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By utilizing a multi-orbital periodic Anderson model with parameters obtained from \textit{ab initio} band structure calculations, combined with degenerate perturbation theory, we derive effective Kondo-Heisenberg and spin Hamiltonians that capture the interaction among the effective magnetic moments. This derivation encompasses fluctuations via both non-magnetic $4f^0$ and magnetic $4f^2$ virtual states, and its accuracy is confirmed through comparison with experimental data obtained from CeIn$_3$. The significant agreement observed between experimental results and theoretical predictions underscores the potential of deriving minimal models from first-principles calculations for achieving a quantitative description of $4f$ materials. Moreover, our microscopic derivation unveils the underlying origin of anisotropy in the exchange interaction between Kramers doublets, shedding light on the conditions under which this anisotropy may be weak compared to the isotropic contribution., Comment: 30 pages, 16 figures

We report measurements of the low temperature magnetization $M$ and specific heat $C$ as a function of temperature and magnetic field of the quasi-one-dimensional spin chain, heavy fermion compound YbFe$_5$P$_3$, which resides close to a quantum critical point. The results are compared to the predictions of scaling laws obtained from a generalized free energy function expected near an antiferromagnetic quantum critical point (AFQCP). The scaling behavior depends on the dimensionality $d$ of the fluctuations, the coherence length exponent $\nu$, and the dynamic exponent $z$. The free energy treats the magnetic field as a relevant renormalization group variable, which leads to a new exponent $\phi=\nu z_h$, where $z_h$ is a dynamic exponent expected in the presence of a magnetic field. When $z_h=z$, $T/H$ scaling is expected, as observed in several compounds close to a QCP; whereas in YbFe$_5$P$_3$, a $T/H^{3/4}$ dependence of the scaling is observed. This dependence reflects the relationship $z_h=(4z/3)$ and a field exponent $\phi =4/3$. A feature of the scaling law is that it restricts the possible values of the exponents to two cases for YbFe$_5$P$_3$: $d$=1, $\nu$=1, $z$=1, and $d$=2, $\nu$=1/2, $z$=2., Comment: 17 pages (including Supplemental Material)

CeRh$_6$Ge$_4$ is unusual in that its ferromagnetic transition can be suppressed continuously to zero temperature, i.e., to a ferromagnetic quantum-critical point (QCP), through the application of modest hydrostatic pressure. This discovery has raised the possibility that the ferromagnetic QCP may be of the Kondo-breakdown type characterized by a jump in Fermi volume, to which thermopower S measurements should be sensitive. Though $S/T$ changes both sign and magnitude around the critical pressure P$_{c}\approx{}0.8$ GPa, these changes are not abrupt but extend over a pressure interval from within the ferromagnetic state up to P$_c$. Together with temperature and pressure variations in electrical resistivity and previously reported heat capacity, thermopower results point to the near coincidence of two sequential effects near P$_c$, delocalization of 4f degrees-of-freedom through orbital-selective hybridization followed by quantum criticality of itinerant ferromagnetism., Comment: 6 pages, 3 figures

We study the magnetic heat capacity of a series of magnetically ordered Ce-based heavy fermion materials, which show an anomalous $T^3$ heat capacity in excess of the phonon contribution in many materials. For compounds for which magnon models have been worked out, we show that the local-moment magnon heat capacity derived from the measured magnon spectra underestimates the experimental specific heat. The excess heat capacity reveals increasing density of states with increasing energy, akin to a pseudogap. We show that this anomalous temperature-dependent term is not associated with proximity to a quantum critical point (QCP), but is strongly correlated with $T_N$, indicating the anomalous excitations are governed by the magnetic exchange interaction. This insight may hold key information for understanding magnetically ordered heavy fermions., Comment: 5 pages, 4 figures

Eu$_5$In$_2$Sb$_6$ is a member of a family of orthorhombic nonsymmorphic rare-earth intermetallics that combines large localized magnetic moments and itinerant exchange with a low carrier density and perpendicular glide planes. This may result in special topological crystalline (wallpaper fermion) or axion insulating phases. Recent studies of Eu$_5$In$_2$Sb$_6$ single crystals have revealed colossal negative magnetoresistance and multiple magnetic phase transitions. Here, we clarify this ordering process using neutron scattering, resonant elastic X-ray scattering, muon spin-rotation, and magnetometry. The nonsymmorphic and multisite character of Eu$_5$In$_2$Sb$_6$ results in coplanar noncollinear magnetic structure with an Ising-like net magnetization along the $a$ axis. A reordering transition, attributable to competing ferro- and antiferromagnetic couplings, manifests as the onset of a second commensurate Fourier component. In the absence of spatially resolved probes, the experimental evidence for this low-temperature state can be interpreted either as an unusual double-$q$ structure or in a phase separation scenario. The net magnetization produces variable anisotropic hysteretic effects which also couple to charge transport. The implied potential for functional domain physics and topological transport suggests that this structural family may be a promising platform to implement concepts of topological antiferromagnetic spintronics.

To search for dark matter candidates with masses below $\mathcal{O}$(MeV), the SPLENDOR (Search for Particles of Light dark mattEr with Narrow-gap semiconDuctORs) experiment is developing novel narrow-bandgap semiconductors with electronic bandgaps on the order of 1-100 meV. In order to detect the charge signal produced by scattering or absorption events, SPLENDOR has designed a two-stage cryogenic HEMT-based amplifier with an estimated charge resolution approaching the single-electron level. A low-capacitance ($\sim$1.6 pF) HEMT is used as a buffer stage at $T=10\,\mathrm{mK}$ to mitigate effects of stray capacitance at the input. The buffered signal is then amplified by a higher-capacitance ($\sim$200 pF) HEMT amplifier stage at $T=4\,\mathrm{K}$. Importantly, the design of this amplifier makes it usable with any insulating material - allowing for rapid prototyping of a variety of novel detector materials. We present the two-stage cryogenic amplifier design, preliminary voltage noise performance, and estimated charge resolution of 7.2 electrons., Comment: 4 pages, 3 figures, 1 table, conference proceedings for LTD20

We present time-domain THz spectroscopy of thin films of the heavy-fermion superconductor CeCoIn$_5$. The complex optical conductivity is analyzed through a Drude model and extended Drude model analysis. Below the $\approx$ 40 K Kondo coherence temperature, a narrow Drude-like peak forms, as the result of the $f$ orbital - conduction electron hybridization and the formation of the heavy-fermion state. Via an extended Drude model analysis, we measure the frequency-dependent scattering rate ($1/ \tau $) and effective mass ($m^*/m_b$). This scattering rate shows a linear dependence on temperature, which matches the dependence of the resistivity as expected. Nonetheless, the width of the low-frequency Drude peak (characterized by a {\it renormalized} quasiparticle scattering rate ($1 / \tau^* = m_b/ m^* \tau $) does show a $T^2$ dependence giving evidence for a hidden Fermi state., Comment: 5 pages, 4 figures

We report a study of the structural, magnetic, transport, and thermodynamic properties of polycrystalline samples of CeRhC$_2$. CeRhC$_2$ crystallizes in a tetragonal structure with space group $P4_1$ and it orders antiferromagnetically below $T_\textrm{N1} \approx$ 1.8 K. Powder neutron diffraction measurements reveal a chiral magnetic structure with a single propagation vector $Q_m = (1/2,1/2,0.228(5))$, indicating an antiferromagnetic arrangement of Ce magnetic moments in the $ab$-plane and incommensurate order along the $c$-axis with a root-mean-square ordered moment of $m_\textrm{ord}$= 0.68 $\mu_\textrm{B}$/Ce. Applying a magnetic field suppresses the N\'{e}el temperature $T_\textrm{N1}$ to zero near $\mu_0H_\textrm{c1}\sim$0.75 T. A second antiferromagnetic phase ($T_\textrm{N2}$), however, becomes apparent in electrical resistivity, Hall and heat capacity measurements in fields above 0.5 T and extrapolates to zero temperature at $\mu_0H_\textrm{c2}\sim$ 1 T. Electrical resistivity measurements reveal that LaRhC$_2$ is a semiconductor with a bandgap of $E_\textrm{g}\sim24$ meV; whereas, resistivity and Hall measurements indicate that CeRhC$_2$ is a semimetal with a low carrier concentration of $n\sim10^{20}$ cm$^{-3}$. With applied hydrostatic pressure, the zero-field antiferromagnetic transition of CeRhC$_2$ is slightly enhanced and CeRhC$_2$ becomes notably more metallic up to 1.36 GPa. The trend toward metallicity is in line with density-functional calculations that indicate that both LaRhC$_2$ and CeRhC$_2$ are semimetals, but the band overlap is larger for CeRhC$_2$, which has a smaller unit cell volume that its La counterpart. This suggests that the bandgap closes due to a lattice contraction when replacing La with Ce in RRhC$_2$ (R = rare-earth), in agreement with experimental results.

Topological superconductivity is a long-sought state of matter in bulk materials, and odd-parity superconductor UTe$_2$ is a prime candidate. The recent observation of a field-trainable spontaneous Kerr signal in UTe$_2$ at the onset of superconductivity provides strong evidence that the superconducting order parameter is multicomponent and breaks time-reversal symmetry. Here, we perform Kerr effect measurements on a number of UTe$_2$ samples -- grown $via$ both chemical vapor transport and the molten-salt-flux methods -- that show a single superconducting transition between 1.6~K and 2.1~K. Our results show no evidence for a spontaneous Kerr signal in zero field measurements. This implies that the superconducting state of UTe$_2$ does not intrinsically break time-reversal symmetry. Instead, we observe a field-trainable signal that varies in magnitude between samples and between different locations on a single sample, which is a sign of inhomogeneous magnetic regions. Our results provide an examination of representative UTe$_2$ samples and place strong constraints on the superconducting order parameter of UTe$_2$.

We report a detailed study of the magnetic, transport, and thermodynamic properties of Ce$_2$Te$_5$ single crystals, a layered $f$-electron van der Waals magnet. Four consecutive transitions at $\sim$ 5.2, 2.1, 0.9, and 0.4 K were observed in the $ac$-plane electrical resistivity $\rho$(T), which were further confirmed in specific heat $C_\textrm{p}$(T) measurements. Analysis of the magnetic susceptibility $\chi$(T), the magnetic-field variation of $\rho$(T), and the increase of the first transition temperature ($T_\textrm{c} \sim$ 5.2 K) with applied magnetic field indicates ferromagnetic order, while the decrease of the other transitions with field suggests different states with dominant antiferromagnetic interactions below $T_2 \sim$ 2.1 K, $T_3 \sim$ 0.9 K, and $T_4$ = 0.4 K. Critical behavior analysis around $T_\textrm{c}$ that gives critical exponents $\beta = 0.31(2)$, $\gamma = 0.99(2)$, $\delta = 4.46(1)$, $T_\textrm{c} = 5.32(1)$ K indicates that Ce$_2$Te$_5$ shows a three-dimensional magnetic critical behavior. Moreover, the Hall resistivity $\rho_{\textrm{xy}}$ indicates that Ce$_2$Te$_5$ is a multi-band system with a relatively high electron mobility $\sim 2900$ cm$^2$ V$^{-1}$ s$^{-1}$ near $T_\textrm{c}$, providing further opportunities for future device applications.

Electrons at the border of localization generate exotic states of matter across all classes of strongly correlated electron materials and many other quantum materials with emergent functionality. Heavy electron metals are a model example, in which magnetic interactions arise from the opposing limits of localized and itinerant electrons. This remarkable duality is intimately related to the emergence of a plethora of novel quantum matter states such as unconventional superconductivity, electronic-nematic states, hidden order and most recently topological states of matter such as topological Kondo insulators and Kondo semimetals and putative chiral superconductors. The outstanding challenge is that the archetypal Kondo lattice model that captures the underlying electronic dichotomy is notoriously difficult to solve for real materials. Here we show, using the prototypical strongly-correlated antiferromagnet CeIn$_3$, that a multi-orbital periodic Anderson model embedded with input from ab initio bandstructure calculations can be reduced to a simple Kondo-Heisenberg model, which captures the magnetic interactions quantitatively. We validate this tractable Hamiltonian via high-resolution neutron spectroscopy that reproduces accurately the magnetic soft modes in CeIn$_3$, which are believed to mediate unconventional superconductivity. Our study paves the way for a quantitative understanding of metallic quantum states such as unconventional superconductivity.

Effective models focused on pertinent low-energy degrees of freedom have substantially contributed to our qualitative understanding of quantum materials. An iconic example, the Kondo model, was key to demonstrating that the rich phase diagrams of correlated metals originate from the interplay of localized and itinerant electrons. Modern electronic structure calculations suggest that to achieve quantitative material-specific models, accurate consideration of the crystal field and spin-orbit interactions is imperative. This poses the question of how local high-energy degrees of freedom become incorporated into a collective electronic state. Here, we use resonant inelastic x-ray scattering (RIXS) on CePd$_3$ to clarify the fate of all relevant energy scales. We find that even spin-orbit excited states acquire pronounced momentum-dependence at low temperature - the telltale sign of hybridization with the underlying metallic state. Our results demonstrate how localized electronic degrees of freedom endow correlated metals with new properties, which is critical for a microscopic understanding of superconducting, electronic nematic, and topological states.

The proposed topological Kondo insulator SmB$_{6}$ hosts a bulk Kondo hybridization gap that stems from strong electronic correlations and a metallic surface state whose effective mass remains disputed. Thermopower and scanning tunneling spectroscopy measurements argue for heavy surface states that also stem from strong correlations, whereas quantum oscillation and angle-resolved photoemission measurements reveal light effective masses that would be consistent with a Kondo breakdown scenario at the surface. Here we investigate the evolution of the surface state via electrical and thermoelectric transport measurements under hydrostatic pressure, a clean symmetry-preserving tuning parameter that suppresses the Kondo gap and increases the valence of Sm from 2.6+ towards a 3+ magnetic metallic state. Electrical resistivity measurements reveal that the surface carrier density increases with increasing pressure, whereas thermopower measurements show an unchanged Fermi energy under pressure. As a result, the effective mass of the surface state charge carriers linearly increases with pressure as the Sm valence approaches 3+. Our results are consistent with the presence of correlation-driven surface states in SmB$_{6}$ and suggest that the surface Kondo effect persists under pressure to 2 GPa.

Piezoresistance, the change of a material's electrical resistance ($R$) in response to an applied mechanical stress ($\sigma$), is the driving principle of electromechanical devices such as strain gauges, accelerometers, and cantilever force sensors. Enhanced piezoresistance has been traditionally observed in two classes of uncorrelated materials: nonmagnetic semiconductors and composite structures. We report the discovery of a remarkably large piezoresistance in Eu$_5$In$_2$Sb$_6$ single crystals, wherein anisotropic metallic clusters naturally form within a semiconducting matrix due to electronic interactions. Eu$_5$In$_2$Sb$_6$ shows a highly anisotropic piezoresistance, and uniaxial pressure along [001] of only 0.4~GPa leads to a resistivity drop of more than 99.95\% that results in a colossal piezoresistance factor of $5000\times10^{-11}$Pa$^{-1}$. Our result not only reveals the role of interactions and phase separation in the realization of colossal piezoresistance, but it also highlights a novel route to multi-functional devices with large responses to both pressure and magnetic field., Comment: 8 pages, 7 figures

The B20-type cobalt germanide CoGe was investigated by measuring the specific heat, resistivity, and $^{59}$Co nuclear magnetic resonance (NMR). We observed a phase transition at $T_Q=13.7$ K, evidenced by a very narrow peak of the specific heat and sharp changes of the nuclear spin-spin ($T_2^{-1}$) and spin-lattice ($T_1^{-1}$) relaxation rates. The fact that the entropy release is extremely small and the Knight shift is almost independent of temperature down to low temperatures as anticipated in a paramagnetic metal indicates that the $T_Q$ transition is of non-magnetic origin. In addition, we detected a crossover scale $T_0\sim30$ K below which the resistivity and the NMR linewidth increase, and $T_1^{-1}$ is progressively distributed in space, that is, a static and dynamical spatial inhomogeneity develops. While the order parameter for the $T_Q$ transition remains an open question, a group-theoretical analysis suggests that the finite electric quadrupole density arising from the low local site symmetry at cobalt sites could drive the crystal symmetry lowering from the P2$_1$3 symmetry that is commensurate to the R3 symmetry with an incommensurate wavevector, which fairly well accounts for the $T_Q$ transition. The quadrupole-order-driven commensurate-incommensurate phase transition may be another remarkable phenomenon arising from the structural chirality inherent in the noncentrosymmetric B20 family., Comment: 9 pages including appendix; 5 figures; published in Physical Review B

Colossal magnetoresistance (CMR) emerges from intertwined spin and charge degrees of freedom in the form of ferromagnetic clusters also known as trapped magnetic polarons. As a result, CMR is rarely observed in antiferromagnetic materials. Here we use electron spin resonance (ESR) to reveal microscopic evidence for the formation of magnetic polarons in antiferromagnetic Eu$_{5}$In$_{2}$Sb$_{6}$. First, we observe a reduction of the Eu$^{2+}$ ESR linewidth as a function of the applied magnetic field consistent with ferromagnetic clusters that are antiferromagnetically coupled. Additionally, the Eu$^{2+}$ lineshape changes markedly below T' ~ 200 K, a temperature scale that coincides with the onset of CMR. The combination of these two effects provide strong evidence that magnetic polarons grow in size below T' and start influencing the macroscopic properties of the system., Comment: 7 pages, 4 figures. Accepted in Phys. Rev. B

Noncentrosymmetric Ce$_{3}$Bi$_{4}$Pd$_{3}$ has attracted a lot of attention as a candidate for strongly correlated topological material, yet its experimental ground state remains a matter of contention. Two conflicting scenarios have emerged from a comparison to prototypical Kondo insulator Ce$_{3}$Bi$_{4}$Pt$_{3}$: either Ce$_{3}$Bi$_{4}$Pd$_{3}$ is a spin-orbit-driven topological semimetal or a Kondo insulator with smaller Kondo coupling than its Pt counterpart. Here we determine the ground state of Ce$_{3}$Bi$_{4}$Pd$_{3}$ via electrical resistivity measurements under hydrostatic pressure, which is a clean symmetry-preserving tuning parameter that increases hybridization but virtually preserves spin-orbit coupling. Ce$_{3}$Bi$_{4}$Pd$_{3}$ becomes more insulating under pressure, which is a signature of Ce-based Kondo insulating materials. Its small zero-pressure gap increases quadratically with pressure, similar to the behavior observed in the series Ce$_{3}$Bi$_{4}$(Pt$_{1-x}$Pd$_{x}$)$_{3}$, which indicates that Pt substitution and applied pressure have a similar effect. Our result not only demonstrates that Kondo coupling, rather than spin-orbit coupling, is the main tuning parameter in this class of materials, but it also establishes that Ce$_{3}$Bi$_{4}$Pd$_{3}$ has a narrow-gap Kondo insulating ground state., Comment: 6 pages, 4 Figures, includes Supplementary Information (6 pages, 5 Figures)

UTe2 is a newly-discovered unconventional superconductor wherein multicomponent topological superconductivity is anticipated based on the presence of two superconducting transitions and time-reversal symmetry breaking in the superconducting state. The observation of two superconducting transitions, however, remains controversial. Here we demonstrate that UTe2 single crystals displaying an optimal superconducting transition temperature at 2 K exhibit a single transition and remarkably high quality supported by their small residual heat capacity in the superconducting state and large residual resistance ratio. Our results shed light on the intrinsic superconducting properties of UTe2 and bring into question whether UTe2 is a multicomponent superconductor at ambient pressure.

Here we investigate the thermodynamic and electronic properties of Eu$_{11}$InSb$_9$ single crystals. Electrical transport data show that Eu$_{11}$InSb$_9$ has a semiconducting ground state with a relatively narrow band gap of $320$~meV. Magnetic susceptibility data reveal antiferromagnetic order at low temperatures, whereas ferromagnetic interactions dominate at high temperature. Specific heat, magnetic susceptibility, and electrical resistivity measurements reveal three phase transitions at $T_{N1}=9.3$~K, $T_{N2} =8.3$~K, and $T_{N3} =4.3$~K. Unlike Eu$_{5}$In$_{2}$Sb$_6$, a related europium-containing Zintl compound, no colossal magnetoresistance (CMR) is observed in Eu$_{11}$InSb$_9$. We attribute the absence of CMR to the smaller carrier density and the larger distance between Eu ions and In-Sb polyhedra in Eu$_{11}$InSb$_9$. Our results indicate that Eu$_{11}$InSb$_9$ has potential applications as a thermoelectric material through doping or as a long-wavelength detector due to its narrow gap., Comment: 5 pages, 4 figures

Analogous to the Hall effect, the Nernst effect is the generation of a transverse voltage due to a temperature gradient in the presence of a perpendicular magnetic field. The Nernst effect has promise for thermoelectric applications and as a probe of electronic structure. In magnetic materials, a so-called anomalous Nernst effect (ANE) is possible in zero magnetic field. Here we report a colossal ANE reaching 23 $\mu$V/K in the ferromagnetic metal UCo$_{0.8}$Ru$_{0.2}$Al. Uranium's $5f$ electrons provide strong electronic correlations that lead to narrow bands, which are a known route to producing a large thermoelectric response. Additionally, the large nuclear charge of uranium generates strong spin-orbit coupling, which produces an intrinsic transverse response in this material due to the Berry curvature associated with the relativistic electronic structure. Theoretical calculations show that at least 148 Weyl nodes and two nodal lines exist within $\pm$ 60 meV of the Fermi level in UCo$_{0.8}$Ru$_{0.2}$Al. This work demonstrates that magnetic actinide materials can host strong Nernst and Hall responses due to their combined correlated and topological nature.

Newly-discovered superconductor UTe$_2$ is a strong contender for a topological spin-triplet state wherein a multi-component order parameter arises from two nearly-degenerate superconducting states. A key issue is whether both of these states intrinsically exist at ambient pressure. Through thermal expansion and calorimetry, we show that UTe$_2$ at ambient conditions exhibits two detectable transitions only in some samples, and the size of the thermal expansion jump at each transition varies when the measurement is performed in different regions of the sample. This result indicates that the two transitions arise from two spatially separated regions that are inhomogeneously mixed throughout the volume of the sample, each with a discrete superconducting transition temperature (T$_c$). Notably, samples with higher T$_c$ only show a single transition at ambient pressure. Above 0.3 GPa, however, two transitions are invariably observed in ac calorimetry. Our results not only point to a nearly vertical line in the pressure-temperature phase diagram but also provide a unified scenario for the sample dependence of UTe$_{2}$., Comment: 6 pages, 4 figures, includes supplemental information, changed conclusion on the origin of double-transition feature observed in some UTe2 samples

We present magnetotransport data on the ferrimagnet GdMn$_6$Sn$_6$. From the temperature dependent data we are able to extract a large instrinsic contribution to the anomalous Hall effect $\sigma_{xz}^{int} \sim$ 32 $\Omega^{-1}cm^{-1}$ and $\sigma_{xy}^{int} \sim$ 223 $\Omega^{-1}cm^{-1}$, which is comparable to values found in other systems also containing kagome nets of transition metals. From our transport anisotropy, as well as our density functional theory calculations, we argue that the system is electronically best described as a three dimensional system. Thus, we show that reduced dimensionality is not a strong requirement for obtaining large Berry phase contributions to transport properties. In addition, the coexistence of rare-earth and transition metal magnetism makes the hexagonal MgFe$_6$Ge$_6$ structure type a promising system to tune the electronic and magnetic properties in future studies.

The Berry curvature in magnetic systems is attracting interest due to the potential tunability of topological features via the magnetic structure. $f$-electrons, with their large spin-orbit coupling, abundance of non-collinear magnetic structures and high electronic tunability, are attractive candidates to search for tunable topological properties. In this study, we measure anomalous Hall effect (AHE) in the distorted kagom$\acute{e}$ heavy fermion antiferromagnet U$_3$Ru$_4$Al$_{12}$. A large intrinsic AHE in high fields reveals the presence of a large Berry curvature. Moreover, the fields required to obtain the large Berry curvature are significantly different between $B \parallel a$ and $B \parallel a^*$, providing a mechanism to control the topological response in this system. Theoretical calculations illustrate that this sensitivity may be due to the heavy fermion character of the electronic structure. These results shed light on the Berry curvature of a strongly correlated band structure in magnetically frustrated heavy fermion materials, but also emphasize 5$f$-electrons as an ideal playground for studying field-tuned topological states.

Here we investigate antiferromagnetic Eu$_{5}$In$_{2}$Sb$_{6}$, a nonsymmorphic Zintl phase. Our electrical transport data show that Eu$_{5}$In$_{2}$Sb$_{6}$ is remarkably insulating and exhibits an exceptionally large negative magnetoresistance, which is consistent with the presence of magnetic polarons. From {\it ab initio} calculations, the paramagnetic state of Eu$_{5}$In$_{2}$Sb$_{6}$ is a topologically nontrivial semimetal within the generalized gradient approximation (GGA), whereas an insulating state with trivial topological indices is obtained using a modified Becke-Johnson potential. Notably, GGA+U calculations suggest that the antiferromagnetic phase of Eu$_{5}$In$_{2}$Sb$_{6}$ may host an axion insulating state. Our results provide important feedback for theories of topological classification and highlight the potential of realizing clean magnetic narrow-gap semiconductors in Zintl materials., Comment: Accepted in npj Quantum Materials. Author list and affiliations corrected

UTe$_2$ is a recently discovered unconventional superconductor that has attracted much interest due to its many intriguing properties - a large residual density-of-states in the superconducting state, re-entrant superconductivity in high magnetic fields, and potentially spin-triplet topological superconductivity. Our ac calorimetry, electrical resistivity, and x-ray absorption study of UTe$_2$ under applied pressure reveals key new insights on the superconducting and magnetic states surrounding pressure-induced quantum criticality at P$_{c1}$ = 1.3 GPa. First, our specific heat data at low pressures, combined with a phenomenological model, show that pressure alters the balance between two closely competing superconducting orders. Second, near 1.5 GPa we detect two bulk transitions that trigger changes in the resistivity which are consistent with antiferromagnetic order, rather than ferromagnetism. The presence of both bulk magnetism and superconductivity at pressures above P$_{c2}$ = 1.4 GPa results in a significant temperature difference between resistively and thermodynamically determined transitions into the superconducting state, which indicates a suppression of the superconducting volume fraction by magnetic order. Third, the emergence of magnetism is accompanied by an increase in valence towards a U$^{4+}$ (5f2) state, which indicates that UTe$_2$ exhibits intermediate valence at ambient pressure. Our results suggest that antiferromagnetic fluctuations may play a more significant role on the superconducting state of UTe$_2$ than previously thought., Comment: 21 pages, 7 figures; added section S1 to supplemental, fixed geometrical factors in current density measurements

At ambient pressure and zero field, tetragonal CeAuSb$_{2}$ hosts stripe antiferromagnetic order at $T_{N} = 6.3$ K. Here we first show via bulk thermodynamic probes and x-ray diffraction measurements that this magnetic order is connected with a structural phase transition to a superstructure which likely breaks $C_{4}$ symmetry, thus signaling nematic order. The temperature-field-pressure phase diagram of CeAuSb$_{2}$ subsequently reveals the emergence of additional ordered states under applied pressure at a multicritical point. Our phenomenological model supports the presence of a vestigial nematic phase in CeAuSb$_{2}$ akin to iron-based high-temperature superconductors; however, superconductivity, if present, remains to be discovered.

Here we report the structural and electronic properties of CeAu$_{2}$Bi, a new heavy-fermion compound crystallizing in a nonsymmorphic hexagonal structure ($P63/mmc$). The Ce$^{3+}$ ions form a triangular lattice which orders antiferromagnetically below $T_{N} = 3.1$~K with a magnetic hard axis along the c-axis. Under applied pressure, $T_{N}$ increases linearly at a rate of $0.07$~K/kbar, indicating that the Ce $f$-electrons are fairly localized. In fact, heat capacity measurements provide an estimate of 150(10) mJ/mol.K$^{2}$ for the Sommerfeld coefficient. The crystal-field scheme obtained from our thermodynamic data points to a ground state with dominantly $|j_{z}=\pm1/2\rangle$ character, which commonly occurs in systems with a hard c-axis. Finally, electronic band structure calculations and symmetry analysis in $k$-space reveal that CeAu$_{2}$Bi hosts symmetry-protected crossings at $k_{z} = \pi$ in the paramagnetic state, Comment: 7 pages, 5 figures. Supplemental Material: 4 pages, 2 figures

Kondo insulators are predicted to undergo an insulator-to-metal transition under applied magnetic field, yet the extremely high fields required to date have prohibited a comprehensive investigation of the nature of this transition. Here we show that Ce3Bi4Pd3 provides an ideal platform for this investigation, owing to the unusually small magnetic field of B ~ 11 T required to overcome its Kondo insulating gap. Above Bc, we find a magnetic field-induced Fermi liquid state whose characteristic energy scale T_FL collapses near Bc in a manner indicative of a magnetic field-tuned quantum critical point. A direct connection is established with the process of Kondo singlet formation, which yields a broad maximum in the magnetic susceptibility as a function of temperature in weak magnetic fields that evolves progressively into a sharper transition at Bc as T -> 0., Comment: 10 pages including 10 figures

In the non-collinear antiferromagnet Mn$_3$Sn, we compare simultaneous measurements of the anomalous Hall effect (AHE) and the magneto-optical Kerr effect (MOKE) through two magnetic phase transitions: the high-temperature paramagnetic/antiferromagnetic phase transition at the N\'eel temperature ($T_N \approx$420~K), and a lower-temperature incommensurate magnetic ordering at $T_1 \approx$270~K. While both the AHE and MOKE are sensitive to the same underlying symmetries of the antiferromagnetic non-collinear spin order, we find that the transition temperatures measured by these two techniques unexpectedly differ by approximately 10~K. Moreover, the applied magnetic field at which the antiferromagnetic order reverses is significantly larger when measured by MOKE than when measured by AHE. These results point to a difference between the bulk and surface magnetic properties of Mn$_3$Sn., Comment: 5 pages, 3 figures; published in APL

We present a detailed nuclear magnetic resonance (NMR) study of ${}^{239}$Pu in bulk and powdered single-crystal plutonium tetraboride (PuB$_4$), which has recently been investigated as a potential correlated topological insulator. This study constitutes the second-ever observation of the ${}^{239}$Pu NMR signal, and provides unique on-site sensitivity to the rich $f$-electron physics and insight into the bulk gap-like behavior in PuB$_4$. The ${}^{239}$Pu NMR spectra are consistent with axial symmetry of the shift tensor showing for the first time that ${}^{239}$Pu NMR can be observed in an anisotropic environment and up to room temperature. The temperature dependence of the ${}^{239}$Pu shift, combined with a relatively long spin-lattice relaxation time ($T_1$), indicate that PuB$_4$ adopts a non-magnetic state with gap-like behavior consistent with our density functional theory (DFT) calculations. The temperature dependencies of the NMR Knight shift and $T_1^{-1}$--microscopic quantities sensitive only to bulk states--imply bulk gap-like behavior confirming that PuB$_4$ is a good candidate topological insulator. The large contrast between the ${}^{239}$Pu orbital shifts in the ionic insulator PuO$_2$ ($\sim$~+24.7~\%) and PuB$_4$ ($\sim$~-0.5~\%) provides a new tool to investigate the nature of chemical bonding in plutonium materials., Comment: Accepted to PRB Dec. 14, 2018

We present nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) measurements performed on single crystalline \ccag{}, a member of a recently discovered family of heavy fermion materials Ce$_2M$Al$_7$Ge$_4$ ($M$ = Co, Ir, Ni, or Pd). Previous measurements indicated a strong Kondo interaction as well as magnetic order below $T_M = 1.8$ K. Our NMR spectral measurements show that the Knight shift $K$ is proportional to the bulk magnetic susceptibility $\chi$ at high temperatures. A clear Knight shift anomaly ($K \not\propto \chi$) is observed at coherence temperatures $T^* \sim 17.5$ K for $H_0 \parallel \hat{c}$ and 10 K for $H_0 \parallel \hat{a}$ at the ${}^{59}$Co site, and $T^* \sim 12.5$ K at the ${}^{27}$Al(3) site for $H_0 \parallel \hat{a}$ characteristic of the heavy fermion nature of this compound. At high temperatures the ${}^{59}$Co NMR spin-lattice relaxation rate $T_1^{-1}$ is dominated by spin fluctuations of the 4$f$ local moments with a weak metallic background. The spin fluctuations probed by ${}^{59}$Co NMR are anisotropic and larger in the basal plane than in the $c$ direction. Furthermore, we find $(T_1TK)^{-1} \propto T^{-1/2}$ at the ${}^{59}$Co site as expected for a Kondo system for $T > T^*$ and $T> T_K$. ${}^{59}$Co NQR \slrr{} measurements at low temperatures indicate slowing down of spin fluctuations above the magnetic ordering temperature $T_M \sim 1.8$ K. A weak ferromagnetic character of fluctuations around $\mathbf{q}=0$ is evidenced by an increase of $\chi T$ versus $T$ above the magnetic ordering temperature. We also find good agreement between the observed and calculated electric field gradients at all observed sites.

The effects of uniaxial compressive stress on the normal state $^{17}$O nuclear magnetic resonance properties of the unconventional superconductor Sr$_{2}$RuO$_{4}$ are reported. The paramagnetic shifts of both planar and apical oxygen sites show pronounced anomalies near the nominal $\mathbf{a}$-axis strain $\varepsilon_{aa}\equiv\varepsilon_v$, that maximizes the superconducting transition temperature, $T_{c}$. The spin susceptibility weakly increases on lowering the temperature below $T$$\simeq$10 K, consistent with an enhanced density of states associated with passing the Fermi energy through a van Hove singularity. Although such a Lifshitz transition occurs in the $\gamma$ band, formed by the Ru $d_{xy}$ states hybridized with in-plane O $p_{\pi}$ orbitals, the large Hund's coupling renormalizes the uniform spin susceptibilty, which, in turn, affects the hyperfine fields of all nuclei. We estimate this \textquotedblleft Stoner\textquotedblright\ renormalization, $S,$ by combining the data with first-principles calculations and conclude that this is an important part of the strain effect, with implications for superconductivity., Comment: 15 pages, 9+6 figures, 0+1 table

CeCo(In$_{0.990}$Hg$_{0.010}$)$_{5}$ is a charge doped variant of the $d$-wave CoCoIn$_{5}$ superconductor with coexistent antiferromagnetic and superconducting transitions occurring at T$_{N}$= 3.4 K and T$_{c}$=1.4 K, respectively. We use neutron diffraction and spectroscopy to show that the magnetic resonant fluctuations present in the parent superconducting phase are replaced by collinear $c$-axis magnetic order with three-dimensional Ising critical fluctuations. No low energy transverse spin fluctuations are observable in this doping-induced antiferromagnetic phase and the dynamic resonant spectral weight predominately shifts to the elastic channel. Static ($\tau$ $>$ 0.2 ns) collinear Ising order is proximate to superconductivity in CeCoIn$_{5}$ and is stabilized through hole doping with Hg., Comment: (main text - 5 pages, 4 figures; supplementary information - 4 pages, 5 figures, to be published in Physical Review Letters)

SmB6 is a candidate topological Kondo insulator that displays surface conduction at low temperatures. Here, we perform torque magnetization measurements as a means to detect de Haas-van Alphen (dHvA) oscillations in SmB6 crystals grown by aluminum flux. We find that dHvA oscillations occur in single crystals containing embedded aluminum, originating from the flux used to synthesize SmB6. Measurements on a sample with multiple, unconnected aluminum inclusions show that aluminum crystallizes in a preferred orientation within the SmB6 cubic lattice. The presence of aluminum is confirmed through bulk susceptibility measurements, but does not show a signature in transport measurements.

Thermodynamic and transport properties are reported on single crystals of the hexagonal antiferromagnet Mn$_3$Sn grown by the Sn flux technique. Magnetization measurements reveal two magnetic phase transitions at $T_1$ = 275 K and $T_2$ = 200 K, below the antiferromagnetic phase transition at $T_N$ $\approx$ 420 K. The Hall conductivity in zero magnetic field is suppressed dramatically from 4.7 $\Omega^{-1}$cm$^{-1}$ to near zero below $T_1$, coincident with the vanishing of the weak ferromagnetic moment. This illustrates that the large anomalous Hall effect (AHE) arising from the Berry curvature can be switched on and off by a subtle change in the symmetry of the magnetic structure near room temperature.

High magnetic fields induce a pronounced in-plane electronic anisotropy in the tetragonal antiferromagnetic metal CeRhIn$_{5}$ at $H^{*} \gtrsim 30$ T for fields $\simeq 20^{\mathrm{o}}$ off the $c$-axis. Here we investigate the response of the underlying crystal lattice in magnetic fields to $45$ T via high-resolution dilatometry. Within the antiferromagnetic phase of CeRhIn$_{5}$, a finite magnetic field component in the tetragonal $ab$-plane explicitly breaks the tetragonal ($C_{4}$) symmetry of the lattice well below $H^{*}$ revealing a finite nematic susceptibility at low fields. A modest magnetostriction anomaly, $dL/L = -1.8 \times 10^{-6}$, at $H^{*} = 31$ T hence presumably marks the crossover to a fluctuating nematic phase with large electronic nematic susceptibility. Magnetostriction quantum oscillations confirm a Fermi surface change at $H^*$ with the emergence of new orbits. By analyzing the field-induced change in the crystal-field ground state, we conclude that the in-plane Ce $4f$ hybridization is enhanced at $H^*$, carrying the in-plane $f$-electron anisotropy to the Fermi surface. We argue that the nematic behavior observed in this prototypical heavy-fermion material is of electronic origin, and is driven by the hybridization between $4f$ and conduction electrons.

At the interface between two distinct materials desirable properties, such as superconductivity, can be greatly enhanced, or entirely new functionalities may emerge. Similar to in artificially engineered heterostructures, clean functional interfaces alternatively exist in electronically textured bulk materials. Electronic textures emerge spontaneously due to competing atomic-scale interactions, the control of which, would enable a top-down approach for designing tunable intrinsic heterostructures. This is particularly attractive for correlated electron materials, where spontaneous heterostructures strongly affect the interplay between charge and spin degrees of freedom. Here we report high-resolution neutron spectroscopy on the prototypical strongly-correlated metal CeRhIn5, revealing competition between magnetic frustration and easy-axis anisotropy -- a well-established mechanism for generating spontaneous superstructures. Because the observed easy-axis anisotropy is field-induced and anomalously large, it can be controlled efficiently with small magnetic fields. The resulting field-controlled magnetic superstructure is closely tied to the formation of superconducting and electronic nematic textures in CeRhIn5, suggesting that in-situ tunable heterostructures can be realized in correlated electron materials.

Unconventional superconductivity and magnetism are intertwined on a microscopic level in a wide class of materials. A new approach to this most fundamental and hotly debated issue focuses on the role of interactions between superconducting electrons and bosonic fluctuations at the interface between adjacent layers in heterostructures. Here we fabricate hybrid superlattices consisting of alternating atomic layers of heavy-fermion superconductor CeCoIn$_5$ and antiferromagnetic (AFM) metal CeRhIn$_5$, in which the AFM order can be suppressed by applying pressure. We find that the superconducting and AFM states coexist in spatially separated layers, but their mutual coupling via the interface significantly modifies the superconducting properties. An analysis of upper critical fields reveals that near the critical pressure where AFM order vanishes, the force binding superconducting electron-pairs acquires an extremely strong-coupling nature. This demonstrates that superconducting pairing can be tuned non-trivially by magnetic fluctuations (paramagnons) injected through the interface, leading to maximization of the pairing interaction., Comment: 8 pages, 9 figures

Here we investigate single crystals of CaCo$_{5}$As$_{3}$ by means of single crystal X-ray diffraction, microprobe, magnetic susceptibility, heat capacity, and pressure-dependent transport measurements. CaCo$_{5}$As$_{3}$ shares the same structure of CaFe$_{4}$As$_{3}$ with an additional Co atom filling a lattice vacancy and undergoes a magnetic transition at $T_{M} = 16$ K associated with a frustrated magnetic order. CaCo$_{5}$As$_{3}$ displays metallic behavior and its Sommerfeld coefficient ($\gamma = 70$ mJ/mol.K$^{2}$) indicates a moderate enhancement of electron-electron correlations. Transport data under pressures to $2.5$ GPa reveal a suppression of $T_{M}$ at a rate of $-0.008$ K/GPa. First-principle electronic structure calculations show a complex 3D band structure and magnetic moments that depend on the local environment at each Co site. Our results are compared with previous data on CaFe$_{4}$As$_{3}$ and provide a scenario for a magnetically frustrated ground state in this family of compounds.

Electronic nematics are exotic states of matter where electronic interactions break a rotational symmetry of the underlying lattice, in analogy to the directional alignment without translational order in nematic liquid crystals. Intriguingly such phases appear in the copper- and iron-based superconductors, and their role in establishing high-temperature superconductivity remains an open question. Nematicity may take an active part, cooperating or competing with superconductivity, or may appear accidentally in such systems. Here we present experimental evidence for a phase of nematic character in the heavy fermion superconductor CeRhIn5. We observe a field-induced breaking of the electronic tetragonal symmetry of in the vicinity of an antiferromagnetic (AFM) quantum phase transition at Hc~50T. This phase appears in out-of-plane fields of H*~28T and is characterized by substantial in-plane resistivity anisotropy. The anisotropy can be aligned by a small in-plane field component, with no apparent connection to the underlying crystal structure. Furthermore no anomalies are observed in the magnetic torque, suggesting the absence of metamagnetic transitions in this field range. These observations are indicative of an electronic nematic character of the high field state in CeRhIn5. The appearance of nematic behavior in a phenotypical heavy fermion superconductor highlights the interrelation of nematicity and unconventional superconductivity, suggesting nematicity to be a commonality in such materials.

Quantum critical points (QCPs) are widely accepted as a source of a diverse set of collective quantum phases of matter. A central question is how the order parameters of phases near a QCP interact and determine the fundamental character of the critical dynamics which drive the quantum critical behavior. One of the most interesting proposals for the quantum critical behavior that occurs in correlated electron systems is that the behavior may arise from local, as opposed to long wavelength, critical fluctuations of the order parameter. The local criticality is believed to give rise to energy over temperature ($E/T$) scaling of the dynamic susceptibility with a fractional exponent near the quantum critical point (QCP). Here we show that $E/T$ scaling is indeed observed for CeCu$_{6-x}$Ag$_x$ but on closer inspection, the fluctuations can be separated into two components, implying that multiple order parameters play an important role in the unconventional critical behavior. Additionally, when the fluctuations corresponding to the magnetically ordered side of the phase diagram are separated, they are found to be three dimensional and to obey the scaling behavior expected for long wavelength fluctuations near an itinerant antiferromagnetic QCP., Comment: 12 pages, 11 figures

Weyl fermions are a new ingredient for correlated states of electronic matter. A key difficulty has been that real materials also contain non-Weyl quasiparticles, and disentangling the experimental signatures has proven challenging. We use magnetic fields up to 95 tesla to drive the Weyl semimetal TaAs far into its quantum limit (QL), where only the purely chiral 0th Landau levels (LLs) of the Weyl fermions are occupied. We find the electrical resistivity to be nearly independent of magnetic field up to 50 tesla: unusual for conventional metals but consistent with the chiral anomaly for Weyl fermions. Above 50 tesla we observe a two-order-of-magnitude increase in resistivity, indicating that a gap opens in the chiral LLs. Above 80 tesla we observe strong ultrasonic attenuation below 2 kelvin, suggesting a mesoscopically-textured state of matter. These results point the way to inducing new correlated states of matter in the QL of Weyl semimetals.

In search of novel, improved materials for magnetic data storage and spintronic devices, compounds that allow a tailoring of magnetic domain shapes and sizes are essential. Good candidates are materials with intrinsic anisotropies or competing interactions, as they are prone to host various domain phases that can be easily and precisely selected by external tuning parameters such as temperature and magnetic field. Here, we utilize vector magnetic fields to visualize directly the magnetic anisotropy in the uniaxial ferromagnet CeRu$_2$Ga$_2$B. We demonstrate a feasible control both globally and locally of domain shapes and sizes by the external field as well as a smooth transition from single stripe to bubble domains, which opens the door to future applications based on magnetic domain tailoring.

Applied pressure drives the heavy-fermion antiferromagnet CeRhIn$_{5}$ towards a quantum critical point that becomes hidden by a dome of unconventional superconductivity. Magnetic fields suppress this superconducting dome, unveiling the quantum phase transition of local character. Here, we show that $5\%$ magnetic substitution at the Ce site in CeRhIn$_{5}$, either by Nd or Gd, induces a zero-field magnetic instability inside the superconducting state. This magnetic state not only should have a different ordering vector than the high-field local-moment magnetic state, but it also competes with the latter, suggesting that a spin-density-wave phase is stabilized in zero field by Nd and Gd impurities - similarly to the case of Ce$_{0.95}$Nd$_{0.05}$CoIn$_{5}$. Supported by model calculations, we attribute this spin-density wave instability to a magnetic-impurity driven condensation of the spin excitons that form inside the unconventional superconducting state.

Two aspects of the ambient pressure magnetic structure of heavy fermion material CeRhIn$_5$ have remained under some debate since its discovery: whether the structure is indeed an incommensurate helix or a spin density wave, and what is the precise magnitude of the ordered magnetic moment. By using a single crystal sample optimized for hot neutrons to minimize neutron absorption by Rh and In, here we report an ordered moment of $m=0.54(2)~\mu_B$. In addition, by using spherical neutron polarimetry measurements on a similar single crystal sample, we have confirmed the helical nature of the magnetic structure, and identified a single chiral domain.

There has been considerable interest in topological semi-metals that exhibit extreme magnetoresistance (XMR). These have included materials lacking inversion symmetry such as TaAs, as well Dirac semi-metals such as Cd3As2. However, it was reported recently that LaSb and LaBi also exhibit XMR, even though the rock-salt structure of these materials has inversion symmetry, and the band-structure calculations do not show a Dirac dispersion in the bulk. Here, we present magnetoresistance and specific heat measurements on NdSb, which is isostructural with LaSb. NdSb has an antiferromagnetic groundstate, and in analogy with the lanthanum monopnictides, is expected to be a topologically non-trivial semi-metal. We show that NdSb has an XMR of 10^4 %, even within the AFM state, illustrating that XMR can occur independently of the absence of time reversal symmetry breaking in zero magnetic field. The persistence of XMR in a magnetic system offers promise of new functionality when combining topological matter with electronic correlations. We also find that in an applied magnetic field below the Neel temperature there is a first order transition, consistent with evidence from previous neutron scattering work., Comment: 5 pages, 6 figures