1. Synergistic ORR catalysis: WS2/CeO2 composite in microbial fuel cells.
- Author
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Rezaei, Ali, Zarenezhad, Hassan, Aber, Soheil, and Teimuri-Mofrad, Reza
- Subjects
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MICROBIAL fuel cells , *CERIUM oxides , *ELECTROCHEMICAL analysis , *CHEMICAL oxygen demand , *OPEN-circuit voltage , *CATALYSIS - Abstract
In this work, WS 2 /CeO 2 heterostructured composite was synthesized to develop a highly active cathodic electrocatalyst in a microbial fuel cell (MFC). The layered structure and distinctive properties of WS 2 (semiconductor behavior, stability, tunable properties, superconductivity, etc.), coupled with the oxygen storage capabilities of CeO 2 , form the basis of this composite approach. Comprehensive characterization techniques confirmed the successful synthesis and highlighted the unique properties of the composite. Electrochemical analyses revealed the enhanced catalytic activity of the WS 2 /CeO 2 composite for ORR. Cyclic voltammetry (CV) and linear sweep voltammetry (LSV) studies demonstrated improved kinetics and current density compared to individual WS 2 and CeO 2 components. Electrochemical impedance spectroscopy (EIS) underscored the collaborative behavior of the composite, leading to improved charge transfer efficiency at the electrode-electrolyte interface. Practical application of the WS 2 /CeO 2 composite in a dual-chamber MFC revealed its potential for enhanced power generation and pollutant removal. The composite cathode exhibited superior performance in terms of power density (129.13 mW/m2), open-circuit voltage (609 mV), and chemical oxygen demand (COD) removal efficiency (76.6%) compared to conventional graphite cathodes. The efficient strategy of using the modified cathode, which exhibit excellent stability, high electric energy output, and simple fabrication, was proven to improve the overall performance of MFC. [Display omitted] [ABSTRACT FROM AUTHOR]
- Published
- 2024
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