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Geological domaining is an essential aspect of mineral resource evaluation. Various explicit and implicit modeling approaches have been developed for this purpose, but most of them are computationally expensive and complex, particularly when dealing with intricate mineralization systems and large datasets. Additionally, most of them require a time-consuming process for hyperparameter tuning. In this research, the application of the Learning Vector Quantization (LVQ) classification algorithm has been proposed to address these challenges. The LVQ algorithm exhibits lower complexity and computational costs compared to other machine learning algorithms. Various versions of LVQ, including LVQ1, LVQ2, and LVQ3, have been implemented for geological domaining in the Darehzar porphyry copper deposit in southeastern Iran. Their performance in geological domaining has been thoroughly investigated and compared with the Support Vector Machine (SVM), a widely accepted classification method in implicit domaining. The overall classification accuracy of LVQ1, LVQ2, LVQ3, and SVM is 90%, 90%, 91%, and 98%, respectively. Furthermore, the calculation time of these algorithms has been compared. Although the overall accuracy of the SVM method is ∼ 7% higher, its calculation time is ∼ 1000 times longer than LVQ methods. Therefore, LVQ emerges as a suitable alternative for geological domaining, especially when dealing with large datasets. Highlights: In this study, the crucial significance of geological domaining in mineral resource evaluation is underscored, highlighting its vital role in comprehending mineralization systems and managing extensive datasets. The research proposes the application of the LVQ classification algorithm as a solution to the challenges posed by computationally expensive and complex modeling approaches. LVQ is highlighted for its lower complexity and computational costs compared to other machine learning algorithms, positioning it as an efficient alternative. The research presents a thorough investigation and comparison of the performance of various LVQ versions with SVM, a widely accepted method in implicit domaining. Finally, LVQ is introduced as a more time-efficient alternative, particularly for dealing with large datasets. [ABSTRACT FROM AUTHOR]

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Abstract Copper mineralization in the Pulang (PL) porphyry deposit, Langdu (LD) porphyry-skarn deposit and Songnuo (SN) porphyry prospect in northwestern Yunnan, China, is closely related to the emplacement of quartz monzonite porphyries. The chemical compositions of biotite and apatite from those porphyries were analyzed to calculate the halogen fugacity and to constrain mineralized and barren porphyries. Our data show that biotites from the PL deposit have higher MgO, SiO2, TiO2 and F contents than those from the LD deposit or SN prospect. Compared to those in the LD deposit and SN prospect, the Mg (atoms per formula unit (apfu)) and AlVI (apfu) value in biotite is greater, and the F content is greater and the SO3 and Ce2O3/Y2O3 ratio in apatite are lower in the PL deposit. Ti-biotite thermometry and apatite-biotite geothermometry show that the crystallization temperature of biotite from the PL deposit is higher than that from the SN prospect or LD deposit. The results suggest that oxygen fugacity, magmatic sulfur, and H2O contents cannot be used to efficiently distinguish the PL deposit from the LD deposit and SN prospect. However, the halogen chemistry of biotite from the PL deposit is distinctly different from that of the LD deposit or SN prospect according to the lower IV (F), indicating that mineralized quartz monzonite porphyries in the PL deposit formed during the late magmatic stage, which is in contrast to those in the LD deposit and SN prospect. The mineralized porphyries display a remarkable negative linear relationship (r = − 0.96) with the log (f HF/f HCl) and log (f H2O/f HF) ratio, which can be used to distinguish the mineralized and barren porphyries. Compared with other typical porphyry Cu systems, there is a remarkable positive linear relationship between IV (Cl) and log (f H2O/f HCl). In addition, the linear slope and intercept for log (f H2O/f HCl) ratios and the IV (Cl) of biotite from the potassic and phyllic alteration zones are significantly greater than those from other porphyries.

Copper mineralization in the Pulang (PL) porphyry deposit, Langdu (LD) porphyry-skarn deposit and Songnuo (SN) porphyry prospect in northwestern Yunnan, China, is closely related to the emplacement of quartz monzonite porphyries. The chemical compositions of biotite and apatite from those porphyries were analyzed to calculate the halogen fugacity and to constrain mineralized and barren porphyries. Our data show that biotites from the PL deposit have higher MgO, SiO2, TiO2 and F contents than those from the LD deposit or SN prospect. Compared to those in the LD deposit and SN prospect, the Mg (atoms per formula unit (apfu)) and AlVI (apfu) value in biotite is greater, and the F content is greater and the SO3 and Ce2O3/Y2O3 ratio in apatite are lower in the PL deposit. Ti-biotite thermometry and apatite-biotite geothermometry show that the crystallization temperature of biotite from the PL deposit is higher than that from the SN prospect or LD deposit. The results suggest that oxygen fugacity, magmatic sulfur, and H2O contents cannot be used to efficiently distinguish the PL deposit from the LD deposit and SN prospect. However, the halogen chemistry of biotite from the PL deposit is distinctly different from that of the LD deposit or SN prospect according to the lower IV (F), indicating that mineralized quartz monzonite porphyries in the PL deposit formed during the late magmatic stage, which is in contrast to those in the LD deposit and SN prospect. The mineralized porphyries display a remarkable negative linear relationship (r = − 0.96) with the log (f HF/f HCl) and log (f H2O/f HF) ratio, which can be used to distinguish the mineralized and barren porphyries. Compared with other typical porphyry Cu systems, there is a remarkable positive linear relationship between IV (Cl) and log (f H2O/f HCl). In addition, the linear slope and intercept for log (f H2O/f HCl) ratios and the IV (Cl) of biotite from the potassic and phyllic alteration zones are significantly greater than those from other porphyries. [ABSTRACT FROM AUTHOR]

Chlorite is present extensively in many types of deposits. The mechanism underlying the chemical variations in chlorite remains unclear. The Naruo porphyry deposit is a giant copper porphyry deposit in the Duolong ore district of Tibet. Chlorite, which is abundant in this deposit, has yet to be studied systematically; hence, we used principal component analysis (PCA) to assess the correlation between chlorite elements and various types of mineral deposits. We then conducted a preliminary investigation into its mineralogy and geochemistry to better understand its formation process and identify potential prospecting indicators. The PCA method proved effective in discerning two distinctive element signatures within the chlorite and categorising them into four deposit types: orogenic Au deposits, granite-type U deposits, and skarn-type Sn deposits that exhibit high FeOand low MgO distinguishing them from porphyry copper deposits. The chlorite in the Naruo deposit is classified as either early metasomatic (M-type), consisting mainly of clinochlore, or late hydrothermal (H-type), primarily consisting of clinochlore and chamosite. This classification suggests that H-type chlorite formed in a reductive environment conducive to Cu precipitation at medium temperatures (255°C-342°C). Al-Si and Fe-Mg substitutions were found to be the primary processes involved in its generation. Additionally, from the mineralisation centre outwards, there was an observed decrease in Si content as well as the Fe/(Fe+Mg) ratio in H-type chlorite, along with decreases in temperature, sulphur, and oxygen fugacity of allchlorites; conversely, increases were observed for Al content along with Mg and Mn elements in H-type chlorite. Chlorite is useful for exploring porphyry copper systems as an indicator mineral. [ABSTRACT FROM AUTHOR]

Chlorite is present extensively in many types of deposits. The mechanism underlying the chemical variations in chlorite remains unclear. The Naruo porphyry deposit is a giant copper porphyry deposit in the Duolong ore district of Tibet. Chlorite, which is abundant in this deposit, has yet to be studied systematically; hence, we used principal component analysis (PCA) to assess the correlation between chlorite elements and various types of mineral deposits. We then conducted a preliminary investigation into its mineralogy and geochemistry to better understand its formation process and identify potential prospecting indicators. The PCA method proved effective in discerning two distinctive element signatures within the chlorite and categorising them into four deposit types: orogenic Au deposits, granite-type U deposits, and skarn-type Sn deposits that exhibit high FeO and low MgO distinguishing them from porphyry copper deposits. The chlorite in the Naruo deposit is classified as either early metasomatic (M-type), consisting mainly of clinochlore, or late hydrothermal (H-type), primarily consisting of clinochlore and chamosite. This classification suggests that H-type chlorite formed in a reductive environment conducive to Cu precipitation at medium temperatures (255°C–342°C). Al-Si and Fe-Mg substitutions were found to be the primary processes involved in its generation. Additionally, from the mineralisation centre outwards, there was an observed decrease in Si content as well as the Fe/(Fe+Mg) ratio in H-type chlorite, along with decreases in temperature, sulphur, and oxygen fugacity of all chlorites; conversely, increases were observed for Al content along with Mg and Mn elements in H-type chlorite. Chlorite is useful for exploring porphyry copper systems as an indicator mineral.

The Mineral Prospectivity Map (MPM) is a powerful tool for identifying target areas for the exploration of undiscovered mineral deposits. In this study, a knowledge-driven Index overlay technique was utilized to create the MPM on a regional scale. The complex distribution patterns of geological features associated with mineral deposits were mapped and correlations between these features and mineral deposits were revealed by integrating geological, geophysical, hydrothermal alteration, and fault density data layers. It was found that 23% of the study area was highly prospective, with 77% of the known porphyry copper occurrences located within this area. The normalized density was equal to 3.35, indicating a significant relationship between the known porphyry copper occurrences and their occupied area. The MPM also identified potential tracts outside the known mineralized areas that can be used for exploration and quantitative assessment of undiscovered resources. It is suggested that the MPM is a valuable tool for mineral exploration and could have significant implications for the mining industry.

Identification of geochemical anomalies is a critical task in mineral exploration targeting. Decades of research and technology have resulted in new algorithms and techniques for recognizing anomaly detection methods at various scales and sample media. However, algorithms cannot always reveal the true nature of geological processes. The mineral system concept may contribute to a better understanding of the geological processes required to form and preserve ore deposits at all spatial and temporal scales. The mineral systems concept investigates the geochemical processes occurring within mineral subsystems in soil samples from the porphyry prospect area. The Cu/(Al + Ca) index was used to compare Cu, Mo, and (Pb* Zn)/(Cu*Mo) to highlight the region of interest for mineral potential mapping and pioneer borehole drilling based on fluid-rock interaction and secondary processes (e.g., alteration, weathering, and leaching). Exploratory boreholes validate a better performing Cu/(Al + Ca) index for detecting and refining soil geochemical anomalies.

Identification of geochemical anomalies is a critical task in mineral exploration targeting. Decades of research and technology have resulted in new algorithms and techniques for recognizing anomaly detection methods at various scales and sample media. However, algorithms cannot always reveal the true nature of geological processes. The mineral system concept may contribute to a better understanding of the geological processes required to form and preserve ore deposits at all spatial and temporal scales. The mineral systems concept investigates the geochemical processes occurring within mineral subsystems in soil samples from the porphyry prospect area. The Cu/(Al + Ca) index was used to compare Cu, Mo, and (Pb* Zn)/(Cu*Mo) to highlight the region of interest for mineral potential mapping and pioneer borehole drilling based on fluid-rock interaction and secondary processes (e.g., alteration, weathering, and leaching). Exploratory boreholes validate a better performing Cu/(Al + Ca) index for detecting and refining soil geochemical anomalies. [ABSTRACT FROM AUTHOR]

The Mineral Prospectivity Map (MPM) is a powerful tool for identifying target areas for the exploration of undiscovered mineral deposits. In this study, a knowledge-driven Index overlay technique was utilized to create the MPM on a regional scale. The complex distribution patterns of geological features associated with mineral deposits were mapped and correlations between these features and mineral deposits were revealed by integrating geological, geophysical, hydrothermal alteration, and fault density data layers. It was found that 23% of the study area was highly prospective, with 77% of the known porphyry copper occurrences located within this area. The normalized density was equal to 3.35, indicating a significant relationship between the known porphyry copper occurrences and their occupied area. The MPM also identified potential tracts outside the known mineralized areas that can be used for exploration and quantitative assessment of undiscovered resources. It is suggested that the MPM is a valuable tool for mineral exploration and could have significant implications for the mining industry. [ABSTRACT FROM AUTHOR]

Integration of multiple data types is beneficial for prediction of geological characteristics. From the perspective that geochemistry characterizes the composition of a rock mass, hyperspectral data characterizes alteration mineralogy and image feature extraction characterizes texture, most geological classifications would be well-informed by the combination of these three features. The process of meaningfully integrating distinctly sourced datasets and producing scale-relevant predictions for geological classifications involves several steps. We demonstrate a workflow to comprehensively structure and integrate these three feature families, refine training data, predict alteration classes and mitigate noise derived from scale mismatch in output predictions. The dataset, compiled from the Josemaria porphyry copper–gold deposit in Argentina, is comprised of more than 14 000 intervals of approximately 2 m, taken from 36 drillholes, where geochemistry was merged with hyperspectral mineralogy represented as tabular pixel abundances, and textural metrics extracted from core imagery, structured into the geochemical interval. Feature engineering and principal component analysis provided insights into the behaviour of the ore system during intermediate steps, as well as providing uncorrelated feature inputs for a random forest predictor. Training data were refined by producing an initial prediction, thresholding the predictions to >70% dominant class probability and using those (high-probability) samples to produce a final model encoding better constrained separation between alteration assemblages. Prediction using the final model returned an accuracy of 82.5%, as a function of model discrepancy combined with logging ambiguity and a scale mismatch between generalized logged intervals and much more granular (2 m) feature inputs. Noise reduction and generalization to the desired resolution of output was achieved by applying the multiscale multivariate continuous wavelet transform tessellation method to class membership probabilities. Ultimately, a large database of logged drill core was homogenized using empirical methodologies. The described workflow is adaptable to distinct scenarios with some modification and is apt for integrating multiple input feature types and using them to systematically define geological classifications in drillhole data. [ABSTRACT FROM AUTHOR]

Data integration can be used to conduct exploratory studies on a regional scale simultaneously on all available data from the study area. The results obtained by considering all the data and the relationship between them are more accurate and reliable. In these cases, mineral potential modeling is utilized to determine promising areas. Although GIS-based mineral prospectivity mapping methods have been established, it is important to review which methods of geochemical data analysis result in anomaly maps that, in turn, lead to better models of mineral prospectivity. In this study, instead of using anomalies of pathfinder elements, using geochemical zonality anomalies as one of the several evidential maps resulted in the improved mapping of mineral prospectivity. In addition, whereas weights-of-evidence analysis was used in this study, other methods of data representation and integration for mineral prospectivity mapping can be used. In this study, a part of Arasbaran metallogenic zone was selected and one-element geochemical control maps, geochemical maps produced by zonality, structural, alteration and geological maps were weighted and produced using the position of known indices by the method of weights-of-evidence. In the next step, weighted layers were combined with logistic regression (LR) method to prepare mineral potential models. [ABSTRACT FROM AUTHOR]

Large volume, intermediate-felsic magma reservoirs are the source of melt and mineralising fluids which generate porphyry copper deposits. Cooling and crystallisation of hydrous magmas drives the exsolution and expulsion of a magmatic volatile phase—a process which remains challenging to constrain in porphyry Cu systems where the record of magma volatile compositions is rarely preserved. Here, we use the halogen compositions of apatite inclusions shielded as inclusions within zircon to constrain volatile evolution in magma reservoirs which pre-date and are synchronous with porphyry Cu mineralisation at Quellaveco, Southern Peru. Geochemical and textural data confirm that the zircon-included apatites escaped re-equilibration with hydrothermal fluids, unlike apatites found in the groundmass of the same rocks. We, therefore, recommend that future studies attempting to reconcile magmatic volatile budgets using apatite in porphyry Cu systems should focus on apatite inclusions in zircon. By combining the apatite inclusion data with numerical modelling, we find evidence that the magma reservoir sourcing porphyry Cu mineralisation remained fluid-saturated for the entire period recorded by apatite crystallisation. By contrast, the pre-mineralisation batholith shows more variable, potentially fluid-undersaturated behaviour. Our modelling suggests that in order to attain the porphyry melt volatile compositions inferred from apatite, the magma reservoir must have exsolved a large proportion of its volatile budget, consistent with having been held at high crystallinity (40–60% crystals). This crystallisation interval coincides with peak chlorine and copper extraction from intermediate-felsic magmas, and would have permitted efficient fluid migration and accumulation at the roof of the system. We suggest that the storage of large-volume, long-lived, crystal-rich magma reservoirs in magmatic arcs may be a critical step in generating world-class porphyry copper deposits. [ABSTRACT FROM AUTHOR]

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The porphyry copper belt in the Geza island arc in southwestern China is the only Indosinian porphyry copper metallogenic belt that has been discovered and evaluated so far. The Pulang porphyry copper deposit (also referred to as the Pulang deposit) in this area has proven copper reserves of 5.11×106 t. This deposit has been exploited on a large scale using advanced mining methods, exhibiting substantial economic benefit. Based on many research results of previous researchers and the authors’ team, this study proposed the following key insights. (1) The Geza island arc was once regarded as an immature island arc with only andesites and quartz diorite porphyrites occurring. This understanding was overturned in this study. Acidic endmember components such as quartz monzonite porphyries and quartz monzonite porphyries have been identified in the Geza island arc, and the mineralization is mainly related to the magmatism of quartz monzonite porphyries. (2) Complete porphyry orebodies and large vein orebodies have developed in the Pulang deposit. Main orebody KT1 occurs in the transition area between the potassium silicate alteration zone of quartz monzonite porphyries and the sericite-quartz alteration zone. Most of them have developed in the potassium silicate alteration zone. The main orebody occurs as large lenses at the top of the hanging wall of rock bodies, with an engineering-controlled length of 1920 m and thickness of 32.5‒630.29 m (average: 187.07 m). It has a copper grade of 0.21%‒1.56% (average: 0.42%) and proven copper resources of 5.11×106 t, which are associated with 113 t of gold, 1459 t of silver, and 170×103 t of molybdenum. (3) Many studies on diagenetic and metallogenic chronology, isotopes, and fluid inclusions have been carried out for the Pulang deposit, including K-Ar/Ar-Ar dating of monominerals (e.g., potassium feldspars, biotites, and amphiboles), zircon U-Pb dating, and molybdenite Re-Os dating. The results show that the porphyries in the Pulang deposit are composite plutons and can be classified into pre-mineralization quartz diorite porphyrites, quartz monzonite porphyries formed during the mineralization, and post-mineralization granite porphyries, which were formed at 223±3.7 Ma, 218±4 Ma, and 207±3.9 Ma, respectively. The metallogenic age of the Pulang deposit is 213‒216 Ma. (4) The petrogeochemical characteristics show that the Pulang deposit has the characteristics of volcanic arc granites. The calculation results of trace element contents in zircons show that quartz monzonite porphyries and granite porphyries have higher oxygen fugacity. The isotopic tracing results show that the diagenetic and metallogenic materials were derived from mixed crust- and mantle-derived magmas.©2022 China Geology Editorial Office.

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The Miocene Daralu Porphyry Copper Deposits (PCDs) is found associated with other porphyries such as Sarcheshmeh and Meiduk in the Kerman Cenozoic Magmatic Arc (KCMA), southern Iran. In this research, we provided whole-rock geochemical data, characteristics of hydrothermal fluid and sulfur isotope composition of the Daralu intrusive body, and discussed the nature, tectonic setting and fluid evolution of this deposit aiming to investigate its fertility. The Daralu porphyry shows adakites affinity, that is, high Sr/Y and La/Yb ratios and positive Eu anomalies. The REEs patterns indicate a strong fractionation ([La/Yb]n= 28.73). High La/Sm and Dy/Yb ratios suggest enrichment of amphibole and garnet as residual phases in melt source, whereas partial melting of plagioclase increases Eu and Sr in the parent magma. The presence of garnet implies a pressure equivalent to the thickness of more than 40km of crust. To elucidate the evolutionary history of fluids and the origin of the Daralu deposit, we focused on the origin and composition of the fluid through petrography, Raman spectroscopy, and microthermometry studies of fluid inclusions. The fluid inclusions have been divided into four types: vapor (type I), aqueous-vapor (type II), CO2-bearing (type III), and multiphase (type IV). The Raman shifts included 1284 and 1388 cm-1 for CO2 and 2750-3900 cm-1 for H2O. The events such as NaCl supersaturation, exhausting of CO2-rich components, high oxygen fugacity and temperature decreasing through mineralization stages were critical in controlling the fertility of the Daralu PCD. The obtained δ34S data for sulfides yielded an average of +5.5‰. Based on the observed features, it was concluded that Daralu porphyry shares formation conditions with other productive porphyries of the KCMA. [ABSTRACT FROM AUTHOR]

[Display omitted] • Late Silurian (∼430 Ma) and early Devonian (∼402 Ma) porphyry events are newly recognized in the ore-hosting intrusive complex at the Nurkazgan deposit. • SIMS U-Pb dating of Cu-rich, hydrothermal rutile yields an age of 428.9 ± 6.9 Ma for the main-stage mineralization at Nurkazgan. • The late Silurian quartz diorite porphyry acts as the causative intrusion at Nurkazgan. • LREE enrichments and high Cu contents are effective discriminators to distinguish porphyry Cu-related rutile from that formed in orogenic gold deposit. The porphyry Cu-related intrusions commonly comprise multiple phases such as the large Nurkazgan porphyry Cu-Au deposit in Central Kazakhstan, hosted in the Karagandinsky dioritic to granitic intrusive complex. Here, SHRIMP and LA-ICP-MS zircon U-Pb dating on the multiple ore-bearing intrusions from this complex confirms a punctuated magmatic history distributed over 35 m.y., and marked by three episodic porphyry events rather than a single event, with the oldest event being the early granodiorite and quartz diorite porphyries at ca. 437–440 Ma, the second being the quartz diorite porphyry at 429.7 ± 2.1 Ma, and the last being the late granodiorite and quartz diorite porphyries at 402.8 ± 3.7 Ma and 402.0 ± 3.9 Ma, respectively. The mineralization is related to the two younger episodic intrusions of quartz diorite porphyry at ∼ 430 Ma and ∼ 402 Ma, respectively. SIMS U-Pb dating of hydrothermal, Cu-rich (up to 20.9 ppm) rutile from the breccia-type ores directly constrains the timing of porphyry mineralization at 428.9 ± 6.9 Ma, which is coincident with the emplacement age of the ∼ 430 Ma quartz diorite porphyry, and thus demonstrates this porphyry as a causative intrusion generating main-stage mineralization. This close genetic link is also supported by the chondrite-normalized REE patterns of rutile, which show remarkably similar light REE-enrichments and moderate negative Eu anomalies to those of the ∼ 430 Ma quartz diorite porphyry. A molybdenite sample obtained from the main-ore stage vein, however, has a Re-Os age of 418.6 ± 1.8 Ma, which is slightly younger than the U-Pb age determinations of rutile. This indicates that the Re-Os isotope system was disturbed by the second (post-ore) thermal event related to ∼ 402 Ma quartz diorite porphyry. In line with published data, this study suggests that the rutile U-Pb age in combination with its REE patterns can be a powerful tool to trace the causative porphyry. Moreover, the typical LREE-enriched REE patterns coupled with the high Cu anomalies, inherited from the causative porphyry and related exsolving fluids, can be as diagnostic proxies for distinguishing the porphyry Cu-related hydrothermal rutile from those formed in orogenic gold deposits. Based on these two geochemical discriminators and U-Pb ages, rutile can serve as unique fingerprints to help improve porphyry copper exploration in green field or covered terranes to complement detrital zircon fertility indicators. [ABSTRACT FROM AUTHOR]

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The area discussed in this exploration methodology case study is situated along the Sistan Suture Zone where the granitoid suite is a mantle-derived multiphase intrusive complex. One of the characteristics of this region is the presence of large areas of sulfide-bearing, quartz-rich stockwork and pyritic veins. Geochemical findings show that it is limited to the calc-alkaline to shoshonitic series intrusions and is associated with a volcanic arc (I-type) formed within an active continental margin subduction setting. The associated intrusive complex has characteristics consistent with Cu productive porphyries, supported by high K-adakitic Sr/Y, La/Yb, Y and Al2O3/TiO2 geochemical signatures. The stockwork mineralization includes the hypogene (chalcopyrite and bornite), with locally superimposed supergene (covellite, malachite, goethite and hematite) zones. The Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) images (visible-near infrared (VNIR), and shortwave infrared (SWIR) bands) and mixture tuned matched filtering (MTMF) algorithm enable identification of each hydrothermal alteration type, especially where pictures were innovatively classified using a concentration–number (C–N) fractal method. Four alteration types are evident (i.e. phyllic, argillic and propylitic), as well as secondary (supergene) jarosite, that are associated with gossans, which are an indicator of the hypogene pyritic shell. The propylitic alteration envelopes the phyllic and argillic varieties, forming a belt around the pyritic shell; alteration assemblages were confirmed by X-ray powder diffraction (XRD) analysis. Finally, all results show a mineralization alteration pattern within the case study region that is similar to those of known porphyry copper and associated molybdenum- and gold-bearing systems in this region of Iran and worldwide. [ABSTRACT FROM AUTHOR]

BACKGROUND Infrared spectroscopy technology, as a green, fast, non-destructive and accurate mineral detection technology, has drawn widespread attention of geologists all over the world in recent years. In view of the high superposition of altered minerals in porphyry deposits, the inconspicuous alteration zone boundaries, many fine-grain altered minerals, and clay altered minerals, this technology has outstanding advantages in the identification of altered minerals and interpretation of exploration information. OBJECTIVES To analyze the characteristics of alteration and mineralization of the porphyry copper deposit in Pulang, Yunnan Province, and to provide the basis theory for porphyry copper deposits (especially in the Pulang deposit) exploration. METHODS The core samples in the drill ZK1801 were detected using HyLogger-3 through infrared spectroscopy technology, and the spectral data was processed and analyzed by TSG 8.0. RESULTS K-silicate alteration, epidote-chlorite alteration, chlorite-illite alteration, quartz-illite alteration and clay alteration were identified in the Pulang porphyry copper deposit. The main altered minerals included quartz, potassium feldspar, sericite, chlorite, epidote, kaolinite, smectite and illite. According to the characteristics of mineralization, it was found that copper ore bodies were widely present in the potassium silicate zone and epidote-chlorite zone. CONCLUSIONS Quartz+potash, feldspar+sericite and epdote+chlorite can be typical altered mineral assemblages for exploration of the Pulang porphyry copper deposit. The Al-OH wavelength from 2210nm to 2205nm of sericite (long-wave sericite) is closely related to mineralization, which can be used as an indicator for prospecting in the Pulang deposit.

[Display omitted] • Semi-supervised machine learning model was developed for identifying metallogenic settings of porphyry copper deposits. • SHAP values reveal the systematic chemical differences between zircons formed in different tectonic environments. • A new zircon trace element discriminant diagram was developed for identifying tectonic settings of PCDs. Porphyry copper deposits (PCDs), as main sources of Cu resources worldwide, have attracted great attention for both scientific research and mining purposes in the past decades. The formation of PCDs is closely related to magmatic-hydrothermal system formed in both (continental/oceanic) arc and non-arc environments. Many low-dimensional geochemistry discriminants were developed for identifying the tectonic environments where ore-related magmas formed. However, long-term geological processes may obscure the geochemistry information recorded in rocks and minerals, which inevitably introduces uncertainties for identifying tectonic environments when using the low-dimensional discriminant diagrams. Here, we proposed a semi-supervised machine learning (ML) approach based on zircon chemistry data (spanning 16 elements) to identify the tectonic environments of PCDs. The results show that the semi-supervised models perform better in identifying the tectonic environments compared to the conventional low-dimensional discriminants. Moreover, as another benefit of big data analysis, ML model can clarify the systematic geochemistry differences of igneous zircons formed in different tectonic environments. The results suggest that (U+Th)/Yb and LREE/HREE are the top two important zircon chemical features for distinguishing PCDs formed in arc or non-arc environments. Specifically, zircons from non-arc show higher (U+Th)/Yb compared to that of continental arc, while zircons from island arc show lowest (U+Th)/Yb and LREE/HREE. Finally, the semi-supervised learning model was applied to the Dexing porphyry copper deposit to approach the longstanding debate regarding the underlying metallogenic setting. The results support the viewpoint that the Dexing porphyry copper deposit was formed in an intracontinental (non-arc) environment related to asthenosphere upwelling. [ABSTRACT FROM AUTHOR]

The purpose of the study was to identify the hypogene mineralization zone in the south of Sungun and Kighal porphyry Cu deposits, based on subsurface data and by using the proposed concentration–array (C–A) multivariate fractal and zonality modeling. The area (Kighal and south of the Sungun mine) is located in northwestern part of the Arasbaran Magmatic Zone (AMZ). AMZ is the host of large porphyry copper and gold epithermal deposits in the northwest of Iran. A litho-geochemical survey used to extract new anomalies. And also, the research has discussed statistics, principal component analysis (PCA) and hierarchical cluster analysis, estimation maps, and multi-element associations in the prospect area. The C-A multivariate fractal and zonality modeling was used for map classification and finally draw promised areas for the litho-geochemical survey in the Kighal prospect. According to multivariate PCA analysis, three groups are determined: the first group is positively correlated with component 2 and reflects the association between Cu and Mo elements that are similar to porphyry copper deposits associated elements and can be a good indicator for porphyry copper mineralization. Investigation of lithogeochemical data and separation of anomalies by C-A multivariate fractal and zonality modeling in south of the Sungun mine and Kighal porphyry prospect revealed that this method has high efficiency in separating anomalies and determining the position of mineralization. Geochemical studies and the field-based obtained data showed that the mineralization and alteration are limited to monzonitic rocks and are located in the southern and eastern parts of the study area, which are in line with the phyllic and mostly potassic alterations. [ABSTRACT FROM AUTHOR]

BACKGROUND The main types of copper deposits are porphyry and skarn types. Dacite porphyry is a rock type commonly developed in the porphyry Cu-Mo-Au system. The rock can be used as a marker clue for ore prospecting and ore-forming rock when there is well-developed hydrothermal alteration. The Dabaoshan deposit is currently the largest copper polymetallic deposit in the South China Block. Previous studies have shown that the dacite porphyry of the mining area is not only the ore-forming parent rock, but also a favorable ore-bearing wall rock. However, there are some debates about the relationship between dacite porphyry and mineralization in this mining area. With the breakthrough of prospecting for medium and large dacite porphyry ore bodies in recent years, the relationship between dacite porphyry and mineralization has once again become a concern. OBJECTIVES To understand the relationship between dacite porphyry alteration and mineralization of the Dabaoshan deposit. METHODS Based on field work and indoor analysis, X-ray fluorescence spectroscopy (XRF) and inductively coupled plasma-mass spectrometry (ICP-MS) were used to determine copper, tungsten, silicon, aluminum and calcium in Dabaoshan dacite porphyry samples. The isotope composition, metal element contents and alteration characteristics of the dacite porphyry in the mining area were used to discuss the relationship between alteration and prospecting direction. RESULTS The copper content ranged from 107 to 6909μg/g, which was consistent with the copper ore grade of 0.3%-0.5% in the mining area. The LOI and other geochemical indicators that can represent the degree of alteration were positively correlated with copper. Hydrothermal alteration was widely developed in dacite porphyry, including potassium, prophyliticition and quartz-sericitization from early to late stage. Among different stages of alterations, the copper content of quartz-sericitization was 2 to 5 times higher than other alteration types, indicating that quartz-sericitization was closely related to copper mineralization and was an important prospecting marker clue. CONCLUSIONS The deep alteration intensity of the dacite porphyry (below the 270m elevation) has not been weakened, suggesting a great prospecting potential. In addition, the contact zone between dacite porphyry and the Jurassic strata, and the xenoliths in the dacite porphyry are also important prospecting directions, which may host skarn-type copper-rich deposits.

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BACKGROUND: Infrared spectroscopy technology, as a green, fast, non-destructive and accurate mineral detection technology, has drawn widespread attention of geologists all over the world in recent years. In view of the high superposition of altered minerals in porphyry deposits, the inconspicuous alteration zone boundaries, many fine-grain altered minerals, and clay altered minerals, this technology has outstanding advantages in the identification of altered minerals and interpretation of exploration information. OBJECTIVES: To analyze the characteristics of alteration and mineralization of the porphyry copper deposit in Pulang, Yunnan Province, and to provide the basis theory for porphyry copper deposits (especially in the Pulang deposit) exploration. METHODS: The core samples in the drill ZK1801 were detected using HyLogger-3 through infrared spectroscopy technology, and the spectral data was processed and analyzed by TSG 8.0.RESULTS: K-silicate alteration, epidote-chlorite alteration, chlorite-illite alteration, quartz-illite alteration and clay alteration were identified in the Pulang porphyry copper deposit. The main altered minerals included quartz, potassium feldspar, sericite, chlorite, epidote, kaolinite, smectite and illite. According to the characteristics of mineralization, it was found that copper ore bodies were widely present in the potassium silicate zone and epidote-chlorite zone. CONCLUSIONS: Quartz+potash, feldspar+sericite and epdote+chlorite can be typical altered mineral assemblages for exploration of the Pulang porphyry copper deposit. The Al—OH wavelength from 2210 nm to 2205 nm of sericite (long-wave sericite) is closely related to mineralization, which can be used as an indicator for prospecting in the Pulang deposit. [ABSTRACT FROM AUTHOR]

Understanding the magmatic-hydrothermal cooling and exhumation history is fundamental for investigating porphyry deposit formation and preservation. In the Zhunuo porphyry copper deposit of southern Tibet, hydrothermal biotite related to early potassic alteration likely formed from 14.7 ± 0.3 Ma (zircon U-Pb age) to 14.23 ± 0.13 Ma (molybdenite Re-Os age) and cooled below the closure temperature for 40Ar/39Ar system at 13.91 ± 0.05 Ma (hydrothermal biotite 40Ar/39Ar plateau age). The 40Ar/39Ar spectra of another hydrothermal biotite sample that was selectively replaced by chlorite record the timing of late phyllic alteration at 13.53 ± 0.08 Ma. Zhunuo hydrothermal alteration and mineralization likely ceased at 13.09 ± 0.07 Ma based on the 40Ar/39Ar plateau age of the fresh magmatic biotite crystals. The biotite 40Ar/39Ar systematics have not been reset by ~ 12.0 Ma post-mineralization granite porphyry within ore district, which is likely due to rapid cooling and/or absence of fluid exsolution for the granite porphyry. In combination with previous zircon U-Pb and molybdenite Re-Os data, two-pulses of magmatic-hydrothermal activity from 14.78 ± 0.11 to 14.44 ± 0.05 Ma and from 14.23 ± 0.13 to 13.53 ± 0.08 Ma can be recognized at Zhunuo. (U-Th)/He thermochronological data on zircon and apatite from the inter-mineralization monzogranite porphyry suggest three cooling events characterized by first-stage magmatic cooling at a rate of ~ 1850 °C/m.y., and two later phases of uplift and exhumation at ~ 70 °C/m.y. and ~ 10 °C/m.y. Approximately 1.4-km thickness of materials have been removed from the Zhunuo Miocene monzogranite porphyry during uplift and erosion, including a large volume of ore. [ABSTRACT FROM AUTHOR]

Pulang copper deposit is of a super-large porphyry type in the eastern Yidun island arc polymetallic ore belt with frequent tectonic magmatic activities and significant superposition of fissure structure and ore forming-ore controlling conditions. However, the research degree is weak. Based on the comprehensive study of tectonic petrography of tunnels in Pulang copper orefield, combined with the regional metallogenic tectonic setting, the paper determines the macroscopic characteristics of folds and faults, and analyzes the joints/fissures in the typical levels. The results show that the mineralization of porphyry copper deposit during the closure of Paleo-Tethys Ocean is closely related to the Late Triassic tectonic evolution and magmatic activity, with Pulang copper deposit formed in subduction orogeny stage. The regional deep faults control the sedimentary formation and magmatite distribution in the orefield. The deposit is generally occurred in the core of Pulang antiform. The secondary NEE- and NE-trending faults control the development of ore-bearing porphyry and joints/fissures, while the ore/mineralized bodies occur at the junction of two groups of faults. The tension joint-dominated compound joint system provides passage and storage space for ore-bearing hydrothermal fluid migration, diffusion and enrichment. The development degree of fissures is positively correlated with copper mineralization. By studying the characteristics of magmatic intrusion-tectonic fissure system and ore-controlling rule in the orefield, it is considered that the hydrothermal vein ore/mineralized bodies are strictly controlled by the reformation and enrichment of tectonic and fissure system, and the site where fissure structure is well-developed is favorable target for vein ore prospecting. [ABSTRACT FROM AUTHOR]

Porphyry Cu ore deposits are a rare product of arc magmatism that often form spatiotemporal clusters in magmatic arcs. The petrogenetic evolution of igneous rocks that cover the temporal window prior to and during porphyry Cu deposit formation may provide critical insights into magmatic processes that are key in generating these systems. This study documents the magmatic evolution of the Palaeocene–Eocene Yarabamba Batholith, Southern Peru, that was incrementally assembled between ~ 67 and ~ 59 Ma and hosts three, nearly contemporaneous, giant porphyry Cu–Mo deposits that formed at 57–54 Ma (Quellaveco, Toquepala and Cuajone). Whole-rock geochemistry, U–Pb geochronology and zircon trace element chemistry are reported from Yarabamba rocks that span the duration of plutonic activity, and from six porphyry intrusions at Quellaveco that bracket mineralisation. A change in whole-rock chemistry in Yarabamba intrusive rocks to high Sr/Y, high La/Yb and high Eu/Eu* is observed at ~ 60 Ma which is broadly coincident with a change in vector of the converging Nazca plate and the onset of regional compression and crustal thickening during the first stage of the Incaic orogeny. The geochemical changes are interpreted to reflect a deepening of the locus of lower crustal magma evolution in which amphibole ± garnet are stabilised as early and abundant fractionating phases and plagioclase is suppressed. Zircons in these rocks show a marked change towards higher Eu/Eu* (> 0.3) and lower Ti (< 9 ppm) compositions after ~ 60 Ma. Numerical modelling of melt Eu systematics and zircon-melt partitioning indicates that the time series of zircon Eu/Eu* in these rocks can be explained by a transition from shallower, plagioclase-dominated fractionation to high-pressure amphibole-dominated fractionation at deep crustal levels from ~ 60 Ma. Our modelling suggests that any redox effects on zircon Eu/Eu* are subordinate compared to changes in melt composition controlled by the fractionating mineral assemblage. We suggest that growth and intermittent recharge of the lower crustal magma reservoir from ~ 60 Ma produced a significant volume of hydrous and metallogenically fertile residual melt which ascended to the upper crust and eventually generated the three giant porphyry Cu–Mo deposits at Quellaveco, Toquepala and Cuajone from ~ 57 Ma. Our study highlights the importance of high-pressure magma differentiation fostered by strongly compressive tectonic regimes in generating world-class porphyry Cu deposits. [ABSTRACT FROM AUTHOR]

The Southwest prospect is located at the southwestern periphery of the Sto. Tomas II porphyry copper–gold deposit in the Baguio District, northwestern Luzon, Philippines. The Southwest prospect hosts a copper‐gold mineralization related to a complex of porphyry intrusions, breccia facies, and overlapping porphyry‐type veinlets emplaced within the basement Pugo metavolcanics rocks and conglomerates of the Zigzag Formation. The occurrences of porphyry‐type veinlets and potassic alteration hosted in the complex are thought to be indications of the presence of blind porphyry deposits within the Sto. Tomas II vicinity. The complex is composed of at least four broadly mineralogically similar dioritic intrusive rocks that vary in texture and alteration type and intensity. These intrusions were accompanied with at least five breccia facies that were formed by the explosive brecciation, induced by the magmatic–hydrothermal processes and phreatomagmatic activities during the emplacement of the various intrusions. Hydrothermal alteration assemblages consisting of potassic, chlorite–magnetite, propylitic and sericite–chlorite alteration, and contemporaneous veinlet types were developed on the host rocks. Elevated copper and gold grades correspond to (a) chalcopyrite–bornite assemblage in the potassic alteration in the syn‐mineralization early‐mineralization diorite (EMD) and contemporaneous veinlets and (b) chalcopyrite‐rich mineralization associated with the chalcopyrite–magnetite–chlorite–actinolite±sericite veinlets contemporaneous with the chlorite–magnetite alteration. Erratic remarkable concentrations of gold were also present in the late‐mineralization Late Diorite (LD). High XMg of calcic amphiboles (>0.60) in the intrusive rocks indicate that the magmas have been oxidizing since the early stages of crystallization, while a gap in the composition of Al between the rim and the cores of the calcic amphiboles in the EMD and LD indicate decompression at some point during the crystallization of these intrusive rocks. Fluid inclusion microthermometry suggests the trapping of immiscible fluids that formed the potassic alteration, associated ore mineralization, and sheeted quartz veinlets. The corresponding formation conditions of the shallower and deeper quartz veinlets were estimated at pressures of 50 and 30 MPa and temperatures of 554 and 436°C at depths of 1.9 and 1.1 km. Temperature data from the chlorite indicate that the chalcopyrite‐rich mineralization associated with the chlorite–magnetite alteration was formed at a much lower temperature (ca. 290°C) than the potassic alteration. Evidence from the vein offsetting matrix suggests multiple intrusions within the EMD, despite the K‐Ar ages of the potassic alteration in EMD and hornblende in the LD of about the same age at 3.5 ± 0.3 Ma. The K‐Ar age of the potassic alteration was likely to be thermally reset as a result of the overprinting hydrothermal alteration. The constrained K‐Ar ages also indicate earlier formed intrusive rocks in the Southwest prospect, possibly coeval to the earliest "dark diorite" intrusion in the Sto. Tomas II deposit. In addition, the range of δ34S of sulfide minerals from +1.8‰ to +5.1‰ in the Southwest prospect closely overlaps with the rest of the porphyry copper and epithermal deposits in the Sto. Tomas II deposit and its vicinity. This indicates that the sulfides may have formed from a homogeneous source of the porphyry copper deposits and epithermal deposits in the Sto. Tomas II orebody and its vicinity. The evidence presented in this work proves that the porphyry copper‐type veinlets and the adjacent potassic alteration in the Southwest prospect are formed earlier and at a shallower level in contrast with the other porphyry deposits in the Baguio District. [ABSTRACT FROM AUTHOR]

This research evaluated the capability of WorldView-3 (WV-3) data in discriminating targets related to porphyry copper mineralization at the Tameh district in the Saveh–Yazd belt, northeastern Isfahan, Iran. The few known porphyry copper deposits in this district were formed in association with Oligo-Miocene intrusive bodies. Hydrothermal alteration zones are characterized by iron oxide/hydroxide, sericite, illite, kaolinite, montmorillonite, chlorite, and epidote minerals. The band rationing method and the mixture-tuned matched filtering (MTMF) algorithm were utilized to map and identify targets. The results of band rationing showed that WV-3 VNIR–SWIR data can map and differentiate corchlorite and epidote as well as kaolinite and montmorillonite because of its superior spatial and spectral resolutions in SWIR region, as compared to ASTER data. Considering the similarity of five SWIR bands of WV-3 to the ASTER bands, both datasets help to enhance sericite–illite in similar patterns; however, areas mapped using WV-3 matched well with field evidence. Implementing the MTMF algorithm on the WV-3 VNIR and SWIR data successfully mapped areas with the highest abundances of desired minerals. Microscopic studies of thin sections, spectral investigations, and X-ray diffraction analysis confirmed the occurrence of alteration minerals, which also corresponded well to surface exposures of alterations in the field. Results showed that WV-3 data, with higher spectral and spatial resolutions, provide capability to map and identify hydrothermal alteration minerals and to produce more detailed mineralogical maps, which are valuable in semi-detailed district-scale exploration stages; in contrast, ASTER data yielded information on hydrothermally alteration zones mainly in regional scale. [ABSTRACT FROM AUTHOR]

BACKGROUND: The main types of copper deposits are porphyry and skam types. Dacite porphyry is a rock type commonly developed in the porphyry Cu - Mo - Au system. The rock can be used for prospecting sign and ore - forming rock when there is well - developed hydrothermal alteration. The Dabaoshan deposit is currently the largest copper polymetallic deposit in South China Block. Previous studies have shown that the dacite porphyry of the mining area is not only the ore - forming parent rock, but also a favorable ore - bearing wall rock. However, there are some debates about the relationship between dacite porphyry and mineralization in this mining area. With the breakthrough of prospecting for medium and large dacite porphyry ore bodies in recent years, the relationship between dacite porphyry and mineralization has once again become a concern. OBJECTIVES : In order to understand the relationship between dacite porphyry alteration and mineralization of the Dabaoshan deposit. METHODS: Based on field work and indoor analysis, this paper uses X - ray fluorescence spectrometry ( XRF) and inductively coupled plasma - mass spectrometry ( ICP - MS) to determine copper, tungsten, silicon, aluminum and calcium in Dabaoshan dacite porphyry samples. The isotope composition, metal element contents and alteration characteristics of the dacite porphyry in the mining area were used to discuss the relationship between alteration and prospecting direction. RESULTS: The copper content changes from 107 to 6909 µg/ g, which is consistent with the copper ore grade of 0. 3% - 0. 5% in the mining area. The LOI and other geochemical indicators that can represent the degree of alteration are positively correlated with copper. Hydrothermal alteration is widely developed in dacite porphyry, including potassium, prophyliticition and quartz - sericitization from early to late stage. Among different stages of alterations, the copper content of quartz - sericitization is 2 to 5 times higher than other alteration types, indicating that quartz - sericitization is closely related to copper mineralization and is an important prospecting sign. CONCLUSIONS: The deep alteration intensity of the dacite porphyry ( below the 270m elevation) has not been weakened, suggesting a great prospecting potential. In addition, the contact zone between dacite porphyry and the Jurassic strata, and the xenoliths in the dacite porphyry are also important prospecting directions, which may host skarn - type copper - rich deposits. [ABSTRACT FROM AUTHOR]

The Bondar Hanza porphyry Cu deposit, hosted by a granitoid stock, is located 120 km south of Kerman city in the elongated NW–SE trending Urumieh‐Dokhtar magmatic arc (UDMA), Iran. The granitoid stock is a multiphase intrusive body, 2 km2 in surface area, which comprises microdiorite–microquartz diorite and granite–granodiorite. Petrological and geochemical analyses show that granitoids are peraluminous, magnesian, calcic to alkali‐calcic, and non‐adakitic intrusions characterized by negative Eu* anomalies. Thermobarometric and oxygen fugacity calculations indicate that magma emplacement occurred at 719–784°C, <100 MPa, and at a log fO2 of NNO +1.6 to +3.2. Sulphur isotopic composition of sulphide minerals (δ34S = 5.0–6.8 ‰) are similar to other porphyry Cu deposits worldwide. Molybdenite separates yield Re–Os ages of 28.22–28.03 Ma, indicating that the Cu mineralization and associated magmatism occurred during the Oligocene. The Bondar Hanza is one of the several granitoids from small porphyry Cu deposits in the UDMA that is related to island arc sub‐productive granitoids. It seems that the largest ore‐hosting porphyry systems within the UDMA are generally restricted to Miocene intrusions with adakitic affinity (e.g., Sarcheshmeh granitoids) and that the temporally discrete non‐adakitic magmatic systems are sub‐productive to barren. These data are interpreted to show that magmatism in the Bondar Hanza region was likely associated with partial melting of juvenile lower crust induced by north‐eastward subduction of the Neo‐Tethys oceanic lithosphere. [ABSTRACT FROM AUTHOR]

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Geometallurgical modeling involves a comprehensive approach to ore characterization in terms of critical processing attributes, particularly in complex deposits. In this study, an algorithm based on localized uniform conditioning (LUC) method is implemented for creation of spatial geometallurgical domains at Sungun porphyry copper deposit. Localized uniform conditioning (LUC) as a nonlinear method is appropriate for optimal grade estimation of small blocks when the input data spacing is too coarse. In some deposits with complicated geometry, the accuracy of the local estimation through this method depends on the block ranking techniques. The proposed idea is the application of direct block simulation (DBSIM) method realizations for the ranking purpose. The total and oxide copper grades were estimated using the main localized uniform conditioning and proposed algorithm at 30 × 30 × 15 m3 blocks. The outcomes show a satisfactory conformity with the geological facts of the Sungun deposit. Also, the comparison between the results of both methods and the real data confirms the superiority of the proposed method. Finally, the precise destination of each block in the mineral processing circuit has been predicted based on the estimated total and oxide copper grade. The results illustrate that the applied method is able to preserve the spatial variation of attributes and provides an accurate ranking and robust recoverable resource estimation. [ABSTRACT FROM AUTHOR]

Copyright of Nonferrous Metals (Mineral Processing Section) is the property of Beijing Research Institute of Mining & Metallurgy Technology Group and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Advanced space-borne thermal emission and reflection radiometer (ASTER) data were evaluated for the hydrothermal alteration mapping of the Nimu porphyry copper deposit, southern Tibet. According to the metallogenic model for porphyry copper, we chose hydrothermal alteration mineral association and then established a remote sensing model. Relative absorption-band depth (RBD) and simple band combination methods in visible near infrared (VNIR) and shortwave infrared (SWIR) bands were used to retrieve information about lithological distributions. Principal component analyses (PCA) were applied to extract the prospecting information based on the spectral information of argillization mineral association, propylitization mineral association, and iron stained (limonite) effects. Results of the study match up well with known copper occurrences and a circular structure in study area, while circular structures usually have close relationship with mineralization. Combined with field validation, ASTER data are proved able to characterise the alteration zone of these porphyry deposits. With VNIR and SWIR bands, argillic, propylitic and ferritization alterations in a single deposit can be effectively discriminated. [ABSTRACT FROM AUTHOR]

Empirical geothermometer dealing with Ti solubility in the Fe‐Mg biotites was originally proposed for biotites in graphitic, peraluminous metapelites containing ilmenite or rutile that equilibrated roughly at 4–6 kbar. Given that biotites are abundant in the porphyry copper systems, this geothermometer has frequently been used for the determination of magmatic–hydrothermal temperatures in the porphyry copper systems. Common associations of porphyry copper deposits (PCDs), that is, low Al content of biotite, biotite chloritization (causes the biotite to become more magnesian and to lose Ti), and biotite formation by amphibole replacement, as well as disequilibrium, local equilibrium, or re‐equilibration of biotites, especially through potassic alteration, may provide significant uncertainty in the temperatures estimated a by Ti‐in‐biotite geothermometer. In addition, besides the calibration range of thermometer for pressure (400–600 MPa), the temperatures of major sulfide precipitation in PCDs (>~400°C) does not fit with the temperature range of thermometer calibration (480–800°C). Worth noting, as confirmed by fluid inclusion data in the Sarkuh PCD, regardless of presence of mineralogical requirements, obtained temperatures of sulfide mineralization using Ti in biotite thermometer could be overestimated. This may be due to the difference between general conditions of sulfide mineralization and calibration range of Ti in the biotite thermometer for pressure and temperature, as well as the metaluminous nature of biotites in PCDs. [ABSTRACT FROM AUTHOR]

Remote sensing (RS) of alteration zones and anomalies can provide information that is useful for geological prospecting and exploration. RS is an effective method for porphyry copper mineral exploration and prospecting prediction. More specifically, the Advanced Spaceborne Thermal Emission and Reflection radiometer (ASTER) data, which include 14 spectral channels from visible light to thermal infrared, are useful in such cases. This study uses visible-shortwave infrared and thermal infrared ASTER data together with surface material spectra from the Duolong porphyry copper ore district to construct an RS-based alteration zonation model of the deposit. In this study, an RS alteration zoning model is established based on ground-spectral alteration zoning results. The methods include PCA (Principal Component Analysis), Ratio, and Slope methods. The information obtained by each method is different. RS-based alteration zonation is developed based on the intersection of maps, resultant from the different methods for extracting information related to different minerals. The alteration zonation information extracted from ASTER RS data is consistent with geological observations. Using information from the RS-based model, we mapped the alteration minerals and zones of the Duolong ore district, thereby identifying prospecting target areas of the deposit.