107 results on '"Rajaković, Ljubinka V."'
Search Results
2. Modelling of cations retention in ion chromatography with methanesulfonic acid as eluent
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Todorović Žaklina N., Rajaković Ljubinka V., and Onjia Antonije E.
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Computer-assisted optimization ,ANN ,MSA ,IC ,Resolution ,Chemical technology ,TP1-1185 - Abstract
The two retention models, the linear solvent strength model (LSS) and the quadratic relationship, in addition to artificial neural network (ANN) approach, were compared in their ability to predict the retention behaviour of common cations (Li, Na, NH4, K, Mg, and Ca) in isocratic ion chromatography using the methanesulfonic acid (MSA) eluent. Over wide variations in the MSA concentration, the quadratic model shows a quite good prediction power. LSS can be used only for monovalent cations and in the proximity of the experimental design point. ANN fails to predict the retention for the data not included in the training set. To find the optimal conditions in the experimental design, the normalized resolution product as a chromatographic objective function was employed. The optimum MSA concentration in the eluent on a Dionex CS12 column was found to be 18 mM, with the total analysis time of less than 10 min. [Projekat Ministarstva nauke Republike Srbije, br. III43009]
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- 2017
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3. Interpretative optimization of the isocratic ion chromatographic separation of anions
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Todorović Žaklina N., Rajaković Ljubinka V., and Onjia Antonije E.
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anions ,ion chromatography ,isocratic ,multiple species analyte/eluent ,resolution product ,Chemistry ,QD1-999 - Abstract
Interpretive retention modeling was utilized to optimize the isocratic ion chromatographic (IC) separation of the nine anions (formate, fluoride, chloride, nitrite, bromide, nitrate, phosphate, sulfate, oxalate). The carbonate-bicarbonate eluent was used and separation was done on a Dionex AS14 ion-exchange column. The influence of combined effects of two mobile phase factors, the total eluent concentration (2 - 6 mM) and the carbonate/bicaronate ratio from 1:9 to 9:1 (which corespondent to pH range 9.35 - 11.27), on the IC separation was studied. The multiple species analyte/eluent model that takes into account ion-exchange equilibria of the eluent and sample anions was used. In order to estimate the parameters in the model, a non-linear fitting of the retention data, obtained at two-factor three-level experimental design, was applied. To find the optimal conditions in the experimental design, the normalized resolution product as a chromatographic objective function was employed. This criterion includes both the individual peak resolution and the total analysis time. A good agreement between experimental and simulated chromatograms was obtained. [Projekat Ministarstva nauke Republike Srbije, br. III43009]
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- 2016
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4. Investigation of different extraction procedures for the determination of major and trace elements in coal by ICP-AES and ion chromatography
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Tasić Aleksandra M., Sredović-Ignjatović Ivana D., Ignjatović Ljubiša M., Anđelković Ivan B., Antić Mališa P., and Rajaković Ljubinka V.
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coal ,extraction ,microwave ,ultrasonic ,ICP-AES ,ion chromatography ,Chemistry ,QD1-999 - Abstract
This paper presents the extraction of major and trace elements from a coal sample, in deionized water, by using three different extraction techniques. Rotary mixing and ultrasonic extraction were examined for different extraction times, while the microwave assisted extraction was performed at different temperatures. Metal concentrations (Na, K, Ca, Mg, Al, Fe, Mn, Be, Cd, Co, Cr, Hg, As, Ni, Se, Sb and Pb) in a solution were determined by employing the inductively coupled plasma atomic emission spectrometry; whereas the results obtained for Na, K, Ca and Mg were compared employing ion chromatography. Comparing the rotary and ultrasonic-assisted extraction it is shown that the former is more efficient for the determination of Fe, Na and Pb, whereas the latter one has proven more efficient for the determination of Co and Cr ions. Microwave-assisted extraction has proven the most efficient method for any elements tested in coal. In addition, sequential extraction of elements was done using microwave digestion. The results of sequential extraction experiments indicated associations of investigated elements with a mineral phase and organic matrix. Sequential extraction provided information on possible leaching of As, Cd, Co, Cr, Ni, Pb, Fe and Mn in environmental conditions. [Projekat Ministarstva nauke Republike Srbije, br. 172030]
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- 2016
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5. The effect of different extractants on lead desorption from a natural mineral
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Đolić, Maja B., Rajaković-Ognjanović, Vladana N., Marković, Jelena P., Janković-Mandić, Ljiljana J., Mitrić, Miodrag N., Onjia, Antonije E., and Rajaković, Ljubinka V.
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- 2015
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6. Analytical techniques for determination and control of silica content in the water in thermal power plants
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Ignjatović Nataša R., Ilić Maja D., and Rajaković Ljubinka V.
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silica ,thermal power plants ,ultapure water ,speciation analysis ,analytical techniques ,Chemical technology ,TP1-1185 - Abstract
Ultrapure water with minimum contents of impurities is used for the preparation of steam in thermal power plants. More recently it has been found that the corrosion process is also influenced by sodium ions, chloride ions, and all forms of silicon in water. At higher temperatures and under high pressure the less soluble compounds of silicon are extracted, which form deposits on the walls of the boiler, the piping system and the turbine blades. Silicon is found in water in the form of different types (species) which are characterized by specific physical and chemical properties. Distinctions can be made between highly reactive species of ionic (silicate anions) and molecular forms (silicic acid) and relatively inert types (suspended, colloidal, and polymerized silicon). The determination of various forms of silicon in water is a complex analytical task. This paper covers relevant research in the field of silicon specification analysis. Maintaining the unchanged, original composition of silicon species during various stages of analysis (sample collection, storage, and conservation) has been given special attention. A large number of methods and procedures have been developed for the analysis of species of silicon, including chromatographic, spectroscopic and electrochemical techniques and combinations thereof. The techniques used for determining both the total amount and individual forms of silicon have been singled out. There is also an overview of the coupled techniques used most frequently in practice by using the methodology which involves preliminary separation of species and then individual specification. The paper offers an overview of analytical properties, advantages and disadvantages of the most representative analytical methods developed specifically for the analysis of silicon species in ultrapure water. The most important studies focusing on the silicon species in water have been highlighted and presented in detail. The determination of silicon content in water is of great importance because of various effects of silicon species (corrodibility and toxicity) and the selection of methods for the efficient removal of silicon from water.
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- 2015
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7. Micro-electro-mechanical systems (MEMS): Technology for the 21st century
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Đakov Tatjana A., Popović Ivanka G., and Rajaković Ljubinka V.
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Micro-electro-mechanical systems (MEMS) ,sensors ,actuators ,chip ,Chemical technology ,TP1-1185 - Abstract
Micro-electro-mechanical systems (MEMS) are miniturized devices that can sense the environment, process and analyze information, and respond with a variety of mechanical and electrical actuators. MEMS consists of mechanical elements, sensors, actuators, electrical and electronics devices on a common silicon substrate. Micro-electro-mechanical systems are becoming a vital technology for modern society. Some of the advantages of MEMS devices are: very small size, very low power consumption, low cost, easy to integrate into systems or modify, small thermal constant, high resistance to vibration, shock and radiation, batch fabricated in large arrays, improved thermal expansion tolerance. MEMS technology is increasingly penetrating into our lives and improving quality of life, similar to what we experienced in the microelectronics revolution. Commercial opportunities for MEMS are rapidly growing in broad application areas, including biomedical, telecommunication, security, entertainment, aerospace, and more in both the consumer and industrial sectors on a global scale. As a breakthrough technology, MEMS is building synergy between previously unrelated fields such as biology and microelectronics. Many new MEMS and nanotechnology applications will emerge, expanding beyond that which is currently identified or known. MEMS are definitely technology for 21st century.
- Published
- 2014
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8. The sorption of inorganic arsenic on modified sepiolite: Effect of hydrated iron(III)-oxide
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Ilić Nikola I., Lazarević Slavica S., Rajaković-Ognjanović Vladana N., Rajaković Ljubinka V., Janaćković Đorđe T., and Petrović Rada D.
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arsenic(III) ,arsenic(V) ,Fe(III)-sepiolite ,sorption ,pH influence ,Chemistry ,QD1-999 - Abstract
The sorption of inorganic arsenic species, As(III) and As(V), from water by sepiolite modified with hydrated iron(III) oxide was investigated at 25 °C through batch studies. The influence of the initial pH value, the initial As concentrations, the contact time and types of water on the sorption capacity was investigated. Two types of water were used, deionized and groundwater. The maximal sorption capacity for As(III) from deionized water was observed at initial and final pH value 7.0, while the bonding of As(V) was observed to be almost pH independent for pH value in the range from 2.0 to 7.0, and the significant decrease in the sorption capacity was observed at pH values above 7.0. The sorption capacity at initial pH 7.0 was about 10 mg gˉ1 for As(III) and 4.2 mg gˉ1 for As(V) in deionized water. The capacity in groundwater was decreased by 40 % for As(III) and by 20 % for As(V). The Langmuir model and pseudo-second order kinetic model revealed good agreement with the experimental results. The results show that Fe(III)-modified sepiolite exhibits significant affinity for arsenic removal and it has a potential for the application in water purification processes. [Projekat Ministarstva nauke Republike Srbije, br. III 45019, III 43009 i TR 37010]
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- 2014
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9. Review: The approaches for estimation of limit of detection for ICP-MS trace analysis of arsenic
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Rajaković, Ljubinka V., Marković, Dana D., Rajaković-Ognjanović, Vladana N., and Antanasijević, Davor Z.
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- 2012
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10. Analytical methods for arsenic speciation analysis
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Rajaković Ljubinka V., Todorović Žaklina N., Rajaković-Ognjanović Vladana N., and Onjia Antonije E.
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arsenic speciation ,adsorption ,extractions ,water ,soil ,biological sample ,Chemistry ,QD1-999 - Abstract
Arsenic exists in the form of various chemical species differing by their physicochemical behavior, in toxicity, bioavailability and biotransformation. The determination of arsenic species is an important issue for environmental, clinical and food chemistry. However, differentiation of these species is a quite complex analytical task. Numerous speciation procedures have been studied that include electrochemical, chromatographic, spectrometric and hyphenated techniques. This review comprehends the relevant research in the field of arsenic speciation analysis with novel applications and significant advances. Stability of arsenic species and each of the analytical steps (sample collection, storage, preservation, extraction) of the arsenic speciation methods was particularly evaluated. Analytical validation and performance of these methods are also reviewed.
- Published
- 2013
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11. Sorption of lead, cadmium and zinc from air sediments applying natural wool fiber
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Babincev Ljiljana M., Budimir Milana V., and Rajaković Ljubinka V.
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Heavy metals ,natural wool fibers ,sorption ,air ,Chemical technology ,TP1-1185 - Abstract
The aim of this study is to investigate the possibilities of removing lead, cadmium, and zinc from air by sorption natural wool fibers (NWF), thus evaluating possible application of the wool materials in direct protection of air from the influence of heavy metals. Metal detection was done (before and after the sorption process) by potentiometric stripping analysis. Sorption experiments were done in two ways: by immersing NWF in model solutions (prepared by the working standard solutions and deionized water), and by immersing NWF in solutions of sediments from the air. The influence of mass sorbent, sorption time, pH, and temperature on the sorption of lead, cadmium, and zinc were experimentally examined. Effectiveness of lead, cadmium, and zinc sorption by applying natural wool fibers is shown as the sorption capacity (a ratio between metal concentration before and after sorption and sorbent mass). Sorbent of 0.1 g NWF mass in neutral environment collects: after 10 min 23,9% of lead, 19,0% of cadmium, and 21,3% of zinc; whereas after 30 min 71.5% of lead, 69.6% of cadmium, and 69.4% of zinc. NWF of the same mass in acidic environment shows lower sorption capabilities, for pH 4.5 the effective sorption is: 68.6% of lead, 66.8% of cadmium, and 66.6% of zinc; whereas for pH 2.1 NWF sorption is 54.6% of lead, 53.2% of cadmium, and 52.9% of zinc. Optimal pH range for application of this sorption during the experiment material is 4.5-7.0. The sorption was made in solutions with pH 2.1 due to potentiometric stripping analysis application conditions. Temperature significantly impacts the tested material sorption characteristics. When temperature slightly increases, regardless of the inflicted damage, NWF keeps its functionality. When temperature is higher than 60°C, the sorbent effectiveness is reduced. The NWF sorption capacity is lowest at 100°C: for lead 11.63 μg g−1, for cadmium 8.18 μg g−1, and for zinc 9.41 μg g−1. Results of the experimental research have shown that a high degree of removal (about 70%) can be achieved provided that the mass of the sorbent rages from 0,06−0,1 g, contact time is long enough (30 min), and that there are no significant effects of temperature and pH.
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- 2013
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12. Enhanced Arsenic Sorption by Hydrated Iron (III) Oxide-Coated Materials— Mechanism and Performances
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Jovanović, Branislava M., Vukašinović-Pešić, Vesna L., and Rajaković, Ljubinka V.
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- 2011
13. Separation and determination of dimethylarsenate in natural waters
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Ben Issa Nureddin, Marinković Aleksandar D., and Rajaković Ljubinka V.
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Arsenic species ,dimethylarsenate ,hybrid resin ,exchange ,adsorption ,ICP-MS ,Chemistry ,QD1-999 - Abstract
A simple and efficient method for separation and determination of dimethylarsenate DMAs(V) was developed in this work. Two resins, a strong base anion exchange (SBAE) resin and iron-oxide coated hybrid (HY) resin were tested. By simple adjusting pH value of water at 7.00, DMAs(V) passed through the HY column without any changes, while all other arsenic species [inorganic arsenic and monomethylarsonate, MMAs(V)] were quantitatively bonded on HY resin. The resin capacity was calculated according to the breakthrough points in a fixed bed flow system. At pH 7.00 the HY resins bonded more than 4150 μg g-1 of As(III), 3500 μg g-1 of As(V) and 1500 μg g1 of MMAs(V). Arsenic adsorption behavior in the presence of impurities showed tolerance with the respect to potential interference of anions commonly found in natural water. DMAs(V) was determined in the effluent by ICP-MS. The detection limit was 0.03 μg L?1 and relative standard deviation (RSD) was between 1.1?7.5 %. Proposed method was established performing standard procedures: with external standard, certified reference material and the standard addition method.
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- 2012
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14. Arsenic removal from water using low-cost adsorbents: A comparative study
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Rajaković Ljubinka V., Veljović Đorđe N., Vukašinović-Pešić Vesna L., and Jovanović Branislava M.
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adsorption ,arsenic removal ,arsenic remediation ,low cost sorbents ,Chemistry ,QD1-999 - Abstract
Inorganic arsenic removal from water using low-cost adsorbents is presented in this paper. Selective removal of As(III) and As(V) from water was performed with natural materials (zeolite, bentonite, sepiolite, pyrolusite and limonite) and industrial by-products (waste filter sand as a water treatment residual and blast furnace slag from steel production); all inexpensive and locally available. Kinetic and equilibrium studies were realized using batch system techniques under conditions that are likely to occur in real water treatment systems. The natural zeolite and the industrial by-products were found to be good and inexpensive sorbents for arsenic while bentonite and sepiolite clays showed little affinity towards arsenic. The highest maximum sorption capacities were obtained for natural zeolite, 4.07 mg As(V) g-1, and waste iron slag, 4.04 mg As(V) g-1.
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- 2011
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15. Woody plant willow in function of river water protection
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Babincev Ljiljana M., Rajaković Ljubinka V., Budimir Milana V., Perić-Grujić Aleksandra A., and Sejmanović Dragana
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Heavy metals ,Woody plant willow ,Bioaccumulation ,Stripping analysis ,Chemical technology ,TP1-1185 - Abstract
Coastal area surrounding the river Ibar, in the area between cities of Kosovska Mitrovica and Leposavić in the north of Kosovo and Metohija, is occupied with seven industrial waste dumps. These dumps were all part of the exploitation and flotation refinement of raw mineral materials, metallurgic refinement of concentrates, chemical industry, industrial refinement and energetic facilities of Trepča industrial complex. The existing waste dumps, both active and inactive, are of heterogenic chemical composition. Its impact on the river water is shown by the content of heavy metals found in it. Removal of lead, cadmium and zinc would be economically unrewarding, regardless of the technology used. Wooden plant that prevails in this area is white willow. This work is focused on the removal of heavy metals (Pb, Cd and Zn) from the water of the river Ibar using white willow. Roots of the willow are cultivated using the method of water cultures in an individual solution of heavy metals and river water sample. The preparation of the samples for analysis was performed by burning the herbal material and dissolving ashes in the appropriate acids. The concentrations of metals were determined by the stripping analysis. In the investigated heavy metal solutions the biomass increase is 25.6% in lead solution, 27.3% in cadmium and 30.7% in zinc solution. The increase of biomass in nutritional solution, without the heavy metals, is 32.4% and in river water sample 27.5%. The coefficient of bioaccumulation in solutions with heavy metals is 1.6% in lead solution, 1.9% in cadmium and 2.2% in zinc solution. Heavy metals accumulation is 18.74 μg of lead, 20.09 μg of cadmium and 22.89 μg of zinc. The coefficient of bioaccumulation of the water samples, that contained 44.83 μg/dm3 of lead, 29.21 μg/dm3 of cadmium and 434.00 μg/dm3 of zinc, during the period of 45 days, was 30.3% for lead, 53.4% for cadmium and 3.9% for zinc. The concentrations of accumulated metals from the river water are 19.01 μg of lead, 21.85 μg of cadmium and 23.96 μg of zinc in grams dry matter. The obtained results indicate that the willow can contribute to the decontamination of moderately contaminated river water from Pb, Cd and Zn.
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- 2011
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16. Improvement of chemical control in the water-steam cycle of thermal power plants
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Rajaković-Ognjanović, Vladana N., Živojinovic, Dragana Z., Grgur, Branimir N., and Rajaković, Ljubinka V.
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- 2011
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17. Simple and cost-effective measures for the improvement of paper mill effluent treatment – A case study
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Žarković, Darja B., Todorović, Žaklina N., and Rajaković, Ljubinka V.
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- 2011
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18. Conservation of resources in the pulp and paper industry derived from cleaner production approach
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Žarković, Darja B., Rajaković-Ognjanović, Vladana N., and Rajaković, Ljubinka V.
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- 2011
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19. Separation and determination of arsenic species in water by selective exchange and hybrid resins
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Issa, Nureddin Ben, Rajaković-Ognjanović, Vladana N., Marinković, Aleksandar D., and Rajaković, Ljubinka V.
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- 2011
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20. Spatial variations in the distribution of trace ionic impurities in the water-steam cycle in a thermal power plant based on a multivariate statistical approach
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Živojinović, Dragana Z., Rajaković-Ognjanović, Vladana N., Onjia, Antonije E., and Rajaković, Ljubinka V.
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- 2013
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21. Determination of inorganic arsenic species in natural waters—Benefits of separation and preconcentration on ion exchange and hybrid resins
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Issa, Nureddin Ben, Rajaković-Ognjanović, Vladana N., Jovanović, Branislava M., and Rajaković, Ljubinka V.
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- 2010
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22. Development of ion chromatography methods for the determination of trace anions in ultra pure water from power plants
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Čičkarić Dragana Z., Deršek-Timotić Ivana, Onjia Antonije E., and Rajaković Ljubinka V.
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trace analysis ,anions ,ultra pure water ,ic ,power plant ,Chemistry ,QD1-999 - Abstract
A suppressed ion chromatography (IC) technique, using a carbonate/hydrogen carbonate or a hydroxide eluent, has been evaluated as a monitoring tool for the detection of major anions (F-, Cl-, NO3-, PO43- and SO42-) in ultra pure water and condensed steam from thermal power plants. An electrical conductivity detector with an anion-exchange column (IonPac AS14), an auto self-regenerating suppressor (ASRS), and an isocratic high-pressure pump system were used for the detection of low concentrations of inorganic anions. It was shown that the suppressed IC technique provides a suitable means for preventing possible damage to generating equipment in power plants. The detection limits of the method for the anions of interest were < 0.3 μg/L.
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- 2005
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23. Analysis of trace anions in the water-steam cycle in power plants
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Čičkarić Dragana Z., Čučković Jagoda, and Rajaković Ljubinka V.
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anion traces ,control and monitoring ,water-steam cycle ,suppressed ion chromatography ,Chemical technology ,TP1-1185 - Abstract
This study offers some insight into the significance of water quality control in thermal power plants. In order to maintain high reliability indices in thermal plants and to realize the expected lifetime of these plants, high water quality should be accomplished. Also, the working tools of the analyst in thermal power plants and the types of problems, which help in solving daily tasks, are discussed. The difficulties the analyst might face are indicated. This review considers the implementation of standard control and diagnostic parameters crucial for water quality in all segments of a water-steam system. The subject of this paper was to analyze anion traces in the water-steam cycle, using a modern, highly sensitive instrumental method the method of ion chromatography (1S). Thus, the possibility of monitoring ionic species that can cause corrosion processes in the water-steam system is examined.
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- 2005
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24. Concept of contemporary methods for monitoring and determination of cyanide in water
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Čičkarić Dragana Z. and Rajaković Ljubinka V.
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cyanide ,control and monitoring ,wastewater ,modern methods and techniques ,Chemical technology ,TP1-1185 - Abstract
The quality of life depends on water quality. Good water quality and the rational use of water are an absolute need of the new millennium. Although it is an ecological and health priority to prohibit the contamination of water and water protection, it is a responsibility for environmental engineers and chemists to develop and apply effective methods for monitoring and controlling of water quality, and at that way prevent ecological and technological catastrophe on time. In this paper modern methods and process for monitoring, control and detection of cyanide in water and wastewater are presented. Recent developments in instrumental techniques and treatment for determination of this toxic substance in water are described, particularly the methods according to green analytical aspects.
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- 2004
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25. Rationalization of water consumption in paper industry
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Žarković Darja, Krgović Milorad V., and Rajaković Ljubinka V.
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water consumption ,rationalization ,economy ,water quality ,environment protection ,Chemical technology ,TP1-1185 - Abstract
The subject of this paper was to consider the possibilities of economical paper production with rationalization of water consumption. In accordance with the principles of viable development. The pulp & paper industry has had to face global market needs and strict regulation concerning the environment. The basic motive was to provide consistent and high product quality, which is competitive on the market. The pulp & paper industry is one of the largest consumers and pollutants of natural resources. In that light, the rationalization of raw material, water, energy and chemicals consumption with minimization of environmental impact is essential. The European directive on environmental protection obliges producers of pulp & paper to decrease the volume of wastewater and to increase the efficiency treatment. Pulp and paper industry in Serbia and Montenegro will also be faced with the demands for environmental protection. Numerous examples of water consumption rationalization and improvement of water quality in the pulp & paper industry could be found in different literature sources. It is necessary to increase water system closure and implement up-to-date treatment methods. The possibilities for water consumption rationalization, in a real system the paperboard mill UMKA, were examined.
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- 2004
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26. Sorption properties of wool
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Radetić Maja M., Jocić Dragan M., Jovančić Petar M., and Rajaković Ljubinka V.
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wool ,sorbent ,metal ion ,oil ,Chemical technology ,TP1-1185 - Abstract
Strict ecological legislation, especially in highly developed countries, imposed requirements for the purification of industrial effluents and the need for efficient oil clean up after sea and inland water spills. Although numerous processes have been developed, the application of sorbents is still one of the most efficient methods to remove heavy metal ions, dyes and crude oil from water. Recently, special attention was paid to sorbents based on natural fibres. A review of studies concerning the sorption properties of wool is presented in this paper. The presence of various functional groups on the wool fibre surface contributes to the efficient sorption of heavy metal ions and dyes. A hydrophobic, scaly surface and fibre crimp strongly influence the high sorption capacity of wool for oil. Wool has great sorption potential even as a recycled material. Accordingly, it can be used as a viable substitute to commercially available synthetic sorbents that show poor biodegradab ility.
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- 2004
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27. Development of analytical control in the water-steam cycle in thermal power plants
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Rajaković Ljubinka V. and Kerečki Jovan
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Analytical control ,water-steam cycle ,Thermal power plants ,Chemical technology ,TP1-1185 - Abstract
In order to maintain high reliability indices in thermal power plants and to realize the expected lifetime of these plants, high water quality should be accomplished. Also, an insight in the working tools of the analyst in thermal power plants and into the types of problems, which help in solving daily tasks, is given. This review considers the implementation of standard control parameters crucial for the indication of water quality in all segments of a water-steam system. A concept of modernization of the system for analytical control and monitoring in the water-steam cycle is suggested.
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- 2003
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28. Conventional and contemporary methods for water treatment: From wastewater to ultra pure water
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Rajaković Vladana N. and Rajaković Ljubinka V.
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Water treatment ,Water purification ,Wastewater ,Ultra pure water ,Modern methods ,Chemical technology ,TP1-1185 - Abstract
In this paper modern methods and techniques for water purification are described. Good water quality and the rational use of water are an absolute need of the new millennium. The quality of life depends on water quality. Although it is an ecological priority to prohibit the contamination of water, it is a responsibility for environmental engineers and chemists to develop and apply effective methods for water purification. Beside well-known methods and techniques, it is necessary to create new methods for water purification and treatment. Water recycling is especially important. Plants with membrane separation technologies enable savings in fresh water with high efficiency. Methods for monitoring and controlling processes and water protection should be developed simultaneously with the development of techniques for the methods for purification.
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- 2003
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29. Inverse gas chromatrography of chromia. Part II. Finite surface coverage
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Onjia Antonije E., Milonjić Slobodan K., and Rajaković Ljubinka V.
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inverse gas chromatography ,chromia ,adsorption ,organics ,isotherms ,isosteric heat. ,Chemistry ,QD1-999 - Abstract
The interactions of n-hexane, benzene, chloroform, and tetrahydrofuran with dried (amorphous) chromia (I) and chromia heated at 1073 K (crystalline) (II), both obtained from a colloidal dispersion, and a commercially available chromia (III) were studied by inverse gas chromatography (IGC) under finite surface coverage conditions. The isotherms, in the temperature range 383 – 423 K, were used to estimate the surface area, the adsorption energy distribution, the isosteric heat of adsorption, and the spreading pressure on the surfaces of the solids. The uniformly reduced adsorption ability of the heated chromia was attributed to the dehydroxylation of the surface at the higher temperatures. Both solids showed an increased affinity toward chloroform molecules, as a result of strong acid-base interaction.
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- 2002
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30. Mogućnosti primene sorbenata aktiviranih jonima metala za mikrobiološko precišćavanje vode
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Mirković, Maja, Lekić, Branislava, Rajaković-Ognjanović, Vladana, Jankovic-Mandić, Ljiljana J., Jović, Mihajlo, Onjia, Antonije, and Rajaković, Ljubinka V.
- Published
- 2014
31. The antimicrobial efficiency of silver activated sorbents
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Đolić, Maja B., primary, Rajaković-Ognjanović, Vladana N., additional, Štrbac, Svetlana B., additional, Rakočević, Zlatko Lj., additional, Veljović, Đorđe N., additional, Dimitrijević, Suzana I., additional, and Rajaković, Ljubinka V., additional
- Published
- 2015
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32. Analitičke metode za analizu arsenovih jedinjenja
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Rajaković, Ljubinka V., Todorović, Žaklina N., Rajaković-Ognjanović, Vladana, and Onjia, Antonije
- Subjects
arsenic speciation ,adsorption ,extractions ,water ,biological sample ,soil - Abstract
Arsenic exists in the form of various chemical species differing in their physicochemical behaviour, toxicity, bioavailability and biotransformation. The determination of arsenic species is an important issue for environmental, clinical and food chemistry. However, differentiation of these species is a quite complex analytical task. Numerous speciation procedures have been studied that include electrochemical, chromatographic, spectrometric and hyphenated techniques. This review presents the relevant research in the field of arsenic speciation analysis with novel applications and significant advances. Stability of arsenic species and each of the analytical steps (sample collection, storage, preservation, extraction) of the arsenic speciation methods is particularly evaluated. Analytical validation and performance of these methods are also reviewed. Arsen se nalazi u mnogobrojnim hemijskim vrstama koje se razlikuju po fizičko-hemijskom ponašanju, toksičnosti, biodostupnosti i biotransformaciji. Određivanje pojedinih arsenovih jedinjenja je neophodno u hemiji životne sredine, kliničkoj hemiji i hemiji hrane. Međutim, diferencijacija ovih vrsta je vrlo složen analitički zadatak. Za analizu arsenovih vrsta razvijen je veliki broj metoda i postupaka koje uključuju hromatografske, spektrometrijske i elektrohemijske tehnike i njihove kombinacije. U ovom preglednom radu obuhvaćena su relevantna istraživanja u oblasti specijacione analize arsena sa naglaskom na najznačajnija dostignuća i primenu. Održavanje nepromenljivog, originalnog sastava arsenovih specija u toku pojedinačnih analitičkih koraka (prikupljanje uzoraka, čuvanje, konzervisanje, ekstrakcija) posebno su razmatrani. Izdvojene su metode za direktno i indirektno određivanje arsenovih vrsta. Pobrojane su spregnute tehnike koje se najčešće primenjuju u praksi primenom metodologije koja podrazumeva preliminarnu separaciju jedinjenja, a zatim pojedinačno određivanje. Dat je pregled analitičkih svojstava, prednosti i nedostataka najprimerenijih analitičkih metoda, razvijenih upravo za analizu tragova arsenovih vrsta od neorganskih do organskih u različitim matricama. Izdvojene su i detaljnije prezentovane najznačajnije studije o arsenovim jedinjenjima u vodi.
- Published
- 2013
33. Analysis quality soil from the aspect of application simultaneous potentiometric stripping analysis
- Author
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Babincev, Ljiljana M., Gurešić, Dejan, Perić-Grujić, Aleksandra, and Rajaković, Ljubinka V.
- Subjects
kadmijum ,zemljište ,cink ,Potenciometrijska striping analiza ,olovo - Abstract
The research described in this paper is directed towards the development and application of simultaneous potentiometric stripping analysis for the determination of heavy metals (lead, cadmium and zinc) in the soil of the northern part of the territory of Kosovo and Metohija. The experiments were carried out: I) the module solution (prepared from standard solutions of metal working and deionized water), II) in the soil samples. The selected two types of land: agricultural (location next to the road in the vicinity of industrial areas) and non-agricultural (parks and playgrounds). To that end are analyzed, compared and separated optimum parameters: The working electrode is formed by depositing layer of mercury on glassy carbon with a constant stream of -49.90 µA, pH 1.6 and time deposit with a 240 s from a solution of mercury(II) nitrate. The extracting of metals from solution was performed at pH 2.1 and the potential of -1.400 V. Soil samples are after the drying, homogenisation and sifting translated in solution by dissolving with concentrated nitric and hydrochloric acid. The results of this study revealed are deviations for: lead -4.58%, cadmium -1.91% and zinc -1.89%. Was found that landfills mining Kombinat Trepca have a significant influence on the quality of the soil. Was found that mining landfills of Trepca have a significant influence on the quality of the soil. The highest content of investigated metals were found in soils in the immediate proximity passive and active mining landfills. Content of investigated elements, on almost all measuring places along the road, have had values above the maximum allowable.
- Published
- 2013
34. Assessment of surface water quality using multivariate statistical techniques: A case study of Sava river
- Author
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Živojinović, Dragana, Lukić, Nataša A., Onjia, Antonije, and Rajaković, Ljubinka V.
- Subjects
klaster analiza ,principal component analysis ,water ,factor analysis ,chemometry ,discriminant analysis ,analiza glavnih komponenti ,monitoring ,faktorska analiza ,multivariate analysis ,hemometrija ,voda ,diskriminaciona analiza ,cluster analysis - Abstract
The main goal of this work is focused on water quality classification of the Sava River (Serbia) and the evaluation of temporal/spatial variations of pollution data and the interpretation of a large complex water quality data set obtained by the monitoring of significant quality parameters measured during the several years of monitoring. Selected chemometrics techniques, such as principal component analysis (PCA), factor analysis (FA), cluster analysis (CA) and discriminant analysis (DA), were applied to the dataset obtained by monitoring more than twenty physico-chemical quality parameters for water samples. Multivariate analysis of very complex matrix demonstrated the power of chemometrics in identification of factors as groups of correlated variables with the highest percentage of explanatory variance. Natural clusters of analyzed variables with a similar pollution character were identified for the investigated period of time. Chemometrics tools appeared as very efficient for river water classification and rapid assessment of water quality necessary for management of water resources. U uzorcima vode iz životne sredine, kao što su površinske, podzemne i otpadne vode nalazi se veliki broj elemenata i jedinjenja, koji redovno moraju biti praćeni, kako bi blagovremeno bili uklonjeni u cilju prečišćavanja vode i održavanja kvaliteta vode u propisanim granicama. Zbog toga je veoma važno na vreme utvrditi pravilnost i zakonomernost u pogledu promene raspodele sadržaja zagađujućih materija i predvideti pravac njihovog daljeg kretanja. U ovom radu pažnja je posvećena analizi sadržaja najvažnijih elemenata koji su bitni za kvalitet vode (teški metali, pojedini katjoni i anjoni, organska jedinjenja), a takođe su mereni i praćeni neki fizičko-hemijski parametri (temperatura, pH, boja, mutnoća, provodljivost). U ispitivanjima je analizirana površinska voda reke Save. Analiza i statistička obrada svih rezultata merenja urađena je primenom multivarijantnih statističkih metoda. Izabrane hemometrijske tehnike, kao što su analiza glavnih komponenata (PCA), faktorska analiza (FA), klasterska analiza (CA) i diskriminaciona analiza (DA) primenjene su na primeru sveobuhvatne analize i procene kvaliteta rečne vode, praćenjem preko 15 fizičko-hemijskih parametara bitnih za kvalitet vode, uzorkovanih u višegodišnjem periodu i u različitim sezonama. Na ovaj način izvršena je karakterizacija i klasifikacija kvaliteta savske vode i evaluacija podataka o zagađujućim materijama.
- Published
- 2013
35. Analytical methods for arsenic speciation analysis
- Author
-
Rajaković, Ljubinka V., Todorović, Žaklina, Rajaković-Ognjanović, Vladana N., and Onjia, Antonije E.
- Subjects
arsenic speciation ,adsorption ,extractions ,water ,water, soil ,biological sample ,soil - Abstract
Arsenic exists in the form of various chemical species differing in their physicochemical behaviour, toxicity, bioavailability and biotransformation. The determination of arsenic species is an important issue for environmental, clinical and food chemistry. However, differentiation of these species is a quite complex analytical task. Numerous speciation procedures have been studied that include electrochemical, chromatographic, spectrometric and hyphenated techniques. This review presents the relevant research in the field of arsenic speciation analysis with novel applications and significant advances. Stability of arsenic species and each of the analytical steps (sample collection, storage, preservation, extraction) of the arsenic speciation methods is particularly evaluated. Analytical validation and performance of these methods are also reviewed. Arsen se nalazi u mnogobrojnim hemijskim vrstama koje se razlikuju po fizičko-hemijskom ponašanju, toksičnosti, biodostupnosti i biotransformaciji. Određivanje pojedinih arsenovih jedinjenja je neophodno u hemiji životne sredine, kliničkoj hemiji i hemiji hrane. Međutim, diferencijacija ovih vrsta je vrlo složen analitički zadatak. Za analizu arsenovih vrsta razvijen je veliki broj metoda i postupaka koje uključuju hromatografske, spektrometrijske i elektrohemijske tehnike i njihove kombinacije. U ovom preglednom radu obuhvaćena su relevantna istraživanja u oblasti specijacione analize arsena sa naglaskom na najznačajnija dostignuća i primenu. Održavanje nepromenljivog, originalnog sastava arsenovih specija u toku pojedinačnih analitičkih koraka (prikupljanje uzoraka, čuvanje, konzervisanje, ekstrakcija) posebno su razmatrani. Izdvojene su metode za direktno i indirektno određivanje arsenovih vrsta. Pobrojane su spregnute tehnike koje se najčešće primenjuju u praksi primenom metodologije koja podrazumeva preliminarnu separaciju jedinjenja, a zatim pojedinačno određivanje. Dat je pregled analitičkih svojstava, prednosti i nedostataka najprimerenijih analitičkih metoda, razvijenih upravo za analizu tragova arsenovih vrsta od neorganskih do organskih u različitim matricama. Izdvojene su i detaljnije prezentovane najznačajnije studije o arsenovim jedinjenjima u vodi.
- Published
- 2013
36. Uklanjanje arsena iz vode adsorpcijom na nekonvencionalnim materijalima
- Author
-
Lekić, Branislava, Ljubisavljević, Dejan, and Rajaković, Ljubinka V.
- Subjects
adsorption ,uklanjanje arsena ,adsorpcija ,arsenic removal ,arsenic ,arsen - Abstract
This paper deals with arsenic removal from water by adsorption with unconventional materials: natural materials (zeolite, bentonite, sepiolite, limonite, pyrolusite), waste materials (waste iron slag, waste sand filter) and modified materials (neutralized waste iron slag, iron(III)-hydroxide coated sand and activated carbon). Under the same conditions are investigated commercial sorbents to compare results. Arsenic removal by adsorption with unconventional materials is investigated in the batch reactor. The best results in batch reactor are obtained with waste materials. Waste iron slag and waste filter sand exhibited equilibrium sorption capacities of 50 μg/g and 30 μg/g, respectively, which is nearly equal to values obtained for the commercial sorbents. Due to the high content of CaO waste iron slag increases significantly water pH (pH=11). In order to minimize its deteriorating impact on the initial water quality, the waste iron slag was neutralized. The new, modified waste iron slag exhibited the highest sorption capacity, 55. U ovom radu su prikazani rezultati istraživanja efikasnosti uklanjanja arsena iz vode sorpcijom na nekonvencionalnim materijalima: prirodnim (zeolit, bentonit, sepiolit, limonit, piroluzit), otpadnim (otpadna šljaka, otpadni filtarski pesak) i modifikovanim (modifikovana otpadna šljaka, kvarcni pesak i aktivni ugalj impregnisani gvožđe(III)-hidroksidom). Pod istim uslovima paralelno su ispitivani komercijalni sorbenti radi poređenja rezultata. Uklanjanje arsena iz vode sorpcijom je ispitivana u šaržnom sistemu Najbolji rezultati u šaržnom sistemu dobijeni su sa otpadnim materijalima: za otpadnu šljaku i 30 μg/g za otpadni filtarski pesak (za Co=0,5 mg/L), što je u nivou vrednosti koje su dobijene za komercijalne sorbente za uklanjanje arsena. Zbog visokog sadržaja CaO, otpadna šljaka značajno povećava pH vrednost vode (pH= 11). Neutralizacijom otpadne šljake dobijen je nov materijal, modifikovana otpadna šljaka, većeg sorpcionog kapaciteta: 55.
- Published
- 2011
37. Experimental Design Optimization of the Determination of Total Halogens in Coal by Combustion–Ion Chromatography
- Author
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Sredović Ignjatović, Ivana D., primary, Onjia, Antonije E., additional, Ignjatović, Ljubiša M., additional, Todorović, Žaklina N., additional, and Rajaković, Ljubinka V., additional
- Published
- 2015
- Full Text
- View/download PDF
38. Sorpciona svojstva vune
- Author
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Radetić, Maja, Jocić, Dragan, Jovančić, Petar, and Rajaković, Ljubinka V.
- Subjects
joni metala ,vuna ,ulje ,wool ,sorbent ,oil ,metal ion - Abstract
Rigorozni ekološki propisi, posebno u visoko razvijenim zemljama, nametnuli su zahteve za prečišćavanjem otpadnih industrijskih voda i potrebu za efikasnim uklanjanjem naftnih mrlja nakon izlivanja nafte i njenih derivata u kopnene i morske vode. Jedan od najefikasnijih načina za uklanjanje jona teških metala, boja i nafte iz vode je sorpcija pomoću efikasnih sorbenata. lako je do sada razvijen veliki broj sorbenata i postupaka, u poslednje vreme posebna pažnja pridaje se proučavanju i primeni sorbenata na bazi prirodnih materijala. U ovom radu je dat pregled rezultata dosadašnjih istraživanja sorpcionih svojstava vune kao prirodnog vlaknastog materijala koji u procesu multifunkcionalne sorpcije (fizičkom adsorpcijom i hemisorpcijom) efikasno vezuje i uklanja nespecifične zagađivače vode. Strict ecological legislation, especially in highly developed countries, imposed requirements for the purification of industrial effluents and the need for efficient oil clean up after sea and inland water spills. Although numerous processes have been developed, the application of sorbents is still one of the most efficient methods to remove heavy metal ions, dyes and crude oil from water. Recently, special attention was paid to sorbents based on natural fibres. A review of studies concerning the sorption properties of wool is presented in this paper. The presence of various functional groups on the wool fibre surface contributes to the efficient sorption of heavy metal ions and dyes. A hydrophobic, scaly surface and fibre crimp strongly influence the high sorption capacity of wool for oil. Wool has great sorption potential even as a recycled material. Accordingly, it can be used as a viable substitute to commercially available synthetic sorbents that show poor biodegradab ility.
- Published
- 2004
39. A New Approach in Regression Analysis for Modeling Adsorption Isotherms
- Author
-
Marković, Dana D., primary, Lekić, Branislava M., additional, Rajaković-Ognjanović, Vladana N., additional, Onjia, Antonije E., additional, and Rajaković, Ljubinka V., additional
- Published
- 2014
- Full Text
- View/download PDF
40. The potential of piezoelectric sensors for characterization of activated carbon cloth applied in adsorption of phenols from air
- Author
-
Rajaković, Ljubinka V. and Onjia, Antonije
- Abstract
Characterisation of activated carbon cloth (ACC) applied for phenols adsorption from the air was performed by a pair of coated piezoelectric quartz crystals as sensors. ACC cloth was impregnated with specific organic compounds, and its sorption properties were monitored in a dynamic flow system. The concentration of phenol was permanently controlled using one coated crystal as the referent inlet and the other one as the indicator outlet sensor. Frequency responses of both sensors in the system provided the data for considering the breakthrough points, and the other sorption parameters. It was concluded that ACC impregnated with specific compounds specially with poly(vinyl pirrolidone) have an optimal capacity from the point of view of both physical adsorption and chemisorption. Also, piezoelectric quartz crystals coated with Triton X-100 and 4-amino-antipyrine were the sensitive tools for the monitoring of sorption process of phenols from the air onto the impregnated ACC.
- Published
- 1998
41. Arsenic Removal from Water Using Industrial By-Products
- Author
-
Lekić, Branislava M., primary, Marković, Dana D., additional, Rajaković-Ognjanović, Vladana N., additional, Đukić, Aleksandar R., additional, and Rajaković, Ljubinka V., additional
- Published
- 2013
- Full Text
- View/download PDF
42. Analitičke tehnike za određivanje i praćenje silicijuma u vodi u termoenergetskim postrojenjima.
- Author
-
Ignjatović, Nataša R., Ilić, Maja D., and Rajaković, Ljubinka V.
- Abstract
Copyright of Chemical Industry / Hemijska Industrija is the property of Association of Chemical Engineers and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
- Published
- 2015
- Full Text
- View/download PDF
43. The potential of the piezoelectric sensor for the characterization of activated carbon cloth applied in the adsorption of phenol from air
- Author
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Onjia, Antonije and Rajaković, Ljubinka V.
- Published
- 1996
44. ENHANCED ARSENIC REMOVAL FROM WATER BY ACTIVATED RED MUD BASED ON HYDRATED IRON(III) AND TITAN(IV) OXIDES
- Author
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Vukašinović-Pešić, Vesna L., primary, Rajaković-Ognjanović, Vladana N., additional, Blagojević, Nada Z., additional, Grudić, Veselinka V., additional, Jovanović, Branislava M., additional, and Rajaković, Ljubinka V., additional
- Published
- 2012
- Full Text
- View/download PDF
45. Application and validation of ion chromatography for the analysis of power plants water: Analysis of corrosive anions in conditioned water–steam cycles
- Author
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Živojinović, Dragana Z., primary and Rajaković, Ljubinka V., additional
- Published
- 2011
- Full Text
- View/download PDF
46. Comparative Analysis of Methods for Determination of Arsenic in Coal and Coal Ash
- Author
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Vukašinović-Pešić, Vesna L., primary, Blagojević, Nada Z., additional, and Rajaković, Ljubinka V., additional
- Published
- 2009
- Full Text
- View/download PDF
47. Danube and Sava river sediment monitoring in Belgrade and its surroundings
- Author
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Crnković, Dragan M., primary, Crnković, Nataša S., additional, Filipović, Anka J., additional, Rajaković, Ljubinka V., additional, Perić-Grujić, Aleksandra A., additional, and Ristić, Mirjana Đ., additional
- Published
- 2008
- Full Text
- View/download PDF
48. Mikro-elektro-mehanički sistemi (MEMS) - Tehnologija za 21. vek.
- Author
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Djakov, Tatjana A., Popović, Ivanka G., and Rajaković, Ljubinka V.
- Subjects
MICROELECTROMECHANICAL systems ,ACTUATORS ,SILICON ,INDUSTRIAL applications ,NANOTECHNOLOGY - Abstract
Copyright of Chemical Industry / Hemijska Industrija is the property of Association of Chemical Engineers and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
- Published
- 2014
- Full Text
- View/download PDF
49. Sensitivity of modified bulk acoustic waves for the detection of phenols in the vapour phase
- Author
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Rajaković, Ljubinka V., primary, Bastić, Milan B., additional, Korenman, Yakov I., additional, Tunikova, Svetlana A., additional, and Bel'skih, Nataša V., additional
- Published
- 1995
- Full Text
- View/download PDF
50. Surface morphology and the response of piezoelectric gas sensors
- Author
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Rajaković, Ljubinka V., primary and Štrbac, Svetlana, additional
- Published
- 1995
- Full Text
- View/download PDF
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