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The increasing popularity of wearable electronics has sparked interest in flexible energy harvesters as alternatives to conventional batteries. Flexible magnetoelectric (ME) composites, known for converting ambient magnetic field energy into useable power, are emerging as promising autonomous energy sources for integration into wearable devices. In this study, we prepared flexible (PVDF-AlN)–(NiO–CNF) based ME composites using two different methods: solution-casting and electrospinning techniques. The ME coupling was confirmed by measuring the ferroelectric and magnetic properties of the composite, and it was qualitatively characterized through the ME coupling coefficient. The electrospinning fibers-based ME composite exhibited an optimal value of 10.6 V/cm.Oe, significantly higher than the solution-casting films-based ME composite (1.3 V/cm.Oe) under a 1 kHz AC magnetic field (off-resonance condition). Subsequently, a flexible magneto-mechano-electric (MME) generator was designed using electrospun-derived material, harvesting a sinusoidal wave with a maximum output peak-to-peak voltage of 9.02 V. The generator displayed an optimal DC power density of 97 μW/m2 when exposed to a weak AC magnetic field of 6 Oe at a frequency of 50 Hz. Consequently, it holds great promise as an efficient autonomous power supply for medical sensing and various miniature electronic applications. [ABSTRACT FROM AUTHOR]

Magneto-mechano-electric (MME) generators efficiently harness ubiquitous stray magnetic fields and convert them into electricity, capturing significant attention for powering innumerable wireless sensors. In this study, lead-free 0-3 particulate magnetoelectric (ME) nano-composite ceramics, specifically x(Ba 0.85 Ca 0.15 Zr 0.1 Ti 0.9 O 3)-(1-x)Ni 0.5 Zn 0.5 Fe 2 O 4 [x(BCT-BZT)–(1-x)NZFO], were synthesized using the sol-gel method. Subsequently, a flexible MME generator was designed, incorporating the optimized ME composite. Structural parameter calculations indicated higher tetragonal distortion of 0.4% in 0.4(BCT-BZT)-0.6NZFO, possibly due to uniform particulate distribution. The ME composites displayed uniform dual-phase microstructures, with 0.4(BCT-BZT)-0.6NZFO showing a higher NZFO concentration. The maximum values of the magnetodielectric (MD) and ME coupling coefficients have been determined to be -3.6% and 2.55 mV cm -1 Oe-1, respectively, for an x = 0.4 composite. The MME generator is designed using an optimized 0.4(BCT-BZT)-0.6NZFO ME composite with film thickness of 34 μm. This MME generator harvests a sinusoidal wave with a maximum output peak-to-peak voltage of 4.1 V when exposed to a weak AC magnetic field of 10 Oe at a frequency of 50 Hz. Additionally, the device demonstrates an exceptional optimal DC power density of 3.89 μW cm-3. The lead-free 0-3 particulate ME composite enables effective magnetic energy harnessing. As a result, it holds great promise as an efficient autonomous power supply for various Internet of Things based applications. [ABSTRACT FROM AUTHOR]

Magneto-mechano-electric (MME) generators efficiently harness ubiquitous stray magnetic fields and convert them into electricity, capturing significant attention for powering innumerable wireless sensors. In this study, lead-free 0-3 particulate magnetoelectric (ME) nano-composite ceramics, specifically x(Ba 0.85 Ca 0.15 Zr 0.1 Ti 0.9 O 3)-(1-x)Ni 0.5 Zn 0.5 Fe 2 O 4 [x(BCT-BZT)–(1-x)NZFO], were synthesized using the sol-gel method. Subsequently, a flexible MME generator was designed, incorporating the optimized ME composite. Structural parameter calculations indicated higher tetragonal distortion of 0.4% in 0.4(BCT-BZT)-0.6NZFO, possibly due to uniform particulate distribution. The ME composites displayed uniform dual-phase microstructures, with 0.4(BCT-BZT)-0.6NZFO showing a higher NZFO concentration. The maximum values of the magnetodielectric (MD) and ME coupling coefficients have been determined to be -3.6% and 2.55 mV cm -1 Oe-1, respectively, for an x = 0.4 composite. The MME generator is designed using an optimized 0.4(BCT-BZT)-0.6NZFO ME composite with film thickness of 34 μm. This MME generator harvests a sinusoidal wave with a maximum output peak-to-peak voltage of 4.1 V when exposed to a weak AC magnetic field of 10 Oe at a frequency of 50 Hz. Additionally, the device demonstrates an exceptional optimal DC power density of 3.89 μW cm-3. The lead-free 0-3 particulate ME composite enables effective magnetic energy harnessing. As a result, it holds great promise as an efficient autonomous power supply for various Internet of Things based applications. [ABSTRACT FROM AUTHOR]

Mechanical energy harvesting and energy storage through lead-free piezoelectric materials is an inevitable source of eco-friendly sustainable powering of electronic devices. Herein, we have synthesized amphoteric rare-earth element praseodymium (Pr) modified Ba 0.85 Ca 0.15 Ti 0.9 Zr 0.1 O 3 (BCZT) ceramics, with a cost-effective solid-state-reaction based two-step sintering method for the controlled grain growth. Their crystalline structures and surface morphology were investigated by using X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The dielectric and ferroelectric properties of the ceramic capacitors were investigated and correlated with structural parameters. In the vicinity of the monotonic phase transition region, with the coexistence of orthorhombic and tetragonal symmetry, the Pr ion addition in BCZT improves the tetragonal phase, which widens its energy harvesting and storage arena. The appreciable energy harvesting ability was found for an optimized energy harvester with a composition of 0.04 wt% Pr added BCZT ceramic, with an open-circuit voltage of about 5.1 V (corresponding power density of 1.213 mW/cm3) from a simple finger tapping and bring about output voltage stability with a maximum output voltage of about 9 V over 10,000 cycles when periodic force is applied by a machine tapping. Furthermore, this optimized Pr added BCZT ceramic capacitor is capable of storing a substantial recoverable energy density of 81.9 mJ/cm3with a considerable energy storage efficiency of 76.4%. These upshots offer a head start in implementing these ceramic capacitors for effective energy harvesting and energy storage applications for powering futuristic miniature electronics. ● The amphoteric praseodymium (Pr) modified BCZT ceramics were synthesized through the two-step sintering (TSS) method. ● The dielectric, ferroelectric properties and energy storage behavior got enriched for the Pr modified BCZT ceramics. ● The optimum ceramic-based mechanical energy harvester offers voltage stability of ~ 9 V for 10,000 cycles. ● The recoverable energy density of 81.9 mJ/cm3 and energy efficiency of 76.4% attained. [ABSTRACT FROM AUTHOR]