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The exponential growth in the consumption of lithium-ion batteries (LIBs) has resulted in a concomitant increase in the spent LIBs. Multi-component recycling is a highly desirable and beneficial process, yet the separator component remains overlooked. This study examined the thermal behavior, kinetics, thermodynamics, and evolved products of separator pyrolysis in N2 and CO2 atmospheres. Furthermore, the conversion was modeled using Aspen Plus and a sensitivity analysis was conducted to investigate the impact of varying operating conditions. The findings indicated that the whole degradation process could be divided into three stages: below 200 °C, 200–550 °C and 550–900 °C. The evolved products at peak temperatures of 485 °C in N2 and 500 °C in CO2 were composed of olefins and alkanes. The average apparent activation energy values were determined to be 222.78 kJ mol−1 and 159.36 kJ mol−1 in the N2 and CO2 atmospheres, respectively. Thermodynamic analysis indicated that the separator decomposition was an endothermic and non-spontaneous process. Aspen Plus modeling results were in agreement with the experimental data. The sensitivity analysis revealed that an increase in temperature lead to an increased content of lighter compounds (≤C9) and a decrease in the proportion of heavier compounds (>C10) in the pyrolysis products.

Recycling the valuable metals found in spent permanent magnets (REPMs) poses a significant global challenge for the future. This study examines the efficiency of back extraction of rare earth elements (REEs) by oxalic acid solution from di-(2-ethylhexyl) phosphoric acid (D2EHPA) in recycling REPMs. To evaluate the efficiency of this process, several experiments were carried out using designed BOX-Behnken methodology to investigate the effects of various operational and chemical parameters, including stripping solution to loaded organic phase volume ratio (in the range of 1.0–2.0), oxalic acid concentration (ranging from 0.25 to 0.75 M), the stirring rate (ranged between 150 and 350 rpm), and stripping time (ranging from 15 to 45 min) on the REEs recovery and the purity of final production. Analysis of variance was applied to rigorously examine the results statistically. The results showed that more than 85 % of light and 80 % of heavy REEs can be recovered under optimal conditions. Moreover, the final product contained 43.5 % REEs and approximately 0.1 % iron. The stripping experiment using phosphoric acid as the reagent demonstrated ∼57 % light and ∼4 % heavy REEs recovery. Additionally, the recyclability of the organic phase showed its effective reuse for up to four cycles. This study underscores significant progress in the selective recovery of rare earth elements through a relatively straightforward process consuming mild reagents.

The reliability assessment of HVDC systems greatly depends on the insulating materials aging level and, among these, the cable insulation layer plays a fundamental role. With this in mind, in this work, the correlation between the electric field distribution and the triggering and evolution of PD in a DC cable containing an internal air void defect and subjected to normal operating conditions has been investigated. The aim is to demonstrate that the PD activity under DC depends on the electric field distribution which, in turn, is related to the conductivity gradient that varies with load. In a previous paper, the field distribution in a cable specimen was simulated. Here, instead, the field profiles have been experimentally obtained starting from the measured space charges detected simultaneously with the PD activity. For the charge detection and for the PD monitoring, an innovative PEA cell and a PD acquisition system have been used, respectively. Measurement results highlight that the PD behavior depends on both the electric field distribution and the time constant $\tau $ . Specifically, during the first 10 minutes of the beginning of the test, the field in the outer cable radius passes from 12 to 17 kV/mm and it is maintained around this last value until 30 minutes. PD are triggered after 1 minutes from the start of the test, corresponding to a PDIEF of 12.6 kV/mm calculated in the healthy cable section. The detected PD activity shows a PDRR with maximum value equal to 110 pulse/min at the beginning of the test. Whereas, after 15 minutes, the electric field variation dE/dt is approximately zero and the PDRR, that is maintained only by $\tau $ , results around 10 pulse/minute.

In recent years, the increasing demand and rising prices of rare earth elements (REEs), along with their attendant supply risk (about 95% of these elements are supplied by China), have led the European Commission to consider REEs as critical raw materials. Developing and optimizing processes for recovering REEs from secondary sources such as NdFeB magnets is fundamental in this context. A novel method to recover REEs by leaching with citric acid and subsequently separating these elements using the solvent extraction method has been introduced. Therefore, this research investigates the leaching efficiency of REEs, Fe, and B from NdFeB magnets. A full factorial design, with 18 experimental setups, was conducted to optimize the citric acid concentration (1–3 mol/L), leaching time (1–3 h), and solid–liquid ratio (5–10%wt./vol.). All tests were carried out at room temperature and 150 rpm. Different optimizations (response surface methodology (RSM) and artificial neural network (ANN) analysis) are used to maximize the REEs’ leaching efficiency. RSM resulted in a maximum extraction yield of total rare earth elements (TREEs) of about 89% in the investigated experimental plan. This result is similar to that for ANN analysis (about 86%), but more accurate than that for RSM. In fact, for the ANN, an overall R-value higher than 0.99 was obtained. This result indicates that the developed ANN can be used as an accurate model for estimating the leaching efficiencies of REEs from NdFeB magnets.

Electronic waste grows globally at a rate of 5% annually, which makes electronic waste recycling (WEEE recycling) an urgent task aimed at achieving (i) environmental protection and (ii) the preservation of mineral resources through the re-introduction of strategic metals into the market. As it turns out, WEEE recycling produces further waste, called WEEE secondary waste, which still contains valuable metals such as gold, silver, and copper. This study assessed the economic viability of recovering these metals and identified the most promising targets and approaches. WEEE secondary waste produced at a plant in southern Europe was sampled and examined for this purpose. The study methods included an ANOVA (analysis of variance) and an OCCP (orthogonal central composition plan). Over 90% gold, silver, and copper extraction was achieved with hydrochloric acid leaching in sodium hypochlorite with sodium chlorite as an oxidizing agent at 60 °C. The significance of the variation in the response for each factor, calculated using the Yates algorithm, demonstrates that by excluding sodium chloride and optimizing the doses of hydrochloric acid and sodium hypochlorite, gold can be selectively recovered through the leaching process. The scenario of HCl (2.5M)/NaClO (5%) leaching results in the maximum extraction effect of Au (91.6%) at the lowest concentrations of Ag and Cu (37–44%).

Printed circuit boards are considered a secondary source of raw materials, such as precious or base metals. One of the most promising solutions for recovering these metals is certainly hydrometallurgy. However, the leaching of different metals from PCBs is hindered by the presence of an organic fraction that lowers the extraction yields. One solution to this problem is a pyrolysis pre-treatment which removes the organic fraction and enhances it through conversion into syngas. A steady-state simulation model was developed using ASPEN PLUS to describe the thermodynamic behavior of PCB pyrolysis. The pyrolysis reactor was modeled as a combination of the Yields reactor and the Gibbs reactor. The model has been validated using various data present in the literature. The composition of the different products was estimated through the minimization of Gibbs’s free energy. A sensitivity analysis was performed to investigate the influence of different parameters on the conversion yield and the syngas quality produced. Thanks to the study, it was possible to describe and analyze the pyrolysis of PCBs without requiring numerous experimental tests. The results show how steam gasification appears to be the most efficient technology for the pre-treatment of PCBs within a hydrometallurgical process.

The high demand for rare earth permanent magnets (REPMs) for use in advanced electrical equipment has led to the classification of some rare earth elements (REEs), such as neodymium, praseodymium, and dysprosium, as strategic raw materials by the European Union. Finding an efficient method with economic benefits and minimal environmental impact is one of the challenges of recycling REPMs. A novel method to recover REPM metals by dissolving them with citric acid and separating the rare earth elements using the solvent extraction method as the next step has been introduced. Therefore, this research investigates the efficiency and kinetics of leaching REPM swarf by citric acid (0.5 to 2.5 M). The results showed that increasing the citric acid concentration from 0.5 M to 1.45 M significantly enhanced the dissolving rate of all studied elements. Although the results showed that the optimal concentration of citric acid in the leaching reagent was between 0.9 and 1.45 M, the REE dissolving reaction with a leaching reagent containing 1.45 M and 0.9 M citric acid reached equilibrium conditions at about 120 and 180 min, respectively. It could be concluded that using citric acid as an organic acid can dissolve the metals in REPM swarf with high efficiency and a fast dissolving rate. This issue can be considered key for recycling REPMs and the future REE supply challenge.

Integrating photovoltaic technology has undergone significant development in recent years, owing to its manifold advantages. One of the most recent domains where this technology has found application is within the transportation sector. The utilization of this technology possesses the potential to initiate a new revolution in transportation by enhancing the range and reducing fuel consumption in vehicles. The performance of these systems is influenced by numerous factors, which have been thoroughly examined in this study. These factors have been categorized into three broad groups: installation site, solar cell characteristics, and environmental conditions. It is important to note that these conditions are inherently interdependent, so this study reveals that the radiation incident on the roof of a van can be 1.09–3.85 times greater than the radiation incident on its sides, according to varying meteorological conditions and different seasons. The current research serves as a valuable foundation for future investigations in this field, offering a targeted and practical overview of the work conducted thus far and summarizing the current state of research.

The recovery of materials and energy from end-of-life products is increasingly a fundamental factor in the sustainable development of various countries. Recovering metals from different types of waste is not only a practice in support of the environment, but is also a profitable economic activity. For this reason, exhausted automotive catalysts can become renewable sources of critical raw materials such as Pt, Pd, and Rh. However, recovering Pt and Pd from spent catalysts through an efficient, economical, and green method remains a challenge. This article presents a new leaching process for the hydrometallurgical recovery of Pt and Pd from exhausted automotive catalysts. The leaching solution consists of an aqueous mixture of hydrochloric acid, two organic acids (citric acid and acetic acid) and hydrogen peroxide. A complete factorial plan on two levels (2k) was performed in order to evaluate the main effects of the analyzed factors and their interactions. The factors that were presumed to be the most influential on the leaching of Pt and Pd were the concentrations of the different reagents and the reaction time. The optimal circumstances for achieving the largest recovery (over 80% Pt and 100% Pd) were achieved using the following conditions: a concentration of HCl of 5 M, a concentration of H2O2 of 10% wt./vol., a concentration of C2H4O2 of 10%vol./vol., and a reaction time of 3 h.

Hydrothermal carbonization enables the valorization of biomass via thermochemical conversion into various products. Today, this technology is experiencing a situation similar to that experienced in the past by other process technologies. Of these technologies, some have become important industrial realities, such as reverse osmosis, while others have never been able to establish themselves fully. This paper presents a brief overview of this technology’s current status, highlighting its strengths and various drawbacks. The primary purpose of the research activity is to identify a possible future scenario toward which this technology is heading. Hydrothermal carbonization has already been established on a laboratory scale for some time, and now it is in a transitional phase between pilot-scale and industrial-scale applications. The interest that HTC has aroused and continues to arouse is evidenced by the growing number of publications and patents published. In particular, the uniform percentage of patents filed in various countries testifies to the worldwide interest. This technology has advantages but also some bottlenecks that have yet to be overcome. Process integration, higher-capacity plants, and the use of Industry 4.0 technologies seem to be the most interesting options to overcome the last limiting factors and make hydrothermal carbonization an established industrial reality.

One of the most common failures or breakdowns that can occur in high-voltage (HV) equipment is due to partial discharges (PDs). This occurs as a result of inadequate insulation, aging, harsh environmental effects, or manufacturing flaws. PD detection and recognition methods have gained growing attention and have seen great progress in the past decades. Radiometric methods are one of the most investigated detection approaches due to their immunity to electromagnetic interference (EMI) and their capabilities to detect and locate PD activities in different applications such as transformers, cables, etc. Several review articles have been published to classify and categorize these works. Nonetheless, some concepts are missing, and some improvement techniques, such as PD detection at high-frequency (HF) and very high-frequency (VHF), have been overlooked. We present in this paper an exhaustive review study of state-of-the-art PD detection based on radiometric methods at different usable radiofrequency bands (i.e., HF, VHF, and UHF). Accordingly, we propose a new generic categorization approach based on the detected electromagnetic wave component (magnetic or electric fields) and pick-up location, either from free space or ground cable.

Partial discharge (PD) diagnosis tests, including detecting, locating, and identifying, are used to trace defects or faults and assess the degree of aging in order to monitor the insulation condition of medium- and high-voltage power cables. In this context, an experimental evaluation of three different printed circuit board (PCB)-based inductive sensor topologies, with spiral, non-spiral, and meander shapes, is performed. The aim is to assess their capabilities for PD detection along a transmission power cable. First, simulation and experimental characterization are carried out to determine the equivalent electrical circuit and the quality factor of the three sensors. PD activity was studied in the lab on a 10-m-long defective MVAC cable. The three PCB-based sensors were tested in three different positions: directly on the defective cable (P1), at a separation distance of 10 cm to 3 m (P2), and on the ground line (P3). For the three positions, all sensors’ outputs present a damped sine wave signal with similar frequencies and durations. Experimental results showed that the best sensitivity was given by the non-spiral inductor, with a peak voltage of around 500 mV in P1, 428 mV in P2, and 45 mV in P3, while the meander sensor had the lowest values, which were approximately 80 mV in P1. The frequency spectrum bandwidth of all sensors was between 10 MHz and 45 MHz. The high sensitivity of the non-spiral inductor could be associated with its interesting properties in terms of quality factor and SFR, which are due to its very low resistivity. To benchmark the performance of the designed three-loop sensors, a comparison with a commercial high-frequency current transformer (HFCT) is also made.

Municipal sewage sludge is the residual material produced as a waste of municipal wastewater purification. It is a sophisticated multi-component material, hard to handle. For many years, it has been landfilled, incinerated, and widely used in agriculture practice. When unproperly discharged, it is very polluting and unhealthy. The rapidly increasing global amount of municipal sewage sludge produced annually depends on urbanization, degree of development, and lifestyle. Some diffused traditional practices were banned or became economically unfeasible or unacceptable by the communities. In contrast, it has been established that MSS contains valuable resources, which can be utilized as energy and fertilizer. The objective of the review was to prove that resource recovery is beneficially affordable using modern approaches and proper technologies and to estimate the required resources and time. The open sources of information were deeply mined, critically examined, and selected to derive the necessary information regarding each network segment, from the source to the final point, where the municipal sewage sludge is produced and disposed of. We found that developed and some developing countries are involved with ambitious and costly plans for remediation, the modernization of regulations, collecting and purification systems, and beneficial waste management using a modern approach. We also found that the activated sludge process is the leading technology for wastewater purification, and anaerobic digestion is the leading technology for downstream waste. However, biological technologies appear inadequate and hydrothermal carbonization, already applicable at full scale, is the best candidate for playing a significant role in managing municipal sewage sludge produced by big towns and small villages.

Partial discharge (PD) detection can be considered one of the most useful tools for assessing the insulation conditions of the power apparatus in high-voltage systems. Under AC conditions, this analysis is widely employed in online and offline tests, such as type tests or commissioning, and can be carried out by applying the phase-resolved PD (PRPD) method, since the patterns can give information about the defect classification. Under DC voltages, the classic pattern recognition method cannot be performed, and the measurements show complexities related to the nature of the phenomena. For this reason, to date, a standard for PD measurements under DC does not exist. In previous papers, a new method for PD detection under DC stress voltages has been proposed by the authors. It is based on the application of a direct current periodic (DCP) waveform useful in obtaining PRPD patterns. The dependence of partial discharge inception voltage (PDIV) and PD repetition rate (PDRR) on the δ shape parameter of the DCP for different materials, as well as the capability to recognize different discharge phenomena, provided valid indications on the behavior of PD in the transition from AC to DC. The aim of this paper is to evaluate the time dependence of PD occurring in a dielectric by applying the DCP waveform. In our previous studies, the investigations were focused on the PD behavior under different values of the DC voltage periodic part. In another work, the DCP waveform with both positive and negative polarity was applied to several dielectric materials. In the proposed work, instead, the DCP waveform is applied for a long time in order to observe its effect on the PD behavior for 72 h. In this way, due to the space charge accumulation phenomenon, the aging effect, also due to the space charge accumulation phenomenon, is evaluated. The methodological approach was to acquire PRPD patterns over time and evaluate their trends in comparison with the sinusoidal case. The experimental results show that, with a DCP waveform having δ = 0.6, the aging effect similar to that provided by pure DC stress is observed, while the acquired PRPD patterns are easily interpretated, as in the AC case.

The production of olive oil involves the sustainable management of the waste produced along the entire production chain. This review examines the developments regarding cultivation techniques, production technologies, and waste management, highlighting the goals to be achieved and the most reasonable prospects. The results show that cultivation and production technology have evolved to an almost final solution to meet economic feasibility, keeping the oil’s high quality. Continuous horizontal decanters will coexist with traditional mills in many countries with old olive oil production and consumption traditions. High-quality products have conquered markets, especially in the wealthiest countries. At the same time, the exploitation of dried pomace by solvent extraction is increasingly an obsolete practice. However, waste management is still looking for one or a few reasonable solutions that meet modern society’s constraints. The enhancement of some experienced technologies and the full-scale application of emerging technologies and strategies should solve this problem in the short–medium term. A short discussion is reported on the possibility of unifying the nature and the quality of the waste, whatever the olive oil production method is. Furthermore, modern thermochemical treatment for solid wet organic waste disposal is examined and discussed.

In recent years, the growing concern for air quality has led to the development of sustainable vehicles to replace conventional internal combustion engine (ICE) vehicles. Currently, the most widespread technology in Europe and Portugal is that of Battery Electric Vehicles (BEV) or plug-in HEV (PHEV) electric cars, but hydrogen-based transport has also shown significant growth in the commercialization of Fuel Cell Electric Vehicles (FCEV) and in the development of new infrastructural schemes. In the current panorama of EV, particular attention should be paid to hydrogen technology, i.e., FCEVs, which is potentially a valid alternative to BEVs and can also be hybrid (FCHEV) and plug-in hybrid (FCPHEV). Several sources cited show a positive trend of hydrogen in the transport sector, identifying a growing trend in the expansion of hydrogen infrastructure, although at this time, it is still at an early stage of development. At the moment, the cost of building the infrastructure is still high, but on the basis of medium/long-term scenarios it is clear that investments in hydrogen refueling stations will be profitable if the number of Fuel Cell vehicles increases. Conversely, the Fuel Cell vehicle market is hampered if there is no adequate infrastructure for hydrogen development. The opportunity to use Fuel Cells to store electrical energy is quite fascinating and bypasses some obstacles encountered with BEVs. The advantages are clear, since the charging times are reduced, compared to charging from an electric charging post, and the long-distance voyage is made easier, as the autonomy is much larger, i.e., the psycho-sociological anxiety is avoided. Therefore, the first part of the paper provides an overview of the current state of electric mobility in Portugal and the strategies adopted by the country. This is necessary to have a clear vision of how a new technology is accepted by the population and develops on the territory, that is the propensity of citizens to technological change. Subsequently, using current data on EV development and comparing information from recent years, this work aims to investigate the future prospects of FCEVs in Portugal by adopting a dynamic model called SERA (Scenario Evaluation and Regionalization Analysis), with which it is possible to identify the Portuguese districts and cities where an FC charging infrastructure is expected to be most beneficial. From the results obtained, the districts of Lisbon, Porto and Aveiro seem to be the most interested in adopting FC technology. This analysis aims to ensure a measured view of the credible development of this market segment.

All the urban areas of developed countries have hydric distribution grids and sewage systems for collecting municipal wastewater to treatment plants. In this way, the municipal wastewater is purified from human excreta and other minor contaminants while producing excess sludges and purified water. In arid and semi-arid areas of the world, the purified water can be used, before discharging, to enhance the energy efficiency of seawater desalination and solve the problems of marine pollution created by desalination plants. Over the past half-century, seawater desalination has gradually met demand in urbanized, oil-rich, arid areas. At the same time, technological evolution has made it possible to significantly increase the energy efficiency of the plants and reduce the unit cost of the produced water. However, for some years, these trends have flattened out. The purified water passes through the hybridized desalination plant and produces renewable osmotic energy before the final discharge in the sea to restart the descent behaviour. Current technological development of reverse osmosis (RO), pressure retarded osmosis (PRO) and very efficient energy recovery devices (ERDs) allows this. Furthermore, it is reasonable to predict that, in the short-medium term, a new generation of membranes specifically designed for improving the performance of the pressure retarded osmosis will be available. In such circumstances, the presently estimated 13-20% decrease of the specific energy consumption will improve up to more than 30%. With the hybrid plant, the salinity of the final discharged brine is like that of seawater, while the adverse effect of GHG emission will be significantly mitigated.

This paper deals with the reliability of the Pulsed Electro-Acoustic (PEA) technique in the case of a specimen containing an air layer. The first approach to this study has been proposed by the authors in previously published works. In these papers, the mathematical description, the PEA cell simulation model, and some experimental tests have been reported. In this work, a more accurate description of the acoustic wave behavior within the PEA cell and specimen with and without an air layer is given. Moreover, the comparison between simulation and experimental tests for both cases (specimen with and without air layer) allowed the validation of the previously developed PEA cell simulation model. The latter was previously validated only for a single layer specimen, here the good performances of the model have also been confirmed in the case of a multilayer specimen, also with an air layer. Experimental and simulation results show that the air layer acts as a barrier for the acoustic signal, due to the different acoustic impedance between the air and the solid dielectric material which constitute the specimen. Therefore, the aim of the present work is to demonstrate that in the case of a three-layers specimen, composed as dielectric-air-dielectric, the PEA cell is not able to provide the complete profile of the entire specimen under test.

To date, it has been widespread accepted that the presence of space charge within the dielectric of high voltage direct current (HVDC) cables is one of the most relevant issues that limits the growing diffusion of this technology and its use at higher voltages. One of the reasons that leads to the establishment of space charge within the insulation of cables is the temperature dependence of its conductivity. Many researchers have demonstrated that high temperature drop over the insulation layer can lead to the reversal of the electric field profile. In certain conditions, this can over-stress the insulation during polarity reversal (PR) and transient over voltages (TOV) events accelerating the ageing of the dielectric material. However, the reference standards for the thermal rating of cables are mainly thought for alternating current (AC) cables and do not adequately take into account the effects related to high thermal drops over the insulation. In particular, the difference in temperature between the inner and the outer surfaces of the dielectric can be amplified during load transients or near sections with axially varying external thermal conditions. For the reasons above, this research aims to demonstrate how much the existence of “hot points” in terms of temperature drop can weaken the tightness of an HVDC transmission line. In order to investigate these phenomena, a two-dimensional numerical model has been implemented in time domain. The results obtained for some case studies demonstrate that the maximum electric field within the dielectric of an HVDC cable can be significantly increased in correspondence with variations along the axis of the external heat exchange conditions and/or during load transients. This study can be further developed in order to take into account the combined effect of the described phenomena with other sources of introduction, forming, and accumulation of space charge inside the dielectric layer of HVDC cables.

Solar plants suffer of partial shading and mismatch problems. Without considering the generation of hot spots and the resulting security issues, a monitoring system for the health of a PV plant should be useful to drive a dynamic reconfiguration system (DRS) to solve bottlenecks due to different panels’ shading. Over the years different DRS architectures have been proposed, but no suggestions about costs and benefits have been provided. Starting from technical subjects such as differences of the topologies driving the hardware complexity and number of components, this paper identifies the cost of DRS and its lifetime, and based on these issues it provides an economic analysis for a 6 kWp PV plant in different European Union countries, in which the dissimilar incentive policies have been considered.

In order to reduce the mismatch effect caused by non-uniform shadows in PV arrays, reconfigurable interconnections approaches have been recently proposed in the literature. These systems usually require the knowledge of the solar radiation affecting every solar module. The aim of this work is to evaluate the effectiveness of three irradiance estimation approaches in order to define which can be well suited for reconfigurable PV arrays. It is presented a real-time solar irradiance estimation device (IrradEst), implementing the three different estimation methods. The proposed system is based on mathematical models of PV modules enabling to estimate irradiation values by sensing a combination of temperature, voltage and current of a PV module. Experimental results showed generally good agreement between the estimated irradiances and the measurements performed by a standard pyranometer taken as reference. Finally one of the three methods was selected as possible solution for a reconfigurable PV system.

Antes de analizar el fenómeno de la globalización en su dimensión universal y, enparticular, en sus proyecciones en los diferentes sectores de las relaciones humanas, también en el sector agrícola, es preciso anteponer brevemente unos elementos básicos que desde siempre han involucrado la vida del hombre en el ámbito natural del medio ambiente.Además, es oportuno destacar, a ese propósito, la importancia de algunos conceptos complementarios e integrantes de los valores sustanciales que han acompañado y acondicionado la evolución del género humano, como los conceptos de interdependencia colectiva y de solidaridad universal (...)

Cable manufacturing industries are constantly trying to improve the electrical performance of power cables. During the years, it was found that one of the most relevant degradation factors influencing the cable lifetime is the presence of space charge in the insulation layer. To detect the accumulated charge, the pulsed electro-acoustic (PEA) method is the most used technique. Despite the wide use of the PEA cell, several issues are still present. In particular, the PEA output signal is strongly disturbed by the acoustic waves reflections within the PEA cell. This causes the distortion of the output signal and therefore the misinterpretation of the charge profiles. This, in turn, may result in an incorrect cable characterization from the space charge phenomenon point of view. In 2017, due to the proved degradation effect of the space charge accumulation phenomenon, the IEEE Std 1732 was developed. This standard describes the steps to be followed for the space charge measurement in cables specimens during pre-qualification or type tests. Therefore, cable manufacturing industries started to take a particular interest in these measures. In the light of this, the aim of the present work is to highlight that the enacted standard is not easily applicable since various problems are still present in the PEA method for cables. In particular, in this work, the effect of multiple reflected signals due to the different interfaces involved, but also the effect of the signal attenuation due to cable dielectric thickness, as well as the effect of the PEA cell ground electrode thickness in the output charge profile, are reported. These issues have been demonstrated by means of an experimental test carried out on a full-size cable in the Prysmian Group High Voltage laboratory. To better understand the PEA cell output signal formation, a PEA cell model was developed in a previous work and it has been experimentally validated here. In particular, simulations have been useful to highlight the effect of the reflection phenomena due to the PEA cell ground electrode thickness on the basis of the specimen under test features. Moreover, by analyzing the simulation results, it was possible to separate the main signal from the reflected waves and, in turn, to calculate the suitable ground electrode thickness for the cable specimen under test.

This review takes into account articles and standards published in recent years concerning the application of the Pulsed Electro Acoustic (PEA) method for space charge measurement on High Voltage Direct Current (HVDC) cables and mini-cables. Since the 80s, the PEA method has been implemented for space charge measurements on flat specimens in order to investigate space charge phenomena and to evaluate the ageing of dielectrics. In recent years, this technique has been adapted to cylindrical geometry. Several studies and experiments have been carried out on the use of the PEA method for full size cables and HVDC cable models. The experiments have been conducted using different arrangements of the measurement setup and focusing attention on different aspects of space charge phenomena. In this work, the importance of space charge measurement is highlighted and the state-of-the-art PEA method application to full size cables and mini-cables is described. The main aim of this paper is to offer a complete and current review of this technique. In addition, limits on the use of PEA method are examined and main possible directions of research are proposed in order to improve the applicability, reliability, and replicability of this method.

The sustainable development of our planet is considerably related to a relevant reduction of CO2 global emissions, with building consumption contributing more than 40%. In this scenario, new technological conceptions, such as building-integrated photovoltaic technology, emerged in order to satisfy the requirements of sustainability imposed by the European Union. Therefore, the aim of this work is to provide a technical and economical comparison of the performances of different vertical-mounted innovative photovoltaic systems, potentially integrated on a building instead of on traditional windows or glass walls. The proposed investigation was carried out by means of experimental tests on three different next-generation vertical structures. The related results are described and discussed, highlighting the advantages and the drawbacks of the proposed technologies.

The presence of a partial discharge phenomenon in an electrical apparatus is a warning signal that could determine the failure of the insulation system, terminating the service of the apparatus and/or the network. In this paper, an innovative partial discharge (PD) measurement instrument based on an antenna sensor is presented and analyzed. Being non-intrusive is one of the most relevant features of the sensor. The frequency response of the antenna sensor and the features to recognize different PD sources and automatically synchronize them with the supply voltage are described and discussed in details. The results show the performance of the instrument can make a fast and correct diagnosis of the health state of insulation systems.

Background: It has been reported that biologically active compounds extracted from Cnidaria venom may induce damage by oxidative stress. Erythrocytes are constantly exposed to oxidative stresses, which can contribute to sulphydril (SH-) group oxidation and cell membrane deformability accompanied with activation of K-Cl co-transport and inhibition of anion transport. In this regard, Band 3 protein is responsible for mediating the electroneutral exchange of chloride (Cl-) for bicarbonate (HCO3-), particularly in erythrocytes, where it is the most abundant membrane protein. The aim of this study was to elucidate the effect of crude venom extracted from Pelagia noctiluca nematocysts on Band 3 -mediated anion transport in human erythrocytes. Methods: Erythrocytes were tested for SO42- uptake, K+ efflux, glutathione (GSH) levels and concentration of SH- groups. Results: The rate constant of SO42- uptake decreased progressively to 58% of control with increasing venom doses, and showed a 28% decrease after 2 mM NEM treatment. These effects can be explained by oxidative stress, which was reflected by decreased GSH levels in venom-treated erythrocytes. Hence, the decreased efficiency of anion transport may be due to changes in Band 3 structure caused by SH-group oxidation and reduced GSH concentration. In addition, an increased Cl--dependent K+ efflux was observed in venom-treated erythrocytes. Conclusion: Our results suggest that crude venom from Pelagia noctiluca alters cell membrane transport in human erythrocytes.

This work presents a preliminary study on the implementation of a new system for power output maximization of photovoltaic generators under non-homogeneous conditions. The study evaluates the performance of an efficient switching matrix and the relevant automatic reconfiguration control algorithms. The switching matrix is installed between the PV generator and the inverter, allowing a large number of possible module configurations. PV generator, switching matrix and the intelligent controller have been simulated in Simulink. The proposed reconfiguration system improved the energy extracted by the PV generator under non-uniform solar irradiation conditions. Short calculation times of the proposed control algorithms allow its use in real time applications even where a higher number of PV modules is required.

Antes de analizar el fenómeno de la globalización en su dimensión universal y, en particular, en sus proyecciones en los diferentes sectores de las relaciones humanas, también en el sector agrícola, es preciso anteponer brevemente unos elementos básicos que desde siempre han involucrado la vida del hombre en el ámbito natural del medio ambiente. Además, es oportuno destacar, a ese propósito, la importancia de algunos conceptos complementarios e integrantes de los valores sustanciales que han acompañado y acondicionado la evolución del género humano, como los conceptos de interdependencia colectiva y de solidaridad universal (...)