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Most European hardwoods are nowadays under-utilized due to drawbacks such as low dimensional stability, durability and surface hardness. Seven hardwood species were thermally and/or chemically modified in order to improve these disadvantages. Heat treatment was carried out in air at atmospheric pressure at three temperatures, while two types of chemical modifications were tested, the first being based on furfuryl alcohol with tartaric acid, the second being based on succinic anhydride and glycerol. Then, modified woods were studied to determine weight loss due to thermal treatment, solution uptake, weight percent gain and swelling due to chemical modification processes. After that, main properties of chemically modified woods were characterized including density, equilibrium moisture content, dimensional stability and surface hardness. Effect of thermal pretreatment on subsequent chemical modification and on properties of modified woods obtained have also been evaluated. Combination of thermal modification with chemical modification had led to better improvements than each separately. Furfurylation treatment appeared to be more efficient than polyester modification. Most of the modified samples were denser, more stable and harder than native wood. These modified woods might compete with imported tropical wood for applications requiring high stability and hardness, such as joinery, decking or flooring, music instruments, handles for tools or kitchen utensils. [ABSTRACT FROM AUTHOR]

An X-ray density analyzer was used to determine the evolution of the moisture content (MC) profiles of a wood board during drying. Tests were performed on quartersawn boards of five wood species (oak, beech, Scotch pine, birch, alder) of two thicknesses (20 and 40 mm) dried at low temperature. The water vapor diffusion coefficient and liquid permeability of each wood species were determined by inverse analysis of the profiles using a computational model of coupled heat and mass transfer. These parameters were also measured by classical methods for validation purposes. The inverse method gives values close to the measured ones when using the evolution of the moisture profile, but also quite remarkably when using only the evolution of moisture at the core of the board. On the contrary, the method is less accurate when using only the average kinetics as experimental information. [ABSTRACT FROM AUTHOR]

In the wooden construction, structural elements are particularly exposed to external climatic conditions during the construction phase. To ensure their durability over their expected lifespan, the required drying time have to be known after a rain shower and before closing the timber structures. This question, involving coupled heat and mass transfer, can be investigated through numerical tools. The aim of this work is to provide experimental data through X-ray imaging to validate the prediction potential of computational models simulating transfer in porous media. Two complementary methods were developed to access the water migration in Norway spruce. The first one allowed to quantitatively measure spatial distribution of moisture content over time. It is based on a rigorous treatment of the X-ray beam attenuation. The second method, using a high-resolution 3D reconstruction, highlighted the role of wood rays on liquid migration within the porous network.

The aim of this article is to characterize the wood-water relationship and certain moisture transfer properties of Central African species for which very little data exists in the literature, i.e. Iroko, Padouk, Bibolo (Dibetou), Moabi, Doussié, Bilinga and Grenadilla. Moisture sorption isotherms were measured using the Dynamic Vapor Sorption method at 35°C. The Hailwood-Horrobin model was used to describe the sorption isotherm and the model parameters are given for each species. A rough estimation of the fiber saturation point could be made and is between 18.5% for Doussié and 26.5% for Bibolo. The water vapour diffusion coefficient in the radial direction of the wood was determined by the cup method at 35°C. Its value ranges from 1.72E-11 for Grenadilla to 1.71E-10 m2/s for Bibolo. It has been shown that the model proposed by Siau (1984) allows a relatively reliable estimation of the value of this parameter from wood density. The gas permeability was also measured on the same samples and ranged from 3.3E-19 m2 for Moabi to 3.78E-16 m2 for Bibolo. From these parameters, the apparent tortuosity and equivalent pore diameter for the mass flow were estimated for each species. [ABSTRACT FROM AUTHOR]

The improvement of durability and dimensional stability of wood properties via modification of the microstructure and wood–water interaction has been widely utilised. This study investigated polyester treatments, a possible alternative, using environmentally friendly chemicals such as malic acid to improve the beech wood (Fagus sylvatica) properties. The modified properties have been studied with four treatments using malic acid, glycerol, butanediol and succinic anhydride, mixing polycarboxylic acids and polyols. Results showed that the anti-swelling-efficiency (ASE) improved up to 70%, and the bulking coefficient improved around 23%, exhibiting an efficient penetration within the cell walls. The leaching rates (LR) of treatments and the extractables remained low, between 0.05 and 2.4%. The equilibrium moisture content (EMC) decreased by 50% for the four treatments, compared to untreated beech wood. [ABSTRACT FROM AUTHOR]

The bark-water relation and the moisture transport in bark are essential for the living tree but also for the industrial utilization of bark. Thus the bark-water relation of beech (Fagus sylvatica ) and spruce (Picea abies ) have been studied in the present work. The sorption isotherms were determined at 35°C for both wood and bark and the water diffusivity was measured under steady state conditions (cup method) and under unsteady state conditions, i.e. via sorption test. The sorption isotherms were calculated based on the Hailwood-Horrobin (HH) model. It was observed that beech wood and bark have a similar hygroscopic behavior, whereas spruce bark is more hygroscopic than spruce wood in all the relative humidity (RH) ranges. The radial diffusivity was in the range 1.2 ⋅ 10-11-2.2 ⋅ 10-11 m² s-1 for spruce and beech bark, respectively, when the driving force of the diffusion is the gradient of bound water. [ABSTRACT FROM AUTHOR]

Intermittent drying may be of interest in the future to address energy issues. Such drying conditions are also likely to help stress relaxation through mechanosorptive creep. The influence of applying oscillations of temperature and relative humidity during the drying of beech timber on time and drying stresses is discussed in the paper by means of nonsymmetrical and loaded drying. Experimental data were used to validate a numerical model in the case of intermittent drying. The model was then used to perform a numerical investigation of the possibility of using an intermittent energy source to dry wood. [ABSTRACT FROM PUBLISHER]

In this study, the drying of thin layers of the “Violet de Galmi” onion (a variety mainly grown in West Africa) is presented in this article, along with the reaction engineering approach (REA) modeling for a comprehensive understanding of the drying kinetics. The experiments were conducted on a lab-scale dryer to form thin layer of cylindrical onion slice. By performing this experiment, the standard activation energy is evaluated and modeled. The model is validated by simulating the drying rates under various drying conditions. The comparison of simulation and experimental data is found to be satisfactory. This approach allows the determination of the internal characteristics of the onion for the further studies such as design of solar dryer for onion. [ABSTRACT FROM PUBLISHER]