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The impact of the land use landscape pattern on river hydrochemistry has significant scale effects. It is the premise and foundation of landscape optimization and the conservation of water resources to accurately identify the core scale of the landscape pattern impacting on river hydrochemistry. Taking Binggou River Basin in the source region of Shiyang River Basin as the study area, this paper selected the three spatial scales of catchment area, buffer zone, and riparian zone, and the relationships between land use types and landscape indices and river hydrochemical characteristics were analyzed at different spatio-temporal scales using redundancy analysis. The results showed that the hydrochemistry characteristics of Binggou River Basin had strong temporal variability, and the rainy season was the key period when the land use landscape pattern affected the river hydrochemistry. The sub-watershed and riparian scales were the core scales of influence of the landscape pattern on river hydrochemistry in Binggou River Basin. In particular, the landscape pattern index contributed the most to the river hydrochemistry at the sub-watershed scale on the whole, which was the core scale affecting river hydrochemistry. The “source” or “sink” functions of the same land use type also changed as the scale changed. Forest land showed weak “source” effect at the sub-watered scale, but a strong interception effect on the soil erosion process at the riparian scale, which is a typical “sink” landscape.

Despite the absence of tectonic activity, cratonic environments are characterized by strongly variable, and in places significant, rock weathering rates. This is shown here through an exploration of the weathering rates in two inter-tropical river basins from the Atlantic Central Africa: the Ogooué and Mbei River basins, Gabon. We analyzed the elemental and strontium isotope composition of 24 water samples collected throughout these basins. Based on the determination of the major element sources we estimate that the Ogooué and Mbei rivers total dissolved solids (TDS) mainly derive from silicate chemical weathering. The chemical composition of the dissolved load and the area-normalized solute fluxes at the outlet of the Ogooué are similar to those of other West African rivers (e.g., Niger, Nyong, or Congo). However, chemical weathering rates (TZsil+ rate expressed as the release rate of the sum of cations by silicate chemical weathering) span the entire range of chemical weathering intensities hitherto recorded in worldwide cratonic environments. In the Ogooué-Mbei systems, three regions can be distinguished: (i) the Eastern sub-basins draining the Plateaux Batéké underlain by quartz-rich sandstones exhibit the lowest TZsil+ rates, (ii) the Northern sub-basins and the Mbei sub-basins, which drain the southern edge of the tectonically quiescent South Cameroon Plateau, show intermediate TZsil+ rates and (iii) the Southern sub-basins characterized by steeper slopes record the highest TZsil+ rates. In region (ii), higher DOC concentrations are associated with enrichment of elements expected to form insoluble hydrolysates in natural waters (e.g., Fe, Al, Th, REEs) suggesting enhanced transport of these elements in the colloidal phase. In region (iii), we suggest that a combination of mantle-induced dynamic uplift and lithospheric destabilization affecting the rim of the Congo Cuvette induces slow base level lowering thereby enhancing soil erosion, exhumation of fresh primary minerals, and thus weathering rates. The study points out that erosion of lateritic covers in cratonic areas can significantly enhance chemical weathering rates by bringing fresh minerals in contact with meteoric water. The heterogeneity of weathering rates amongst cratonic regions thus need to be considered for reconstructing the global, long-term carbon cycle and its control on Earth climate.

• The rainy season was the key period when land use landscape pattern affected the river water chemistry. • The sub-watershed scale was the core scale that affects river water chemistry as a whole. • The "source-sink" functions of the same land use type changes with the change of scale. • Forestland and grassland have obvious interception effect on soil erosion at riparian scale. The impact of the land use landscape pattern on river hydrochemistry has significant scale effects. It is the premise and foundation of landscape optimization and the conservation of water resources to accurately identify the core scale of the landscape pattern impacting on river hydrochemistry. Taking Binggou River Basin in the source region of Shiyang River Basin as the study area, this paper selected the three spatial scales of catchment area, buffer zone, and riparian zone, and the relationships between land use types and landscape indices and river hydrochemical characteristics were analyzed at different spatio-temporal scales using redundancy analysis. The results showed that the hydrochemistry characteristics of Binggou River Basin had strong temporal variability, and the rainy season was the key period when the land use landscape pattern affected the river hydrochemistry. The sub-watershed and riparian scales were the core scales of influence of the landscape pattern on river hydrochemistry in Binggou River Basin. In particular, the landscape pattern index contributed the most to the river hydrochemistry at the sub-watershed scale on the whole, which was the core scale affecting river hydrochemistry. The "source" or "sink" functions of the same land use type also changed as the scale changed. Forest land showed weak "source" effect at the sub-watered scale, but a strong interception effect on the soil erosion process at the riparian scale, which is a typical "sink" landscape. [ABSTRACT FROM AUTHOR]