42 results on '"Rasmussen, Maren"'
Search Results
2. COMAP Early Science: VII. Prospects for CO Intensity Mapping at Reionization
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Breysse, Patrick C., Chung, Dongwoo T., Cleary, Kieran A., Ihle, Håvard T., Padmanabhan, Hamsa, Silva, Marta B., Bond, J. Richard, Borowska, Jowita, Catha, Morgan, Church, Sarah E., Dunne, Delaney A., Eriksen, Hans Kristian, Foss, Marie Kristine, Gaier, Todd, Gundersen, Joshua Ott, Harris, Andrew I., Hobbs, Richard, Keating, Laura, Lamb, James W., Lawrence, Charles R., Lunde, Jonas G. S., Murray, Norman, Pearson, Timothy J., Philip, Liju, Rasmussen, Maren, Readhead, Anthony C. S., Rennie, Thomas J., Stutzer, Nils-Ole, Viero, Marco P., Watts, Duncan J., Wehus, Ingunn Katherine, and Woody, David P.
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Astrophysics - Cosmology and Nongalactic Astrophysics ,Astrophysics - Astrophysics of Galaxies - Abstract
We introduce COMAP-EoR, the next generation of the Carbon Monoxide Mapping Array Project aimed at extending CO intensity mapping to the Epoch of Reionization. COMAP-EoR supplements the existing 30 GHz COMAP Pathfinder with two additional 30 GHz instruments and a new 16 GHz receiver. This combination of frequencies will be able to simultaneously map CO(1--0) and CO(2--1) at reionization redshifts ($z\sim5-8$) in addition to providing a significant boost to the $z\sim3$ sensitivity of the Pathfinder. We examine a set of existing models of the EoR CO signal, and find power spectra spanning several orders of magnitude, highlighting our extreme ignorance about this period of cosmic history and the value of the COMAP-EoR measurement. We carry out the most detailed forecast to date of an intensity mapping cross-correlation, and find that five out of the six models we consider yield signal to noise ratios (S/N) $\gtrsim20$ for COMAP-EoR, with the brightest reaching a S/N above 400. We show that, for these models, COMAP-EoR can make a detailed measurement of the cosmic molecular gas history from $z\sim2-8$, as well as probe the population of faint, star-forming galaxies predicted by these models to be undetectable by traditional surveys. We show that, for the single model that does not predict numerous faint emitters, a COMAP-EoR-type measurement is required to rule out their existence. We briefly explore prospects for a third-generation Expanded Reionization Array (COMAP-ERA) capable of detecting the faintest models and characterizing the brightest signals in extreme detail., Comment: Paper 7 of 7 in series. 19 pages, 10 figures, to be submitted to ApJ
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- 2021
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3. COMAP Early Science: V. Constraints and Forecasts at $z \sim 3$
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Chung, Dongwoo T., Breysse, Patrick C., Cleary, Kieran A., Ihle, Håvard T., Padmanabhan, Hamsa, Silva, Marta B., Bond, J. Richard, Borowska, Jowita, Catha, Morgan, Church, Sarah E., Dunne, Delaney A., Eriksen, Hans Kristian, Foss, Marie Kristine, Gaier, Todd, Gundersen, Joshua Ott, Harper, Stuart E., Harris, Andrew I., Hensley, Brandon, Hobbs, Richard, Keating, Laura C., Kim, Junhan, Lamb, James W., Lawrence, Charles R., Lunde, Jonas Gahr Sturtzel, Murray, Norman, Pearson, Timothy J., Philip, Liju, Rasmussen, Maren, Readhead, Anthony C. S., Rennie, Thomas J., Stutzer, Nils-Ole, Uzgil, Bade D., Viero, Marco P., Watts, Duncan J., Wechsler, Risa H., Wehus, Ingunn Kathrine, and Woody, David P.
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Astrophysics - Cosmology and Nongalactic Astrophysics ,Astrophysics - Astrophysics of Galaxies - Abstract
We present the current state of models for the $z\sim3$ carbon monoxide (CO) line-intensity signal targeted by the CO Mapping Array Project (COMAP) Pathfinder in the context of its early science results. Our fiducial model, relating dark matter halo properties to CO luminosities, informs parameter priors with empirical models of the galaxy-halo connection and previous CO(1-0) observations. The Pathfinder early science data spanning wavenumbers $k=0.051$-$0.62\,$Mpc$^{-1}$ represent the first direct 3D constraint on the clustering component of the CO(1-0) power spectrum. Our 95% upper limit on the redshift-space clustering amplitude $A_{\rm clust}\lesssim70\,\mu$K$^2$ greatly improves on the indirect upper limit of $420\,\mu$K$^2$ reported from the CO Power Spectrum Survey (COPSS) measurement at $k\sim1\,$Mpc$^{-1}$. The COMAP limit excludes a subset of models from previous literature, and constrains interpretation of the COPSS results, demonstrating the complementary nature of COMAP and interferometric CO surveys. Using line bias expectations from our priors, we also constrain the squared mean line intensity-bias product, $\langle{Tb}\rangle^2\lesssim50\,\mu$K$^2$, and the cosmic molecular gas density, $\rho_\text{H2}<2.5\times10^8\,M_\odot\,$Mpc$^{-3}$ (95% upper limits). Based on early instrument performance and our current CO signal estimates, we forecast that the five-year Pathfinder campaign will detect the CO power spectrum with overall signal-to-noise of 9-17. Between then and now, we also expect to detect the CO-galaxy cross-spectrum using overlapping galaxy survey data, enabling enhanced inferences of cosmic star-formation and galaxy-evolution history., Comment: Paper 5 of 7 in series. 17 pages + appendix and bibliography (30 pages total); 15 figures, 6 tables; accepted for publication in ApJ; v3 reflects the accepted version with minor changes and additions to text
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- 2021
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4. COMAP Early Science: VI. A First Look at the COMAP Galactic Plane Survey
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Rennie, Thomas J., Harper, Stuart E., Dickinson, Clive, Philip, Liju, Cleary, Kieran A., Bond, Richard J., Borowska, Jowita, Breysse, Patrick C., Catha, Morgan, Cepeda-Arroita, Roke, Chung, Dongwoo T., Church, Sarah E., Dunne, Delaney A., Eriksen, Hans Kristian, Foss, Marie Kristine, Gaier, Todd, Gunderson, Joshua Ott, Harris, Andrew I., Hensley, Brandon, Hobbs, Richard, Ihle, Håvard T., Lamb, James W., Lawrence, Charles R., Lunde, Jonas G. S., Paladini, Roberta, Pearson, Timothy J., Rasmussen, Maren, Readhead, Anthony C. S., Stutzer, Nils-Ole, Watts, Duncan J., Wehus, Ingunn Kathrine, and Woody, David P.
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Astrophysics - Astrophysics of Galaxies - Abstract
We present early results from the COMAP Galactic Plane Survey conducted between June 2019 and April 2021, spanning $20^\circ<\ell<40^\circ$ in Galactic longitude and $|b|<1.\!\!^{\circ}5$ in Galactic latitude with an angular resolution of $4.5^{\prime}$. The full survey will span $\ell \sim 20^{\circ}$- $220^{\circ}$ and will be the first large-scale radio continuum survey at $30$ GHz with sub-degree resolution. We present initial results from the first part of the survey, including diffuse emission and spectral energy distributions (SEDs) of HII regions and supernova remnants. Using low and high frequency surveys to constrain free-free and thermal dust emission contributions, we find evidence of excess flux density at $30\,$GHz in six regions that we interpret as anomalous microwave emission. Furthermore we model UCHII contributions using data from the $5\,$GHz CORNISH catalogue and reject this as the cause of the $30\,$GHz excess. Six known supernova remnants (SNR) are detected at $30\,$GHz, and we measure spectral indices consistent with the literature or show evidence of steepening. The flux density of the SNR W44 at $30\,$GHz is consistent with a power-law extrapolation from lower frequencies with no indication of spectral steepening in contrast with recent results from the Sardinia Radio Telescope. We also extract five hydrogen radio recombination lines to map the warm ionized gas, which can be used to estimate electron temperatures or to constrain continuum free-free emission. The full COMAP Galactic plane survey, to be released in 2023/2024, will be an invaluable resource for Galactic astrophysics., Comment: Paper 6 of 7 in series. 28 pages, 10 figures, submitted to ApJ
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- 2021
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5. COMAP Early Science: IV. Power Spectrum Methodology and Results
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Ihle, Håvard T., Borowska, Jowita, Cleary, Kieran A., Eriksen, Hans Kristian, Foss, Marie K., Harper, Stuart E., Kim, Junhan, Lunde, Jonas G. S., Philip, Liju, Rasmussen, Maren, Stutzer, Nils-Ole, Uzgil, Bade D., Watts, Duncan J., Wehus, Ingunn Kathrine, Bond, J. Richard, Breysse, Patrick C., Catha, Morgan, Church, Sarah E., Chung, Dongwoo T., Dickinson, Clive, Dunne, Delaney A., Gaier, Todd, Gundersen, Joshua Ott, Harris, Andrew I., Hobbs, Richard, Lamb, James W., Lawrence, Charles R., Murray, Norman, Readhead, Anthony C. S., Padmanabhan, Hamsa, Pearson, Timothy J., Rennie, Thomas J., and Woody, David P.
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Astrophysics - Cosmology and Nongalactic Astrophysics ,Astrophysics - Astrophysics of Galaxies - Abstract
We present the power spectrum methodology used for the first-season COMAP analysis, and assess the quality of the current data set. The main results are derived through the Feed-feed Pseudo-Cross-Spectrum (FPXS) method, which is a robust estimator with respect to both noise modeling errors and experimental systematics. We use effective transfer functions to take into account the effects of instrumental beam smoothing and various filter operations applied during the low-level data processing. The power spectra estimated in this way have allowed us to identify a systematic error associated with one of our two scanning strategies, believed to be due to residual ground or atmospheric contamination. We omit these data from our analysis and no longer use this scanning technique for observations. We present the power spectra from our first season of observing and demonstrate that the uncertainties are integrating as expected for uncorrelated noise, with any residual systematics suppressed to a level below the noise. Using the FPXS method, and combining data on scales $k=0.051-0.62 \,\mathrm{Mpc}^{-1}$ we estimate $P_\mathrm{CO}(k) = -2.7 \pm 1.7 \times 10^4\mu\textrm{K}^2\mathrm{Mpc}^3$, the first direct 3D constraint on the clustering component of the CO(1-0) power spectrum in the literature., Comment: Paper 4 of 7 in series. 18 pages, 11 figures, as accepted in ApJ
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- 2021
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6. COMAP Early Science: III. CO Data Processing
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Foss, Marie K., Ihle, Håvard T., Borowska, Jowita, Cleary, Kieran A., Eriksen, Hans Kristian, Harper, Stuart E., Kim, Junhan, Lamb, James W., Lunde, Jonas G. S., Philip, Liju, Rasmussen, Maren, Stutzer, Nils-Ole, Uzgil, Bade D., Watts, Duncan J., Wehus, Ingunn K., Woody, David P., Bond, J. Richard, Breysse, Patrick C., Catha, Morgan, Church, Sarah E., Chung, Dongwoo T., Dickinson, Clive, Dunne, Delaney A., Gaier, Todd, Gundersen, Joshua Ott, Harris, Andrew I., Hobbs, Richard, Lawrence, Charles R., Murray, Norman, Readhead, Anthony C. S., Padmanabhan, Hamsa, Pearson, Timothy J., and Rennie, Thomas J.
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Astrophysics - Instrumentation and Methods for Astrophysics ,Astrophysics - Cosmology and Nongalactic Astrophysics ,Astrophysics - Astrophysics of Galaxies - Abstract
We describe the first season COMAP analysis pipeline that converts raw detector readouts to calibrated sky maps. This pipeline implements four main steps: gain calibration, filtering, data selection, and map-making. Absolute gain calibration relies on a combination of instrumental and astrophysical sources, while relative gain calibration exploits real-time total-power variations. High efficiency filtering is achieved through spectroscopic common-mode rejection within and across receivers, resulting in nearly uncorrelated white noise within single-frequency channels. Consequently, near-optimal but biased maps are produced by binning the filtered time stream into pixelized maps; the corresponding signal bias transfer function is estimated through simulations. Data selection is performed automatically through a series of goodness-of-fit statistics, including $\chi^2$ and multi-scale correlation tests. Applying this pipeline to the first-season COMAP data, we produce a dataset with very low levels of correlated noise. We find that one of our two scanning strategies (the Lissajous type) is sensitive to residual instrumental systematics. As a result, we no longer use this type of scan and exclude data taken this way from our Season 1 power spectrum estimates. We perform a careful analysis of our data processing and observing efficiencies and take account of planned improvements to estimate our future performance. Power spectrum results derived from the first-season COMAP maps are presented and discussed in companion papers., Comment: Paper 3 of 7 in series. 26 pages, 23 figures, submitted to ApJ
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- 2021
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7. COMAP Early Science: I. Overview
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Cleary, Kieran A., Borowska, Jowita, Breysse, Patrick C., Catha, Morgan, Chung, Dongwoo T., Church, Sarah E., Dickinson, Clive, Eriksen, Hans Kristian, Foss, Marie Kristine, Gundersen, Joshua Ott, Harper, Stuart E., Harris, Andrew I., Hobbs, Richard, Håvard, Ihle, T., Kim, Junhan, Kocz, Jonathon, Lamb, James W., Lunde, Jonas G. S., Padmanabhan, Hamsa, Pearson, Timothy J., Philip, Liju, Powell, Travis W., Rasmussen, Maren, Readhead, Anthony C. S., Rennie, Thomas J., Silva, Marta B., Stutzer, Nils-Ole, Uzgil, Bade D., Watts, Duncan J., Wehus, Ingunn Kathrine, Woody, David P., Basoalto, Lilian, Bond, J. Richard, Dunne, Delaney A., Gaier, Todd, Hensley, Brandon, Keating, Laura C., Lawrence, Charles R., Murray, Norman, Reeves, Rodrigo, Viero, Marco P., and Wechsler, Risa
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Astrophysics - Cosmology and Nongalactic Astrophysics ,Astrophysics - Astrophysics of Galaxies - Abstract
The CO Mapping Array Project (COMAP) aims to use line intensity mapping of carbon monoxide (CO) to trace the distribution and global properties of galaxies over cosmic time, back to the Epoch of Reionization (EoR). To validate the technologies and techniques needed for this goal, a Pathfinder instrument has been constructed and fielded. Sensitive to CO(1-0) emission from $z=2.4$-$3.4$ and a fainter contribution from CO(2-1) at $z=6$-8, the Pathfinder is surveying $12$ deg$^2$ in a 5-year observing campaign to detect the CO signal from $z\sim3$. Using data from the first 13 months of observing, we estimate $P_\mathrm{CO}(k) = -2.7 \pm 1.7 \times 10^4\mu\mathrm{K}^2 \mathrm{Mpc}^3$ on scales $k=0.051-0.62 \mathrm{Mpc}^{-1}$ - the first direct 3D constraint on the clustering component of the CO(1-0) power spectrum. Based on these observations alone, we obtain a constraint on the amplitude of the clustering component (the squared mean CO line temperature-bias product) of $\langle Tb\rangle^2<49$ $\mu$K$^2$ - nearly an order-of-magnitude improvement on the previous best measurement. These constraints allow us to rule out two models from the literature. We forecast a detection of the power spectrum after 5 years with signal-to-noise ratio (S/N) 9-17. Cross-correlation with an overlapping galaxy survey will yield a detection of the CO-galaxy power spectrum with S/N of 19. We are also conducting a 30 GHz survey of the Galactic plane and present a preliminary map. Looking to the future of COMAP, we examine the prospects for future phases of the experiment to detect and characterize the CO signal from the EoR., Comment: Paper 1 of 7 in series. 18 pages, 16 figures, submitted to ApJ
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- 2021
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8. COMAP Early Science: II. Pathfinder Instrument
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Lamb, James W., Cleary, Kieran A., Woody, David P., Catha, Morgan, Chung, Dongwoo T., Gundersen, Joshua Ott, Harper, Stuart E., Harris, Andrew I., Hobbs, Richard, Ihle, Håvard T., Kocz, Jonathon, Pearson, Timothy J., Philip, Liju, Powell, Travis W., Basoalto, Lilian, Bond, J. Richard, Borowska, Jowita, Breysse, Patrick C., Church, Sarah E., Dickinson, Clive, Dunne, Delaney A., Eriksen, Hans Kristian, Foss, Marie Kristine, Gaier, Todd, Kim, Junhan, Lawrence, Charles R., Lunde, Jonas G. S., Padmanabhan, Hamsa, Rasmussen, Maren, Readhead, Anthony C. S., Reeves, Rodrigo, Rennie, Thomas J., Stutzer, Nils-Ole, Watts, Duncan J., and Wehus, Ingunn Kathrine
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Astrophysics - Instrumentation and Methods for Astrophysics ,Astrophysics - Cosmology and Nongalactic Astrophysics ,Astrophysics - Astrophysics of Galaxies - Abstract
Line intensity mapping (LIM) is a new technique for tracing the global properties of galaxies over cosmic time. Detection of the very faint signals from redshifted carbon monoxide (CO), a tracer of star formation, pushes the limits of what is feasible with a total-power instrument. The CO Mapping Project (COMAP) Pathfinder is a first-generation instrument aiming to prove the concept and develop the technology for future experiments, as well as delivering early science products. With 19 receiver channels in a hexagonal focal plane arrangement on a 10.4 m antenna, and an instantaneous 26-34 GHz frequency range with 2 MHz resolution, it is ideally suited to measuring CO($J$=1-0) from $z\sim3$. In this paper we discuss strategies for designing and building the Pathfinder and the challenges that were encountered. The design of the instrument prioritized LIM requirements over those of ancillary science. After a couple of years of operation, the instrument is well understood, and the first year of data is already yielding useful science results. Experience with this Pathfinder will drive the design of the next generations of experiments., Comment: Paper 2 of 7 in series. 27 pages, 28 figures, submitted to ApJ
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- 2021
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9. Solvothermal synthesis and selected properties of {[Ni(dien)2]3[V6As8O26]}2+·2 Cl– featuring the small [V6IVAs8IIIO26]4– cluster anion
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Rasmussen, Maren, Näther, Christian, and Bensch, Wolfgang
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HYDROGEN bonding interactions , *ELECTRONIC spectra , *SURFACE analysis , *INTERMOLECULAR interactions , *MATHEMATICAL complexes , *POLYHEDRA - Abstract
A new arsenato-polyoxovanadate with the composition {[Ni(dien)2]3[V6As8O26]}2+·2 Cl– has been crystallized under solvothermal conditions as turquoise block-like crystals. The central structural feature is the [V6IVAs8IIIO26]4– cluster anion, which is composed of two trinuclear {V3O11} groups consisting of three edge-sharing VO5 polyhedra. Pairs of pyramidal AsO3 moieties share a common corner forming As2O5 units, which interconnect the {V3O11} groups. One of the [Ni(dien)2]2+ complexes adopts the s-fac (Ni1) and the second complex the mer configuration (Ni2). The Cl− anion is involved in strong hydrogen bonding interactions and links the [Ni(dien)2]2+ complexes to form twelve-membered rings which host the [V6As8O26]4– cluster anions. The Hirshfeld surface analysis yields a detailed picture of the intermolecular interactions revealing clear differences for the two unique [Ni(dien)2]2+ complexes. Intermolecular contacts also include As⋯H, O⋯H and H⋯H interactions. In the electronic spectrum the bands of d–d transitions of the vanadyl group and of the Ni2+ cations overlap, preventing a detailed analysis. [ABSTRACT FROM AUTHOR]
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- 2024
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10. Solvothermal synthesis and selected properties of {[Ni(dien)2]3[V6As8O26]}2+·2 Cl–featuring the small [V6IVAs8IIIO26]4–cluster anion
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Rasmussen, Maren, Näther, Christian, and Bensch, Wolfgang
- Abstract
A new arsenato-polyoxovanadate with the composition {[Ni(dien)2]3[V6As8O26]}2+·2 Cl–has been crystallized under solvothermal conditions as turquoise block-like crystals. The central structural feature is the [V6IVAs8IIIO26]4–cluster anion, which is composed of two trinuclear {V3O11} groups consisting of three edge-sharing VO5polyhedra. Pairs of pyramidal AsO3moieties share a common corner forming As2O5units, which interconnect the {V3O11} groups. One of the [Ni(dien)2]2+complexes adopts the s-fac(Ni1) and the second complex the merconfiguration (Ni2). The Cl−anion is involved in strong hydrogen bonding interactions and links the [Ni(dien)2]2+complexes to form twelve-membered rings which host the [V6As8O26]4–cluster anions. The Hirshfeld surface analysis yields a detailed picture of the intermolecular interactions revealing clear differences for the two unique [Ni(dien)2]2+complexes. Intermolecular contacts also include As⋯H, O⋯H and H⋯H interactions. In the electronic spectrum the bands of d–dtransitions of the vanadyl group and of the Ni2+cations overlap, preventing a detailed analysis.
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- 2024
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11. New As-Rich Arsenato-Polyoxovanadate Clusters: Solvothermal Synthesis and Selected Properties of [V6IVAs8IIIO26]4− Cluster-Containing Compounds
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Rasmussen, Maren, primary, Näther, Christian, additional, and Bensch, Wolfgang, additional
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- 2022
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12. Composition-driven archetype dynamics in polyoxovanadates
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Kondinski, Aleksandar, Rasmussen, Maren, Mangelsen, Sebastian, Pienack, Nicole, Simjanoski, Viktor, Näther, Christian, Stares, Daniel L, Schalley, Christoph A, Bensch, Wolfgang, Kondinski, Aleksandar [0000-0002-0559-0172], Mangelsen, Sebastian [0000-0003-2121-9514], Simjanoski, Viktor [0000-0001-8686-2397], Näther, Christian [0000-0001-8741-6508], Stares, Daniel L [0000-0002-4497-6537], Schalley, Christoph A [0000-0002-8634-3578], Bensch, Wolfgang [0000-0002-3111-580X], Apollo - University of Cambridge Repository, and Apollo-University Of Cambridge Repository
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3402 Inorganic Chemistry ,molecular metal oxides ,34 Chemical Sciences ,General Chemistry ,500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften ,common structural frameworks ,polyoxovanadates - Abstract
Funder: Isaac Newton Trust, Funder: Alexander von Humboldt-Stiftung, Molecular metal oxides often adopt common structural frameworks (i.e. archetypes), many of them boasting impressive structural robustness and stability. However, the ability to adapt and to undergo transformations between different structural archetypes is a desirable material design feature offering applicability in different environments. Using systems thinking approach that integrates synthetic, analytical and computational techniques, we explore the transformations governing the chemistry of polyoxovanadates (POVs) constructed of arsenate and vanadate building units. The water-soluble salt of the low nuclearity polyanion [V6As8O26]4- can be effectively used for the synthesis of the larger spherical (i.e. kegginoidal) mixed-valent [V12As8O40]4- precipitate, while the novel [V10As12O40]8- POVs having tubular cyclic structures are another, well soluble product. Surprisingly, in contrast to the common observation that high-nuclearity polyoxometalate (POM) clusters are fragmented to form smaller moieties in solution, the low nuclearity [V6As8O26]4- anion is in situ transformed into the higher nuclearity cluster anions. The obtained products support a conceptually new model that is outlined in this article and that describes a continuous evolution between spherical and cyclic POV assemblies. This new model represents a milestone on the way to rational and designable POV self-assemblies.
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- 2022
13. COMAP Early Science. VII. Prospects for CO Intensity Mapping at Reionization
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Breysse, Patrick C., primary, Chung, Dongwoo T., additional, Cleary, Kieran A., additional, Ihle, Håvard T., additional, Padmanabhan, Hamsa, additional, Silva, Marta B., additional, Bond, J. Richard, additional, Borowska, Jowita, additional, Catha, Morgan, additional, Church, Sarah E., additional, Dunne, Delaney A., additional, Eriksen, Hans Kristian, additional, Foss, Marie Kristine, additional, Gaier, Todd, additional, Gundersen, Joshua Ott, additional, Harris, Andrew I., additional, Hobbs, Richard, additional, Keating, Laura, additional, Lamb, James W., additional, Lawrence, Charles R., additional, Lunde, Jonas G. S., additional, Murray, Norman, additional, Pearson, Timothy J., additional, Philip, Liju, additional, Rasmussen, Maren, additional, Readhead, Anthony C. S., additional, Rennie, Thomas J., additional, Stutzer, Nils-Ole, additional, Viero, Marco P., additional, Watts, Duncan J., additional, Wehus, Ingunn Kathrine, additional, and Woody, David P., additional
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- 2022
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14. COMAP Early Science. II. Pathfinder Instrument
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Lamb, James W., primary, Cleary, Kieran A., additional, Woody, David P., additional, Catha, Morgan, additional, Chung, Dongwoo T., additional, Gundersen, Joshua Ott, additional, Harper, Stuart E., additional, Harris, Andrew I., additional, Hobbs, Richard, additional, Ihle, Håvard T., additional, Kocz, Jonathon, additional, Pearson, Timothy J., additional, Philip, Liju, additional, Powell, Travis W., additional, Basoalto, Lilian, additional, Bond, J. Richard, additional, Borowska, Jowita, additional, Breysse, Patrick C., additional, Church, Sarah E., additional, Dickinson, Clive, additional, Dunne, Delaney A., additional, Eriksen, Hans Kristian, additional, Foss, Marie Kristine, additional, Gaier, Todd, additional, Kim, Junhan, additional, Lawrence, Charles R., additional, Lunde, Jonas G. S., additional, Padmanabhan, Hamsa, additional, Rasmussen, Maren, additional, Readhead, Anthony C. S., additional, Reeves, Rodrigo, additional, Rennie, Thomas J., additional, Stutzer, Nils-Ole, additional, Viero, Marco P., additional, Watts, Duncan J., additional, and Wehus, Ingunn Kathrine, additional
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- 2022
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15. COMAP Early Science. V. Constraints and Forecasts at z ∼ 3
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Chung, Dongwoo T., primary, Breysse, Patrick C., additional, Cleary, Kieran A., additional, Ihle, Håvard T., additional, Padmanabhan, Hamsa, additional, Silva, Marta B., additional, Richard Bond, J., additional, Borowska, Jowita, additional, Catha, Morgan, additional, Church, Sarah E., additional, Dunne, Delaney A., additional, Kristian Eriksen, Hans, additional, Kristine Foss, Marie, additional, Gaier, Todd, additional, Ott Gundersen, Joshua, additional, Harper, Stuart E., additional, Harris, Andrew I., additional, Hensley, Brandon, additional, Hobbs, Richard, additional, Keating, Laura C., additional, Kim, Junhan, additional, Lamb, James W., additional, Lawrence, Charles R., additional, Gahr Sturtzel Lunde, Jonas, additional, Murray, Norman, additional, Pearson, Timothy J., additional, Philip, Liju, additional, Rasmussen, Maren, additional, Readhead, Anthony C. S., additional, Rennie, Thomas J., additional, Stutzer, Nils-Ole, additional, Uzgil, Bade D., additional, Viero, Marco P., additional, Watts, Duncan J., additional, Wechsler, Risa H., additional, Kathrine Wehus, Ingunn, additional, and Woody, David P., additional
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- 2022
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16. COMAP Early Science. I. Overview
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Cleary, Kieran A., primary, Borowska, Jowita, additional, Breysse, Patrick C., additional, Catha, Morgan, additional, Chung, Dongwoo T., additional, Church, Sarah E., additional, Dickinson, Clive, additional, Eriksen, Hans Kristian, additional, Foss, Marie Kristine, additional, Gundersen, Joshua Ott, additional, Harper, Stuart E., additional, Harris, Andrew I., additional, Hobbs, Richard, additional, Ihle, Håvard T., additional, Kim, Junhan, additional, Kocz, Jonathon, additional, Lamb, James W., additional, Lunde, Jonas G. S., additional, Padmanabhan, Hamsa, additional, Pearson, Timothy J., additional, Philip, Liju, additional, Powell, Travis W., additional, Rasmussen, Maren, additional, Readhead, Anthony C. S., additional, Rennie, Thomas J., additional, Silva, Marta B., additional, Stutzer, Nils-Ole, additional, Uzgil, Bade D., additional, Watts, Duncan J., additional, Wehus, Ingunn Kathrine, additional, Woody, David P., additional, Basoalto, Lilian, additional, Bond, J. Richard, additional, Dunne, Delaney A., additional, Gaier, Todd, additional, Hensley, Brandon, additional, Keating, Laura C., additional, Lawrence, Charles R., additional, Murray, Norman, additional, Paladini, Roberta, additional, Reeves, Rodrigo, additional, Viero, Marco P., additional, and Wechsler, Risa H., additional
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- 2022
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17. COMAP Early Science. IV. Power Spectrum Methodology and Results
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Ihle, Håvard T., primary, Borowska, Jowita, additional, Cleary, Kieran A., additional, Eriksen, Hans Kristian, additional, Foss, Marie K., additional, Harper, Stuart E., additional, Kim, Junhan, additional, Lunde, Jonas G. S., additional, Philip, Liju, additional, Rasmussen, Maren, additional, Stutzer, Nils-Ole, additional, Uzgil, Bade D., additional, Watts, Duncan J., additional, Wehus, Ingunn Kathrine, additional, Bond, J. Richard, additional, Breysse, Patrick C., additional, Catha, Morgan, additional, Church, Sarah E., additional, Chung, Dongwoo T., additional, Dickinson, Clive, additional, Dunne, Delaney A., additional, Gaier, Todd, additional, Gundersen, Joshua Ott, additional, Harris, Andrew I., additional, Hobbs, Richard, additional, Lamb, James W., additional, Lawrence, Charles R., additional, Murray, Norman, additional, Readhead, Anthony C. S., additional, Padmanabhan, Hamsa, additional, Pearson, Timothy J., additional, Rennie, Thomas J., additional, and Woody, David P., additional
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- 2022
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18. COMAP Early Science. III. CO Data Processing
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Foss, Marie K., primary, Ihle, Håvard T., additional, Borowska, Jowita, additional, Cleary, Kieran A., additional, Eriksen, Hans Kristian, additional, Harper, Stuart E., additional, Kim, Junhan, additional, Lamb, James W., additional, Lunde, Jonas G. S., additional, Philip, Liju, additional, Rasmussen, Maren, additional, Stutzer, Nils-Ole, additional, Uzgil, Bade D., additional, Watts, Duncan J., additional, Wehus, Ingunn K., additional, Woody, David P., additional, Bond, J. Richard, additional, Breysse, Patrick C., additional, Catha, Morgan, additional, Church, Sarah E., additional, Chung, Dongwoo T., additional, Dickinson, Clive, additional, Dunne, Delaney A., additional, Gaier, Todd, additional, Gundersen, Joshua Ott, additional, Harris, Andrew I., additional, Hobbs, Richard, additional, Lawrence, Charles R., additional, Murray, Norman, additional, Readhead, Anthony C. S., additional, Padmanabhan, Hamsa, additional, Pearson, Timothy J., additional, and Rennie, Thomas J., additional
- Published
- 2022
- Full Text
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19. COMAP Early Science. VI. A First Look at the COMAP Galactic Plane Survey
- Author
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Rennie, Thomas J., primary, Harper, Stuart E., additional, Dickinson, Clive, additional, Philip, Liju, additional, Cleary, Kieran A., additional, Bond, Richard J., additional, Borowska, Jowita, additional, Breysse, Patrick C., additional, Catha, Morgan, additional, Cepeda-Arroita, Roke, additional, Chung, Dongwoo T., additional, Church, Sarah E., additional, Dunne, Delaney A., additional, Eriksen, Hans Kristian, additional, Foss, Marie Kristine, additional, Gaier, Todd, additional, Gundersen, Joshua Ott, additional, Harris, Andrew I., additional, Hensley, Brandon, additional, Hobbs, Richard, additional, Ihle, Håvard T., additional, Lamb, James W., additional, Lawrence, Charles R., additional, Lunde, Jonas G. S., additional, Paladini, Roberta, additional, Pearson, Timothy J., additional, Rasmussen, Maren, additional, Readhead, Anthony C. S., additional, Stutzer, Nils-Ole, additional, Watts, Duncan J., additional, Wehus, Ingunn Kathrine, additional, and Woody, David P., additional
- Published
- 2022
- Full Text
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20. Composition-driven archetype dynamics in polyoxovanadates
- Author
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Kondinski, Aleksandar, primary, Rasmussen, Maren, additional, Mangelsen, Sebastian, additional, Pienack, Nicole, additional, Simjanoski, Viktor, additional, Näther, Christian, additional, Stares, Daniel L., additional, Schalley, Christoph A., additional, and Bensch, Wolfgang, additional
- Published
- 2022
- Full Text
- View/download PDF
21. Front Cover: Mn2+ substitution within the {V14As8} polyoxovanadate archetype results in {Mn2V12As8} shells with trans‐positioned heterometal positions (Z. Anorg. Allg. Chem. 22/2021)
- Author
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Rasmussen, Maren, primary, Näther, Christian, additional, Kögerler, Paul, additional, and Bensch, Wolfgang, additional
- Published
- 2021
- Full Text
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22. Mn2+ substitution within the {V14As8} polyoxovanadate archetype results in {Mn2V12As8} shells with trans‐positioned heterometal positions
- Author
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Rasmussen, Maren, primary, Näther, Christian, additional, Kögerler, Paul, additional, and Bensch, Wolfgang, additional
- Published
- 2021
- Full Text
- View/download PDF
23. New As-Rich Arsenato-Polyoxovanadate Clusters: Solvothermal Synthesis and Selected Properties of [V 6 IV As 8 III O 26 ] 4− Cluster-Containing Compounds.
- Author
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Rasmussen, Maren, Näther, Christian, and Bensch, Wolfgang
- Subjects
ELECTRONIC spectra ,SURFACE analysis ,UNIT cell ,LATTICE constants ,INTERMOLECULAR interactions - Abstract
Three new arsenato-polyoxovanadates with the composition [M(en)
3 ]2 [V6 As8 O26 ] (M = Co2+ (I), Zn2+ (II), and Cd2+ (III)) were synthesized under solvothermal conditions in high yields, thus significantly enhancing the knowledge of As-rich polyoxovanadate cluster chemistry. The compounds are isostructural and feature the very rare [V6 IV As8 III O26 ]4− cluster anion. The cluster shell is constructed by interconnection of two trimeric {V3 O11 } groups consisting of three edge-sharing VO5 polyhedra and four As2 O5 units, which are formed by two corner-sharing AsO3 pyramids. While the As2 O5 group is a common structural feature in arsenato-polyoxovanadates, the {V3 O11 } unit is only observed in V-rich high-nuclear heteroatom-containing polyoxovanadates {V14 E8 } (E = As, Sb, Ge). The complexes adopt the Λ (δδδ) conformation, which is the most stable arrangement. Interestingly, the unit cell parameters do not scale with the volume of the [M(en)3 ]2+ complexes, assuming a constant volume of the anion. Only a very detailed Hirshfeld surface analysis revealed that the van der Waals volume of the {V6 As8 O26 } moiety is the smallest for the Cd-containing compound, while the volumes of the anions in the other two compounds are very similar. Therefore, the observed trends of the lattice parameters can be explained on the basis of these findings. Furthermore, intermolecular interactions include As⋯H contacts in addition to O⋯H and H⋯H interactions. The electronic spectrum of I contains d–d transitions of the vanadyl group and of the Co2+ cation. As expected only the d–d transitions of the VO2+ unit occur for II and III. [ABSTRACT FROM AUTHOR]- Published
- 2022
- Full Text
- View/download PDF
24. The Coordination Polymer Cr(en) 2 As 2 VO 7 Consisting of Alternating VO 4 Tetrahedra and As 2 O 5 Handles Decorated by Cr 3+ Centered Complexes
- Author
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Rasmussen, Maren, primary, Näther, Christian, additional, and Bensch, Wolfgang, additional
- Published
- 2021
- Full Text
- View/download PDF
25. Data selection for intensity mapping experiments using machine learning
- Author
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Rasmussen, Maren
- Abstract
The CO Mapping Array Pathfinder (COMAP) experiment is an intensity mapping experiment, currently in an early stage where learning how to process the data is one of the top points on the priority list. This includes the process of data selection, where bad data are discarded. In the COMAP experiment, two important challenges are weather contaminated observations and observations containing spikes. This thesis aims to use machine learning in the form of one-dimensional convolutional neural networks for sorting out data that have been contaminated by the weather. It also aims to develop an algorithm for detecting spikes in the data. Through the thesis we test different preprocessing techniques of the raw telescope data before feeding it into a convolutional neural network. We also fine-tune the convolutional neural network, and find that we can change the cutoff value for predicting bad weather to ensure that few bad weather samples are classified as good weather. We have found that with a cutoff value of 0.23 for the probability of bad weather, we get a training accuracy of 93.2%, a validation accuracy of 95.5%, and a testing accuracy of 97.0%. Hence we have shown that machine learning can be used for distinguishing between the observations that are contaminated by the weather, and the observations that are not. We have also found that 37.9% of the data are somewhat contaminated by the weather. By using a robust spike detection algorithm, called Smoothed z-score, we further have found that 66.3% of the data contain at least one spike. Most of the data contain only a few spikes, but some contain more than 2000 spikes. The spikes come in a variety of widths and amplitudes. Finally, we have looked at cross-spectrum of our current COMAP data, and have seen that there are still some challenges that need to be sorted out.
- Published
- 2020
26. Fra nedgang til suksess? En casestudie av implementering av Lean hos Malm Orstad
- Author
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Lyngstad, Mathilde Sofie, Rasmussen, Maren, and Nygård, Stine Ravndal
- Subjects
Social science: 200::Economics: 210::Business: 213 [VDP] ,Lean ,motstand ,endringsledelse ,motivasjon ,produksjonsbedrift - Abstract
Master's thesis in Change management Dette forskningsprosjektet tar for seg implementeringsprosessen av Lean som har blitt gjennomført hos virksomheten Malm Orstad. Hensikten med prosjektet er å besvare følgende problemstillinger: 1) Hva kjennetegner endringsleders rolle i de ulike implementeringsfasene av Lean hos Malm Orstad? og 2) Hvordan opplevde de ansatte at de ble motivert og ivaretatt gjennom implementeringsprosessen? Intensjonen med prosjektet har vært å se på implementeringsprosessen av Lean hos Malm Orstad. Vi ønsket å få et dypere innblikk i hvordan endringsleder opptrådte gjennom implementeringsprosessen, og hvordan de ansatte opplevde prosessen. Forskningsprosjektet har som hensikt å være et bidrag til refleksjon, og gi en bedre forståelse til andre virksomheter som skal gjennomføre en implementeringsprosess. Forskningsprosjektet er en enkeltcasestudie, og utvalget for studien har vært ansatte fra ledelsen og ansatte på operatørnivå hos Malm Orstad. Studien har foregått over en seks måneders periode, fra januar 2019 til juni 2019, med intervju som metode. Det teoretiske rammeverket for å belyse forskningsprosjektets tema, er forankret i teori om endringsledelse, implementeringsprosesser, motivasjon og motstand. Basert på forskningsprosjektets empiriske fundament har vi kommet fram til to hovedfunn, informasjon og involvering. Hovedfunnene viser til at det er en stor sammenheng mellom endringsleders rolle i de ulike implementeringsfasene, og de ansattes opplevelse av motivasjon og ivaretakelse. Funnene indikerer at endringsleder både har motivert og ivaretatt de ansatte, men også hatt et manglende fokus på enkelte områder i implementeringsprosessen. Informasjon og involvering kan dermed sees på som avgjørende faktorer for de ansattes motivasjon i en implementeringsprosess, noe som også er i overensstemmelse med vårt teoretiske rammeverk.
- Published
- 2019
27. Mn2+ substitution within the {V14As8} polyoxovanadate archetype results in {Mn2V12As8} shells with trans‐positioned heterometal positions.
- Author
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Rasmussen, Maren, Näther, Christian, Kögerler, Paul, and Bensch, Wolfgang
- Subjects
- *
MAGNETIC susceptibility , *MAGNETIC measurements , *ARCHETYPES , *LIGANDS (Chemistry) , *DIETHYLENETRIAMINE - Abstract
Solvothermal exploration of the As, V, Mn reaction system in the presence of aqueous diethylenetriamine (=dien) solution led to the discovery of [MnII4VIV12AsIII8O40(dien)4(H2O)] ⋅ 3.5H2O, containing the first arsenato‐polyoxovanadate featuring a {Mn2V12As8O40} cluster shell. In comparison to its parental {V14As8O42} archetype, two vanadyl (VO2+) units at opposite ends of the polyoxovanadate shell here are substituted by Mn2+ centers. In the solid state, these {Mn2V12As8O40} units are joined into rods by sharing common Mn−O−V linkages. Expansion of the cluster shell by two further Mn2+ sites via Mn−O=V bridges generates a {Mn4V12As8O40} moiety. Three Mn2+ cations are joined by monodentate‐coordinating dien ligands, which link the rods into layers. The dien ligands here coexist in three different coordination modes: monodentate, bidentate and tridentate, which is rarely observed. Magnetic susceptibility measurements show the expected significant antiferromagnetic coupling interactions between all spin centers present in the title compound, namely the isotropic spin‐5/2 Mn2+ centers and the isotropic spin‐1/2 vanadyl groups, in line with most other heterometal‐substituted arsenato‐polyoxovanadate(IV) clusters. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
28. The Coordination Polymer Cr(en)2As2VO7 Consisting of Alternating VO4 Tetrahedra and As2O5 Handles Decorated by Cr3+ Centered Complexes.
- Author
-
Rasmussen, Maren, Näther, Christian, and Bensch, Wolfgang
- Subjects
- *
COORDINATION polymers , *HYDROGEN bonding interactions , *ABSORPTION spectra , *SURFACE analysis , *CRYSTAL structure , *TETRAHEDRA - Abstract
The new coordination polymer Cr(en)2As2VO7 (en=ethylenediamine) was synthesized under solvothermal conditions as deep red crystals. In the crystal structure VO4 tetrahedra and As2O5 handles formed by corner-sharing of two AsO3 pyramidal units are joined by common oxygen atoms into an undulated chain that is directed along the crystallographic b-axis. The chain is decorated by [Cr(en)2]3+ complexes with the Cr3+ cation having bonds to two terminal O2- anions of the As²O5 moiety thus generating a CrN4O2 octahedron, which displays a cis-configuration. The connection mode between Cr3+ and As2O5 leads to formation of a six-membered CrAs2O3 ring. The chains are arranged in a layer-like fashion in the (001) plane and these layers are stacked along [001]. A large number of N-H···O and C-H···O hydrogen bonds generate a three dimensional network. A Hirshfeld surface analysis was performed for visualizing the extended interchain interactions. The hydrogen bonding interactions are clearly detected in the IR spectrum. The UV-Vis spectrum shows an absorption at 2.3 eV which is in agreement with the red color of the sample. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
29. Unprecedented Connection Mode of [V 16 Sb 4 O 42 (H 2 O)] 8– Cluster Anions by Mn 2+ Centered Complexes: Solvothermal Synthesis and Properties of {[Mn(teta)] 4 V 16 Sb 4 O 42 (H 2 O}n·[(H 2 O) 12 ]n
- Author
-
Rasmussen, Maren, primary, Näther, Christian, additional, van Leusen, Jan, additional, Kögerler, Paul, additional, and Bensch, Wolfgang, additional
- Published
- 2017
- Full Text
- View/download PDF
30. Correction to Covalent Co–O–V and Sb–N Bonds Enable Polyoxovanadate Charge Control
- Author
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Rasmussen, Maren, primary, Näther, Christian, additional, van Leusen, Jan, additional, Kögerler, Paul, additional, Zhechkov, Lyuben, additional, Heine, Thoma, additional, and Bensch, Wolfgang, additional
- Published
- 2017
- Full Text
- View/download PDF
31. Covalent Co–O–V and Sb–N Bonds Enable Polyoxovanadate Charge Control
- Author
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Rasmussen, Maren, primary, Näther, Christian, additional, van Leusen, Jan, additional, Kögerler, Paul, additional, Zhechkov, Lyuben, additional, Heine, Thoma, additional, and Bensch, Wolfgang, additional
- Published
- 2017
- Full Text
- View/download PDF
32. 'Be og du skal få'
- Author
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Rasmussen, Maren Skuterud
- Subjects
Social science: 200::Economics: 210::Business: 213 [VDP] ,endringsledelse ,selvledelse - Abstract
Master's thesis in Change management Formålet med denne masterstudien har vært å undersøke om selvledelse og behovet for anerkjennelse kan stå i strid med hverandre i organisasjonen. Målet har vært å belyse hvordan opplever medarbeidere som leder seg selv å bli sett og anerkjent av ledelsen, og hvilke utfordringer kan oppstå hvis deres behov for anerkjennelse ikke dekkes. Metoden som er brukt i denne undersøkelsen er casestudie med kvalitative dybdeintervjuer. Datainnsamlingen er gjort med 12 informanter i et eiendomsutviklingsfirma. Resultatene fra undersøkelsen viser at som en konsekvens av bedriftens selvledelseskultur har det spunnet ut en be og du skal få kultur, fordi når medarbeidere leder seg selv ser ikke lederen hva de gjør, og de er nødt til å synliggjøre seg for ham og be om feedback og anerkjennelse for å få det. Resultatene viser at det er et gap mellom det å måtte be om feedback og anerkjennelse og behov for gjensidig feedback og gjensidig anerkjennelse hos et klart mindretall, og det er sannsynlig at god kollegastøtte virker kompenserende da felleskapet tillegges stor vekt. Utfordringene handler om å måtte selv ta initiativ, ikke verdsatt for ekstra innsats, ny og utrygg i rollen og grensesettingsproblemer.
- Published
- 2014
33. Expansion of Germanato-Polyoxovanadate Cluster Cores: Solvothermal Syntheses and Selected Properties of (trenH2)2[{M(tren)}4V15Ge6O48(H2O)] (M= Co and Zn)
- Author
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Wendt, Michael, primary, Rasmussen, Maren, additional, Näther, Christian, additional, and Bensch, Wolfgang, additional
- Published
- 2016
- Full Text
- View/download PDF
34. Small, beautiful and magnetically exotic: {V4W2}- and {V4W4}-type polyoxometalates
- Author
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Rasmussen, Maren, primary, Näther, Christian, additional, van Leusen, Jan, additional, Warzok, Ulrike, additional, Schalley, Christoph A., additional, Kögerler, Paul, additional, and Bensch, Wolfgang, additional
- Published
- 2016
- Full Text
- View/download PDF
35. ChemInform Abstract: A Keggin‐Type Structure Expanded by an Eight‐Membered Ring of Alternating Edge‐Sharing VO5 and VO6 Polyhedra: Solvothermal Synthesis, Crystal Structure, and Magnetic Properties.
- Author
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Rasmussen, Maren, primary, Naether, Christian, additional, van Leusen, Jan, additional, Koegerler, Paul, additional, and Bensch, Wolfgang, additional
- Published
- 2015
- Full Text
- View/download PDF
36. A Keggin-Type Structure Expanded by an Eight-Membered Ring of Alternating Edge-Sharing VO5and VO6Polyhedra: Solvothermal Synthesis, Crystal Structure, and Magnetic Properties
- Author
-
Rasmussen, Maren, primary, Näther, Christian, additional, van Leusen, Jan, additional, Kögerler, Paul, additional, and Bensch, Wolfgang, additional
- Published
- 2015
- Full Text
- View/download PDF
37. Unprecedented Connection Mode of [V16Sb4O42(H2O)]8- Cluster Anions by Mn2+ Centered Complexes: Solvothermal Synthesis and Properties of {[Mn(teta)]4V16Sb4O42(H2O} n·[(H2O)12] n
- Author
-
Rasmussen, Maren, Näther, Christian, Bensch, Wolfgang, van Leusen, Jan, and Kögerler, Paul
- Subjects
- *
MANGANESE compounds , *ANIONS , *VANADIUM oxide , *CRYSTAL structure , *CRYSTALLIZATION - Abstract
The new compound {[Mn(teta)]4V16Sb4O42} n ·[(H2O)12] n ( 1) was synthesized under solvothermal conditions. The crystal structure features the high nuclearity [V16IVSb4IIIO42(H2O)]8- cluster anion, which consists of two rings composed of 8 edge-sharing VO5 polyhedra. The rings are perpendicular to each other generating four niches, which are occupied by two VO5 pyramids and two handle-like Sb2O5 units. The two unique anions are each surrounded by eight Mn2+ centered complexes via Mn-Oterm-V bonds. Such an expansion has never been observed in heterometal polyoxovanadate chemistry. The connection mode between cluster anions and complex cations generates two individual layers stacked onto each other. Between the layers weak Sb ···O contacts are observed. The crystal water molecules are mainly located in the empty space between the layers. Upon heating H2O molecules are removed, while the crystal structure remains intact. The magnetic behavior is dominated by strong antiferromagnetic exchange interactions between the central V4+ ions, while the interaction between the cluster anion and central Mn2+ ions is significantly less pronounced. [ABSTRACT FROM AUTHOR]
- Published
- 2017
- Full Text
- View/download PDF
38. Unprecedented Connection Mode of [V16Sb4O42(H2O)]8- Cluster Anions by Mn2+ Centered Complexes: Solvothermal Synthesis and Properties of {[Mn(teta)]4V16Sb4O42(H2O} n·[(H2O)12] n
- Author
-
Rasmussen, Maren, Näther, Christian, Bensch, Wolfgang, van Leusen, Jan, and Kögerler, Paul
- Subjects
MANGANESE compounds ,ANIONS ,VANADIUM oxide ,CRYSTAL structure ,CRYSTALLIZATION - Abstract
The new compound {[Mn(teta)]
4 V16 Sb4 O42 }n ·[(H2 O)12 ]n ( 1) was synthesized under solvothermal conditions. The crystal structure features the high nuclearity [V16 IV Sb4 III O42 (H2 O)]8- cluster anion, which consists of two rings composed of 8 edge-sharing VO5 polyhedra. The rings are perpendicular to each other generating four niches, which are occupied by two VO5 pyramids and two handle-like Sb2 O5 units. The two unique anions are each surrounded by eight Mn2+ centered complexes via Mn-Oterm -V bonds. Such an expansion has never been observed in heterometal polyoxovanadate chemistry. The connection mode between cluster anions and complex cations generates two individual layers stacked onto each other. Between the layers weak Sb ···O contacts are observed. The crystal water molecules are mainly located in the empty space between the layers. Upon heating H2 O molecules are removed, while the crystal structure remains intact. The magnetic behavior is dominated by strong antiferromagnetic exchange interactions between the central V4+ ions, while the interaction between the cluster anion and central Mn2+ ions is significantly less pronounced. [ABSTRACT FROM AUTHOR]- Published
- 2017
- Full Text
- View/download PDF
39. Expansion of Germanato-Polyoxovanadate Cluster Cores: Solvothermal Syntheses and Selected Properties of (trenH2)2[{ M(tren)}4V15Ge6O48(H2O)] ( M = Co and Zn).
- Author
-
Wendt, Michael, Rasmussen, Maren, Näther, Christian, and Bensch, Wolfgang
- Subjects
- *
MOLECULAR clusters , *METAL complexes , *MOLECULAR shapes , *CHEMICAL synthesis , *TRANSITION metals - Abstract
Two germanato-polyoxovanadates with the {V15Ge6O48} cluster core are extended by covalent bonds to four transition metal amine complexes [ M(tren)]2+ ( M = Co and Zn, tren = tris(2-aminoethyl)amine). The complexes have bonds to terminal atoms of the Ge2O7 units and such expansion of a germanato-polyxovanadate was never observed before. The characterization of these compounds revealed the presence of two protonated tren molecules charge balancing the negative charges of the [{ M(tren)}4V15Ge6O48(H2O)]4- anion. [ABSTRACT FROM AUTHOR]
- Published
- 2017
- Full Text
- View/download PDF
40. Small, beautiful and magnetically exotic: {V4W2}- and {V4W4}-type polyoxometalates.
- Author
-
Rasmussen, Maren, Näther, Christian, van Leusen, Jan, Warzok, Ulrike, Schalley, Christoph A., Kögerler, Paul, and Bensch, Wolfgang
- Subjects
- *
POLYOXOMETALATES , *COORDINATION compounds , *FERROMAGNETISM , *OCTAHEDRA , *POLYOXOTUNGSTATES - Abstract
Minimal-nuclearity vanadato-tungstate clusters in [{VIV(dien)}4WVI2O14]·4H2O (1) and [{VIV(dien)}4WVI4O20]·6H2O (2) feature cores of edge-sharing WO6 octahedra, surrounded by a ring of four vanadyl groups. Surprisingly, the V(iv) centers in both 1 and 2 are ferromagnetically coupled, in contrast to all other known vanadato-polyoxotungstates featuring the ubiquituos V–O–W–O–V exchange pathways. [ABSTRACT FROM AUTHOR]
- Published
- 2016
- Full Text
- View/download PDF
41. A Keggin-Type Structure Expanded by an Eight-Membered Ring of Alternating Edge-Sharing VO5 and VO6 Polyhedra: Solvothermal Synthesis, Crystal Structure, and Magnetic Properties.
- Author
-
Rasmussen, Maren, Näther, Christian, van Leusen, Jan, Kögerler, Paul, and Bensch, Wolfgang
- Subjects
- *
CRYSTAL structure , *KEGGIN anions , *ANTIFERROMAGNETIC materials , *SPIN-spin interactions , *ELECTRON delocalization - Abstract
The new tungstovanadate (trenH)2(trenH2)2[W4V13O44]· ca.11H2O was prepared under solvothermal conditions in a basic solution at pH ≈ 12. The cluster core contains VIV/VV centers with delocalized spins exhibiting strong antiferromagnetic exchange interactions as evidenced by temperature-dependent magnetic susceptibility measurements pointing to an S = 1/2 magnetic ground state. The structure features an eight-membered ring composed of four alternating edge-sharing VO5 pyramids and VO6 octahedra encapsulating a central Keggin fragment. [ABSTRACT FROM AUTHOR]
- Published
- 2015
- Full Text
- View/download PDF
42. Covalent Co-O-V and Sb-N Bonds Enable Polyoxovanadate Charge Control
- Author
-
Rasmussen, Maren, Näther, Christian, Van Leusen, Jan, Kögerler, Paul, Zhechkov, Lyuben, Heine, Thoma, and Bensch, Wolfgang
- Subjects
3. Good health - Abstract
Inorganic chemistry 56(12), 7120-7126 (2017). doi:10.1021/acs.inorgchem.7b00724, Published by American Chemical Society, Washington, DC
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