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In an eastern-Pacific coral assemblage at Devil’s Crown, Galapagos Islands, Ecuador, two coral species, Psammocora stellata and Cycloseris (Diaseris) distorta, form dense populations of unattached colonies on sand and rubble substrata. In the Galapagos, living C. (D.) distorta is found only at this single site, whereas populations of P. stellata are found throughout the Archipelago. Six cores dating to ~ 7700 yBP showed P. stellata to be dominant throughout the history of this isolated community, but C. (D.) distorta increased in abundance from ~ 2200 yBP and reached peak abundance between 1471 yBP and the present. The relative frequency of the two coral species may be linked to millennial-scale climatic variability, and this site may represent a refuge for C. (D.) distorta from unfavorable climatic fluctuations on millennial timescales. Our results demonstrate that some corals can persist in isolated populations for millennia.

In this study, we present a Holocene rainfall index based on three high-resolution speleothem records from the Western Mediterranean, a region under the influence of the westerly winds belt modulated by the North Atlantic Oscillation (NAO). On centennial to millennial timescales, we show that the North Atlantic ice-rafting events were likely associated with negative NAO-like conditions during the Early Holocene and the Late Holocene. However, our data reveal that this is not clearly the case for the mid-Holocene ice-rafting events, during which we also show evidence of positive NAO-like patterns from other paleo-oceanographic and paleo-atmospheric data. Hence, contradictory mechanisms involving prolonged periods of both north and south shifts of the westerly winds belt (resembling positive and negative NAO-like patterns) might at least partially trigger or amplify the ice-rafting events and the slowdown of the Atlantic Meridional Overturning Circulation. Plain Language Summary During the Holocene, periods of enhanced ice-rafting, associated with cooling and sea ice expansion in the North Atlantic high latitudes, have been recognized over distant regions. While the causes of these events are still a matter of debate, changes in the atmospheric circulation have been proposed as a potential trigger or amplifier. Here, we use speleothems to establish a precisely dated record of rainfall variability in the Western Mediterranean, a highly sensitive region to the westerly winds belt modulated by the North Atlantic Oscillation. Our results reveal new insights about the dynamics of NAO-like patterns during the Holocene. On centennial to millennial timescales, prolonged periods of both north and south shifts of the westerly winds belt might trigger or amplify the slowdown of the Atlantic Meridional Overturning Circulation and the North Atlantic ice-rafting. However, not all ice-rafting events are associated with either positive or negative NAO-like conditions.

The “4.2 ka event” is frequently described as a major global climate anomaly between 4.2 and 3.9 ka, which defines the beginning of the current Meghalayan age in the Holocene epoch. The “event” has been disproportionately reported from proxy records from the Northern Hemisphere, but its climatic manifestation remains much less clear in the Southern Hemisphere. Here, we present highly resolved and chronologically well-constrained speleothem oxygen and carbon isotopes records between ∼6 and 3 ka from Rodrigues Island in the southwestern subtropical Indian Ocean, located ∼600 km east of Mauritius. Our records show that the 4.2 ka event did not manifest itself as a period of major climate change at Rodrigues Island in the context of our record's length. Instead, we find evidence for a multi-centennial drought that occurred near-continuously between 3.9 and 3.5 ka and temporally coincided with climate change throughout the Southern Hemisphere.

First Greenland speleothem record indicates warmer and wetter climate between c.588 and c.549 ka ago., The five interglacials before the Mid-Brunhes Event (MBE) [c.430 thousand years (ka) ago] are generally considered to be globally cooler than those post-MBE. Inhomogeneities exist regionally, however, which suggest that the Arctic was warmer than present during Marine Isotope Stage (MIS) 15a. Using the first speleothem record for the High Arctic, we investigate the climatic response of northeast Greenland between c.588 and c.549 ka ago. Our results indicate an enhanced warmth of at least +3.5°C relative to the present, leading to permafrost thaw and increased precipitation. We find that δ18O of precipitation was at least 3‰ higher than today and recognize two local cooling events (c.571 and c.594 ka ago) thought to be caused by freshwater forcing. Our results are important for improving understanding of the regional climatic response leading up to the MBE and specifically provide insights into the climatic response of a warmer Arctic.

Cryogenic cave carbonates (CCC) are rare speleothems that form when water freezes inside cave ice bodies. CCC have been used as an proxy for permafrost degradation, permafrost thickness, or subsurface ice formation. The presence of these minerals is usually attributed to warm periods of permafrost degradation. We found coarse crystalline CCC types within transparent, massive congelation ice in two Pyrenean ice caves in the Monte Perido Massif: Devaux, located on the north face at 2828 m a.s.l., and Sarrios 6, located in the south face at 2780 m a.s.l. The external mean annual air temperature (MAAT) at Devaux is ~ 0°C, while at Sarrios 6 is ~ 2.5°C. In the Monte Perdido massif discontinuous permafrost is currently present between 2750 and 2900 m a.s.l. and is more frequent above 2900 m a.s.l. in northern faces. In Devaux, air and rock temperatures, as well as the presence of hoarfrost and the absence of drip sites indicate a frozen host rock. Moreover, a river flows along the main gallery, and during winters the water freezes at the spring causing backflooding in the cave. In contrast, Sarrios 6 has several drip sites, although the gallery where CCC were collected is hydrologically inactive. This gallery opened in recent years due to ice retreat. During spring, water is present in the gallery due to the overflow of ponds forming beneath drips. CCC commonly formed as sub-millimeter-size spherulites, rhombohedrons and rafts. 230Th ages of the same CCC morphotype indicate that their formation took place at 1953±7, 1959±14, 1957±14, 1958±15, 1974±16 CE in Devaux, while in Sarrios 6 they formed at 1964±5, 1992±2, 1996±1 CE. The cumulative probability density function indicates that the most probable formation occurred 1957-1965 and 1992-1997. The instrumental temperature record at 2860 m a.s.l. indicates positive MAAT in 1964 (0.2°C) and 1997 (0.8°C). CCC formation could thus correspond with those two anomalously warm years. The massive and transparent ice would indicate a sudden ingress of water and subsequent slow freezing inside both caves during those years. Probably, CCC formation took place at a seasonal scale during the annual cycle.

[1] Abrupt decreases of the Atlantic meridional overturning circulation (MOC) during the Late Pleistocene have been directly linked to catastrophic discharges of glacimarine freshwater, triggering disruption of northward marine heat transport and causing global climate changes. Here we provide measurements of excess sedimentary 231 Pa/ 230 Th from a high-accumulation sediment drift deposit in the NE Atlantic that record a sequence of sudden variations in the rate of MOC, associated deep ocean ventilation and surface-ocean climatology. The data series reveal a sequential decrease in the MOC rate at � 18.0 ka BP ago that coincides with only transient and localized freshwater inputs. This change represents a substantial, though not total, cessation in MOC that predates the major Heinrich (H1) meltwater event by at least 1,200 years. These results highlight the potential of targeted freshwater perturbations in promoting substantial MOC changes without a direct linking with catastrophic freshwater surges. Citation: Hall, I. R., S. B. Moran, R. Zahn, P. C. Knutz, C.-C. Shen, and R. L. Edwards (2006), Accelerated drawdown of meridional overturning in the late-glacial Atlantic triggered by transient pre-H event freshwater perturbation, Geophys. Res. Lett., 33, L16616, doi:10.1029/2006GL026239.

A new paleoclimate record from Cyprus gives valuable insights into climatic variations during Marine Isotope Stages (MIS) 6–5 for the East Mediterranean region. Two stalagmites from Pentadactylos cave in the Kyrenia mountain range (800 m altitude) in Cyprus grew from 174.6 ± 0.7 to 112.2 ± 0.5 ka BP with major hiatuses at 163–142 and 132–128 ka. During early MIS6 the stalagmite suggests through a relatively low growth rate (57–5 mm/ka) and variable, but rather negative d18O that climate conditions were highly variable on a millennial scale, with wet and cold climate conditions during Sapropel 6 deposition. At the end of MIS6 (141–132 ka), growth rate varied from 123 to 18 mm/ka and less negative δ 18 O c suggests general dry/cold conditions followed by a growth stop during H11. The onset of MIS5e is marked by the highest growth rate (217 mm/ka). The most negative δ18O values at the onset and during the Eemian wet period in Cyprus are driven mostly by the source effect (Sapropel 5) and enhanced rainfall amounts. Stable conditions during MIS 5e were rather short as shown in the growth and isotopic signal, consistent with other EM records. After 122 ka, growth decreased drastically (8–2 mm/ka) and a slow deterioration of the soil cover is suggested from continuously less negative δ13C values. Fluid inclusion d18O shows a clear shift (4–5‰) between end-MIS 6 and MIS 5e. Clumped isotopes measurements indicate kinetic effects between calcite and water of up to ∼1‰. After correction for kinetic effects using Δ47, a minimum estimate for the MIS 6–5 temperature shift in the EM is ca. 9 °C. Similarly, drastic changes in rainfall amounts are inferred from measured (fluid inclusion) and calculated water d18O.

Accurate estimation of central tropical Pacific (CTP) climate variability on interannual to centennial time scales is required for robust projections of future global climate trends. Here we outline an approach that blends instrumental and coral proxy observations to yield a continuous, monthly resolved record of climate evolution in the CTP spanning the past 160 years. We concatenate coral oxygen isotope (δ¹⁸O) records from multiple living and fossil corals collected from Fanning Island (4°N, 160°W) and Palmyra Island (5°N; 162°W) located in the heart of the El Nino–Southern Oscillation. We use the regularized expectation maximization (RegEM) method to impute missing data across short gaps of 5 to 23 years within and beyond individual coral records. The resulting monthly resolved Fanning/Palmyra Island climate record spans continuously from 1863 to 2016 and provides an example of how extended time series can be built from shorter coral segments. The extended record highlights the strong trend toward warmer and wetter mean conditions in late twentieth century, in agreement with the majority of climate model hindcast simulations. The continuous reconstruction also enables a direct comparison of four exceptionally strong El Nino events (1877–1878, 1940–1941, 1997–1998, and 2015–2016). Three of these very strong El Nino events in the CTP featured a precursor warm event in the prior year and that may have favored the development of a strong El Nino event.

Thermophilisation is the response of plants communities in mountainous areas to increasing temperatures, causing an upward migration of warm-adapted (thermophilic) species and consequently, the timberline. This greening, associated with warming, causes enhanced evapotranspiration that leads to intensification of the hydrological cycle, which is recorded by hydroclimate-sensitive archives, such as stalagmites and flowstones formed in caves. Understanding how hydroclimate manifests at high altitudes is important for predicting future water resources of many regions of Europe that rely on glaciers and snow accumulation. Using proxy data from three coeval speleothems (stalagmites and flowstone) from the Italian Alps, we reconstructed both the ecosystem and hydrological setting during the Last Interglacial (LIG); a warm period that may provide an analogue to a near-future climate scenario. Our speleothem proxy data, including calcite fabrics and the stable isotopes of calcite and fluid inclusions, indicate a +4.3 ± 1.6 °C temperature anomaly at ~2000 m a.s.l. for the peak LIG, with respect to present-day values (1961–1990). This anomaly is significantly higher than any low-altitude reconstructions for the LIG in Europe, implying elevation-dependent warming during the LIG. The enhanced warming at high altitudes must be accounted for when considering future climate adaption strategies in sensitive mountainous regions.

Petrographic features, mineralogy, and stable isotopes from two stalagmites, ANJB-2 and MAJ-5, respectively from Anjohibe and Anjokipoty caves, allow distinction of three intervals of the Holocene in NW Madagascar. The Malagasy early Holocene (between ca. 9.8 and 7.8 ka) and late Holocene (after ca. 1.6 ka) intervals (MEHI and MLHI, respectively) record evidence of stalagmite deposition. The Malagasy middle Holocene interval (MMHI, between ca. 7.8 and 1.6 ka) is marked by a depositional hiatus of ca. 6500 years. Deposition of these stalagmites indicates that the two caves were sufficiently supplied with water to allow stalagmite formation. This suggests that the MEHI and MLHI intervals may have been comparatively wet in NW Madagascar. In contrast, the long-term depositional hiatus during the MMHI implies it was relatively drier than the MEHI and the MLHI. The alternating wet–dry–wet conditions during the Holocene may have been linked to the long-term migrations of the Intertropical Convergence Zone (ITCZ). When the ITCZ's mean position is farther south, NW Madagascar experiences wetter conditions, such as during the MEHI and MLHI, and when it moves north, NW Madagascar climate becomes drier, such as during the MMHI. A similar wet–dry–wet succession during the Holocene has been reported in neighboring locations, such as southeastern Africa. Beyond these three subdivisions, the records also suggest wet conditions around the cold 8.2 ka event, suggesting a causal relationship. However, additional Southern Hemisphere high-resolution data will be needed to confirm this.

We present two isotopic (δ18O and δ13C) sequences of a twin-stalagmite from Zhuliuping Cave, southwestern China, with 230Th dates from 14.6 to 4.6 ka. The stalagmite δ18O record characterizes orbital- to decadal-scale variability of Asian summer monsoon (ASM) intensity, with the Holocene optimum period (HOP) between 9.8 and 6.8 ka BP which is reinforced by its co-varying δ13C data. The large multi-decadal scale amplitude of the cave δ18O indicates its high sensitivity to climate change. Four centennial-scale weak ASM events during the early Holocene are centered at 11.2, 10.8, 9.1 and 8.2 ka. They can be correlated to cold periods in the northern high latitudes, possibly resulting from rapid dynamics of atmospheric circulation associated with North Atlantic cooling. The 8.2 ka event has an amplitude more than two-thirds that of the Younger Dryas (YD), and is significantly stronger than other cave records in the Asia monsoon region, likely indicating a more severe dry climate condition at the cave site. At the end of the YD event, the δ13C record lags the δ18O record by 300–500 yr, suggesting a multi-centennial slow response of vegetation and soil processes to monsoon enhancement.

We present two isotopic (δ18O and δ13C) sequences of a twin-stalagmite from Zhuliuping Cave, southwestern China, with 230Th dates from 14.6 to 4.6 ka. The stalagmite δ18O record characterizes orbital- to decadal-scale variability of Asian summer monsoon (ASM) intensity, with the Holocene optimum period (HOP) between 9.8 and 6.8 ka BP which is reinforced by its co-varying δ13C data. The large multi-decadal scale amplitude of the cave δ18O indicates its high sensitivity to climate change. Four centennial-scale weak ASM events during the early Holocene are centered at 11.2, 10.8, 9.1 and 8.2 ka. They can be correlated to cold periods in the northern high latitudes, possibly resulting from rapid dynamics of atmospheric circulation associated with North Atlantic cooling. The 8.2 ka event has an amplitude more than two-thirds that of the Younger Dryas (YD), and is significantly stronger than other cave records in the Asia monsoon region, likely indicating a more severe dry climate condition at the cave site. At the end of the YD event, the δ13C record lags the δ18O record by 300–500 yr, suggesting a multi-centennial slow response of vegetation and soil processes to monsoon enhancement.

Accurate and precise chronologies are essential in understanding the rapid and recurrent climate variations of the Last Glacial – known as Dansgaard-Oeschger (D-O) events – found in the Greenland ice cores and other climate archives. The existing chronological uncertainties during the Last Glacial, however, are still large. Radiometric age data and stable isotopic signals from speleothems are promising to improve the absolute chronology. We present a record of several precisely dated stalagmites from caves located at the northern rim of the Alps (NALPS), a region that favours comparison with the climate in Greenland. The record covers most of the interval from 120 to 60 ka at an average temporal resolution of 2 to 22 yr and 2σ-age uncertainties of ca. 200 to 500 yr. The rapid and large oxygen isotope shifts of 1 to 4.5‰ occurred within decades to centuries and strongly mimic the Greenland D-O pattern. Compared to the updated Greenland ice-core timescale (GICC05modelext) the NALPS record confirms the timing of rapid warming and cooling transitions between 118 and 106 ka, but suggests younger ages for D-O events between 106 and 60 ka. As an exception, the timing of the rapid transitions into and out of the stadial following GI 22 is earlier in NALPS than in the Greenland ice-core timescale. In addition, there is a discrepancy in the duration of this stadial between the ice-core and the stalagmite chronology (ca. 2900 vs. 3650 yr). The short-lived D-O events 18 and 18.1 are not recorded in NALPS, provoking questions with regard to the nature and the regional expression of these events. NALPS resolves recurrent short-lived climate changes within the cold Greenland stadial and warm interstadial successions, i.e. abrupt warming events preceding GI 21 and 23 (precursor-type events) and at the end of GI 21 and 25 (rebound-type events), as well as intermittent cooling events during GI 22 and 24. Such superimposed events have not yet been documented outside Greenland.

Coarse crystalline cryogenic cave carbonates (CCCcoarse) dated to the last glacial period are common in central European caves and provide convincing evidence of palaeo-permafrost during this time. Little is known, however, about the exact nature of the environment in which CCCcoarse formed as no modern analogue setting is known. Here, we report the first findings of sub-recent, albeit inactive, CCCcoarse from a cave of the Western Alps which is located in the present-day permafrost zone. The globular shape and the presence of ubiquitous euhedral crystal terminations are comparable to previously described aggregates from the last glacial period and strongly suggest that these aggregates formed subaqueously in pools lacking agitation. Furthermore, stable isotope values of mm-sized spheroids point to calcite precipitation in a closed system with respect to CO2 strongly supporting the hypothesis of a cryogenic origin associated with the freezing of water ponds. U-series analyses revealed three clusters of late Holocene calcite precipitation intervals between 2129 and 751 a b2k. These ages correlate with known periods of elevated summer temperatures, suggesting that warming and thawing of the permafrozen catchment above the cave allowed water infiltration into the karst system. The growth of CCCcoarse resulted from the re-freezing of this water in the still cold karst cavities.

A global array of proxy records suggests that the 4.2 ka event marks an ~ 300-year period of major climate anomaly. However, the climatic manifestation of this event, including its onset, duration, and termination, remain less clear in the Indian summer monsoon (ISM) domain. Here, we present a new speleothem oxygen isotope (δ 18 O) record from Mawmluh Cave, Northeast India, which provides an annually-resolved record of changes in ISM strength between ~ 4.440 and 3.780 ka BP. Our δ 18 O record is constrained by 18 230 Th dates with an average age uncertainty of p13 years and a dating resolution of ~ 40 years, which allow us to characterize the timing and structure of the 4.2 ka event with an unprecedented detail. The overall expression of the 4.2 ka event in our record shares broad similarities with a previous δ 18 O record from the Mawmluh Cave as well as with other previous lower-resolution proxy reconstructions of the ISM. However, unlike some previous ISM records, where the 4.2 ka event has been described as a singular multi-centennial period of anomalously weak ISM, our data suggest a more variable response of ISM during this period. The 4.2 ka event in our record exhibits a three-stage structure, characterized by highly variable ISM between ~ 4.255 and 4.070 ka BP and a distinct pluvial phase from ~ 4.070–4.010 ka BP. The latter abruptly ( 10 years) culminated into a relatively weaker phase of ISM, which was punctuated by a number of multidecadal periods of anomalously drier conditions. While, our record shows evidence of a discernible beginning for the 4.2 ka event, there is no clear evidence of its end in thus, suggesting that the ISM experienced a major regime-shift or transition at ~ 4.0 ka BP.

In this study we present dissolved and particulate 230Th and 232Th results, as well as particulate 234Th data, obtained as part of the GEOTRACES central Arctic Ocean sections GN04 (2015) and IPY11 (2007). Samples were analyzed following GEOTRACES methods and compared to previous results from 1991. We observe significant decreases in 230Th concentrations in the deep waters of the Nansen Basin. We ascribe this nonsteady state removal process to a variable release and scavenging of trace metals near an ultraslow spreading ridge. This finding demonstrates that hydrothermal scavenging in the deep‐sea may vary on annual time scales and highlights the importance of repeated GEOTRACES sections.

The Levant constitutes an important region for assessing linkages between climate and societal changes throughout the course of human history. However, large uncertainties remain in our understanding of the region's hydroclimate variability under varying boundary conditions. Here we present a new high-resolution, precisely dated speleothem oxygen-carbon isotope and Sr/Ca records, spanning the last 20 ka from Jeita Cave, northern Levant. Our record reveals a higher (lower) precipitation-evaporation (P-E) balance during the Last Glacial Maximum and Bolling interstadial (Heinrich stadial 1). The early-middle Holocene is characterized by a trend toward higher P-E state, culminating between similar to 7 and 6 ka. The middle-late Holocene is characterized by two millennial-length drier periods during 5.3-4.2 and 2.8-1.4 ka. On submillennial time scale, the northern Levant climate variability is dominated by 500 year periodicity. Comparisons with the regional proxy records suggest persistent out-of-phase climate variability between the northern and southern Levant on a wide range of timescales.

The West Antarctic Ice Sheet Divide (WAIS Divide, WD) ice core is a newly drilled, high-accumulation deep ice core that provides Antarctic climate records of the past ∼68 ka at unprecedented temporal resolution. The upper 2850 m (back to 31.2 ka BP) have been dated using annual-layer counting. Here we present a chronology for the deep part of the core (67.8–31.2 ka BP), which is based on stratigraphic matching to annual-layer-counted Greenland ice cores using globally well-mixed atmospheric methane. We calculate the WD gas age–ice age difference (Δage) using a combination of firn densification modeling, ice-flow modeling, and a data set of δ15N-N2, a proxy for past firn column thickness. The largest Δage at WD occurs during the Last Glacial Maximum, and is 525 ± 120 years. Internally consistent solutions can be found only when assuming little to no influence of impurity content on densification rates, contrary to a recently proposed hypothesis. We synchronize the WD chronology to a linearly scaled version of the layer-counted Greenland Ice Core Chronology (GICC05), which brings the age of Dansgaard–Oeschger (DO) events into agreement with the U/Th absolutely dated Hulu Cave speleothem record. The small Δage at WD provides valuable opportunities to investigate the timing of atmospheric greenhouse gas variations relative to Antarctic climate, as well as the interhemispheric phasing of the "bipolar seesaw".

The mid-Holocene dynamics of the East Asian Monsoon (EAM) and Indian Monsoon (IM) are important for understanding the Holocene climate system. To clarify the relationship between EAM and IM subsystems during the mid-Holocene, a 2085-year (6,270–4,185 a BP) high-resolution record from stalagmite (FL4) in Yunnan, China was reconstructed using ICP-MS-230Th series dating and carbon and oxygen isotope analysis (δ13C and δ18O). In the study period, successive positive δ18O trends revealed a generally weakening Asian monsoon, with the monsoon climate tending toward gradual drying, especially during three centennial-scale drought events in 6,270–6,126 a BP, 5,347–5,140 a BP, and 4,810–4,620 a BP. On the other hand, the uninterrupted negative trend in δ13C signified natural improvements in vegetation overlying the cave, and a serious deficit (~2.5 ‰) in δ13C during 5,519–5,345 a BP implied a heavy rainfall event, in precise phase with δ18O, demonstrating an enhanced Indian Monsoon subsystem. The dense sawtooth-shaped pattern of the carbon and oxygen isotope records indicates that a series of decadal-scale abrupt climate changes were superimposed on the centennial-scale monsoon climate changes. FL4 stalagmite records in the mid-Holocene reflect a gradually weakening monsoon climate with superimposed decadal–centennial events, but natural improvements in local vegetation through self-adjustment.

International audience; Uranium-series data provide essential dating and tracer tools for a broad spectrum of geologic processes. Data reported in U-series geochronology studies often contain insufficient information to completely assess the data collected. It is frequently not possible to calculate a date using the information provided or to re-calculate using different parameters, ultimately limiting the value of the data. The decay constants used are particularly important in that some of the relevant U-series isotopes have been revised. Here we provide a rationale for a minimum set of required data that will enable most calculations and facilitate later data comparisons. Along with these data reporting norms, we discuss additional metadata that will improve understanding of the data and also enhance the ability to re-interpret and assess them in the context of other studies. We posit that these recommendations will provide a foundation for increasing the longevity and usefulness of measurements in the discipline of U-series geochronology. (C) 2017 The Authors. Published by Elsevier B.V.

International audience

This paper focuses on the climate variability in central China since AD 1300, involving: (1) a well-dated, 1.5-year resolution stalagmite δ18O record from Lianhua Cave, central China (2) links of the δ18O record with regional dry–wet conditions, monsoon intensity, and temperature over eastern China (3) correlations among drought events in the Lianhua record, solar irradiation, and ENSO (El Niño–Southern Oscillation) variation. We present a highly precise, 230Th / U-dated, 1.5-year resolution δ18O record of an aragonite stalagmite (LHD1) collected from Lianhua Cave in the Wuling Mountain area of central China. The comparison of the δ18O record with the local instrumental record and historical documents indicates that (1) the stalagmite δ18O record reveals variations in the summer monsoon intensity and dry–wet conditions in the Wuling Mountain area. (2) A stronger East Asian summer monsoon (EASM) enhances the tropical monsoon trough controlled by ITCZ (Intertropical Convergence Zone), which produces higher spring quarter rainfall and isotopically light monsoonal moisture in the central China. (3) The summer quarter/spring quarter rainfall ratio in central China can be a potential indicator of the EASM strength: a lower ratio corresponds to stronger EASM and higher spring rainfall. The ratio changed from 1 after 1950, reflecting that the summer quarter rainfall of the study area became dominant under stronger influence of the Northwestern Pacific High. Eastern China temperatures varied with the solar activity, showing higher temperatures under stronger solar irradiation, which produced stronger summer monsoons. During Maunder, Dalton and 1900 sunspot minima, more severe drought events occurred, indicating a weakening of the summer monsoon when solar activity decreased on decadal timescales. On an interannual timescale, dry conditions in the study area prevailed under El Niño conditions, which is also supported by the spectrum analysis. Hence, our record illustrates the linkage of Asian summer monsoon precipitation to solar irradiation and ENSO: wetter conditions in the study area under stronger summer monsoon during warm periods, and vice versa. During cold periods, the Walker Circulation will shift toward the central Pacific under El Niño conditions, resulting in a further weakening of Asian summer monsoons.

Speleothem records in southeastern China provide key evidence for past environmental changes. However, the climatic interpretation of these proxies has remained a great controversy. Earlier work interprets the cave δ18O signal associated with regional rainfall of the East Asia Summer Monsoon (EASM) or monsoon rainfall upstream of China. Recent isotope modeling supports the latter but show little correspondence between the precipitation δ18O and rainfall in China. Here, we examine the evolution of the climate and precipitation δ18O for the last 21,000 years in models and observations. Recognizing the regional difference of the EASM rainfall, we propose an interpretation of the Chinese δ18O record that reconciles its representativeness of EASM and its driving mechanism of upstream depletion. The δ18O records do represent the intensity of the EASM system. The monsoon intensity is best characterized by enhanced southerly monsoon winds, which correlate strongly with negative δ18O over China and enhanced monsoon rainfall in northern China, as well as the continental scale Asian monsoon rainfall response in the upstream regions.

Precession-related forcing of seasonal insolation changes in the northern hemisphere (NH) alternates between maximum NH seasonality (summer perihelion–increased insolation; winter aphelion–decreased insolation) and minimum NH seasonality (summer aphelion, and winter perihelion). With maximum NH seasonality, climate models simulate stronger NH summer monsoons that bring increased precipitation to North Africa and South and East Asia, in agreement with the in-phase relation of precipitation and NH summer insolation found in many paleoclimatic records. However paleoclimatic records in parts of the Mediterranean, the Middle East, and the interior of Asia also indicate increased moisture at times of maximum NH seasonality, a change not always clearly linked to stronger summer monsoons—either because these regions are at or beyond the boundaries of the present-day monsoon or because the observations allow multiple causal interpretations, or both. This study focuses on the possible role of changes in NH winter climate in explaining these wetter episodes. Using climate model simulations, we show that the ‘NH winter aphelion–decreased NH winter insolation’ orbital configuration is linked to the Mediterranean storm track and increased winter rains in the Mediterranean, the Middle East, and interior Asia. We conclude that wetter periods at precession time scales in these particular regions may have resulted either from increased wintertime storm track precipitation, or from a combination of increased winter and summer rainfall. Given this seasonal ambiguity, both possibilities need to be considered.

ENSO Variability The El Niño–Southern Oscillation (ENSO) is the most energetic, quasiperiodic climate oscillation in the world—every few years warming large expanses of the surface equatorial Pacific Ocean surface and impacting temperatures and rainfall patterns across the globe. A pressing question, in the context of global warming, is whether ENSO might be affected by the rising atmospheric temperatures caused by anthropogenic greenhouse gas emissions. Climate models do not agree on the answer to this question, but one place to look for data about how global temperatures might influence ENSO is the record of past ENSO variability. Cobb et al. (p. 67 ) present a record of ENSO variability spanning the past 7000 years, in an attempt better to define its response to insolation forcing over this same period. The findings reveal high variability in ENSO behavior that has no clear dependence on insolation, which implies that a link to warming, if it exists, may be difficult to detect.

WOS:000391139900001; International audience; Deposition of continental mineral aerosols (dust) in the Eastern Tropical North Atlantic Ocean, between the coast of Africa and the Mid-Atlantic Ridge, was estimated using several strategies based on the measurement of aerosols, trace metals dissolved in seawater, particulate material filtered from the water column, particles collected by sediment traps and sediments. Most of the data used in this synthesis involve samples collected during US GEOTRACES expeditions in 2010 and 2011, although some results from the literature are also used. Dust deposition generated by a global model serves as a reference against which the results from each observational strategy are compared. Observation-based dust fluxes disagree with one another by as much as two orders of magnitude, although most of the methods produce results that are consistent with the reference model to within a factor of 5. The large range of estimates indicates that further work is needed to reduce uncertainties associated with each method before it can be applied routinely to map dust deposition to the ocean. Calculated dust deposition using observational strategies thought to have the smallest uncertainties is lower than the reference model by a factor of 2-5, suggesting that the model may overestimate dust deposition in our study area. This article is part of the themed issue 'Biological and climatic impacts of ocean trace element chemistry'.

Earthquakes hit urban centres in Europe infrequently, but occasionally with disastrous effects. Obtaining an unbiased view of seismic hazard (and risk) is therefore very important. In principle, the best way to test probabilistic seismic hazard assessments (PSHAs) is to compare them with observations that are entirely independent of the procedure used to produce PSHA models. Arguably, the most valuable information in this context should be information on long-term hazard, namely maximum intensities (or magnitudes) occurring over time intervals that are at least as long as a seismic cycle. The new observations can provide information of maximum intensity (or magnitude) for long timescale as an input data for PSHA studies as well. Long-term information can be gained from intact stalagmites in natural caves. These formations survived all earthquakes that have occurred over thousands of years, depending on the age of the stalagmite. Their 'survival' requires that the horizontal ground acceleration (HGA) has never exceeded a certain critical value within that time period. Here, we present such a stalagmite-based case study from the Little Carpathians of Slovakia. A specially shaped, intact and vulnerable stalagmite in the Plavecka priepast cave was examined in 2013. This stalagmite is suitable for estimating the upper limit of horizontal peak ground acceleration generated by prehistoric earthquakes. The critical HGA values as a function of time going back into the past determined from the stalagmite that we investigated are presented. For example, at the time of Joko event (1906), the critical HGA value cannot have been higher than 1 and 1.3 m/s(2) at the time of the assumed Carnuntum event (similar to 340 AD), and 3000 years ago, it must have been lower than 1.7 m/s(2). We claimed that the effect of Joko earthquake (1906) on the location of the Plavecka priepast cave is consistent with the critical HGA value provided by the stalagmite we investigated. The approach used in this study yields significant new constraints on the seismic hazard, as tectonic structures close to Plavecka priepast cave did not generate strong earthquakes in the last few thousand years. The results of this study are highly relevant given that the two capitals, Vienna and Bratislava, are located within 40 and 70 km of the cave, respectively. Web of Science 21 5 1130 1111

Middle Holocene cultures have been widely studied around the Eastern-Mediterranean basin in the last 30 years and past cultural activities have been commonly linked with regional climate changes. However, in many cases such linkage is equivocal, in part due to existing climatic evidence that has been derived from areas outside the distribution of ancient settlements, leading to uncertainty from complex spatial heterogeneity in both climate and demography. A few high-resolution well-dated paleoclimate records were recently established using speleothems in the Central and Eastern-Mediterranean basin, however, the scarcity of such records in the western part of the Mediterranean prevents us from correlating past climate evolutions across the basin and deciphering climate–culture relation at fine timescales. Here we report the first decadal-resolved Mid-Holocene climate proxy records from the Western-Mediterranean basin based on the stable carbon and oxygen isotopes analyses of two U/Th dated stalagmites from the Gueldaman GLD1 Cave in Northern Algeria. Comparison of our records with those from Italy and Israel reveals synchronous (multi) centennial dry phases centered at ca. 5600, ca. 5200 and ca. 4200 yr BP across the Mediterranean basin. New calibrated radiocarbon dating constrains reasonably well the age of rich anthropogenic deposits (e.g., faunal remains, pottery, charcoal) excavated inside the cave, which allows the comparison between in situ evidence of human occupation and of climate change. This approach shows that the timing of a prolonged drought at ca. 4400–3800 yr BP blankets the onset of cave abandonment shortly after ca. 4403 cal yr BP, supporting the hypothesis that a climate anomaly may have played a role in this cultural disruption.

δ 18 O in speleothems is a powerful proxy for reconstruction of precipitation patterns in tropical and sub-tropical regions. The aim of this study is to calibrate the δ 18 O record of speleothems against historical precipitation and river discharge data in central Brazil, a region directly influenced by the Southern Atlantic Convergence Zone (SACZ), a major feature of the South American Monsoon System (SAMS). The present work is based on a sub-annual resolution speleothem record covering the last 141 years (the period between the years 1870 and 2011) from a cave in central Brazil. The comparison of this record with instrumental hydroclimate records since 1921 allows defining a strong relationship between precipitation variability and stable oxygen isotope ratios from speleothems. The results from a monitoring program of climatic parameters and isotopic composition of rainfall and cave seepage waters performed in the same cave, show that the rain δ 18 O variability is dominated by the amount effect in this region, while δ 18 O drip water remains almost constant over the monitored period (1.5 years). The δ 18 O of modern calcite, on the other hand, shows clear seasonal variations, with more negative values observed during the rainy season, which implies that other factors also influence the isotopic composition of carbonate. However, the relationship between δ 18 O of carbonate deposits and rainwater is supported by the results from the comparison between speleothem δ 18 O records and historical hydroclimate records. A significant correlation between speleothem δ 18 O and monsoon rainfall variability is observed on sub-decadal time scales, especially for the monsoon period (DJFM and NDJFM), once the rainfall record have been smoothed with a 7–9 years running mean. This study confirms that speleothem δ 18 O is directly associated with monsoon rainfall variability in central Brazil. The relationship between speleothem δ 18 O records and hydroclimatic historical records allows approximation of the absolute changes in mean annual rainfall during the last millennia in the SACZ/SAMS domain.

Knowledge of the evolution of pedogenic processes in the carbonate area is important to understand the dynamics of rock desertification. A precisely-dated stalagmite δ13C record between 61.3 and 50.5 ka BP from southwestern China, potentially related to soil biogenic CO2 production, shifts within a narrow range between −9‰ and −7‰, and exhibits a prominent cycle of 350–470 a, independent of the Asian monsoon changes. This indicates that a threshold effect might control the amplitude of calcite δ13C variability, likely associated with the vertical soil loss in the carbonate area. The periodic δ13C changes reflect that the loss/recovery of soil cover can operate on centennial scale. Thus, the rock desertification in southwestern China might at least initiate 60 ka ago and should be of natural origin.

We present the updated Holocene section of the Sofular Cave record from the southern Black Sea coast (northern Turkey); an area with considerably different present-day climate compared to that of the neighboring Eastern Mediterranean region. Stalagmite δ 13 C, growth rates and initial ( 234 U/ 238 U) ratios provide information about hydrological changes above the cave; and prove to be more useful than δ 18 O for deciphering Holocene climatic variations. Between ∼9.6 and 5.4 ka BP (despite a pause from ∼8.4 to 7.8 ka BP), the Sofular record indicates a remarkable increase in rainfall amount and intensity, in line with other paleoclimate studies in the Eastern Mediterranean. During that period, enhanced summertime insolation either produced much stronger storms in the following fall and winter through high sea surface temperatures, or it invoked a regional summer monsoon circulation and rainfall. We suggest that one or both of these climatic mechanisms led to a coupling of the Black Sea and the Mediterranean rainfall regimes at that time, which can explain the observed proxy signals. However, there are discrepancies among the Eastern Mediterranean records in terms of the timing of this wet period; implying that changes were probably not always occurring through the same mechanism. Nevertheless, the Sofular Cave record does provide hints and bring about new questions about the connection between regional and large scale climates, highlighting the need for a more extensive network of high quality paleoclimate records to better understand Holocene climate.

The hydrological balance of the Black Sea is governed by riverine input and by the exchange with the Mediterranean Sea. A speleothem record from a cave in northern Turkey that tracks the isotopic signature of Black Sea surface water suggests an open connection to the Mediterranean Sea in at least twelve periods in the past 670,000 years.

The suitability of in situ Secondary Ionisation Mass Spectrometry (SIMS) techniques for measuring O isotopes in speleothems is critically examined by applying this technique to a 500-year interval of the well-known Hulu Cave record (Wang, Y.J., Cheng, H, Edwards, R.L., An, Z.S., Wu, J.Y., Shen, C.C., Dorale, J.A., 2001. A high-resolution absolute dated late Pleistocene monsoon record from Hulu Cave, China. Science, 294: 2345–2348). This interval includes a large abrupt + 2‰ shift in δ18O at 16.07 ka, which may correlate to Heinrich Event I (H1). The high-resolution SIMS method provides annual to near-annual δ18O data, thereby increasing the temporal resolution of the previously published Hulu Cave isotopic data by approximately tenfold. SIMS δ18O data reveal that 75% of the abrupt isotopic shift at 16.07 ka occurred in just 1 to 2 years and the full + 2‰ occurs over 6 years, compared with an upper limit of 20 years as previously determined by conventional methods employing micro-cutting, acid-digestion and CO2-gas source mass spectrometry methods. SIMS δ18O data also reveal numerous high amplitude (1–3‰), high frequency (

An absolute-dated stalagmite from Kaite Cave (Ojo Guareña Karst Complex, N Spain) provides a nearly continuous, high-resolution record of a proxy of regional precipitation patterns through the 4.9–0.9 ka BP interval. This record is based on the Mg/Ca ratio of the calcite and its variation through the stalagmite stratigraphy, which is interpreted to be primarily driven by changes in precipitation amount. The calibration of the proxy is supported by the present-day monitoring carried out in the cave for the last 10 years, which reveals a robust inverse relationship between the inter-annual/inter-decadal variability of rainfall and the Mg concentration of dripwaters and precipitating speleothems. The record of paleoprecipitation, based on 2400 Mg/Ca measurements, shows strong variability at inter-annual to inter-decadal scales, and more subtle but significant changes at secular to millennial scales. This long-term paleohydrological evolution outlines five successive intervals with consistent trends, which are bounded by abrupt shifts in the regional precipitation. These shifts took place at 4.65, 4.2, 2.6, and 1.3 ka BP. Significantly, the intervals of maximum precipitation of the whole record (around 4.9–4.65, 2.6–2.45, and 1.3–1.1 ka BP) can be related with episodes of minimum solar activity and correlated with cold climatic events elsewhere., Contribution to research projects 28 CGL2010-21499-BTE and CGL2013-43257-R of the Spanish R+D National Program 29 (MINECO) and research groups ‘‘Paleoclimatology and Global Change’’ and ‘‘Laser Induced 30 Breakdown Spectroscopy (LIBS)’’ from the UCM (Spain).

The Seso Cave System (SCS, South Central Pyrenees, Northeastern Spain) develops in poorly soluble marly interstratum between limestone beds of Eocene age. We propose an innovative and singular pseudokarstic speleogenetic model under vadose conditions based on cave morphological evidence, physicochemical and mineralogical characteristics of the Eocene marly host rock, U-Th dating of cave deposits, and local geological and geomorphological information. Eocene marls are shown to be sensitive to dispersion processes supported by their high clay content and the high concentration of sodium and low electrical conductivity in the seepage water. Runoff inside the cave results from water that infiltrates through joints and seepage water in cave walls. Thereby piping processes become very active, triggering mechanical scouring and outwashing mechanisms. The hydraulic gradient required to develop piping activity is determined by regional fluvial incision. The base level controlling water discharge during opening of the SCS coincides with a terrace of the Ara River dated at 65. ka. BP. Considering this age, as well as the U-Th age of the oldest speleothems dated in the cave at 38. ka. BP, the timing of the SCS interstratal piping-cave speleogenesis is constrained to the Upper Pleistocene; very likely at the end of Marine Isotope Stage 4 during a period characterized by high water availability following glacial retreat in northern Iberian mountains. © 2014 Elsevier B.V., This research was funded by CGL2009-10455/BTE and CGL2010-16376 (HIDROPAST) projects of the Spanish Government (Ministerio de Ciencia e Inovación) and the European Regional Development Fund (FEDER) and a Sobrarbe Geopark research grant. It is a contribution of the PaleoQ Group (Aragón Regional Government). We thank Julie Retrum and Yanbin Lu (University of Minnesota) and Enrique Oliver (Universidad de Zaragoza) for the help in the laboratory work and Jaume Mas and Xavier Fuertes (Grupd'Espeleologia de Badalona) for field cave mapping support and Josu Aranbarri for Fig. 1 design.We appreciate very much the comments by Prof. Jo De Waele, an anonymous reviewer and Prof. Andrew J. Plater (Editor), which have improved the final version of the manuscript.

Seven U-Th dates, 560 δ 18 O data and microscopic sequences were measured for stalagmites from two high-altitude caves in Shennongjia area, Hubei Province. Variations of the decadal-resolution stalagmite δ 18 O record from Swan Cave (1600 m elevation) reflect large spatial changes in circulation strength and precipitation of Asian monsoon. The evidence comes from a great similarity among the stalagmite δ 18 O records from Nanjing, Jiangsu Province; Libo, Guizhou Province and here studied area during the last deglaciation, including a part interval of Younger-Dryas event and Bolling-Allerod. A 30-year-resolution stalagmite δ 18 O record from Yongxing Cave (1400 m elevation), 70 km away from Swan Cave, reveals a rapid transition of Asian monsoon climate during Termination 3 at about 245±5 kaBP. Based on 3 U-Th dates and about 5000 continuous annual bands, a millennial dry episode has been observed during Asian monsoonal Termination 3 from the Yongxing δ 18 O profile. With respect to its structure, duration and transition, the dry reversal, as indicated by our stalagmite δ 18 O record, generally agrees with the pattern of the YD event well-expressed in the Chinese stalagmite δ 18 O records. This YD-type event is characterized by a large decrease in δ 18 O value as much as 2.30‰, more than half of the δ 18 O excursion between glacial/interglacial periods, and lasts 1371±59 a determined by the annual counting chronology. After this event, the monsoon climate shifted abruptly into the interglacial period within 74±4 a. Our data corroborate the view that the repeated occurrence of YD-type event was not an “accident”, possibly resulted from the coupling of ice-sheet and oceanic/atmospheric circulations.

The time sequence of paleoclimatic changes from 245.2 to 147.9 ka B.P. has been established by high precision U-series dating by Thermal Ionization Mass Spectrometry and the analysis of the oxygen isotopes from a stalagmite of Shuinan Cave in Guilin. The oxygen isotope pattern is divided into three main intervals. The top part of the stalagmite (interval C) displays mainly relatively heavy oxygen isotopes, mostly −7 to −5‰VPDB, but at a depth of 86.5 cm below the top, there is a sharp change to values lighter than −8 ‰. This boundary, dated at 192.6 ±3.9 ka B.P. is correlated with the boundary between marine oxygen isotope stages 6 and 7. The underlying interval B has δ18O values consistently between −7.5 and −8.5‰ until 271 cm depth when there is a sharp rise in δ18O values towards values as heavy as −5‰. The upper position of this change is dated at 242.5±6.4 ka B.P. and is correlated with the boundary between marine isotope stages 7 and 8. Carbon isotope values lie between −8.5 and −11‰ and are not uniquely high or low in the three intervals, but also show rapid changes at the boundaries between intervals in the same sense as the shifts in δ18O. The pronounced shifts in δ18O are attributed to changes in the paleo-monsoon intensity which reflect major reorganizations of the climate system, but some regional characteristics are also present. The results are also consistent with previous studies of climate proxies from loess-palaesol sequences in northern China. These characteristics show that paleo-climate evolution since the late stage of the middle Pleistocene Epoch in the Guilin area not only follows the global characteristics, but also has the strong district or regional patterns.

Activities of 231Pa and 230Th in surface sediments from the Arctic Ocean and Greenland–Norwegian Seas are used to examine the redistribution of these water-column produced tracers between the low productivity interior basins and high particle flux marginal areas. Sediment 231Paxs/230Thxs ratios throughout the Canadian and Eurasian Basins and the high particle flux Chukchi slope region are essentially invariant (average = 0.063 ± 0.014, N = 39) and significantly below the water column production ratio (0.093). 231Paxs/230Thxs ratios are also below the production ratio in the seasonally high productivity Greenland–Norwegian Sea basins (average = 0.082 ± 0.024, N = 13), though they are ∼ 30% higher than the interior Arctic. The low sediment 231Paxs/230Thxs ratios are attributed to the net export of ∼ 39% of dissolved 231Pa produced in intermediate/deep waters, as opposed to ∼ 10% of 230Th, through Fram Strait. The negligible 230Th export, combined with the reported low 230Thxs inventory of basin sediments and high 230Thxs inventory in Chukchi slope sediments, points to significant boundary scavenging of 230Th in the Arctic. The invariant 231Paxs/230Thxs ratios further indicate that scavenging of 230Th is comparable to 231Pa (i.e., fractionation to a similar degree between the two nuclides) in both the interior basins and margins. Thus, while significant boundary scavenging of both 231Pa and 230Th occurs in the Arctic, there is a distinct lack of basin-margin fractionation and a sizable export of 231Pa. There is also likely to be export of other similarly particle-reactive radionuclides (e.g., 10Be, Pu isotopes) out of the Arctic.

The isotope records which range from 3.9 kaBP to 15.7 kaBP with an average resolution of 90 a have been obtained from 45 cm to 193.6 cm of the upper part of D4 stalagmite from Dongguo Cave in Libo, Guizhou, by using system TIMS U-series dating and carbon and oxygen stable isotope analyses.The study indicates that the last cold event, the YD (Younger Dryas) event, of the last glacial period was apparently shown in D4 record, which started from 12.80 kaBP and ended in 11.58 kaBP, with a great range of drop in temperature. The end of the last glacial period was consistent with the termination I in oceanic isotope records and was with time limit of 11.3 kaBP. The three most distinct cold events in the early and middle Holocene occurred respectively in 10.91 kaBP, 8.27 kaBP and 4.75 kaBP, with a range of drop in tem- perature reaching 2—5℃. The climate abrupt events in thousand and hundred years scale re- corded in stalagmite δ O can be compared to those in GISP2 ice cores from Greenland in their 18 happening time and the range of their lasting time. The cold events in 8.27 kaBP and 4.75 kaBP can also be compared to CC3 stalagmite records in Ireland, which indicate that climate changes of short range in China monsoon areas, western Europe and polar regions, have the same driv- ing factor. This has a global significance. In addition, the trend of record curves in some time- stages is apparently different, which reflects probably the difference between environment in monsoon climate areas and in polar regions.

Young rhyolites and associated lavas andmagmatic enclaves from the Katmai---Novarupta volcanic system (Alaskan Peninsula), and the Crater Lake and Medicine Lake volcanic system (Cascades) were analyzed for U and Th isotope abundances, as well as major and trace element concentrations, to investigate the time-scales of the processes that lead to rhyolite generation in continental arcs. Basalts and basaltic andesites typically migrate from the mantle to the surface within several thousand years. Variations in (Th)/(Th) and (U)/(Th) ratios with SiO2 concentrations in intermediate lavas appear to result from crystal fractionation combined with assimilation of recently crystallized magmas. These data also suggest that 10---10 years of mafic magmatism are required at a volcanic center to generate silicic andesites and dacites. Rhyolite genesis involves varying proportions of crystal fractionation of intermediate magmas and assimilation of crust. The nearequilibrium (U)/(Th) ratios for all of the rhyolites suggest an average time since U was last fractionated from Th for the constituents making up these rhyolites of 410 years. Therefore, the residence times of continental magmas and their entrained crystals appear to increase by a minimum of 2---3 orders of magnitude with increasing SiO2 concentrations from basalt to rhyolite.

We have dated Huon Peninsula, Papua New Guinea and Barbados corals that formed at times since the Last Interglacial Period, applying both 230 Th and 231 Pa dating techniques as a test of age accuracy. We show that Marine Isotope Stage (MIS) 5e ended prior to 113.1 8 0.7 kyr, when sea level was 319 m. During MIS 5b sea level was 357 m at 92.6 8 0.5 kyr, having dropped about 40 m in approximately 10 kyr during the MIS 5c^5b transition. Sea level then rose more than 40 m during the MIS 5b^5a transition, also in about 10 kyr. MIS 5a lasted until at least 76.2 8 0.4 kyr, at a level of 324 m at that time. Combined with earlier data that places MIS 4 sea level at 381 m at 70.8 kyr, our late MIS 5a data indicate that sea level fell almost 60 m in less than 6 kyr (10.6 m/kyr) during the MIS 5^4 transition. The magnitude of the drop is half that of the glacial^interglacial amplitude and approximatelyequivalent to the volume of the present-dayAntarctic Ice Sheet. During this interval the minimum average rate of net continental ice accumulation was 18 cm/yr, likely facilitated by efficient moisture transport from lower latitudes. At three specific times (60.6 8 0.3, 50.8 8 0.3, and 36.8+0.2 kyr) during MIS 3, sea level was between 385 and 374 m. Sea level then dropped to 3107 m at 23.7 8 0.1 kyr early in MIS 2, before dropping further to Last Glacial Maximum (LGM) values and then rising to present values during the last deglaciation. Times of rapid sea-level drop correspond to times of high winter insolation at low northern latitudes and high winter latitudinal gradients in northern hemisphere insolation, supporting the idea that these factors mayhave resulted in high water-vapor pressure in moisture sources and efficient moisture transport to high-latitude glaciers, therebycontributing to glacial buildup. We combined our sea-level results with deep-sea N 18 O records as a means of estimating the temperature and ice-volume components in the marine N 18 O record. This analysis confirms large deep-ocean temperature shifts following MIS 5e and during Termination I. Deep-ocean temperatures changed bymuch smaller amounts between MIS 5c and 2. Maximum temperature shift in the deep Pacific is about 2‡, whereas the shift at a site in the Atlantic is 4‡. Under glacial conditions temperatures at both sites are near the freezing point. The shift in the Atlantic is likelycaused bya combination of changing proportions of northern and southern source waters as well as changing temperature at the sites where these deep waters form.

Of the possible uranium-series dating schemes, the most important and most widely applied to marine carbonates is 230Th dating, with 231Pa dating playing an increasingly important role. For this reason, this review will focus on these two methods. 230Th dating, also referred to as U/Th dating or 238U-234U-230Th dating, involves calculating ages from radioactive decay and ingrowth relationships among 238U, 234U, and 230Th. 232Th is also typically measured as a long-lived, essentially stable index isotope (over the time scales relevant to 230Th dating). At present 230Th dating can, in principle, be used to date materials as young as 3 years and in excess of 600,000 years (Edwards et al. 1987a, 1993; Edwards 1988; see Stirling et al. 2001 for an example of dating corals in excess of 600,000 years old). 231Pa dating, also referred to as U/Pa dating, involves calculating ages from the ingrowth of 231Pa from its grandparent 235U. At present 231Pa dating can be used to date materials as young as 10 years and as old 250,000 years (Edwards et al. 1997). 230Th dating covers all of the 231Pa time range and more, with somewhat higher precision, and is therefore the method of choice if a single method is applied. However, the combination of 231Pa and 230Th dating is of great importance in assessing possible diagenetic mobilization of the pertinent nuclides, and thereby, the accuracy of the ages (Allegre 1964; Ku 1968). Even if the primary age exceeds the 250,000 year limit of 231Pa dating, the combined methods can be used to assess the degree to which the samples have remained closed over the past 250,000 years (e.g., Edwards et al. 1997). Thus …

A stalagmite that grew during the Holocene (between 4.9 and 0.9 ka BP) in Kaite Cave (Ojo Guarena Karst Complex, Burgos, N Spain) has been analyzed by Laser-Induced Breakdown Spectroscopy (LIBS) with the aim of reconstructing secular variations in the hydrochemistry of the karst system, in turn related to changes in the environment outside the cave. LIBS analyses yield significant changes in Mg/Ca and Sr/Ca intensity ratios through the stalagmite, which reveal consistent trends and patterns at decadal to centennial scales. The origin of the observed changes in Mg/Ca and Sr/Ca ratios is discussed in the framework of the cave system and the regional climatic variability, particularly the changes in precipitation.

Research on global ice-volume changes during Pleistocene glacial cycles is hindered by a lack of detailed sea-level records for time intervals older than the last interglacial. Here we present the first robustly dated, continuous and highly resolved records of Red Sea sea level and rates of sea-level change over the last 500,000 years, based on tight synchronization to an Asian monsoon record. We observe maximum ‘natural’ (pre-anthropogenic forcing) sea-level rise rates below 2 m per century following periods with up to twice present-day ice volumes, and substantially higher rise rates for greater ice volumes. We also find that maximum sea-level rise rates were attained within 2 kyr of the onset of deglaciations, for 85% of such events. Finally, multivariate regressions of orbital parameters, sea-level and monsoon records suggest that major meltwater pulses account for millennial-scale variability and insolation-lagged responses in Asian monsoon records.

We have re-determined the 234 U and 230 Th half-lives to be 245,250±490 years (2σ) and 75,690±230 years (2σ), respectively. Using high precision thermal ionization mass spectrometric (TIMS) methods, we measured 234 U / 238 U and 230 Th / 238 U atomic ratios in 4 different materials that were likely to have behaved as closed systems for 106 years or more: zircons with concordant 238 U – 206 Pb , 235 U – 207 Pb , and 232 Th – 208 Pb ages, Iceland Spar, Table Mountain Latite, and aliquots of a solution of Harwell uraninite (HU-1). We calibrated the TIMS multipliers using U-500, U and Th gravimetric standards, and U double spike. Consistent 234 U / 238 U values for all measured materials and consistent 230 Th / 238 U values for all materials with the exception of our HU-1 solution support the secular equilibrium status. The new half-lives agree within error with previously determined values; however, errors in our values are generally smaller than those in the earlier determinations. Our 234 U half-life is about 3‰ higher than that commonly used in 230 Th dating laboratories and our 230 Th half-life is about 4‰ higher. 230 Th ages calculated with the new half-lives are generally older than those calculated with the previously used half-lives. The difference in age, though, is small throughout the 230 Th age range because our revised 234 U and 230 Th half-lives are offset from earlier values in the same sense (both to higher values). In the case of dating materials older than 350 ka in laboratories that rely solely on gravimetric standardization procedures, use of our decay constants and their associated errors will considerably reduce the errors in age arising from uncertainty in the decay constants.

The geographical origin of modern humans is the subject of ongoing scientific debate. The 'multiregional evolution' hypothesis argues that modern humans evolved semi-independently in Europe, Asia and Africa between 100,000 and 40,000 years ago 1, whereas the 'out of Africa' hypothesis contends that modern humans evolved in Africa between 200 and 100 kyr ago, migrating to Eurasia at some later time(2). Direct palaeontological, archaeological and biological evidence is necessary to resolve this debate. Here we report the discovery of early Middle Stone Age artefacts in an emerged reef terrace on the Red Sea coast of Eritrea, which we date to the last interglacial (about 125 kyr ago) using U-Th mass spectrometry techniques on fossil corals. The geological setting of these artefacts shows that early humans occupied coastal areas and exploited near-shore marine food resources in East Africa by this time. Together with similar, tentatively dated discoveries from South Africa(3) this is the earliest well-dated evidence for human adaptation to a coastal marine environment, heralding an expansion in the range and complexity of human behaviour from one end of Africa to the other. This new, widespread adaptive strategy may, in part, signal the onset of modern human behaviour, which supports an African origin for modern humans by 125 kyr ago.