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Porphyry, epithermal, and volcanogenic massive sulfide (VMS) deposits can form together in the same mineral district in convergent margin environments. Their spatial association and superposition indicate evolving tectonic settings. The Artvin Au-Cu district is one of the major clusters of VMS bimodal-felsic, porphyry, and epithermal deposits in the Eastern Pontides belt in northeast Turkey. Whereas ore-forming processes, timing, and tectonic setting of VMS mineralization are well defined in Artvin, those for porphyry and epithermal mineralization remain less constrained. Our district-scale field study focused on the Hod gold corridor in the Artvin district, which is defined by the NE-trending alignment of the recent Au-Cu mineral discoveries (~205 t Au; ~0.33 Mt Cu; e.g., Hod Maden, Ardala-Salinbaş, and Taç-Çorak) that include Au-rich porphyry, highand intermediate-sulfidation epithermal, carbonate-replacement, and hybrid VMS-epithermal mineralization styles. Our new U-Pb, 40Ar/39Ar, and Re-Os geochronological results interpreted with previously compiled data show that magmatism in the Artvin district formed in the Carboniferous (358–325 Ma), Jurassic (182–174 Ma), Late Cretaceous (92–78 Ma), Eocene (51–40 Ma), and Oligocene (30 Ma). Porphyry and epithermal mineralization along the Hod gold corridor peaked in the Early (~113 Ma; Berta prospect) and Late Cretaceous (~86.5-82 Ma; e.g., Taç and Çorak deposits) and Eocene (~50 Ma; e.g., Ardala deposit), whereas VMS bimodal-felsic mineralization only formed in the Late Cretaceous (~91–85 Ma). Therefore, we interpret that the Hod gold corridor was a long-lived, deep crustal-scale structural feature along which the successive magmatic and mineralization events were emplaced. In addition, the timing of porphyry Cu-Mo mineralization can significantly (>20 Ma) postdate the crystallization age of the intrusive host rocks in the Artvin district, such as at Berta and Balcılı camp, which emphasizes the importance of dating mineralization directly to correctly attribute the tectonic setting. The distribution of Late Cretaceous mineral occurrences suggests a possible eastward temporal evolution from VMS (~91–85 Ma) to epithermal-porphyry systems (~86.5–82 Ma), transitioning from back-arc to arc settings at the onset of the Northern Neotethyan oceanic slab rollback and accompanied by increasingly elevated gold content eastwards across the Artvin district.

The Taurus porphyry Cu-Mo district contains four mineralized porphyry centers in the eastern interior of Alaska. All four centers were emplaced during a magmatic episode that spanned from ca. 72 to 67 Ma, with seven distinct igneous suites. Each igneous suite resulted in hydrothermal alteration and mineralization, with younger pulses overprinting older pulses. Each magmatic-hydrothermal system is not present at all four mineralized centers. Apart from the Dennison occurrence, each mineralized center records pulses of repeated intermediate-silicic magmatism and associated alteration and mineralization. Laser ablation-inductively coupled plasma-mass spectrometry U-Pb zircon crystallization ages indicate that an early quartz porphyry dike swarm ranges in age from ca. 71 to 70 Ma and is associated with potassic, sericitic, and propylitic alteration. Quartz latite intrusions were emplaced at ca. 69 Ma and exhibit early sodiccalcic alteration overprinted by potassic, sericitic, and propylitic alteration. The Taurus monzonite suite is cut by quartz latite but yielded an ca. 70 Ma emplacement age and exhibits the largest footprint of potassic and sericitic alteration. Feldspar porphyry dikes were emplaced ca. 69 Ma and have significant tourmaline-bearing potassic and sericitic alteration. This suite was followed by development of an igneous breccia with a monzonitic igneous matrix. Sodic-calcic alteration was associated with the igneous brecciation. A small stock of monzonite was emplaced at ca. 68 Ma causing locally pervasive sericite-tourmaline-pyrite alteration. The youngest suite of magmatism dated in the district is a series of granodiorite porphyry dikes with weak sodic-calcic and propylitic alteration that truncates earlier alteration assemblages. Mineralization in the district consists of chalcopyrite and molybdenite associated with sugary quartz veins with potassium feldspar and biotite alteration envelopes (A veins). Less common banded quartz-molybdenite veins (B veins) occur with potassium feldspar envelopes. Gold occurs throughout the district and is strongly correlated with copper grade. Sericitic alteration contains lower copper contents and is predominantly associated with quartz-pyrite veins with sericite envelopes (D veins). Pyrrhotite and local arsenopyrite are present in sericitic assemblages. Pyrrhotite also occurs as inclusions in pyrite within D veins. Magmas across the district exhibit oxidized characteristics, evidenced by the presence of abundant magnetite, rare titanite, and elevated Eu/Eu* and Ce/Ce* in zircon. Zircon Th/U and Yb/Gd compositions suggest a fractionation path controlled by apatite, titanite, and hornblende. Zircon rare earth element ratios and trace element data indicate two distinct batches of magma evolved from mafic parental compositions to monzonite and granodioritic compositions via fractional crystallization. In the early pulse of magma (ca. 72–69 Ma), fractional crystallization was key to ore formation. Earlier, better mineralized suites evolve to less negative Eu anomalies (Eu/Eu* > 0.7), indicating more oxidized and higher-water-pressure conditions evidenced by the suppression of plagioclase crystallization, compared to later, more poorly mineralized suites. The temporal and spatial evolution of the district was determined from mapping and U-Pb and Re-Os geochronology. Mapping of igneous and hydrothermal assemblages indicates that the locus of the intrusive suites and hydrothermal systems shifted spatially over time, based on the presence of high-temperature (K-silicate–dominant) alteration, which is coincident with the highest Cu and Au grades. The earliest hydrothermal system was centered at Bluff and East Taurus and transitioned to West Taurus during emplacement of the second magmatic suite. Emplacement of the third magmatic suite was centered back at East Taurus, and the fourth and fifth suites were centered at West Taurus. The latest suites were widespread without a core of high-temperature alteration marking a central locus. East Taurus contains the overlap of six of the seven magmatic and hydrothermal suites and has the highest intersected grades and tonnages in the district. The Bluff and Dennison occurrences exhibit fewer igneous suites and hydrothermal assemblages with weak mineralization. Sodic-calcic alteration, common on the deep and distal flanks of porphyry systems, is only present at West Taurus and is indicative of a localized source of high-salinity nonmagmatic fluids.

We report the discovery of one of the largest ancient (>3.0 Ga) crustal terranes on Earth. Granitoids with crystallization ages >3.0 Ga and/or Sm-Nd depleted mantle model ages ≥3.2 Ga define a ~1000 × 100 km belt on the western margin of the Rae craton, Canada, referred to herein as the Perry River terrane (PRT). Zircon U-Pb-Hf-O isotope and whole-rock geochemical data from granitoids show that the PRT is a predominantly juvenile 3.3–3.2 Ga terrane that was partially reworked by more evolved ca. 3.1 Ga magmatism. These findings call for a reassessment of the timing and extent of ancient continental growth on Earth. A global compilation of zircon Hf isotope data from 3.6 to 3.0 Ga igneous rocks reveals clusters of relatively juvenile (initial εHf −2 to +3) rocks at ca. 3.31 and ca. 3.23 Ga, which include samples from the PRT and 13 other terranes worldwide. Other global zircon data sets also document age peaks between 3.3 and 3.2 Ga, and a cluster of broadly chondritic initial εHf values around 3.2 Ga. The 3.3–3.2 Ga period may therefore have been a time of enhanced net continental growth on Earth, and the PRT is one of the largest terranes preserved from that time. Furthermore, zircon Hf isotope data from 3.3–3.1 Ga PRT granitoids and 3.5–3.0 Ga igneous rocks worldwide yield little evidence for parent magmas that interacted with or derived from pre–3.6 Ga continental material. Contrary to some continental-growth models, this latter observation suggests that the volume of continental crust established by 3.6 Ga was relatively small.

The crustally derived Tungsten Plutonic Suite (TPS) in the northern Canadian Cordillera is responsible for several of the world’s most important tungsten (W) resources, but the actual source rocks to these exceptionally metallogenic magmas have never been identified. Detrital zircon studies have improved our knowledge of exposed supracrustal packages in the region, such that a U-Pb study of inherited zircon cores in the TPS provides an opportunity to determine the age and provenance of the melt source to these magmas. The TPS is dominated by Neoarchean to Paleoproterozoic inherited zircons that are typical of a northwest Laurentian “cratonic” detrital zircon signature (e.g., 2.8−1.8 Ga). Cross-correlation statistical analysis of detrital zircon populations combined with whole-rock neodymium isotopic compositions indicate that mid- to late Cambrian sedimentary rocks in the Selwyn Basin are the most likely melt source for the TPS magmas. Despite the presence of prospective intrusions across the Selwyn Basin, world-class W metallogeny is limited to the narrow belt of TPS plutons in the eastern Selwyn Basin near the ancient continental margin, possibly due to depositional or structural controls on the source strata. Today, the early Phanerozoic melt source to the TPS must be present at depths of at least 15−17 km and is notably younger than suggested by current geophysical interpretations for the middle crust, requiring a reconsideration of the crustal architecture in the northern Cordillera.

The multi-orogenic crustal segment of the Central Western Carpathians comprises a Variscan basement that is host to small nickel–cobalt (Ni–Co) arsenide and sulfarsenide mineralizations at Ľubietová-Kolba and Čierna Lehota (Slovakia). Here, we constrain the timing of Ni–Co mineralization by using rhenium-osmium (Re–Os) isotope geochemistry of (1) gersdorffite (NiAsS) after krutovite (NiAs2) at Ľubietová-Kolba, and (2) a mixture of skutterudite-pararammelsbergite (CoAs3–NiAs2) from the Čierna Lehota deposit, hosted by metamorphosed carbonaceous rocks. Gersdorffite, which is bereft of common Os, returns a Re–Os model age of 238.2 ± 1.0 (2σ) million years (Ma). Four aliquots of the skutterudite-pararammelsbergite mixture define a robust model 1 isochron at 238.2 ± 12.7 (2σ) Ma (mean square weighted deviates – MSDW = 0.95). A crustal source of Os, and by inference other metals, is inferred from the initial 187Os/188Os ratio of 0.90 ± 0.01 of this isochron. We conclude that studied Ni–Co mineralizations are related to an extensional tectonic regime and hydrothermal fluid flow in connection with the opening of the Meliata ocean in the Middle Triassic (Ladinian).

The Archean low-grade, large-tonnage Côté Gold Au(-Cu) deposit is the first large gold deposit discovered in the Swayze greenstone belt, Ontario, Canada. The deposit is hosted by the Chester Intrusive Complex, a low-Al composite, subvolcanic intrusion composed of tonalite, quartz diorite, and diorite that was previously constrained to ca. 2741 to 2739 Ma (U-Pb zircon). Presented here is the first detailed study of the mineralization and related alteration, along with the relative and absolute age (U-Pb, Re-Os) constraints on gold mineralization. The earliest hydrothermal stage is represented by rare Au-bearing amphibole-rich veins and breccias. The main ore stage consists of biotite-rich alteration centered on an Au(-Cu)–bearing magmatic-hydrothermal biotite breccia body with spatially related disseminated biotite and veins of both sheeted and stockwork type. Extensive fracture-controlled and replacement-style Au ± Cu-bearing muscovite alteration overprints biotite-altered rocks in the core of the deposit. Barren fracture-controlled and disseminated epidote alteration is localized to the north of the deposit and above the magmatic-hydrothermal biotite breccia. Late, texturally destructive albite alteration overprints the mineralized hydrothermal alteration in the deposit core. U-Pb isotope dilution-thermal ionization mass spectrometry and laser ablation-inductively coupled plasmamass spectrometry ages for hydrothermal titanite from amphibole (2745 ± 3 Ma) and albite (2737.5 +2.2/–1.8, 2745 ± 9, and 2736 ± 7 Ma) alteration assemblages constrain hydrothermal activity to ca. 2740 Ma. The timing of gold and sulfide mineralization is also constrained by two Re-Os molybdenite ages of 2736.1 ± 11.4 (biotite alteration) and 2746.8 ± 11.4 Ma (muscovite alteration). These new ages overlap with the ca. 2741 to 2739 Ma magmatism for the Chester Intrusive Complex, thereby suggesting a synintrusion, magmatic-hydrothermal origin for the gold mineralization and related alteration. This is significant, as it represents a new gold metallogenic event in the Abitibi subprovince, for which regional importance remains to be defined. Considering the spatial association of the deposit with a dioritic intrusion and the temporal overlap of igneous activity with alteration (i.e., amphibole, biotite, sericite) and mineralization (i.e., breccias, veins, disseminations), the deposit is interpreted as an Archean magmatic-hydrothermal ore system sharing analogies with Phanerozoic Au-Cu porphyry deposits. It suggests that Archean porphyry-type deposits can form in low-Al composite intrusions, which are known to host Cu-Mo-Au breccia, vein, and disseminated mineralization and underlie temporally and genetically related felsic to intermediate volcanic rocks that host volcanogenic massive sulfide deposits.

Micas are among the most commonly-dated minerals by the 40Ar/39Ar technique to determine the crystallization or cooling ages of rocks. Interpretation of the geological significance of these ages is largely dependent on understanding how 40Ar* (radiogenic argon) can be retained or released from the mineral during the thermal history of a terrane. The interlayer ionic porosity (Zi) model, serving as a measure of a mineral’s atomic packing density, has been proposed in an attempt to understand and explain the diffusive behaviour of argon (Ar) and its retention in micas. We tested this model by dating micas from several outcrops using the 40Ar/39Ar and Rb/Sr techniques along a ∼5.2 km transect in the Frontenac terrane, Grenville Province, Ontario. This transect is ideal because: (a) the rocks in this small area experienced the same geologic history, and (b) there are a variety of lithologies containing trioctahedral and dioctahedral micas with different chemical compositions. Our results show that trioctahedral and dioctahedral micas yielded 40Ar/39Ar plateau ages that differ by ∼150 Ma. Significantly, although both Mg# and F# correlate with Zi, as predicted by the model, there is no correlation between Mg#, F#, and Zi and the age of the micas in similar lithologies. This suggests that the interlayer ionic porosity model, in itself, may not be suitable for explaining mechanisms of Ar mobility in micas alone. Instead, both internal (chemical composition, bulk rock properties) and external (fluid composition, open/closed-system behaviour) factors that may influence Ar retentivity in micas should be more broadly considered in order to elucidate the significance of their 40Ar/39Ar ages.

Pend Oreille, a carbonate-hosted Zn-Pb sulfide deposit, is the only base metal mine recently in production within the historically prolific Kootenay arc belt. The deposit consists of two spatially and lithologically distinct types of stratabound, carbonate-hosted Zn-Pb mineralization: Josephine and Yellowhead. The Yellowhead-type sulfide mineralization, the focus of this study, consists of en échelon tabular to lensoidal pyrite-sphalerite–rich orebodies hosted by the middle Cambrian to Early Ordovician Metaline Formation. The Yellowhead-type mineralization is characterized by carbonate replacement and open-space filling textures, indicating diagenetic and epigenetic origin. As with most low-temperature deposits not directly associated with igneous activity, the timing of sulfide mineralization has traditionally been difficult to constrain using radiometric methods. In this study, we present a new Re-Os age of 512 ± 17 Ma from the Yellowhead mineralization. Combining this age date with the Cambrian-Ordovician fossil record of the host Metaline Formation and detailed textural analysis of the mineralization, we conclude that the Yellowhead sulfide mineralization is largely diagenetic in origin. Such an origin for the Yellowhead mineralization is similar to that of Irish-type deposits worldwide. For explorationists, the presence of Irish-type deposits in the United States portion of the Kootenay arc opens the possibility of discovering similar mineralization in the Canadian extension of the Kootenay arc.

Clastic dominant-type massive sulfide deposits are well preserved in Upper Devonian carbonaceous mudstones in the Macmillan Pass district (Yukon, Canada). The Macmillan Pass deposits have been considered to be type examples of sedimentary exhalative Zn-Pb mineralization, whereby sulfides precipitated when hydrothermal fluids were vented into a euxinic (H2S-bearing) water column. We propose a new mineralization model, documenting the mineralogical evolution of layered mineralization. We show that textures previously interpreted to form via depositional processes actually formed by subseafloor replacement of diagenetic barite. Mineral assemblages associated with barite dissolution in the layered mineralization include (1) barium carbonate phases (witherite, barytocalcite, and norsethite), which are intergrown with Zn-Pb sulfides and represent localized Ba mass transfer, and (2) barium feldspar (celsian, hyalophane) that is abundant in the mudstones surrounding the layered mineralization. The barium feldspar formed following transport of Ba in low-sulfate fluids on the margins of the subseafloor replacement system. This resulted in whole-rock Ba enrichments (up to 5 wt %) in mudstones 15 m below and above the layered mineralization. High Ba in these surrounding mudstones is coupled with decreasing K/Al ratios, indicative of secondary illite and kaolinite. The source(s) of fluids related to the diagenetic (barite, barytocalcite) and hydrothermal (ankerite) assemblages can be constrained using Sr isotopes. Whereas highly radiogenic 87Sr/86Sr values (>0.714) in ankerite correspond with host-rock alteration within the vent complex, the overlying barite and barytocalcite preserve lower 87Sr/86Sr values (

The Productora Cu-Au-Mo deposit is hosted by a Cretaceous hydrothermal breccia complex in the Coastal Cordillera of northern Chile. The current resource, which includes the neighboring Alice Cu-Mo porphyry deposit, is estimated at 236.6 Mt grading 0.48% Cu, 0.10 g/t Au, and 135 ppm Mo. Local wall rocks consist of a thick sequence of broadly coeval rhyolite to rhyodacite lapilli tuffs (128.7 ± 1.3 Ma; U-Pbzircon) and two major intrusions: the Cachiyuyito tonalite and Ruta Cinco granodiorite batholith (92.0 ± 1.0 Ma; U-Pbzircon). Previous studies at Productora concluded the deposit had strong affinities with the iron oxide copper-gold (IOCG) clan and likened the deposit to Candelaria. Based on new information, we document the deposit geology in detail and propose a new genetic model and alternative classification as a magmatic-hydrothermal breccia complex with closer affinities to porphyry systems. Hydrothermal and tectonic breccias, veins, and alteration assemblages at Productora define five paragenetic stages: stage 1 quartz-pyrite–cemented breccias associated with muscovite alteration, stage 2 chaotic matrix-supported tectonic-hydrothermal breccia with kaolinite-muscovite-pyrite alteration, stage 3 tourmaline-pyrite-chalcopyrite ± magnetite ± biotite-cemented breccias and associated K-feldspar ± albite alteration, stage 4 chalcopyrite ± pyrite ± muscovite, illite, epidote, and chlorite veins, and stage 5 calcite veins. The Productora hydrothermal system crosscuts earlier-formed sodic-calcic alteration and magnetite-apatite mineralization associated with the Cachiyuyito stock. Main-stage mineralization at Productora was associated with formation of the stage 3 hydrothermal breccia. Chalcopyrite is the dominant hypogene Cu mineral and occurs predominantly as breccia cement and synbreccia veins with pyrite. The Alice Cu-Mo porphyry deposit is characterized by disseminated chalcopyrite and quartz-pyrite-chalcopyrite ± molybdenite vein stockworks hosted by a granodiorite porphyry stock. Alice is spatially associated with the Silica Ridge lithocap, which is characterized by massive, fine-grained, quartz-altered rock above domains of alunite, pyrophyllite, and dickite. Rhenium-Os dating of molybdenite indicates that main-stage mineralization at Productora occurred at 130.1 ± 0.6 Ma, and at 124.1 ± 0.6 Ma in the Alice porphyry. Chalcopyrite and pyrite from Productora have δ34Ssulfide values from –8.5 to +2.2‰, consistent with a magmatic sulfur source and fluids evolving under oxidizing conditions. No significant input from evaporite- or seawater-sourced fluids was detected. Stage 3 tourmalines have average initial Sr of 0.70397, consistent with an igneous-derived Sr source. The Productora magmatic-hydrothermal breccia complex formed as a result of explosive volatile fluid release from a hydrous intrusive complex. Metal-bearing fluids were of magmatic affinity and evolved under oxidizing conditions. Despite sharing many similarities with the Andean IOCG clan (strong structural control, regional sodic-calcic alteration, locally anomalous U), fluid evolution at the Productora Cu-Au-Mo deposit is more consistent with that of a porphyry-related magmatic hydrothermal breccia (sulfur-rich, acid alteration assemblages and relatively low magnetite contents

The Rosen copper veins in southeastern Bulgaria are recognized for the first time as an iron oxide-copper-gold (IOCG) district. The veins are located in the East Srednogorie segment of the Carpathian-Balkan calc-alkaline volcano-plutonic arc and were formed during an end-stage interval of extreme slab rollback and intra-arc rifting, which gave rise farther east to seafloor spreading in the Western Black Sea basin. The resulting submarine volcano-sedimentary rift basin is dominated by intermediate to mafic shoshonitic to ultrapotassic volcanism and subsidiary gabbro to syenite intrusion. The E- to NE-striking veins define a NW-striking alignment along the western contact of the syenite-dominated Rosen pluton, inferred to be part of a large ring dike. More than 40 veins, the most important formerly mined to depths as great as 1,000 m, contain an early, pegmatoidal, calcic-potassic assemblage followed by predominant magnetite (including the mushketovite variety), chlorite, and carbonates but also quartz, chalcopyrite, pyrite, and numerous other metallic minerals, which combine to give an unusual Fe-Cu-Au-Mo-Co-Ni-U-light rare earth element (LREE)-W-Bi-Zn-Pb geochemical signature. The close correlation between Fe, Cu, U, and LREEs is evident even in the flotation tailings. Vein molybdenite was dated during this study at 80.6 ± 0.4 Ma, which is similar to a U-Pb zircon age for monzosyenite from the Rosen pluton. The mineralogic and compositional features of the Rosen district are comparable to those of well-known IOCG deposits worldwide and geometrically similar to the vertically extensive IOCG veins in the Coastal Cordillera province of northern Chile. The subsidiary granitophile signature that accompanies the characteristic siderophile IOCG suite was also recognized recently at the giant Olympic Dam deposit in South Australia and elsewhere. Although no exposed intrusion is definitively implicated in the genesis of the Rosen veins, coexisting gabbro and syenite fluid sources may be hypothesized at depth in or beneath the coeval ring dike.

Hyper-enriched black shale (HEBS) Ni-Mo-Zn-Pt-Pd-Au-Re mineralization is geographically widespread across the Richardson trough in northern Yukon (Canada), where it discontinuously outcrops at the regional contact between the Road River Group and overlying Canol Formation. Stratigraphic relationships indicate that the contact is Middle Devonian, but there are no precise age constraints for the HEBS. We apply Re-Os geochronology to HEBS mineralization from two localities that are 130 km apart, the Nick prospect and the Peel River showing, to date directly the age of sulfide mineralization. The Nick prospect yields an isochron age of 390.7 ± 5.1 (2σ) Ma, whereas the Peel River showing yields an isochron age of 387.5 ± 4.4 (2σ) Ma. Within error, these ages are identical and overlap with the biostratigraphically constrained age of the sedimentary host rocks, indicating that mineralization and sedimentation were coeval. Significantly, the ages of the HEBS overlap those of Middle Devonian Kačák, pumilio, and Taghanic global-scale biotic events which are characterized by eustatic sea-level rise and black shale deposition. Linkage of the Yukon HEBS to one (or more) of these bio-events indicates that sea-level rise may have been requisite to formation of basin-scale HEBS mineralization in northwestern Canada during latest Eifelian and Givetian time.

The Tongkuangyu copper deposit in the Zhongtiaoshan region, southern Trans-North China orogen, is hosted by a poorly constrained sequence of Paleoproterozoic volcano-sedimentary (quartz-sericite schist and biotite schist) and granitic rocks that have been metamorphosed to lower greenschist facies and variably deformed. The deposit has previously been proposed to be either a porphyry-type or a sediment-hosted stratiform Cu deposit, and its age of formation has been debated. The quartz-sericite schist is interpreted to be a felsic crystal tuff and consists of angular quartz crystals in a fine-grained sericite-altered matrix. Two quartz-sericite schist samples yielded zircon U-Pb upper concordia intercept ages of 2512 ± 12 (2σ, mean square of weighted deviates [MSWD] = 0.19) and 2335 ± 16 Ma (2σ, MSWD = 0.80). Biotite schist, which is interleaved locally with the quartz-sericite schist and is interpreted to be a basaltic-andesitic sill, yielded a younger zircon U-Pb upper concordia intercept age of 2191 ± 10 Ma (2σ, MSWD = 1.7). Five samples of granodiorite and granodiorite porphyry that intruded the schist sequence yielded similar zircon U-Pb ages, with a weighted mean upper concordia intercept age of 2182 ± 7 Ma (2σ, MSWD = 1.3). These results suggest that the volcanic sequence was deposited between ∼2.5 and 2.3 Ga and was intruded by basaltic-andesitic sills and a suite of granodiorite and granodiorite porphyry intrusions at ∼2.19 to 2.18 Ga. Two stages of copper mineralization are interpreted to have formed after pervasive sericite alteration of the felsic volcanic rocks. Stage 1 mineralization includes disseminated and deformed quartz veinlets containing chalcopyrite ± pyrite ± magnetite ± molybdenite associated with biotite ± K-feldspar alteration in granodiorite porphyry and schist. Stage 2 comprises undeformed quartz-chlorite-carbonate veins with bornite ± chalcopyrite ± magnetite associated with local chlorite and silicic alteration. Allanite crystals intergrown with chalcopyrite in the granodiorite porphyry yielded an approximate concordia U-Pb age of 2115 ± 31 Ma (2σ, MSWD = 2.3). Two molybdenite samples in a deformed quartz-chalcopyrite-molybdenite vein yielded Re-Os model ages of 2106 ± 9 and 2089 ± 9 Ma (2σ), consistent with previously published results. Hydrothermal monazite grains with Cu-Fe sulfide inclusions in the granodiorite porphyry, quartz-sericite schist, and undeformed chlorite-bornite-quartz veins yielded much younger U-Pb upper concordia intercept ages of 1832 ± 16 (2σ, MSWD = 0.48), 1810 ± 14 (2σ, MSWD = 0.92), and 1809 ± 12 Ma (2σ, MSWD = 0.38), respectively. The results are in agreement with four Re-Os model ages for pyrite mineral separates from undeformed quartz-sulfide veins, which yielded a weighted mean age of 1807 ± 4 Ma (2σ, n = 4, MSWD = 0.42). In contrast, hydrothermal rutile crystals in the quartz-sericite schist and biotite schist yielded a range of roughly concordant ages between 2.1 and 1.8 Ga, reflecting isotopic disturbance. We interpret these results to indicate original copper mineralization at ∼2.1 Ga that is significantly later than the granodiorite (∼2.18 Ga) and schists (∼2.5–2.2 Ga), followed by hydrothermal remobilization and metamorphism at ∼1.8 Ga. The metavolcanic and granodiorite porphyry host rocks, alteration styles, and disseminated and veinlet form of the earlier mineralization are strongly reminiscent of porphyry Cu deposits, and ages of ∼2.1 Ga have been reported for one intrusion and three volcanic rock samples from the district. The Tongkuangyu, therefore, represents one of the oldest known porphyry copper deposits. Remobilization of copper occurred at ∼1.8 Ga during the Zhongtiao orogeny.

The newly defined, 1,500-km-long, late Cenozoic Anatolian metallogenic trend of Turkey is the central segment of the western Tethyan metallogenic belt and formed after the closure of the southern Neotethys Ocean. Mineral deposit discoveries along this trend show that the Oligocene to Miocene igneous units are highly prospective for gold-rich porphyry- and epithermal-style mineralization (~27 Moz) but that copper endowment is poor. However, the temporal and spatial constraints on late Cenozoic gold districts and isolated prospects and their tectonic affinity are poorly known, despite recent efforts. We herein provide new U-Pb and Re-Os age data and field observations from Miocene gold prospects and deposits throughout the Anatolian trend, which we interpret together with previously published age data in the region. We define nine new porphyry and epithermal districts: Simav, İzmir, Uşak, Bodrum, Konya, Aksaray, Kayseri, Tunceli, and Ağri. Gold-rich porphyry and epithermal systems peaked at (1) 25 to 17 Ma in eastern Anatolia, (2) 21 to 9 Ma in western Anatolia, and (3) 10 to 3 Ma in central Anatolia. The westward migration of porphyry and epithermal mineralization from eastern to central Anatolia is interpreted to reflect slab break-off propagation and gap opening after the onset of the Arabian continental collision. Conversely, the southwestward migration of the magmatic front and associated mineralization in western Anatolia resulted from the acceleration of the Aegean slab rollback and subsequent lateral tearing (15–8 Ma). Thus, the bulk of gold mineralization formed in response to the slab segmentation and thermal events at 25 and 15 Ma.

The ca. 1050 Ma Bylot Supergroup in Arctic Canada is one of the best-preserved archives of late Mesoproterozoic geochemistry and biology and offers evidence that this period of Earth history may have been more biogeochemically dynamic than previously appreciated. The Bylot Supergroup was deposited in the Borden Basin and is the most thoroughly studied stratigraphic succession from a series of broadly contemporaneous late Mesoproterozoic intracratonic basins known as the Bylot basins. This ∼6-km-thick mixed carbonate-siliciclastic succession has undergone minimal postdepositional deformation and is now exposed on Baffin and Bylot Islands, Nunavut, Canada. Deep-water and tidally influenced carbonate facies, traditionally interpreted as marine, have yielded important insights into the evolution of Proterozoic seawater chemistry; however, more recent studies indicate that the Borden Basin was restricted marine or lacustrine for portions of its depositional history. Here, we present new multiproxy radiogenic isotope chemostratigraphic data spanning the Bylot Supergroup. A comparison of stratigraphic trends in radiogenic isotope data from hydrogenous (black shale 187Os/188Os and limestone 87Sr/86Sr) and detrital (whole-rock mudstone 143Nd/144Nd) sedimentary phases elucidates the complex hydrologic history of the Borden Basin and reconciles these disparate interpretations. Episodic coupling and decoupling between the composition of basin waters (from Os and Sr isotopes) and the local weathering input to the basin (from Nd isotopes) indicate that depositional environments within the Borden Basin fluctuated between marine and nonmarine (i.e., lacustrine). Variations in basin hydrology controlled secular sedimentation patterns through changes in basin water chemistry. These interpretations help to characterize the environment in which the early red algal fossil Bangiomorpha pubescens evolved. Episodically restricted epeiric seaways, such as within the Borden Basin, were relatively widespread within Rodinia and may have exerted unique selective pressures on eukaryotic evolution in the Mesoproterozoic Era. Hydrogenous and detrital radiogenic isotope chemostratigraphy, as implemented in this study, may provide a useful paleoenvironmental framework for future paleontological studies aimed at testing the role of freshwater environments in eukaryotic evolution. In addition, 87Sr/86Sr compositions from 81 new middle Bylot Supergroup marine limestone samples, calibrated by recent Re-Os geochronology, contribute to the terminal Mesoproterozoic marine 87Sr/86Sr curve. These data display a rise from ∼0.705 to 0.706 that reflects weathering of the active Grenville orogenic belt and demonstrates a global increase in chemical weathering during the amalgamation of Rodinia.

The calc-alkalic Mitchell Au-Cu-Ag-Mo porphyry deposit, hosted in intrusive rocks of the Stikine volcanic arc terrane of northwestern British Columbia, is the largest undeveloped gold resource in Canada, with 40.72 Moz of contained gold. It lies within the KSM trend, a 12-km-long linear porphyry array in the Sulphurets district. It is genetically related to Early Jurassic Sulphurets stocks: phase 1 diorite to monzodiorite hosts Cu-Au mineralization in potassic assemblages (stage 1), a phase 2 granodiorite plug cores a molybdenum halo (190.3 ± 0.8 Ma, 191.3 ± 0.7 Ma; Re-Os, molybdenite) that is accompanied by phyllic alteration (stage 2), and a poorly mineralized phase 3 diorite plug temporally overlaps with quartz-pyrophyllite alteration at shallow levels (stage 3). Two deformation events (D1 and D2), attributed to orogen-scale mid-Cretaceous transpression, structurally modified Mitchell. D1 deformation, expressed as steep E-striking pressure solution cleavage (S1) and related W-plunging folded veins (F1), is heterogeneously developed as a function of alteration type. D2 is divided into two progressive events: D2a, defined by N-plunging, folded veins (F2a), and D2b, defined by E-vergent thrust faults, including the Mitchell thrust fault, which offsets the updip continuation of Mitchell (the Snowfield deposit, 192.0 ± 1.0 Ma, 191.1 ± 0.8 Ma; Re-Os, molybdenite) ~1,600 m to the east-southeast. Host structures for the KSM trend may have been long-lived, N-striking basement lineaments that provided transcrustal magma and fluid pathways. East-trending intrusions, hydrothermal veins, alteration and metal distribution at Mitchell are attributed to subsidiary E-striking cross faults. These original anisotropies in turn influenced the geometry of Cretaceous faults and flattening domains within the deposit.

The Slave craton underwent widespread extension during the Paleoproterozoic. The East Arm basin of Great Slave Lake formed during this period and preserves a protracted record of sedimentation and volcanism in the southeastern Slave craton. Within the East Arm basin package, the Union Island Group represents voluminous mafic volcanism with subordinate sedimentary strata. We report the first high precision U–Pb zircon and baddeleyite dates for the Union Island Group; 2045.8 ± 1.0 Ma for a volcaniclastic unit from the lower basalt formation and 2042.7 ± 3.0 Ma for a diabase intrusion within volcaniclastic horizons in the lower basalt formation. We fundamentally revise the lower basin stratigraphy and demonstrate that the Union Island Group is the oldest identified supracrustal package in the East Arm basin, ∼120 Myr older than previously thought. This revised stratigraphy is supported by detrital zircon provenance age distribution in two Union Island Group sedimentary samples, which is dominated by 2.76–2.56 Ga ages, reflecting prominent input from the local Archean Slave basement. The Union Island Group contains two geochemically distinct mafic volcanic packages. The lower basalt package is predominantly alkaline, characterized by an OIB-like chemical signature with high and variable incompatible element contents (108–438 ppm Zr, 13–62 ppm Nb). In contrast, the upper basalt package is tholeiitic, contains much lower and uniform incompatible element contents (83–101 ppm Zr, 2–4 ppm Nb), and has an E-MORB-like chemical signature. Both packages display overlapping, depleted time-integrated eNd(i) values (+1.1 to +3.2). Petrological modeling suggests the lower package originated as OIB-like melts from the asthenosphere that interacted with a depleted reservoir; the upper package was produced by larger degree of partial melting of a similar mantle source, in addition to possible lithospheric input. The petrogenesis established in this study is consistent with a passive continental rift origin for the Union Island Group magmatism and is further supported by geochemical similarities with Proterozoic and Phanerozoic rift successions. We therefore propose that the 2046 Ma Union Island Group represents an incipient rift basin sequence formed during Paleoproterozoic extension that marked the initial breakup of the southern margin of the Slave craton from a pre-Laurentia supercontinent.

The ca. 1,500 to 1,325 Ma Mesoproterozoic Belt-Purcell Basin is an exceptionally preserved archive of Mesoproterozoic Earth and its paleoenvironmental conditions. The Belt-Purcell Basin is also host to world-class base metal sediment-hosted mineralization produced in a variety of settings from the rift stage of basin evolution through the subsequent influence of East Kootenay and Grenvillian orogenies. The mineral potential of this basin has not been fully realized yet. New rhenium-osmium (Re-Os) data presented here for chalcopyrite, pyrite, and black shale contribute to refine a robust genetic model for the origin of the Black Butte copper +/- cobalt +/- silver (Cu +/- Co +/- Ag) deposit hosted by the ca. >1,475 Ma Newland Formation in the Helena Embayment of the Belt-Purcell Basin in Montana, USA. Chalcopyrite Re-Os data yield an isochron age (1,488 +/- 34 Ma, unradiogenic initial Os-187/Os-188 composition Osi-ctudcoprite = 0.13 +/- 0.11) that overlaps with the geological age of the Newland Formation. Further, the Re-Os data of synsedimentary to diagenetic massive pyrite yield evidence of resetting with an isochron age (1,358 +/- 42 Ma) coincident with the timing of the East Kootenay orogeny. The unradiogenic Osi-ctudcoprite at ca. 1,488 Ma (0.13 +/- 0.11) argues for derivation of Os from a magmatic source with a Os-18(7)/Os-18(8) isotopic composition inherited from the upper mantle in the Mesoproterozoic (Os-mantle (1,475 Ma) = 0.12 +/- 0.02). The unradiogenic Osi-ctudcoprite also suggests limited contamination from a continental crustal source. This source of Os and our new sulfur isotopic signatures of chalcopyrite (-4.1 to +2.1 parts per thousand-VCDT) implies a dominantly magmatic source for metals. We integrate our new results and previously published geological and geochemical evidence to conceptualize a genetic model in which Cu and metals were largely contributed by moderate-temperature, reduced magmatic-hydrothermal fluids carrying reduced sulfur species with a magmatic origin and flowing as highly metalliferous fluids within the shale sequence. A subsidiary derivation of metals during thermally forced shale diagenesis is possible. Chalcopyrite mineralization replaced locally massive synsedimentary to diagenetic pyrite units close to the sediment-water interface, i.e., an ideal locus where magmatic-hydrothermal fluids could cool and the solubility of chalcopyrite would fall. We suggest that Cu mineralization was coeval with the timing of an enhanced thermal gradient in the Helena Embayment triggered until ca. 1,455 Ma by tholeiitic dike swarm that intruded into Archean basement rocks and intersected the NE-SW-trending Great Falls Tectonic Zone. ISSN:1941-8264 ISSN:1947-4253

Superimposed porphyry systems are a subset of telescoped porphyry deposits, whereby significantly younger ore zones overprint older, nongenetically related systems. Recognition of superimposed features in porphyry systems is important for determining and assessing their prospectivity. The Mount Nansen gold corridor in the southern Dawson Range gold belt of Yukon, Canada, contains porphyry prospects and epithermal deposits with enigmatic genetic models. Geologic, petrologic, temporal (U-Pb zircon, Re-Os molybdenite), and geochemical (whole-rock) studies are used to demonstrate the presence of superimposed porphyry systems in this district. The arc-related episodic magmatism of the Mount Nansen gold corridor has been classified into four intrusive suites: (1) Late Triassic Minto, (2) mid-Cretaceous Whitehorse, (3) Late Cretaceous Casino (eLKc; 80–72 Ma), and (4) Late Cretaceous Prospector Mountain (lLKp; 72–65 Ma). Geochemical fingerprinting of these suites indicates intermediate to evolved, calc-alkaline compositions with a common lower crust melt source. The eLKc and lLKp suites lack an Eu anomaly and show increasing amounts of light rare earth element (LREE) enrichment and heavy rare earth element (HREE) depletion over time. These features suggest that garnet was stable in the melt source and oxidized magmas were generated in these Late Cretaceous suites. The mildly alkaline lLKp and associated Carmacks Group shoshonitic basalts reflect localized extension in an overall compressive arc setting in the Mount Nansen gold corridor, hence a setting conducive for Au-rich porphyry and epithermal systems. The ca. 79 to 72 Ma Casino suite is commonly interpreted as the causative magmatic event for most well-endowed porphyry deposits (76 to 74 Ma in age) in the Dawson Range gold belt. However, our detailed study of the Klaza setting shows that at this locality, intermediate-sulfidation epithermal veins are a distal expression of a Prospector Mountain-age (ca. 71 Ma) porphyry system, which overprints two Casino-age porphyry systems (ca. 77 and 80 Ma). The Mount Nansen gold corridor thus hosts at least two spatially and temporally overprinting Late Cretaceous magmatic-hydrothermal systems in the Dawson Range gold belt. Importantly, recognition of this feature at other porphyry deposit settings in the Dawson Range gold belt (e.g., Freegold Mountain district) is critical as it provides the potential for metal (Cu-Au-Mo)-enriched hypogene ore shells.

The Anarraaq clastic-dominated (CD) Zn-Pb-Ag deposit (Red Dog district, Alaska, USA) has an inferred mineral resource of 19.4 Mt at 14.4% Zn, 4.2% Pb, and 73 g/t Ag and is spatially associated with a separate ~1 Gt barite body. This study presents new cross sections and petrographic evidence from the Anarraaq area. The barite body, previously shown to have formed in a shallow subsurface environment akin to a methane cold seep, contains multiple generations of barite with locally abundant calcite masses, which are discordant to sedimentary laminae, and is underlain by an interval of massive pyrite containing abundant framboids and radiolarians. Calcite and pyrite are interpreted to have formed by methane-driven diagenetic alteration of host sediment at the sulfate-methane transition (SMT). The sulfide deposit contains two zones of Zn-Pb mineralization bounded by faults of unknown displacement. The dominant hydrothermal minerals are marcasite, pyrite, sphalerite, quartz, and galena. The presence of hydrothermal pseudomorphs after barite, early pyrite resembling diagenetic pyrite associated with the barite body, and hydrothermal quartz and sphalerite filling voids formed by dissolution of carbonate all suggest that host sediment composition and origin was similar to that of the barite body prior to hydrothermal mineralization. Rhenium-osmium isochron ages of Ikalukrok mudstone (339.1 ± 8.3 Ma), diagenetic pyrite (333.0 ± 7.4 Ma), and hydrothermal pyrite (334.4 ± 5.3 Ma) at Anarraaq are all within uncertainty of one another and of an existing isochron age (~338 Ma) for the Main deposit in the Red Dog district. This indicates that the Anarraaq deposit formed soon after sedimentation and that hydrothermal activity was approximately synchronous in the district. The initial Os composition of the Anarraaq isochrons (0.375 ± 0.019–0.432 ± 0.025) is consistent with contemporaneous seawater, indicating that a mantle source was not involved in the hydrothermal system. This study highlights the underappreciated but important role of early, methane-driven diagenetic processes in the paragenesis of some CD deposits and has important implications for mineral exploration.

The origin, transport pathway, and spatial variability of total organic carbon (OC) in the western Himalayan glaciers are poorly understood compared to those of black carbon (BC) and dust, but it is critically important to evaluate the climatic role of OC in the region. By applying the distribution of OC activation energy; 14C activity; and radiogenic isotopes of 208Pb/204Pb, 207Pb/204Pb, and 206Pb/204Pb in glacial debris and atmospheric particulate matter (PM10 size fraction), we demonstrate that 98.3 ± 1.6 and 1.7 ± 1.6% of OC in western Himalayan glaciers are derived from biomass and petrogenic sources, respectively. The δ13C and N/C composition indicates that the biomass is a complex mixture of C3 vegetation and autochthonous photoautotrophic input modified by heterotrophic microbial activity. The data set reveals that the studied western Himalayan glacier has negligible contributions from fossil-fuel-derived particles, which contrasts to the central and eastern Himalayan glaciers that have significant contributions from fossil fuel sources. We show that this spatial variability of OC sources relates to regional differences in air mass transport pathways and precipitation regimes over the Himalaya. Moreover, our observation suggests that biomass-derived carbon could be the only primary driver of carbon-induced glacier melting in the western Himalaya.

Muruntau in the Central Kyzylkum desert of the South Tien Shan, western Uzbekistan, with past production of ~3,000 metric tons (t) Au since 1967, present annual production of ~60 t Au, and large remaining resources, is the world’s largest epigenetic Au deposit. The host rocks are the mainly Cambrian-Ordovician siliciclastic flysch of the Besapan sequence. The rocks were deformed into a broadly east-west fold-and-thrust belt prior to ca. 300 Ma during ocean closure along the South Tien Shan suture. A subsequent tectonic transition was characterized by left-lateral motion on regional splays from the suture and by a massive thermal event documented by widespread 300 to 275 Ma magmatism. The Besapan rocks were subjected to middle to upper greenschist-facies regional metamorphism, an overprinting more local thermal metamorphism to produce a large hornfels aureole, and then Au-related hydrothermal activity all during early parts of the thermal event. The giant Muruntau Au deposit formed in the low-strain hornfels rocks at ca. 288 Ma at the intersection of one of the east-west splays, the Sangruntau-Tamdytau shear zone, with a NE-trending regional fault zone, the Muruntau-Daugyztau fault, which likely formed as a cross fault during the onset of left-lateral translation on the regional splays. Interaction between the two faults opened a large dilational zone along a plunging anticlinorium fold nose that served as a major site for hydrothermal fluid focusing. The Au ores are dominantly present as a series of moderately to steeply dipping quartz ± K-feldspar stockwork systems surrounding uncommon central veins and with widespread lower Au-grade metasomatites (i.e., disseminated ores). Pervasive alteration is biotite-K-feldspar, although locally albitization is dominant. Sulfides are mainly arsenopyrite, pyrite, and lesser pyrrhotite, and scheelite may be present both in preore ductile veins and in the more brittle auriferous stockwork systems. The low-salinity, aqueous-carbonic ore-forming fluids probably deposited the bulk of the ore at 400° ± 50°C and 6-to 10-km paleodepth. The genesis of the deposit remains controversial with metamorphic, thermal aureole gold (TAG), and models related to mantle upwelling all having been suggested in recent years. More importantly, the question as to why there was such a focusing of so much Au and fluid into this one location, forming an ore system an order of magnitude larger than other giant Au deposits in metamorphic terranes, remains unresolved.

The southern portion of the Rae craton in the Canadian Shield is host to multiple ca. 2.63 Ga Ni-Cu-rich metamorphosed mafic intrusions with noritic, noritic-anorthositic and pyroxenitic compositions, including those hosting the undeveloped Axis Lake and Nickel King deposits found in northern Saskatchewan and southeast Northwest Territories. In order to understand the setting of these intrusions, and their concomitant mineralization, we investigated their geochemical and isotopic characteristics. Mineralized intrusions at Axis Lake and Nickel King are metamorphosed up to granulite facies, with local partial melting. The intrusions preserve whole-rock major element geochemistry consistent with a sub-alkaline basaltic composition (e.g., SiO2 = 46–54 wt%; TiO2 The Nd isotope values of the Axis Lake intrusion (ɛNdt2630 = +0.3 to +2.1) are more juvenile and closer to the depleted mantle value, relative to those of the Nickel King deposit (ɛNdt2630 = −2.4 to −0.4). This agrees with their also distinctive Th/Yb and Nb/Yb distributions suggesting oceanic and continental arc-like settings, respectively. The Axis Lake and Nickel King Nd isotope compositions are indistinguishable from other arc-like 2.61 to 2.58 Ga mafic to felsic intrusions and volcanic rocks recognized in the Rae craton and the neighboring Chesterfield block. The age, spatial distribution and geochemistry of the studied intrusions coincide with the initial stages of a recently defined 2.63–2.60 Ga continental arc, the roots of which are found in the south Rae craton. Our data indicate that Neoarchean intrusions with an arc-like geochemistry may be a significant exploration target in the Rae craton. This broadens possible host suites beyond the established Paleoproterozoic rift-related rocks most commonly considered as the prime target for Ni-Cu-PGE mineralization.

The early Cambrian to late Neoproterozoic Kelvin kimberlite pipe is located in the southeast of the Archean Slave Craton in northern Canada, eight km northeast of the Gahcho Kue diamond mine. Kelvin was first discovered in 2000 by De Beers Canada. Subsequent exploration undertaken by Kennady Diamonds Inc. between 2012 and 2016 resulted in the discovery of significant thicknesses of volcaniclastic kimberlite that had not previously been observed. Through extensive delineation drilling Kelvin has been shown to present an atypical, steep-sided inclined L-shaped pipe-like morphology with an overall dip of 15 to 20°. With a surface expression of only 0.08 ha Kelvin dips towards the northwest before turning north. The body (which remains open at depth) has been constrained to a current overall strike length of 700 m with varying vertical thickness (70 to 200 m) and width (30 to 70 m). Detailed core logging, petrography and microdiamond analysis have shown that the pipe infill comprises several phases of sub-horizontally oriented kimberlite (KIMB1, KIMB2, KIMB3, KIMB4, KIMB7 and KIMB8) resulting from multiple emplacement events. The pipe infill is dominated by Kimberley-type pyroclastic kimberlite or “KPK”, historically referred to as tuffisitic kimberlite breccia or “TKB”, with less common hypabyssal kimberlite (HK) and minor units with textures transitional between these end-members. An extensive HK sheet complex surrounds the pipe. The emplacement of Kelvin is believed to have been initiated by intrusion of this early sheet system. The main pipe-forming event and formation of the dominant KPK pipe infill, KIMB3, was followed by late stage emplacement of additional minor KPK and a hypabyssal to transitional-textured phase along the upper contact of the pipe, cross-cutting the underlying KIMB3. Rb-Sr age dating of phlogopite from a late stage phase has established model ages of 531 ± 8 Ma and 546 ± 8 Ma. Texturally and mineralogically, the Kelvin kimberlite is similar to other KPK systems such as the Gahcho Kue kimberlites and many southern African kimberlites; however, the external morphology, specifically the sub-horizontal inclination of the pipe, is unique. The morphology of Kelvin and the other kimberlites in the Kelvin-Faraday cluster defines a new type of exploration target, one that is likely not unique to the Kennady North Project area. Extensive evaluation work by Kennady Diamonds Inc. has resulted in definition of a maiden Indicated Mineral Resource for Kelvin of 8.5 million tonnes (Mt) of kimberlite at an average grade of 1.6 carats per tonne (cpt) with an average diamond value of US$ 63 per carat (ct).

The Red Chris porphyry Cu-Au deposit is located in the Stikinia island-arc terrane in northwest British Columbia. It is hosted by the Red Stock, which has five phases of porphyry intrusions: P1, P2E, P2I, P2L, and P3. New U-Pb dating of zircon shows that these intrusions were emplaced over a similar to 10 m.y. period, with P1 intruded at 211.6 +/- 1.3 Ma (MSWD = 0.85), P2I at 206.0 +/- 1.2 Ma (MSWD = 1.5), P2L at 203.6 +/- 1.8 Ma (MSWD = 1.5), and P3 at 201.7 +/- 1.2 Ma ( MSWD = 1.05). The ore-forming event at Red Chris was a short-lived event at 206.1 +/- 0.5 Ma (MSWD = 0.96; weighted average age of three Re-Os molybdenite analyses), implying a duration of Zircons from P1 to P3 porphyry rocks have consistently high Eu-N /Eu-N* ratios (mostly > 0.4), indicating that their associated magmas were moderately oxidized. The magmatic water contents estimated from plagioclase and amphibole compositions suggest H2O contents of similar to 5 wt %. Taken together, the P1 to P3 porphyries are interpreted to be moderately oxidized and hydrous. The porphyry phases are differentiated by sulfur and chlorine contents. The SO3 contents of igneous apatite microphenocrysts from the mineralization-related P2 porphyries are higher (P2E: 0.28 +/- 0.10 wt %, n = 19; P2I: 0.32 +/- 0.17, n = 15; P2L: 0.29 +/- 0.18 wt %, n = 100) than those from the premineralization P1(0.11 +/- 0.03 wt %, n = 34) and postmineralization P3 porphyries (0.03 +/- 0.01 wt %, n = 13). The chlorine contents in apatite grains from the P2E, P2I, and P2L porphyries are 1.47 +/- 0.22 (n = 19), 0.82 +/- 0.10 (n = 15), and 1.47 +/- 0.28 wt % (n = 100), also higher than those from P1 (0.51 +/- 0.3 wt % Cl, n = 34) and P3 (0.02 +/- 0.02 wt % Cl, n = 17). These results imply that the sulfur and chlorine contents of the P2 magmas were higher than in the P1 and P3 magmas, suggesting that elevated magmatic S-Cl contents in the P2 porphyries may have been important for ore formation. Although the process that caused the increase in sulfur and chlorine is not clear, reverse zoning seen in plagioclase phenocrysts from the P2 porphyry, and the occurrence of more mafic compositions in P2L, suggest that recharge of the deeper magma chamber by a relatively S-Cl-rich mafic magma may have triggered the ore-forming hydrothermal event.

The Kasperske Hory deposit represents one of the economically most important hydrothermal gold deposits in the Bohemian Massif (Czech Republic). We present new Re–Os age determinations for sulfides complemented by Ar–Ar determinations on silicate minerals in order to provide temporal constraints on the deposit formation. Arsenopyrite and molybdenite formed during gold-bearing stages I–III yielded similar Re–Os ages between ~ 341 and 333 Ma, overlapping with the Ar–Ar cooling age of the metamorphic host rocks below ~ 500 °C. Continuous cooling of the ore system below 270 °C during stage III is reflected by Ar–Ar muscovite ages spanning from ~ 332 to 325 Ma representing the long interval of formation of gold-productive stage III. Thus, the Kasperske Hory gold deposit is younger than the gold deposits spatially associated with the Central Bohemian Plutonic Complex (~ 349–339 Ma) belonging to the Central Bohemian Metallogenetic Zone (e.g., Mokrsko-West, Jilove, Petrackova Hora). This may indicate a rather close relationship to the nearby Moldanubian Batholith while still suggesting an intimate link between mineralization and Variscan orogenesis and associated magmatism.

The central Superior Craton hosts both the diamondiferous 1.1 Ga Kyle Lake and Jurassic Attawapiskat kimberlites. A major thermal event related to the Midcontinent Rift at ca. 1.1 Ga induced an elevated geothermal gradient that largely destroyed an older generation of diamonds, raising the question of when, and how, the diamond inventory beneath Attawapiskat was formed. We determined Re–Os isotope systematics of sulphides included in diamonds from Victor by isotope dilution negative thermal ionisation mass spectrometry in order to obtain insights into the age and nature of the diamond source in the context of regional tectonothermal evolution. Regression of the peridotitic inclusion data ( n = 14 of 16) yields a 718 ± 49 Ma age, with an initial 187Os/188Os ratio of 0.1177 ± 0.0016, i.e. depleted at the time of formation ( γ Os −3.7 ± 1.3). Consequently, Re depletion model ages calculated for these samples are systematically overestimated. Given that reported 187Os/188Os in olivine from Attawapiskat xenoliths varies strongly (0.1012–0.1821), the low and nearly identical initial Os of sulphide inclusions combined with their high 187Re/188Os (median 0.34) suggest metasomatic formation from a mixed source. This was likely facilitated by percolation of amounts of melt sufficient to homogenise Os, (re)crystallise sulphide and (co)precipitate diamond; that is, the sulphide inclusions and their diamond host are synchronous if not syngenetic. The ∼720 Ma age corresponds to rifting beyond the northern craton margin during Rodinia break-up. This suggests mobilisation of volatiles (C, N, S) and Os due to attendant mantle stretching and metasomatism by initially oxidising and S-undersaturated melts, which ultimately produced lherzolitic diamonds with high N contents compared to older Kyle Lake diamonds. Thus, some rift-influenced settings are prospective with respect to diamond formation. They are also important sites of hidden, intra-lithospheric volatile redistribution that can be revealed by diamond studies. Later emplacement of the Attawapiskat kimberlites, linking the carbon cycle to the surface, was associated with renewed disturbance during passage of the Great Meteor Hotspot. Lherzolitic diamond formation from oxidising small-volume melts may be the expression of an early and deep stage of the lithospheric conditioning required for the successful eruption of kimberlites, which complements the late and shallow emplacement of volatile-rich metasomes after upward displacement of a redox freezing front.

The final publication is available at Elsevier via https://doi.org/10.1016/j.gca.2018.01.036 © 2018. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/

The high-grade (8.1 million ounces of gold; 15.6 Mt grading 16.1 g/t Au; Pretium, 2016) Brucejack epithermal Au-Ag deposits are located in the Canadian Cordillera of northwestern British Columbia, and formed in association with extensive early Mesozoic island arc magmatism. Porphyry-type Cu-Au-Mo mineralization occurs nearby at the Kerr-Sulphurets-Mitchell (196–190 Ma; Febbo et al., 2015), Bridge Zone (191.7 ± 0.8 Ma, 191.5 ± 0.8 Ma), and West Zone (188.9 ± 0.9 Ma) prospects. Gold-silver vein-type mineralization at Brucejack is hosted by variably altered and deformed Early Jurassic porphyritic latite lava flows, volcaniclastic rocks, and volcanic-derived sandstones, siltstones, and conglomerates. This study focuses on the Valley of the Kings Zone at Brucejack, where host rocks have been dated at 188–184 Ma (U-Pb, zircon). Post-mineralization (but not post-alteration) basaltic and trachybasaltic dikes that cut the veins are geochemically similar to the host volcanic sequence and follow the same structural trends of the mineralized vein corridors. We suggest these dikes are broadly coeval with mineralization, and that ore formation at the Valley of the Kings formed during the overall Jurassic tectonomagmatic event. Gold-silver mineralization is hosted by quartz-carbonate veins that cut sericitized and pyritized volcaniclastic rocks. Six stages of veining are defined, with Au-Ag mineralization (electrum) focused in stages III–V: stage I–III veins consist of quartz with minor carbonate, chlorite, sericite, and sulfide minerals; stage IV quartz veins contain more abundant base metal sulfides (pyrite, sphalerite, and galena with minor sulfosalts); stage V veins are dominantly calcitic; late post-mineralization stage VI veins are quartz-calcite and contain sparse pyrite and chlorite, but no electrum. The veins are interpreted to be syn- to late-tectonic, with deformation decreasing from locally penetrative in the host-rocks prior to veining (resulting in local foliation of sericite and pressure shadows around pyrite), to dismemberment and shearing of early stage I–II quartz veins, brittle disruption of stage III–IV quartz and stage V carbonate veins, and minimal deformation of post-mineralization stage VI quartz-carbonate veins. A much younger set of extensional muscovite veins locally cuts the deposit with Late Cretaceous apparent ages, and appears to be associated with a weak thermal overprint that has reset K-Ar and 40Ar/39Ar ages in sericite throughout the district. The deformation experienced by the vein system, particularly in the later stages (III–V), was not uniform, and original undeformed vein textures and fluid inclusion assemblages are locally preserved. We report fluid inclusion microthermometric data from carefully selected primary fluid inclusion assemblages from quartz, calcite, and sphalerite from vein stages III–IV, many of which show evidence for boiling (coexisting liquid- and vapor-rich primary fluid inclusions). Liquid-rich fluid inclusions from stage III and V veins have moderate homogenization temperatures (∼170 °C and ∼160 °C respectively) and salinities of 2–8 wt% NaCl equiv., whereas inclusions from base-metal-sulfide-bearing stage IV veins show evidence of mixing with a cooler, more saline brine (∼140 °C, ∼10–15 wt% NaCl equiv.). Carbon dioxide was observed as clathrate during cooling in some fluid inclusions, suggesting that minor amounts of CO2 were present in the fluids. Calculated oxygen isotopic compositions of fluids in equilibrium with quartz and calcite from vein stages III–V range from δ18Ofluid = −10.7 to +1.8‰, whereas δ13CCO2 ranges from −9.5 to −4.5‰, and δ34Spyrite ranges from −1.7 to +0.6‰. Taken together, these data suggest a magmatic source for S and some C, carried by a fluid of evolved or diluted magmatic origin, which variably mixed with meteoric-derived groundwater or seawater containing carbon of sedimentary (organic) origin. Mixing is supported by large salinity ranges of vein stage IV fluid inclusions, where individual assemblages range from ∼1 to 15 wt% NaCl equiv. These fluid temperatures, salinities, and isotopic compositions are typical of epithermal deposits where distal magmatic fluids mix with local heated groundwaters. The low fluid temperatures but evidence of boiling suggest formation at shallow crustal depths. This is despite the evidence for penetrative deformation in the sericitized volcanosedimetary host rocks, which we attribute to rapid uplift immediately prior to or during the earliest stages of mineralization. The vein system is therefore interpreted to have formed during the later stages of a deformational event related to arc accretion.

The Hearne craton comprises the southeastern part of the western Churchill craton. The central part of the craton has been well studied in Nunavut and northeastern Saskatchewan in comparison with the southern part of the craton, which is mainly exposed south of the Athabasca Basin in Saskatchewan. Mapping and analytical results indicate that the southern Hearne craton is dominated by a felsic orthogneiss complex derived mainly from tonalites with crystallisation ages in the range 2.81–2.78 Ga and ca. 2.73 Ga. Sm-Nd isotopic analysis suggests that these evolved plutons (mean ƐNd = −3.3) were derived from a Mesoarchean to Paleoarchean source. Other components of the orthogneisses include leucotonalite intrusions dated at ca. 2.664 Ga and regionally extensive K-feldspar phyric granites emplaced between 2.63 and 2.60 Ga. Both of these suites have Sm-Nd isotopic signatures similar to the older tonalites. A suite of granodiorite and quartz diorite, one of which yielded a crystallisation age of 2.654 Ga, has unique Sm-Nd isotopic results with ƐNd values near CHUR. The felsic orthogneiss complex is unconformably overlain by the Black Birch Lake assemblage, which contains dominantly orthquartzites, mafic volcanic rocks and pelites. Detrital zircon signatures in the orthoquartzites are dominated by Archean sources and indicate that the supracrustal rocks were deposited after 2.60 Ga. The central Hearne Province extends into northeastern corner of Saskatchewan. It contains oceanic mafic volcanic rocks of the Ennadai Group that were intruded by juvenile tonalites at 2.71–2.70 Ga. The age and isotopic character of these tonalites contrasts markedly with those in the felsic orthogneiss complex of the southern Hearne Province. A comparison of plutonic suites and supracrustal assemblages of the central and southern Hearne Provinces suggests that there is heterogeneity between the two entities. Analysis of geophysical data, coupled with existing geological maps, suggest that an important tectonic boundary separates them. The current age relationships in the central and southern parts of the Hearne province imply that the two were juxtaposed after 2.60 Ga; however, the time of suturing remains equivocal.

The Tumpangpitu porphyry and high-intermediate-sulfidation epithermal deposit is the largest deposit in the Tujuh Bukit district, southeast Java, Indonesia. The porphyry resource contains 1.9 billion tonnes @ 0.45% Cu and 0.45 g/t Au, for 28.1 Moz Au and 19 billion lbs of Cu. There are an additional 2.1 Moz Au and 72.9 Moz of Ag in oxidized high-sulfidation epithermal mineralization. Tumpangpitu is located along a NW-striking structural corridor covering an area of 12 × 5 km that hosts several Cu-Au-Mo mineralized tonalitic porphyries, each with varying degrees of metal enrichment. At least eight discrete intrusions spanning the alteration-mineralization sequence have been identified at Tumpangpitu. What is unusual, however, is the presence of both a premineralization, relatively dry volcanic breccia pipe (Tanjung Jahe) and a late-mineralization diatreme complex associated with a significant, large magmatic-hydrothermal system (Tumpangpitu) in the same district. Magmatism, mineralization, and alteration at Tumpangpitu occurred in response to north-directed subduction of the Indo-Australian plate beneath the Asian continental plate margin. The Tujuh Bukit district is floored by early to late Miocene sedimentary and andesitic volcanic rocks. Volcanic-hydrothermal activity at Tujuh Bukit began with the formation of the weakly altered Tanjung Jahe diatreme complex (U-Pbzircon ages of 8.78 ± 0.22-8.52 ± 0.21 Ma). Mineralization at Tumpangpitu was preceded by the intrusion of a large, equigranular, dioritic batholith (5.81 ± 0.20-5.18 ± 0.27 Ma). Hydrothermal activity associated with mineralization has been constrained by U-Pb age determinations from syn- to late-mineralization porphyries that were emplaced in the early Pliocene from 5.40 ± 0.46 to 3.94 ± 0.69 Ma. High- and intermediate-sulfidation Au-Ag ± Cu mineralization and associated advanced argillic alteration (part of a district-scale lithocap) has overprinted and significantly upgraded the top of the porphyry orebody. Ar/Ar dating of alunite (4.385 ± 0.049 Ma) and Re-Os dating of molybdenite (4.303 ± 0.018 Ma) have defined a short time period between the high-sulfidation epithermal and porphyry mineralization events. This suggests extreme rates of uplift, exhumation, and erosion in the vicinity of the Sunda-Banda magmatic arc. Volcanic-hydrothermal activity associated with the Tumpangpitu diatreme occurred during epithermal mineralization (breccia matrix zircon age of 2.7 ± 1.0 Ma with systematic errors). Clasts of high-sulfidation state mineralized rocks are a minor but significant component of the diatreme, and late-stage epithermal veins cutting the diatreme demonstrate an intermineralization timing with respect to epithermal activity in the district, implying that epithermal mineralization continued intermittently for 1 to 1.5 m.y. after porphyry mineralization ceased at Tumpangpitu.

The Wafi-Golpu district of Papua New Guinea contains contrasting high- and intermediate-sulfidation styles of epithermal veins and alteration that have overprinted and partially obscured the giant, high-grade Golpu porphyry Cu-Au deposit. The initial stages of magmatic-hydrothermal activity produced high-grade porphyrystyle assemblages that are zoned about the Golpu diorite intrusions, with most mineralization formed between 8.76 ± 0.02 and 8.73 ± 0.01 Ma. Porphyry mineralization was followed by the eruption of the Wafi diatreme, after which upward-widening zones of epithermal alteration and mineralization have overprinted both the mineralized Golpu diorites and the Wafi diatreme. Above the top of the Golpu porphyry, vein and alteration assemblages include quartz (locally vuggy), alunite, pyrophyllite, kaolinite, dickite, and diaspore, with high-sulfidation mineralization consisting of pyrite-covellite-chalcocite-tennantite ± enargite ± bornite that transitions outward to a distal assemblage of disseminated pyrite-sphalerite ± tennantite. A zone of intermediate-sulfidation epithermal carbonate-sulfide ± quartz ± adularia veins and montmorillonite-chlorite ± muscovite ± illite alteration occurs along the margins of the high-sulfidation domain. Most of the epithermal Au occurs near the transition from the high- to intermediate-sulfidation domains. New geochronological results indicate that the main stage of Golpu porphyry mineralization to the last stage of Wafi epithermal veins lasted between 120 and 220 k.y.

Instituto de Geociencias e Ciencias Exatas Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Avenida 24 A, No. 1515

The Obři důl Fe–Cu–As polymetallic sulfide skarn deposit is developed in a metamorphic series in the West Sudetes, Bohemian Massif. It consists of lenses of marble, calc–silicate rocks, and skarns. We studied the Gustav orebody, which is located few hundred meters away from the contact with a large, late-orogenic Variscan Krkonose–Jizera Plutonic Complex (KJPC) emplaced into shallow crust. Mineralogical and fluid inclusion study evidence indicates that the main sulfide stage, dominated by pyrrhotite, arsenopyrite, and chalcopyrite originated from aqueous hydrothermal fluids with salinity up to 8 wt% NaCl eq. with minimum homogenization temperatures ranging from 324 to 358 °C. These fluids mainly replaced carbonate-rich lithologies. Carbon, oxygen, and strontium isotope data in Ca-rich rocks imply total overprinting by channelized metasomatic fluid flow, which is most probably related to the intrusion of the KJPC, whereas δ34S values of sulfides argue for a magmatic source of sulfur. The Re–Os age of arsenopyrite overlaps published age data for the KJPC and suggests synchronous formation of the main sulfide mineralization and pluton emplacement.

The magnetite deposits of the Turgai belt (Kachar, Sarbai and Sokolov), in the Valerianovskoe zone of the southern Urals, Kazakhstan, contain a combined resource of over 3 Gt of iron oxide ore. The deposits are hosted by carbonate sediments and volcaniclastic rocks of the Carboniferous Valerianovka Supergroup, and are spatially related to the gabbroic to granitoid composition intrusive rocks of the Sarbai–Sokolov intrusive series. The magnetite deposits are developed dominantly as metasomatic replacement of limestone, but also, to a lesser extent, of volcanic rocks. Pre-mineralisation metamorphism and alteration resulted in the formation of wollastonite and the silicification of limestone. Magnetite mineralisation is associated with the development of a high temperature skarn assemblage of diopside, grossular–andradite garnet, actinolite, epidote and apatite. Sub-economic copper-bearing sulphide mineralisation overprints the magnetite mineralisation and is associated with deposition of hydrothermal calcite and the formation of an extensive sodium alteration halo dominated by albite and scapolite. Chlorite formation accompanies this stage and further later stage hydrothermal overprints. The replacement has in places resulted in preservation of primary features of the limestone, including fossils and sedimentary structures in magnetite, skarn calc-silicates and sulphides. Analysis of Re–Os isotopes in molybdenite indicates formation of the sulphide mineral assemblage at 336.2 ± 1.3 Ma, whilst U–Pb analyses of titanite from the skarn alteration assemblage suggests skarn alteration at 326.6 ± 4.5 Ma with re-equilibration of isotope systematics down to ~ 270 Ma. Analyses of mineral assemblages, fluid inclusion microthermometry, O and S isotopes suggest initial mineralisation temperatures in excess of 600 °C from hypersaline brines (45–50 wt.% NaCl eq.), with subsequent cooling and dilution of fluids to around 150 °C and 20 wt.% NaCl eq. by the time of calcite deposition in late stage sulphide-bearing veins. δ 18 O in magnetite (− 1.5 to + 3.5‰) and skarn forming silicates (+ 5 to + 9‰), δ 18 O and δ 13 C in limestone and skarn calcite (δ 18 O + 5.4 to + 26.2‰; δ 13 C − 12.1 to + 0.9‰) and δ 34 S in sulphides (− 3.3 to + 6.6‰) and sulphates (+ 4.9 to + 12.9‰) are all consistent with the interaction of a magmatic-equilibrated fluid with limestone, and a dominantly magmatic source for S. All these data imply skarn formation and mineralisation in a magmatic–hydrothermal system that maintained high salinity to relatively late stages resulting in the formation of the large Na-alteration halo. Despite the reported presence of evaporites in the area there is no evidence for evaporitic sulphur in the mineralising system. These skarns show similarities to some members of the iron oxide–apatite and iron oxide–copper gold deposit classes and the model presented here may have implications for their genesis. The similarity in age between the Turgai deposits and the deposits of the Magnitogorsk zone in the western Urals suggests that they may be linked to similar magmatism, developed during post-orogenic collapse and extension following the continent–continent collision, which has resulted in the assembly of Laurussian terranes with the Uralide orogen and the Kazakh collage of the Altaids or Central Asian Orogenic Belt. This model is preferred to the model of simultaneous formation of very similar deposits in arc settings at either side of an open tract of oceanic crust forming part of the Uralian ocean.

The sediment-hosted stratiform Cu ± Co deposits and prospects of the Central African Copperbelt are characterized by two intimately associated mineralization styles: disseminated sulfides and sulfide-bearing quartz-carbonate veins and veinlets. It has been widely accepted that the disseminated mineralization was introduced during sediment diagenesis in a rift setting, and possibly in multiple events spanning several hundred million years. In contrast, the veinlet-hosted mineralization is commonly thought to have been derived either by remobilization of the disseminated sulfides during the Lufilian collisional orogeny or introduced at broadly the same time(s) as the disseminated sulfides during diagenesis and subsequent orogeny. The results of 15 Re-Os molybdenite age determinations from Cu ± Co deposits and prospects across the Zambian part of the Central African Copperbelt suggest that both the disseminated and veinlet mineralization styles were indeed generated together, but in a 50-myr Cambrian window (~540–490 Ma) during the later stages of the Lufilian collisional orogeny. The molybdenite ages for the disseminated stratiform mineralization at two localities do not support the notion of syndiagenetic Cu introduction. The molybdenite ages also show that individual deposits formed over minimum time intervals of ~10–24 myr.

The Cerro la Mina Au (Cu-Mo) porphyry-high sulfidation prospect is located in Chiapas State, southeastern Mexico, outside of the major metallogenic provinces of Mexico. The prospect is hosted by Pleistocene alkaline volcanic rocks of the Chiapanecan volcanic arc that formed in a complex triple-junction tectonic setting. Cerro la Mina's stratigraphy comprises pyroclastic flows that were intruded by monzodiorites and diorites at 1.04 ± 0.04 Ma (U-Pb, zircon), and that were overlain by debris flows and synvolcanic trachyandesite domes. The volcanic stratigraphy of Cerro la Mina is dominated by pyroclastic flows and rare basalts that are cut by the Cerro la Mina breccia pipe, a matrix-rich granular, vertically oriented, downward-tapering, polymict lithic rock unit that is host to all of the significant alteration and mineralization. A NW-trending sinistral wrench fault, which was active throughout the history of Cerro la Mina, is responsible for dismembering the prospect after mineralization. The magmatic hydrothermal system was composed of early porphyry-style potassic veins (quartz + K-feldspar ± biotite) and stage 1 pyrite that are preserved in clasts within the breccia pipe, suggesting that brecciation disrupted an embryonic porphyry system. Late potassic alteration occurred after the formation of the breccia pipe, as its matrix is strongly K-feldspar altered. Hydrothermal fluids then produced phyllic alteration composed of quartz, muscovite, illite, illite-smectite, and chlorite that is associated with stage 2 pyrite ± chalcopyrite ± molybdenite ± quartz veins. An unusual zoned pattern of advanced argillic-argillic alteration overprinted potassic and phyllic alteration. This zoning included a low-temperature ( 120°C) quartz + dickite ± kaolinite ± pyrophyllite ± alunite that occurs from 250 m to the present-day surface. The advanced argillic-argillic altered rocks host the most significant Au-Cu mineralization, which is associated with stage 3 marcasite, sphalerite, galena, and barite, and stage 4 arsenian pyrite ± enargite ± covellite. The magmatic hydrothermal system at Cerro la Mina began sometime between monzodiorite emplacement (1.04 ± 0.04 Ma; zircon U-Pb) and the precipitation of porphyry stage 2 molybdenite at 780 ± 10 ka (Re-Os). 40Ar/39Ar dating of biotite (689 ± 13 ka) records the age at which the hydrothermal system cooled below the biotite closure temperature of ~300°C and provides a maximum estimate for the onset of advanced argillic-argillic alteration. Sulfur isotope results of sulfides (–2.5 to +4.9‰; mean +0.7‰; n = 20) and a sulfate (barite; +10.5‰; n = 1) suggest a magmatic source of sulfur for all four stages of mineralization. The lack of residual quartz, rare alunite, and anomalous halloysite-kaolinite alteration may be explained by the high acid-buffering capacity of alkaline volcanic host rocks, high CO2 contents of the alkaline magma, and/or potentially by a highly reduced magmatic hydrothermal fluid. At the regional metallogenic scale, the Cerro la Mina prospect along with the nearby Santa Fe mine and Campamento deposit represent parts of a porphyry copper system—specifically, a porphyry/high-sulfidation, proximal skarn and intermediate sulfidation deposit, respectively. The characteristics of Cerro la Mina (i.e., anomalous halloysite-kaolinite alteration) broaden the window for additional discoveries to be made in the porphyry-epithermal environment.

Porphyry Cu ± Mo ± Au and iron oxide copper-gold (IOCG) deposits share many similarities (e.g., Fe, Cu, and Au contents), but also have important differences (e.g., the predominance of sulfide minerals in porphyry deposits and iron oxides in IOCG deposits). Genetic comparisons are complicated by the broad definition of IOCG deposits; here we restrict our study to IOCG deposits that are related to igneous intrusive systems. In the Mesozoic Coastal Cordillera of northern Chile, both porphyry and IOCG deposits occur in close spatial and temporal proximity, offering the chance to examine what controls their different modes of formation. From detailed examination of the timing, geochemistry, and tectonic setting of associated igneous rocks, based on new and published data, we find that rocks associated with mid-Cretaceous IOCG deposits (~125–110 Ma) are largely indistinguishable from those associated with slightly earlier (>125 Ma) and later (

The Merlin deposit, located in the Cloncurry district, Mt. Isa Inlier, is the world’s highest-grade Mo-Re deposit. Although the district is renowned for iron oxide copper-gold (IOCG)–type mineralization, Merlin and other Mo-rich occurrences in the district cannot be classified as IOCG-type deposits. The Merlin deposit is hosted by the Kuridala Group (1690–1650 Ma), which comprises interbedded phyllite and carbonaceous slate, calcsilicate rocks, and silicified metasiltstone. The Mount Dore Granite, part of the Williams-Naraku batholith (ca. 1540–1490 Ma), is locally thrust over the metasedimentary rock package. An early Cu-Pb-Zn sulphide stage (Mount Dore deposit) mostly overlies, with only partial spatial overlap, the younger Mo-Re mineralization (Merlin deposit). Cu-Pb-Zn is mainly hosted by carbonaceous slate as infill of hydrothermal coast-supported carbonate breccias; the younger Mo-Re mineralization (Merlin deposit) occurs as molybdenite infill of hydrothermal matrix-supported breccias along or near the contact between carbonaceous slate and calc-silicate rocks, and locally cuts the Cu-Pb-Zn mineralization. Based on detailed petrography and radiometric age dating (U-Pb zircon and titanite ages, Re-Os molybdenite ages), we define four main stages of hydrothermal alteration. Stage 1 represents the earliest hydrothermal stage, dated here by U-Pb titanite geochronology at 1551 ± 12 Ma, and is characterized by Na-(Ca) alteration with the formation of hematite-dusted albite + amphibole + carbonates + titanite + apatite + quartz ± magnetite ± epidote. Stage 2 is characterized by the formation of K-feldspar + tourmaline + carbonates + quartz ± apatite and Cu-Pb-Zn mineralization with chalcopyrite + sphalerite + pyrite ± galena. Stage 3 is dated at 1535 ± 6 Ma (Re-Os molybdenite) and consists of the main Mo-Re event that formed intensely mineralised, matrix-supported breccias accompanied by K-feldspar ± chlorite alteration. Stage 4, dated here at 1521 ± 3 Ma (Re-Os molybdenite), is of an age similar to that of the emplacement of the Mount Dore Granite (1517 ± 7 Ma; U-Pb zircon), and is interpreted as either a remobilization event or a later addition of Mo-Re in veins and disseminations that extends several meters below the Mo-Re breccias, with formation of chlorite + K-feldspar + apatite ± rutile. The Mount Dore Granite was thrust above the metasedimentary package at ca. 1500 Ma, which coincided with the waning of the hydrothermal activity in the Cloncurry district. This event is interpreted to be manifested at the Merlin deposit as minor, millimeter-scale Mo-Re vein formation. Collectively, our data indicate that the Merlin and the Mount Dore mineralization formed via a complex and protracted hydrothermal history that includes a time period (ca. 1560–1540) that has previously been regarded as unprospective for ore deposit formation in the region.

We report the first study of the Re-Os systematics of cobaltite (CoAsS) using disseminated grains and massive sulfides from samples of two breccia-type and two stratabound deposits in the Co-Cu-Au Idaho cobalt belt (ICB), Lemhi subbasin to the Belt-Purcell Basin, Idaho, USA. Using a 185Re + 190Os spike solution, magnetic and non-magnetic fractions of cobaltite mineral separates give reproducible Re-Os analytical data for aliquot sizes of 150 to 200 mg. Cobaltite from the ICB has highly radiogenic 187Os/188Os ratios (17–45) and high 187Re/188Os ratios (600–1800) but low Re and total Os contents (ca. 0.4–4 ppb and 14–64 ppt, respectively). Containing 30 to 74% radiogenic 187Os, cobaltite from the ICB is amenable to Re-Os age determination using the isochron regression approach. Re-Os data for disseminated cobaltite mineralization in a quartz-tourmaline breccia from the Haynes-Stellite deposit yield a Model 1 isochron age of 1349 ± 76 Ma (2σ, n = 4, mean squared weighted deviation MSWD = 2.1, initial 187Os/188Os ratio = 4.7 ± 2.2). This middle Mesoproterozoic age is preserved despite a possible metamorphic overprint or a pulse of metamorphic-hydrothermal remobilization of pre-existing cobaltite that formed along fold cleavages during the ca. 1190–1006 Ma Grenvillian orogeny. This phase of remobilization is tentatively identified by a Model 3 isochron age of 1132 ± 240 Ma (2σ, n = 7, MSWD = 9.3, initial 187Os/188Os ratio of 9.0 ± 2.9) for cobaltite in the quartz-tourmaline breccia from the Idaho zone in the Blackbird mine. All Mesoproterozoic cobaltite mineralization in the district was affected by greenschist- to lower amphibolite-facies (garnet zone) metamorphism during the Late Jurassic to Late Cretaceous Cordilleran orogeny. However, the fine- to coarse-grained massive cobaltite mineralization from the shear zone-hosted Chicago zone, Blackbird mine, is the only studied deposit that has severely disturbed Re-Os systematics with evidence for a linear trend of mixing with (metamorphic?) fluids. The new Re-Os ages and extremely high initial 187Os/188Os ratios of cobaltite reported here favor a magmatic-hydrothermal genetic model for a multi-stage REE-Y-Co-Cu-Au mineralization occurring at ca. 1370 to 1349 Ma, and related to the emplacement of the Big Deer Creek granite pluton at ca. 1377 Ma. In our model, deposition of paragenetically early xenotime and gadolinite was followed by an influx of Mesoproterozoic evaporitic brines and magmatic-hydrothermal fluids containing metals and reduced sulfur derived from mafic and oceanic island-arc Archean to Paleoproterozoic rocks in the Laurentian basement. Cobaltite mineralization occurred upon cooling of these fluids at an inferred temperature of 300 °C or below.

Lollingite and arsenopyrite aggregates occur in spessartine-almandine garnet rocks (garnetite) metamorphosed to granulite facies, which are spatially associated with Pb-Zn-Ag mineralization in the giant Broken Hill deposit, southern Curnamona Province, New South Wales, Australia. Sulfarsenide and sulfide minerals comprise lollingite and coexisting arsenopyrite ± galena ± tetrahedrite that occur interstitial to garnet crystals. Lollingite formed first while gold-bearing lollingite, which occurs as rare relicts in arsenopyrite, was destroyed to produce arsenopyrite ± detectable micro-inclusions of invisible gold. Standard mineral separation procedures produced pure separates of lollingite, arsenopyrite, and mixtures of arsenopyrite ± lollingite and lollingite ± arsenopyrite. In a plot of 187 Re/ 188 Os versus 187 Os/ 188 Os, samples of lollingite and lollingite ± arsenopyrite have 187 Re/ 188 Os ratios between 6.87 and 7.40 and 187 Os/ 188 Os ratios between 0.8506 and 0.8651, whereas arsenopyrite and arsenopyrite ± lollingite samples have higher 187 Re/ 188 Os ratios (7.14 to 11.32) and more radiogenic 187 Os/ 188 Os ratios (0.8828 to 0.9654). Thirteen analyses of arsenopyrite and arsenopyrite ± lollingite define a Model 1 isochron with an age of 1574 ± 38 Ma (2σ; MSWD = 1.4, initial 187 Os/ 188 Os ratio of 0.666 ± 0.006), whereas the five lollingite and lollingite ± arsenopyrite samples define a Model 1 isochron with an age of 1707 ± 290 Ma (2σ; MSWD = 0.32, initial 187 Os/ 188 Os ratio of 0.652 ± 0.036) that is indistinguishable from the arsenopyrite age. Rhenium and Os contents are extremely high for lollingite and arsenopyrite (Re = 120–475 ppb; Os = 65–345 ppb), likely as a result of concentration of Re and Os in these minerals during granulite-facies metamorphism from the inferred exhalite protolith. Petrographic observations combined with the Model 1 Re-Os ages and literature SHRIMP U-Pb ages of monazite in garnetite suggest that arsenopyrite formed on the retrograde path at the expense of lollingite. Cooling from peak Olarian P-T conditions (∼800 °C at 1602 Ma) to at least 550 °C (first temperature of stability of arsenopyrite) at ca . 1574 Ma occurred at a rate of ∼9 °C/Myr, which is similar to the rate of cooling determined for previously published SHRIMP U-Pb ages from successive monazite generations (McFarlane & Frost 2009). These results are consistent with the late phase of retrograde metamorphism that began between ca . 1590 and 1575 Ma.

Accurate and precise geochronology using the Re-Os isotopic system in pyrite is an invaluable tool for developing and confirming genetic models of ore systems. However, as a bulk method, the results produced by pyrite Re-Os geochronology are commonly complex, and many imprecise isochrons exist in the literature. Using LA-ICPMS methods it is now possible to map and quantify Re distribution at the ppb level, allowing an unprecedented look into the Re-Os systematics of pyrite-bearing ore. Two samples from the Lisheen Zn-Pb ore deposit in Ireland showing disparate Re-Os isotopic behavior were investigated. In-situ sulfur isotope measurements using SIMS, an analytical technique not previously attempted on the Irish deposits, was used to supplement the Re-Os dataset. A massive pyrite sample from the Main Zone produced a precise, low-scatter isochron (346.6 ± 3.0 Ma, MSWD = 1.6). The Re distribution in this sample is relatively homogeneous, with the Re budget dominated by pyrite containing 1–5 ppb Re, but the δ34S varies significantly from −45.2‰ to 8.2‰. A second, more paragenetically complex, sample from the Derryville Zone produced a younger age with high scatter (322 ± 11 Ma, MSWD = 206) and this also displays a large variation in δ34S (−53‰ to +4‰). The cores of grains of main-stage iron sulfide are depleted in trace elements and show low Re abundances (