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1. Unusual palladium-catalyzed silaboration of allenes using organic iodides as initiators: Mechanism and application

Author

Kuo-Jui Chang, Rayabarapu, Kumar, Feng-Yu Yang, and Chien-Hong Cheng

Subjects
Palladium -- Chemical properties, Iodides -- Chemical properties, Chemistry
Abstract

A new and efficient method for silaboration of allenes catalyzed by palladium complexes and initiated by organic iodides is demonstrated. The method provides a convenient and general route to various 2-silylallylboronates in good yields with excellent regio- and stereoselectivity.

Published
2005

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