting., Comment: 41 pages

In the centre of mass frame, we have studied theoretically the Z -boson resonant production in the presence of an intense laser field via the weak process e + e − → μ + μ − . Dressing the incident particles by a Circularly Polarized laser field (CP-laser field), at the first step, shows that for a given laser field’s parameters, the Z - boson cross section decreases by several orders of magnitude. We have compared the Total Cross Section (TCS) obtained by using the scattering matrix method with that given by the Breit-Wigner approach in the presence of a CP-laser field and the results are found to be very consistent. This result indicates that Breit-Wigner formula is valid not only for the laser-free process but also in the presence of a CP-laser field. The dependence of the laser-assisted differential cross section on the Centre of Mass Energy (CME) for different scattering angles proves that it reaches its maximum for small and high scattering angles. At the next step and by dressing both incident and scattered particles, we have shown that the CP-laser field largely affects the TCS, especially when its strength reaches 1 0 9 V . c m − 1 . This result is interpreted by the fact that heavy interacting particles require high laser field intensities to affect the collision’s cross section.

Significant leaps in the understanding of quantum systems have been driven by the exploration of geometry, topology, dimensionality, and interactions with ultracold atomic ensembles. A system where atoms evolve while confined on an ellipsoidal surface represents a heretofore unexplored geometry and topology. Realizing such an ultracold bubble system (potentially Bose-Einstein condensed) has areas of interest including quantized-vortex flow respecting topological constraints imposed by closed surfaces, new collective modes, and self-interference via free bubble expansion. Large ultracold bubbles, created by inflating smaller condensates, directly tie into Hubble-analog expansion physics. Here, we report observations from the NASA Cold Atom Lab facility aboard the International Space Station of bubbles of ultracold atoms created using a radiofrequency-dressing protocol. We observe a variety of bubble configurations of differing sizes and initial temperature, and explore bubble thermodynamics, demonstrating significant cooling associated with inflation. Additionally, we achieve partial coverings of bubble traps greater than 1 mm in size with ultracold films of inferred few-$\mu$m thickness, and we observe the dynamics of shell structures projected into free-evolving harmonic confinement. The observations are part of the first generation of scientific measurements made with ultracold atoms in space, exploiting the benefits of perpetual free-fall to explore gravity-free evolution of quantum systems that are prohibitively difficult to create on Earth. This work points the way to experiments focused on the nature of the Bose-Einstein condensed bubble, the character of its excitations, and the role of topology in its evolution; it also ushers in an era of orbital microgravity quantum-gas physics.

We prove the convergence of the density on the scale $Z^{-1}$ to the density of the Bohr atom (with infinitely many electrons) (strong Scott conjecture) for a model that is known to describe heavy atoms accurately.

OBJETIVES: To assess the effect of various factors on laser fiber tip degradation with the Thulium Fiber Laser (Tm-fiber): fiber stripping, adjustable laser settings (energy, frequency, peak power)...

Experimental data for the generation of optical frequency combs in magnesium fluoride microcavities with whispering gallery modes at 780 nm are presented. This wavelength corresponds to the normal group velocity dispersion for pumping by a laser diode operating in self-injection locking regime. It is shown that the excitation of frequency combs is caused both by the processes in the microresonator and by the processes in the laser diode. It is found that, in the self-injection locking regime, initially suppressed, longitudinal modes of the laser diode can be amplified, which leads to the generation of hybrid, laser-enhanced side components. As a result, combs with a highly effective conversion of pumping energy and a low level of phase noise are excited.

Evaporative cooling is a widely used energy-saving and environmentally friendly cooling technology. Evaporative cooling can be defined as a mass and heat transfer process in which the air is cooled by the evaporation of water and as a result a large amount of heat is transferred from the air to the water and thus the air temperature decreases. Evaporative cooling is mainly used in many cooling technologies used in buildings, factories, agricultural in addition to it is used industrially in cooling towers, evaporative condensers, humidification, and humidity control applications. Evaporative cooling is divided into direct evaporative cooling and indirect evaporative cooling, as well as water evaporative cooling and air evaporative cooling. This paper reviews the most important developments and technologies in evaporative cooling that lead to lower energy consumption and provide suitable cooling comfort.

Despite quantum electrodynamics (QED) being one of the most stringently tested theories underpinning modern physics, recent precision atomic spectroscopy measurements have uncovered several small discrepancies between experiment and theory. One particularly powerful experimental observable that tests QED independently of traditional energy level measurements is the `tune-out' frequency, where the dynamic polarizability vanishes and the atom does not interact with applied laser light. In this work, we measure the `tune-out' frequency for the $2^{3\!}S_1$ state of helium between transitions to the $2^{3\!}P$ and $3^{3\!}P$ manifolds and compare it to new theoretical QED calculations. The experimentally determined value of $725\,736\,700\,$$(40_{\mathrm{stat}},260_{\mathrm{syst}})$ MHz is within ${\sim} 1.7\sigma$ of theory ($725\,736\,252(9)$ MHz), and importantly resolves both the QED contributions (${\sim} 30 \sigma$) and novel retardation (${\sim} 2 \sigma$) corrections., Comment: Main text 6 pages, 4 figures, SI 21 pages 11 figures. Changed title from "Precision Measurement of the Helium $2^{3\!}S_1- 2^{3\!}P/3^{3\!}P$ Tune-Out Frequency as a Test of QED"

International audience; Finite element simulation modeling permits to predict hydrogen concentration for various initial boundary-values problems, but the results depend on the underlying transport mechanisms accounted for. Trapping process is a key factor in the apparent hydrogen diffusion, and the case of mobile traps as dislocations needs modification of the hydrogen transport equation usually considered in the literature. An extension of this model is proposed where hydrogen dragging by mobile traps is modeled by reaction-diffusion equations, involving trapping and detrapping kinetic, and is applied for evolving trap density with plastic strain. The consequences of trapped hydrogen mobility on diffusive hydrogen repartition in a reference Small Scale Yielding configuration are focused on, especially in term of acceleration of hydrogen transport. The potentiality of the model is illustrated by the modeling of the trapped hydrogen breakaway from fast moving dislocations.

application/pdf, Novel energy styles and energy productions are so required, hydrogen energy has been much attraction from the viewpoint of the environment. Many utilities of the hydrogen energy have been studied, and the industry studies of hydrogen production have also been done. In Fig. 1, it is shown that the facility of the hydrogen production in Jülich. The "Green hydrogen technologies" project has been demonstrated, and the hydrogen gas has been sourced continuously from solar heat. It has the advantage of storing sustainable "solar energy", which can be irradiated from the sun to the earth as the form of "hydrogen energy". So, it makes good sense to convert intermittently solar energy (clean energy) to hydrogen energy (clean energy). Considering these points, Kodama et al. has studied new energy production of the solar thermochemical production by an oxidation‐reduction reaction of the cerium oxide (CeO2, ceria). In Fig. 2, the hydrogen production facility uses the solar thermochemical process at Miyazaki University in Japan. The flow of hydrogen production is shown in Fig. 3. Then, the sunlight can be concentrated by many heliostats and converted to thermal energy. The hydrogen gas can be generated by the thermal redox reaction with control of the reaction temperature. Moreover, the redox reaction is the cycle reaction that consisted of two‐step reactions, which makes it possible to produce hydrogen gas efficiently. If the solar energy can be supplied stably, we can get hydrogen energy continuously.

Let $\mathfrak{g}$ be a finite-dimensional complex Lie algebra and $\textrm{HLie}_{m}(\mathfrak{g})$ be the affine variety of all multiplicative Hom-Lie algebras on $\mathfrak{g}$. We use a method of computational ideal theory to describe $\textrm{HLie}_{m}(\mathfrak{gl}_{n}(\mathbb{C}))$, showing that $\textrm{HLie}_{m}(\mathfrak{gl}_{2}(\mathbb{C}))$ consists of two 1-dimensional and one 3-dimensional irreducible components, and showing that $\textrm{HLie}_{m}(\mathfrak{gl}_{n}(\mathbb{C}))=\{\textrm{diag}\{\delta,\dots,\delta,a\}\mid \delta=1\textrm{ or }0,a\in\mathbb{C}\}$ for $n\geqslant 3$. We construct a new family of multiplicative Hom-Lie algebras on the Heisenberg Lie algebra $\mathfrak{h}_{2n+1}(\mathbb{C})$ and characterize the affine varieties $\textrm{HLie}_{m}(\mathfrak{u}_{2}(\mathbb{C}))$ and $\textrm{HLie}_{m}(\mathfrak{u}_{3}(\mathbb{C}))$. We also study the derivation algebra $\textrm{Der}_{D}(\mathfrak{g})$ of a multiplicative Hom-Lie algebra $D$ on $\mathfrak{g}$ and under some hypotheses on $D$, we prove that the Hilbert series $\mathcal{H}(\textrm{Der}_{D}(\mathfrak{g}),t)$ is a rational function., Comment: To appear in Linear and Multilinear Algebra

Coherent anti-Stokes Raman spectroscopy (CARS) and Ccherent anti-Stokes hyper-Raman spectroscopy (CAHRS), as other high-order nonlinear spectroscopy techniques, are widely exploited in many research fields, such as dynamic processes, gene expression spectrum screening, high-resolution spectroscopy, and nonlinear high-resolution imaging. However, it is difficult to make a quantitative analysis of the spectral signals that involve a large number of high-order micropolarizability tensors. It is reported that the CARS and CAHRS microscopic hyperpolarizability tensor elements can be decomposed into the product of the differentiation of Raman microscopic polarizability tensor α′i′j′ and hyper-Raman microscopic polarizability tensor β′i′j′k′ so that the high-order spectra can be simplified to the analysis of low-order spectra. In this paper, we use the bond additivity model (BAM) combined with experimental corrections to address the carbon dioxide (CO2) molecule and present the simplified scheme for differentiation of hyper-Raman microscopic polarizability tensor elements β′i′j′k′. Taking advantage of this approach, combined with the experimental correction, the differentiation of Hyper-Raman microscopic polarizability tensor elements β′i′j′k′ of the CO2 is obtained and the expressions of β′i′j′k′ for antisymmetric vibrations of CO2 are deduced. Finally, substituting the differentiation of Raman microscopic polarizability tensor elements α′i′j′ reported in the literature into the ratio above can obtain the proportional relationship between the microscopic polarizability tensor elements of CARS and CAHRS of the CO2. This method can provide the basis for the quantitative analysis of high-order nonlinear spectral profiles.

Femtosecond laser ablation is widely applied in high-precision machining of microholes in aeroengine turbine blades. To further explore the mechanism of action during the laser processing of microholes, numerical simulations were performed on the basis of a molecular dynamics (MD) method coupled with a two-temperature model (TTM). Laser irradiation on the surface of copper for different femtosecond-laser processing parameters is investigated in this work. Through the femtosecond-laser single-pulse central ablation simulation model, the laser energy flux density in a Gaussian laser spot range was discretized and analyzed to calculate the ablation depth at multiple points separately. The cross-sectional morphology of the femtosecond-laser single-pulse ablation pits was approximated and fitted. Finally, a 3D simulation model of the whole process of multiscale femtosecond-laser spiral processing microholes was established by superimposing multipulse femtosecond-laser spiral trajectories. This provides a theoretical basis for analyzing the evolution of geometric parameters and morphological characteristics of the hole during machining with specific laser and process parameters.

We investigate decay near boundary of the volume of sublevel sets in Cegrell classes of m − subharmonic function on bounded domains in ℂ n . On the reverse direction, some sufficient conditions for membership in certain Cegrell’s classes, in terms of the decay of the sublevel sets, are also discussed.

Ultracold atomic gases with the right balance of interactions enter a phase that demonstrates a superposition of seemingly opposing properties.

The replacement of hydrogen with conventional fossil fuel has been viewed as a feasible route to the ZERO emission transportation. Nowadays, the water electrolysis method has become mature and efficient enough to produce large-scale of hydrogen, and the condensation and reliquefaction technologies also greatly reduce the hydrogen loss via pipeline transmission, which both motivate the applications of hydrogen as a fuel. In this study, a combined power-hydrogen network is planned to supply the power demand of residential blocks and the charging/fueling demand for electrical vehicles and hydrogen vehicles, respectively. However, the joint scheduling of power-hydrogen network is challenging due to the non-linearity and non-convexity inherited from the hydraulic dynamics of hydrogen transmission. To resolve this problem, a convex-concave based sequential convex approximation method is proposed. A revised 37-bus system is used to demonstrate the validity of proposed method.

In this work, we establish a comprehensive spectral model to realize effective design of high-power ytterbium-Raman fiber amplifiers (YRFAs) employing different types of Raman-pump lasers, and propose an intuitive approach for the optimization of high-power YRFAs. Quantitative comparisons with the experimental results are given in two high-power YRFAs employing Raman-pump lasers with different spectral linewidth. The consistency of measured and simulated power ratios and spectral properties of different components in the two YRFAs confirms the fidelity of the spectral model. Further theoretical analysis reveals that the impact of Raman-pump lasers on YRFAs is mainly determined by the relative intensity noise (RIN) of Raman-pump lasers up to the cutoff frequency of the pump RIN transfer function of the YRFA. Notably, the RIN of Raman-pump lasers could provide a well reference for the superior design of Raman-pump lasers in high-power YRFAs.

Based on state-of-the-art ab initio potential energy functions and classical kinetic theory, some transport properties (diffusion, viscosity and thermal conductivity coefficients) of two-component dilute gas media of radium and halogen (F, Cl, Br, I) atoms were predicted as functions of the translation temperature up to 3000 K. Calculations were performed by sequential analytical and (or) numerical computations of deflection angle, cross-section and collision integrals. A detailed methodology for the calculation of the transport properties using the Morse potential was developed. Some numerical difficulties arising due to the singularity of the integrands and discontinuous character of the variable of integration are considered. The dependence of transport properties on isotope mass is also shown. Possible errors introduced by using the model Morse potential function instead of the real potential for the interaction between atoms are estimated. These data can be useful for the planning of the experiments on the direct laser cooling of the monohalides of alkaline earth metals.

Niels Bohr successfully predicted in 1913 the energy levels for the hydrogen atom by applying certain quantization rules to classically obtained periodic orbits. Many physicists tried to apply similar methods to other atoms. In his well-known 1921 paper, I.~Langmuir established numerically the existence of a periodic orbit in the helium atom considered as a classical three body problem. In this paper we give an analytic proof of the existence of Langmuir's periodic orbit., Comment: 12 pages, 2 figures. We would like to thank C.Viterbo for pointing out a mistake in our description of the historical development of Symplectic Geometry. The mathematical content has not changed

We report a comparative analysis of the limits of laser cooling of atoms in light fields both on the basis of a numerical solution of the quantum kinetic equation for the atomic density matrix, which makes it possible to accurately take into account quantum recoil effects during the interaction of atoms with field photons, and within the framework of the semiclassical approach using various forms of the Fokker – Plank equation. The analysis allows one to outline the limits of applicability of the semiclassical approach, as well as to choose an unambiguous form for introducing the diffusion contribution to the Fokker – Planck equation in the semiclassical description of atomic kinetics.

All the main directions of energy development suggest or already implement the use of hydrogen. In addition, the interaction of low-energy hydrogen atoms with metals is also of considerable interest, both from the point of view of fundamental research and in connection with the operation of large tokamaks and thermonuclear reactors. The paper presents a literature review of the features of the interaction of hydrogen with metals. It is shown that metal-hydrogen reactions, which lead to the formation of metal hydrides, are considered as a special type of such interaction. Modern methods of experimental study of heterogeneous reactions, topochemistry of metal - hydrogen reactions, dependences of the rate of interaction on pressure and temperature are considered, models of surface processes occurring during the interaction of hydrogen with a metal are discussed. A kinetic method for studying the mechanism of interaction of atomic hydrogen with hydride-forming metals is proposed.

Trapping phenomena degrade the dynamic performance of wide-bandgap transistors. However, the identification of the related traps is challenging, especially in presence of non-ideal defects. In this paper, we propose a novel methodology (trap-state mapping) to extract trap parameters, based on the mathematical study of stretched exponential recovery kinetics. To demonstrate the effectiveness of the approach, we use it to identify the properties of traps in AlGaN/GaN transistors, submitted to hot-electron stress. After describing the mathematical framework, we demonstrate that the proposed methodology can univocally describe the properties of the distribution of trap states. In addition, to prove the validity and the usefulness of the model, the trap properties extracted mathematically are used as input for TCAD simulations. The results obtained by TCAD closely match the experimental transient curves, thus confirming the accuracy of the trap-state mapping procedure. This methodology can be adopted also on other technologies, thus constituting a universal approach for the analysis of multiexponential trapping kinetics.

Anapole states in isolated, homogeneous and isotropic dielectric spheres are studied theoretically in accordance with Mie theory, numerically by full-wave electromagnetic simulations and by measurements at microwave and millimeter-wave frequency. Depending on size and material properties of the dielectric spheres, the practical limitations of detection and possible applications of non-radiating anapole states are investigated. The electromagnetic signature, generated by anapole states of a spherical dielectric scatterer, in terms of finite extinction cross-section, is verified by measurements, for both its electric and magnetic versions, in Silicon and Alumina spheres, respectively. In addition, the existence and the detection of higher-order and hybrid anapole states are demonstrated. Finally, an approach to engineer electric field hotspots in a subwavelength-sized gap between two magnetic anapole coupled Alumina ceramic spheres is demonstrated.

Nature Communications 13(1), 818 (2022). doi:10.1038/s41467-022-28382-w, Associative electronic detachment (AED) between anions and neutral atoms leads to the detachment of the anion’s electron resulting in the formation of a neutral molecule. It plays a key role in chemical reaction networks, like the interstellar medium, the Earth’s ionosphere and biochemical processes. Here, a class of AED involving a closed-shell anion (OH$^−$) and alkali atoms (rubidium) is investigated by precisely controlling the fraction of electronically excited rubidium. Reaction with the ground state atom gives rise to a stable intermediate complex with an electron solely bound via dipolar forces. The stability of the complex is governed by the subtle interplay of diabatic and adiabatic couplings into the autodetachment manifold. The measured rate coefficients are in good agreement with ab initio calculations, revealing pronounced steric effects. For excited state rubidium, however, a lower reaction rate is observed, indicating dynamical stabilization processes suppressing the coupling into the autodetachment region. Our work provides a stringent test of ab initio calculations on anion-neutral collisions and constitutes a generic, conceptual framework for understanding electronic state dependent dynamics in AEDs., Published by Nature Publishing Group UK, [London]

The former reports of coherent beam combining (CBC) in the ultra-intense ultra-short laser field focus on the phase control technology and two-beam CBC. To study the four-beam tiled-aperture CBC in the ultra-intense and ultra-short laser field, we demonstrate four-beam CBC of femtosecond laser pulses based on chirped pulse amplification (CPA) scheme. In this experiment, the four beams were compressed using two grating compressors to simulate the situation in ultra-intense and ultra-short laser CBC systems. To achieve real-time measurement of the phase error between the four beams, we introduced a continuous reference laser and the phases of beams 2, 3, and 4 were locked to beam 1.A combined efficiency of 57% was achieved. Although the coherent combining efficiency is not very high, the possibility of a four-beam CBC based on the CPA scheme was confirmed, especially with different grating compressors which can reduce the limitation of gratings in single beam petawatt lasers. Finally, the remaining difficulties in the implementation of CBC of four beams and the methods to improve its efficiency were analyzed. The use of CBC in ultra-intense and ultrashort laser systems is of considerable significance.

Recent molecular-beam experiments of high-velocity atomic oxygen (O), atomic nitrogen (N), and molecular oxygen (O2) impacting carbon material at high temperature produced detailed surface chemistr...

Gravitational interference The Aharonov-Bohm effect is a quantum mechanical effect in which a magnetic field affects the phase of an electron wave as it propagates along a wire. Atom interferometry exploits the wave characteristic of atoms to measure tiny differences in phase as they take different paths through the arms of an interferometer. Overstreet et al . split a cloud of cold rubidium atoms into two atomic wave packets about 25 centimeters apart and subjected one of the wave packets to gravitational interaction with a large mass (see the Perspective by Roura). The authors state that the observed phase shift is consistent with a gravitational Aharonov-Bohm effect. —ISO

Previously published analytical results for the effects of a high-frequency laser field on hydrogen Rydberg atoms demonstrated that the unperturbed elliptical orbit of the Rydberg electron, generally is engaged simultaneously in the precession of the orbital plane about the direction of the laser field and in the precession within the orbital plane. These results were obtained while disregarding relativistic effects. In the present paper, we analyze the relativistic effect for hydrogenic Rydberg atoms or ions in a high-frequency linearly- or circularly-polarized laser field, the effect being an additional precession of the electron orbit in its own plane. For the linearly-polarized laser field, the general case, where the electron orbit is not perpendicular to the direction of the laser field, we showed that the precession of the electron orbit within its plane can vanish at some critical polar angle θc of the orbital plane. We calculated analytically the dependence of the critical angle on the angular momentum of the electron and on the parameters of the laser field. Finally, for the particular situation, where the electron orbit is perpendicular to the direction of the laser field, we demonstrated that the relativistic precession and the precession due to the laser field occur in the opposite directions. As a result, the combined effect of these two kinds of the precession is smaller than the absolute value of each of them. We showed that by varying the ratio of the laser field strength F to the square of the laser field frequency ω, one can control the precession frequency of the electron orbit and even make the precession vanish, so that the elliptical orbit of the electron would become stationary. This is a counterintuitive result.

Pump-repump-probe spectroscopy with a burst mode of photoexcitation was applied to the direct observation of the photoionization dynamics of perylene in the solution phase. Irradiation of a pump pulse train generated with birefringent crystals effectively accumulated an intermediate S

We have proposed and experimentally demonstrated a four-channel wavelength-tunable in-series DFB laser array with 100-GHz channel spacing. Compared to the in-parallel laser array, the optical combiner is not utilized and the extra power loss induced by the combiner is avoided. A linearly chirped Bragg grating with multiple phase shifts implemented in the laser cavity is utilized to reduce the grating interference among different lasers. Besides, the reflector sections are inserted at two ends to provide grating feedback for two side channels. With the feedback, all the channels work with low threshold currents. The linearly chirped Bragg grating requires precise control of grating phase variation, which is quite difficult for traditional e-beam-lithography-based method. Here we used the reconstruction-equivalent-chirp technique to fabricate the grating, and precise control of the grating phase is achieved. From the experimental results, the laser arrays work with high output power (>10 mW), relative intensity noise near the relaxation oscillation frequency of below -130 dB/Hz, stable single-mode operation, and high-uniform channel spacing. Fast channel switchings (

We report on a high-resolution spectroscopic survey of ${}^{6}\textrm{Li}{}^{40}\textrm{K}$ molecules near the $2\textrm{S}+4\textrm{P}$ dissociation threshold and produce a fully empirical representation for the $\textrm{B}^{1}\Pi$ potential by connecting available short- and long-range data. The purpose is to identify a suitable intermediate state for a coherent Raman transfer to the absolute ground state, and the creation of a molecular gas with dipolar interactions. Starting from weakly bound ultracold Feshbach molecules, the transition frequencies to twenty-six vibrational states are determined. Our data are combined with long-range measurements [Ridinger et al., EPL, 2011, 96, 33001], and near-dissociation expansions for the spin-orbit coupled potentials are fitted to extract the $C_6$ dispersion coefficients. A suitable vibrational level is identified by resolving its Zeeman structure and by comparing the experimentally attained g-factor to our theoretical prediction. Using mass-scaling of the short-range data for the $\textrm{B}^{1}\Pi$ [Pashov et al., Chem. Phys. Lett., 1998, 292, 615-620] and an updated value for its depth, we model the short- and the long-range data simultaneously and produce a Rydberg-Klein-Rees curve covering the entire range.

Ion trap quantum computing utilizes electronic states of atomic ions such as Ca+ to encode information on to a qubit.

A systematic ab initio study suggests the co-existence of both long τQTM and high Ueff as a concise criterion for high-performance SMMs.