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The earliest atmospheres of rocky planets originate from extensive volatile release during magma ocean epochs that occur during assembly of the planet. These establish the initial distribution of the major volatile elements between different chemical reservoirs that subsequently evolve via geological cycles. Current theoretical techniques are limited in exploring the anticipated range of compositional and thermal scenarios of early planetary evolution, even though these are of prime importance to aid astronomical inferences on the environmental context and geological history of extrasolar planets. Here, we present a coupled numerical framework that links an evolutionary, vertically resolved model of the planetary silicate mantle with a radiative-convective model of the atmosphere. Using this method, we investigate the early evolution of idealized Earth-sized rocky planets with end-member, clear-sky atmospheres dominated by either H2, H2O, CO2, CH4, CO, O2, or N2. We find central metrics of early planetary evolution, such as energy gradient, sequence of mantle solidification, surface pressure, or vertical stratification of the atmosphere, to be intimately controlled by the dominant volatile and outgassing history of the planet. Thermal sequences fall into three general classes with increasing cooling timescale: CO, N2, and O2 with minimal effect, H2O, CO2, and CH4 with intermediate influence, and H2 with several orders of magnitude increase in solidification time and atmosphere vertical stratification. Our numerical experiments exemplify the capabilities of the presented modeling framework and link the interior and atmospheric evolution of rocky exoplanets with multiwavelength astronomical observations.

The presence of minerals formed under the occurrence of liquid water during the first billion years on Mars was a key discovery, but there is still a large number of open issues that make the study of these mineral deposits a main focus of remote sensing and laboratory studies. Moreover, even though there is extensive research related to the study of the spectral behavior of mixtures, we still lack a full understanding of the problem. The main goal of this work is the analysis of the detection limits of hydrated and carbonate phases within mixtures with basaltic-like fine regolith in the spectral region 1.0–5.5 µm (1818–10,000 cm−1). We selected two different basalt samples and mixed them with two carbonate phases: a dolomite and a calcite. Spectral features have been investigated isolating the main carbonate absorption features and overtones; deriving trends of spectral parameters such as band depth, band area, full-width-half-maximum; percentage and grain size variations. The results obtained in this work show how the presence of a basaltic component can strongly influence the appearance of the hydrated and carbonate features showing different trends and intensities depending on the grain size and percentage of the carbonate components. [ABSTRACT FROM AUTHOR]

The geology of Earth and super‐Earth sized planets will, in many cases, only be observable via their atmospheres. Here, we investigate secondary volcanic atmospheres as a key base case of how atmospheres may reflect planetary geochemistry. We couple volcanic outgassing with atmospheric chemistry models to simulate the growth of C‐O‐H‐S‐N atmospheres in thermochemical equilibrium, focusing on what information about the planet's mantle fO2 and bulk silicate H/C ratio could be determined by atmospheric observation. 800 K volcanic atmospheres develop distinct compositional groups as the mantle fO2 is varied, which can be identified using sets of (often minor) indicator species: Class O, representing an oxidized mantle and containing SO2 and sulfur allotropes; Class I, formed by intermediate mantle fO2's and containing CO2, CH4, CO and COS; and Class R, produced by reduced mantles, containing H2, NH3 and CH4. These atmospheric classes are robust to a wide range of bulk silicate H/C ratios. However, the H/C ratio does affect the dominant atmospheric constituent, which can vary between H2, H2O and CO2 once the chemical composition has stabilized to a point where it no longer changes substantially with time. This final atmospheric state is dependent on the mantle fO2, the H/C ratio, and time since the onset of volcanism. The atmospheric classes we present are appropriate for the closed‐system growth of hot exoplanets, and may be used as a simple base for future research exploring the effects of other open‐system processes on secondary volcanic atmospheres. Plain Language Summary: To understand the geology of rocky planets, we must learn to use observations of their atmospheres to infer the properties of their interiors. When rocky planets have atmospheres made up of gases released by volcanoes, the chemistry of the atmosphere can be linked back to the volatile content and availability of oxygen in the planet's interior. In order to understand what the atmospheres of these rocky planets might look like, we use computer simulations to analyze their evolution and chemical signatures. We find that planets with Venus‐like surface temperatures will produce atmospheres whose chemical compositions enable them to be split into three distinct categories. These three classes are identified using diagnostic combinations of species. Key Points: Varying the mantle fO2 of hot rocky planets can produce three distinct atmospheric classesThe planet's mantle fO2, H/C ratio and age control whether the main atmospheric species is H2O, H2 or CO2The chemical speciation of volcanic atmospheres is robust to a wide range of bulk silicate planet H/C mass ratios [ABSTRACT FROM AUTHOR]

The recently adopted Ariel ESA mission will measure the atmospheric composition of a large number of exoplanets. This information will then be used to better constrain planetary bulk compositions. While the connection between the composition of a planetary atmosphere and the bulk interior is still being investigated, the combination of the atmospheric composition with the measured mass and radius of exoplanets will push the field of exoplanet characterisation to the next level, and provide new insights of the nature of planets in our galaxy. In this white paper, we outline the ongoing activities of the interior working group of the Ariel mission, and list the desirable theoretical developments as well as the challenges in linking planetary atmospheres, bulk composition and interior structure. [ABSTRACT FROM AUTHOR]

The earliest atmospheres of rocky planets originate from extensive volatile release during magma ocean epochs that occur during assembly of the planet. These establish the initial distribution of the major volatile elements between different chemical reservoirs that subsequently evolve via geological cycles. Current theoretical techniques are limited in exploring the anticipated range of compositional and thermal scenarios of early planetary evolution, even though these are of prime importance to aid astronomical inferences on the environmental context and geological history of extrasolar planets. Here, we present a coupled numerical framework that links an evolutionary, vertically resolved model of the planetary silicate mantle with a radiative‐convective model of the atmosphere. Using this method, we investigate the early evolution of idealized Earth‐sized rocky planets with end‐member, clear‐sky atmospheres dominated by either H2, H2O, CO2, CH4, CO, O2, or N2. We find central metrics of early planetary evolution, such as energy gradient, sequence of mantle solidification, surface pressure, or vertical stratification of the atmosphere, to be intimately controlled by the dominant volatile and outgassing history of the planet. Thermal sequences fall into three general classes with increasing cooling timescale: CO, N2, and O2 with minimal effect, H2O, CO2, and CH4 with intermediate influence, and H2 with several orders of magnitude increase in solidification time and atmosphere vertical stratification. Our numerical experiments exemplify the capabilities of the presented modeling framework and link the interior and atmospheric evolution of rocky exoplanets with multiwavelength astronomical observations. Plain Language Summary: The climate and surface conditions of rocky planets are sensitive to the composition of their atmospheres, but the origins of these atmospheres remain unknown. During the final stages of planetary accretion, when the whole of the planet solidifies from lava to solid rock, volatiles can rapidly cycle between interior and atmosphere, and control the cooling properties of the planet. In order to understand how cooling planets with different volatile compositions evolve, we use computer simulations to analyze their thermal evolution, outgassing, and observable signatures. We find the planetary cooling sequence to differ by orders of magnitude depending on the primary volatile. CO, N2, and O2 rapidly outgas, but allow planets to solidify efficiently. H2O, CO2, and CH4 build an intermediate class with substantially delayed cooling, but varying outgassing rate. H2 most efficiently inhibits solidification relative to the other cases. All considered volatiles show distinctive evolution of the atmosphere and interior and display different atmospheric signals that can be measured by astronomical surveys. Deviations in the geological properties of the planetary interior similarly manifest in the atmospheric signal. Future observations may isolate distinctive features in exoplanet atmospheres to infer interior state and composition. Key Points: Magma oceans with different volatiles display varying timescales of solidification, outgassing, and atmospheric stratificationAtmospheric blanketing and cooling time increase in three principle classes from N2, CO, O2 to H2O, CO2, CH4 to H2Coupled mantle–atmosphere systems display distinctive features that link the interior and surface state to atmospheric spectrum and climate [ABSTRACT FROM AUTHOR]

Jupiter is in the class of planets that we call gas giants, not because they consist of gas but because they were primarily made from hydrogen-helium gas, which upon gravitational compression becomes a metallic fluid. Juno, in orbit about Jupiter since 2016, has changed our view: The gravity data are much improved, and the simplest interpretation of the higher order even harmonics implies that the planet may have a diluted central concentration of heavy elements. Jupiter has strong winds extending to perhaps ∼3,000-km depth that are evident in the odd zonal harmonics of the gravity field. Jupiter's distinctive magnetic field displays some limited local structure, most notably the Great Blue Spot (a region of downward flux near the equator), and some evidence for secular variation, possibly arising from the winds. However, Juno is ongoing; it has not answered all questions and has posed new ones. ▪ Juno's mission reveals Jupiter's interior. ▪ A core exists but is diluted by hydrogen. ▪ The mission revealed wind depth and magnetic field. [ABSTRACT FROM AUTHOR]

Geochemical studies of planetary accretion and evolution have invoked various degrees of collisional erosion to explain differences in bulk composition between planets and chondrites. Here we undertake a full, dynamical evaluation of ‘crustal stripping’ during accretion and its key geochemical consequences. Crusts are expected to contain a significant fraction of planetary budgets of incompatible elements, which include the major heat producing nuclides. We present smoothed particle hydrodynamics simulations of collisions between differentiated rocky planetesimals and planetary embryos. We find that the crust is preferentially lost relative to the mantle during impacts, and we have developed a scaling law based on these simulations that approximates the mass of crust that remains in the largest remnant. Using this scaling law and a recent set of N -body simulations of terrestrial planet formation, we have estimated the maximum effect of crustal stripping on incompatible element abundances during the accretion of planetary embryos. We find that on average approximately one third of the initial crust is stripped from embryos as they accrete, which leads to a reduction of ∼20% in the budgets of the heat producing elements if the stripped crust does not reaccrete. Erosion of crusts can lead to non-chondritic ratios of incompatible elements, but the magnitude of this effect depends sensitively on the details of the crust-forming melting process on the planetesimals. The Lu/Hf system is fractionated for a wide range of crustal formation scenarios. Using eucrites (the products of planetesimal silicate melting, thought to represent the crust of Vesta) as a guide to the Lu/Hf of planetesimal crust partially lost during accretion, we predict the Earth could evolve to a superchondritic 176 Hf/ 177 Hf (3–5 parts per ten thousand) at present day. Such values are in keeping with compositional estimates of the bulk Earth. Stripping of planetary crusts during accretion can lead to detectable changes in bulk composition of lithophile elements, but the fractionation is relatively subtle, and sensitive to the efficiency of reaccretion. [ABSTRACT FROM AUTHOR]

We used a sample of super-Earth-like planets detected by the Doppler spectroscopy and transit techniques to explore the dependence of orbital parameters of the planets on the metallicity of their host stars. We confirm the previous results (although still based on small samples of planets) that super-Earths orbiting around metal-rich stars are not observed to be as distant from their host stars as we observe their metal-poor counterparts to be. The orbits of these super-Earths with metal-rich hosts usually do not reach into the Habitable Zone (HZ), keeping them very hot and inhabitable. We found that most of the known planets in the HZ are orbiting their GK-type hosts which are metal-poor. The metal-poor nature of planets in the HZ suggests a high Mg abundance relative to Si and high Si abundance relative to Fe. These results lead us to speculate that HZ planets might be more frequent in the ancient Galaxy and had compositions different from that of our Earth. [ABSTRACT FROM AUTHOR]

We compute the maximum radius a planet can have in order to fulfill two constraints that are likely necessary conditions for habitability: 1- surface temperature and pressure compatible with the existence of liquid water, and 2- no ice layer at the bottom of a putative global ocean, that would prevent the operation of the geologic carbon cycle to operate. We demonstrate that, above a given radius, these two constraints cannot be met: in the Super-Earth mass range (1-12 M), the overall maximum that a planet can have varies between 1.8 and 2.3 R. This radius is reduced when considering planets with higher Fe/Si ratios, and taking into account irradiation effects on the structure of the gas envelope. [ABSTRACT FROM AUTHOR]

We know that giant planets played a crucial role in the making of our Solar System. The discovery of giant planets orbiting other stars is a formidable opportunity to learn more about these objects, what their composition is, how various processes influence their structure and evolution, and most importantly how they form. Jupiter, Saturn, Uranus, and Neptune can be studied in detail, mostly from close spacecraft flybys. We can infer that they are all enriched in heavy elements compared to the Sun, with the relative global enrichments increasing with distance to the Sun. We can also infer that they possess dense cores of varied masses. The intercomparison of presently characterized extrasolar giant planets shows that they are also mainly made of hydrogen and helium, but that they either have significantly different amounts of heavy elements, have had different orbital evolutions, or both. Hence, many questions remain and need to be answered to make significant progress on the origins of planets. [ABSTRACT FROM AUTHOR]

The earliest atmospheres of rocky planets originate from extensive volatile release during magma ocean epochs that occur during assembly of the planet. These establish the initial distribution of the major volatile elements between different chemical reservoirs that subsequently evolve via geological cycles. Current theoretical techniques are limited in exploring the anticipated range of compositional and thermal scenarios of early planetary evolution, even though these are of prime importance to aid astronomical inferences on the environmental context and geological history of extrasolar planets. Here, we present a coupled numerical framework that links an evolutionary, vertically resolved model of the planetary silicate mantle with a radiative-convective model of the atmosphere. Using this method, we investigate the early evolution of idealized Earth-sized rocky planets with end-member, clear-sky atmospheres dominated by either H 2 , H 2 O, CO 2 , CH 4 , CO, O 2 , or N 2 . We find central metrics of early planetary evolution, such as energy gradient, sequence of mantle solidification, surface pressure, or vertical stratification of the atmosphere, to be intimately controlled by the dominant volatile and outgassing history of the planet. Thermal sequences fall into three general classes with increasing cooling timescale: CO, N 2 , and O 2 with minimal effect, H 2 O, CO 2 , and CH 4 with intermediate influence, and H 2 with several orders of magnitude increase in solidification time and atmosphere vertical stratification. Our numerical experiments exemplify the capabilities of the presented modeling framework and link the interior and atmospheric evolution of rocky exoplanets with multiwavelength astronomical observations., (© 2021. The Authors.)