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[Display omitted] • Real-time monitoring of CaCO 3 reactive crystallization by in situ microscope probe. • Insights into real-time agitation control in fast kinetic precipitation processes. • Comparison of in-line and offline techniques for micron-sized particle measurement. • Sustainable production of calcium carbonate as a by-product of CO 2 capture (CCUS). In the present study, a crystallization monitoring unit consisting of an in-situ digital microscope camera and real-time image analysis is utilized for monitoring and control of a micron-sized, liquid-liquid crystallization of calcium carbonate. The crystallization process is integrated with a membrane contactor-based carbon dioxide capture process to demonstrate a sustainable CO 2 -to-chemical unit operation. The measurement probe transilluminates the crystal suspension and provides a live view from the crystallizer. In a series of open-loop experiments, the effects of several operating conditions such as feed flow rate and volumetric power on crystal size and particle count are investigated. For comparison purposes, solid product crystals are assessed with an offline laser diffraction technique. In the closed-loop experiments, the controlled variable is average particle diameter, and the manipulated variable is mixing intensity. The implemented set-point tracking PI controller generates actuating signals based on real-time image analysis measurement of the crystal size. Experimental results demonstrate a practical approach for measuring micron-sized particle suspensions, which is a challenge for particles with a mean diameter smaller than 15–20 μm, provides insights into the mixing intensity-based particle size controllability in fast-reaction precipitation systems and offers a framework to implement a direct design feedback control policy. [ABSTRACT FROM AUTHOR]

Industrial water electrolyzers mainly use old thyristor-based rectifiers to obtain the DC current required to run because of the low voltage level and high current requirements of the processes. These rectifiers cause significant ripple in the electrolyzer input current, leading to dynamic operation of the electrolyzer. Even though industrial-scale water electrolyzers are operated under such dynamic conditions, the effect on the electrolyzer performance is not well explored. In this study, current measurements from an industrial alkaline electrolyzer plant were used to define the common current ripple amplitude and frequency caused by the thyristor-based rectification. Based on the parameters obtained, laboratory measurements were conducted using an alkaline water electrolyzer to define the power losses incurred at various ripple amplitudes and frequencies. Additionally, the linearization of the electrolyzer current–voltage behavior as a function of frequency was studied using two electrode sets made of different materials. The laboratory measurements carried out in the study show that the ripple amplitude has a significant effect on increasing the losses, whereas the ripple frequency counteracts this. Thus, dynamic operation can have a large impact on losses, especially at partial loads, where the ripple current amplitudes increase significantly when using thyristor rectifiers. Lastly, the frequencies where the electrolyzer starts to behave linearly were observed to be at 68 Hz with the first electrode set and at 5 Hz with the second one. The considerable difference between the electrode sets indicates that the electrode materials and microstructure play a significant role in defining the electrolyzer frequency behavior. Because common thyristor-based power delivery systems operate at 300 Hz or 600 Hz, the results also imply that when modeling these systems, a linear model can be used for the electrolyzer to simplify the simulation. [Display omitted] • Large amplitude current ripple on alkaline electrolyzers is studied. • Ripple amplitude increases power losses, while frequency counteracts it. • As ripple frequency is increased, the electrolyzer starts to behave linearly. • The linear slope is determined purely based on the impedance. • At high frequencies, power usage can be determined from EIS measurement. [ABSTRACT FROM AUTHOR]

The interest in green hydrogen has been increasing in recent years for several applications, such as energy storage and different industrial sectors. The green hydrogen is produced from water electrolysis supplied by renewable electricity. The operation of industrial large-scale water electrolysis is characterized by a high DC current in the kiloampere range and a few hundred volts. Therefore, the rectifier unit plays an important role in converting AC current of the electricity grid into DC current supplied to the electrolyzer. The power electronic converters are also considered as one of the main cost components of the water electrolyzer system. The objective of this paper is to study whether the operation at a higher voltage than typical values (200 V–300 V) can be beneficial both for the cost and energy efficiency of the power converters in water electrolyzer systems. In this study, three different rectifier topologies considered for an industrial-scale electrolyzer are analyzed and compared in terms of energy efficiency and cost. The simulation models of each topology are carried out in the Matlab/Simulink environment. • The effect of voltage elevation on industrial water electrolyzer system is studied. • Thyristor and transistor-based rectifiers for water electrolyzers are analyzed. • Voltage elevation improves the energy efficiency and cost of rectifiers. • Buck-rectifier provides lowest specific energy consumption of electrolyzer stack. [ABSTRACT FROM AUTHOR]

Water electrolysis will be used to produce renewable hydrogen for energy storage and Power-to-X applications in the future renewable-energy-based energy systems. Therefore, the energy efficiency of hydrogen production will probably become a major issue. In this study, the effect of practical supply power converters on the specific energy consumption of megawatt (MW)-scale alkaline electrolyzers is studied and compared with an ideal dc power supply. The current quality and the stack specific energy consumption are studied in the case of traditional thyristor rectifiers and a transistor-based converter. The stack specific energy consumption is analyzed based on the simulated current waveforms and the electrical equivalent circuit of the electrolyzer stack. It is found that the transistor-based converter offers up to 14% lower electrolyzer stack specific energy consumption than the 6-pulse thyristor rectifier and up to 9.2% lower electrolyzer stack specific energy consumption than the 12-pulse thyristor rectifier as the current varies between 5000 and 1000 A. The simulated change in the stack specific energy consumption of the MW-scale alkaline water electrolyzer outweighs the losses occurring in the rectifiers. Further, selection of the ac voltage level may have a more adverse effect on the stack specific energy consumption with the thyristor rectifier topologies compared with the transistor-based topologies. [ABSTRACT FROM AUTHOR]

Electromagnetic design of a moving magnet frictionless linear actuator with self‐holding functionality for mechanical gear shifting in a transmission application is presented. The actuator consists of a tubular magnetic circuit with stationary armature and axially moving rotating permanent magnet assembly with radial magnetisation in the air gap. The armature contains a two‐piece magnetic core with a space for a winding. The effects of armature slot opening and magnetic circuit materials on the self‐holding force and the acting force are studied in the whole moving range. The designed moving magnet linear actuator improves the performance of the vehicle by enabling shift times below 50 ms with no energy consumption between the shifts. [ABSTRACT FROM AUTHOR]

Electromagnetic design of a moving magnet frictionless linear actuator with self-holding functionality for mechanical gear shifting in a transmission application is presented. The actuator consists of a tubular magnetic circuit with stationary armature and axially moving rotating permanent magnet assembly with radial magnetisation in the air gap. The armature contains a two-piece magnetic core with a space for a winding. The effects of armature slot opening and magnetic circuit materials on the self-holding force and the acting force are studied in the whole moving range. The designed moving magnet linear actuator improves the performance of the vehicle by enabling shift times below 50 ms with no energy consumption between the shifts. [ABSTRACT FROM AUTHOR]

A modular power-hardware-in-loop (PHIL) simulator for water electrolyzers is developed to study the electrolyzer as part of a smart grid and to examine the characteristics of various electrolyzer power supply electronics. A PHIL simulator up to 405 A of continuous current is built using commercially available power electronic converters. The design and operating principle of the emulator are analyzed. The experimental dynamics tests are performed to verify the PHIL simulator operation and suitability for water electrolysis emulation considering the effect of supply power quality. Finally, the PEM stack model is implemented, and the PHIL simulator is used to emulate a commercial PEM electrolyzer following the measured solar photovoltaic (PV) output power. [ABSTRACT FROM AUTHOR]

Power-electronics-based power-hardware-in-loop (PHIL) simulator for water electrolyzer emulation with a nominal current of 405 A is developed to study the electrolyzer as part of a smart grid and to analyze the characteristics of various electrolyzer power supply electronics. A simplified model of a proton exchange membrane (PEM) electrolyzer is implemented into the PHIL simulator to describe the voltage and current characteristics of the electrolyzer stack. The model is verified comparing the current and the estimated hydrogen production of the PHIL simulator with the measured values of the commercial PEM electrolyzer following the measured solar photovoltaic (PV) system output power. [ABSTRACT FROM AUTHOR]

Traditionally, the core losses of permanent magnet synchronous motors are assumed to vary as a function of rotational speed and the supply voltage. In this paper, the effect of armature reaction on the core losses under constant speed and stator voltage is studied. The load angle of the machine is varied, and the core losses are determined using the finite element analysis. To explain the core loss results, the flux densities with harmonic analyses in different parts of the machine are studied and discussed. It is found out that armature reaction should be taken into account if a high-accuracy core loss prediction is required. [ABSTRACT FROM AUTHOR]

Fast methods to estimate iron losses of the permanent magnet traction motor during the drive cycle of the electrical vehicle are compared. The methods use the iron loss information calculated by a finite-element analysis as a function of rotational speed both at no load and with a short-circuited stator to take into account the variable frequency and field weakening of the traction motor. The effect of iron losses on the optimal current components, providing the maximum efficiency, is studied. Several methods yield a good accuracy even based on the no-load iron loss only, but the accuracy can be improved especially in deep field weakening by including the short-circuit iron loss information in the analysis. [ABSTRACT FROM PUBLISHER]

This paper introduces a method for the drive cycle performance analysis of a permanent-magnet traction motor based on a fast magnetostatic finite-element analysis (FEA). The flux linkage and torque behavior of the permanent-magnet synchronous machine is studied by a nonlinear magnetostatic FEA as a function of direct- and quadrature-axis stator current components. In the analytical machine performance analysis, the current combinations producing the desired torque and minimizing the losses are determined. The iron loss is calculated with the time-transient FEA at no load. The maximum stator flux linkage, limited by the battery voltage, is taken into account. The drive cycle analysis, based on optimal current component surfaces, is carried out for a traction motor of an electric sports car. The results are compared with values measured for the drive cycle on a racetrack. [ABSTRACT FROM PUBLISHER]

Most of the high-power, low-speed, direct-driven permanent magnet synchronous generators for wind energy applications apply a cooling solution where the stator core is divided into a number of substacks. Cooling air is blown through the stator through radial cooling channels formed between the adjacent stator substacks. The use of the stator substacks has an effect on the equivalent length of the generator, and thus, if neglected, leads to an incorrect no-load voltage and synchronous inductance calculation. In this paper, the design issues related to the thermal and electromagnetic design of permanent magnet synchronous machines are highlighted. The analysis starts with a preliminary electromagnetic design. Then, the allowable number and width of cooling ducts are calculated based on the maximum allowable temperatures and fluid flow speed with a thermal resistance network model. The effect of cooling ducts on the no-load voltage and synchronous inductances of the machine are discussed in detail. The calculated no-load voltage and synchronous inductances are used in the analytical performance evaluation. It is shown that the cross-saturation of the synchronous inductances must be taken into account in order to get realistic results. [ABSTRACT FROM PUBLISHER]

An algorithm to calculate the electrical efficiency of permanent magnet synchronous machines with four different control methods is presented. The direct- and quadrature-axis stator current components are optimized to find the control method producing the maximum electrical efficiency. The developed computation algorithm was tested with three different permanent magnet synchronous machine applications, i.e., a low-speed high-torque direct-driven wind power generator with rotor surface magnets, a hybrid drive for an energy recovery system and a geared wind power generator with rotor buried magnets. The performance of the developed computation algorithm was verified by comparing the calculated electrical efficiencies with the measurements in the case of the hybrid drive machine. [ABSTRACT FROM AUTHOR]

The effect of lamination stack ends and radial cooling channels on the effective stator stack length, no-load voltage, and synchronous inductances of a permanent-magnet synchronous machine are studied using three-dimensional finite element analysis. The stack ends and the radial cooling channels decrease the equivalent electrical length of the machine, thus leading to the fact that a two-dimensional (2-D) approach overestimates the no-load voltage. The effect of stack ends and radial cooling channels on the electrical length of the machine can be compensated by making the rotor stack and permanent magnets longer than the corresponding stator stack. It is shown that in case of no radial cooling channels, synchronous inductances are typically overestimated with the 2-D approach. However, in the case of stator structure having several radial cooling channels, inductances are underestimated using the 2-D approach. [ABSTRACT FROM PUBLISHER]

Mechanical interactions between a wind turbine and a direct-driven permanent-magnet synchronous generator (PMSG) are studied, and a model to analyze the system behavior is suggested. The proposed model can be applied to analyze the mechanical vibrations of direct-driven wind turbine installations both in steady state and in dynamic cases. The cogging torque and torque ripple of the PMSG are used as excitation sources in the mechanical model. Four different permanent-magnet rotor constructions are analyzed. It is shown that the maximum allowable value of the cogging torque of the direct-driven permanent-magnet wind generator in this case is 1.5%–2% of the rated torque even when the corresponding resonance frequency does not occur in the operational speed range of the wind turbine. Furthermore, it was noticed that the resonance caused by the excitation torque should occur at the lowest possible speed. [ABSTRACT FROM AUTHOR]

Permanent-magnet synchronous machines (PMSMs) are gaining popularity in the industry and, especially, in distributed generation, for instance in windmill applications. Some of the traditional analytical design principles seem not to be valid for permanent magnets in machine excitation. We report on the effects of the permanent-magnet length in machine design. [ABSTRACT FROM PUBLISHER]

Anthropogenic emissions of CO 2 and other greenhouse gases have increased since the pre-industrial era, driven largely by economic and population growth, and are now higher than ever. In this scope, hybrid biological–inorganic systems represent a sustainable and versatile chemical synthesis platform using CO 2 as a feedstock which realizes the idea of 'Cleaner Production'. Practical implementation of hybrid biological–inorganic systems for the production of value-added chemical products requires development of scalable and robust electrobioreactors with a high energy efficiency and an adequate size. This work reports an in situ water electrolyzer stack design as part of an electrobioreactor system required for the pilot-scale operation of the hybrid biological–inorganic process approaching the aforementioned requirements. The electrolyzer is designed by applying fluid dynamics simulation tools to model the electrolyte flow. The design takes into consideration the problem of leakage currents, reported in the previous works, which is tackled by applying an electrically insulating coating. Different electrode surface modification approaches, such as coating with electrocatalysts and etching, are used to further enhance the performance and energy efficiency of the electrolyzer. The performance of the electrolyzer stack was evaluated in a pH-neutral solution required for the hybrid biological–inorganic processes. The in situ water electrolyzer developed in this study showed a high Faraday efficiency close to 90% and acceptable specific energy consumption below 90 kWh kg H2 −1. The obtained energy-efficiency values are the highest reported for similar applications with a similar scale which emphasizes the successful design of the in situ water electrolyzer stack. All data collected during experimental work might be applied to further investigation, simulation, and optimization of electrobioreactors operating at neutral pH. Overall, the results achieved in this study are promising and represent a crucial step toward the industrial implementation of hybrid biological–inorganic systems. • Novel pilot-scale in situ water electrolyzer for electrobioreactor is presented. • Fluid dynamics simulation tools are used to model and improve the electrolyte flow. • Leakage currents are tackled by insulating Teflon coating. • Performance of the electrolyzer is further improved by Co–Fe–P-based electrocatalysts. [ABSTRACT FROM AUTHOR]

The pace at which the human population is growing raises serious concerns related to food security while at the same time conventional agriculture-based food production is becoming a major cause of environmental pollution and greenhouse gas emissions. Numerous solutions have been proposed to boost food production among which edible microbial biomass is considered a promising alternative to conventional sources of food and feed with lower environmental footprint. This work introduces the Neo-Carbon Food concept that is a pilot-scale hybrid biological–inorganic process suitable for the production of microbial biomass. The concept includes integrated hydrogen production by water electrolysis, direct air capture (DAC) of carbon dioxide, and its subsequent assimilation by autotrophic hydrogen-oxidizing bacteria (HOB). The hydrogen production with in situ electrolysis achieved specific energy consumption just below 100 kWh/kgH 2 while the specific energy consumption of DAC was around 20 kWh/kg CO 2. Image 1 • Microbial protein could be a sustainable source of protein. • A pilot-scale hybrid biological-inorganic system is presented. • Novel in situ water electrolysis stack is introduced. • Energy consumption of hydrogen production and direct air capture of CO2 is studied. [ABSTRACT FROM AUTHOR]

• The effect of current ripple on PEM water electrolysis is analyzed. • A semi empirical PEM electrolyzer cell model is presented. • Higher power quality lowers energy consumption for water electrolysis. • High power quality reduces cell area up to five times at the same efficiency. Water electrolyzer technologies may play a key role in the decarbonization of the fossil-fueled world economy. Electrolytic hydrogen production could bridge emission-free power generation and various energy end-use sectors to drive the energy system towards a net zero-emission level. In order to reduce the economic cost of the required energy transition, both the overall system efficiency in converting electrical energy into the chemical energy carried by hydrogen, and the material used to build electrolytic cell stacks, should be optimal. The effect of power quality on the specific energy consumption of proton exchange membrane (PEM) water electrolyzers is investigated with a semi-empirical cell model. An experimentally-defined polarization curve is applied to analyze cell-specific energy consumption as a function of time in the case of sinusoidal current ripples and ripples excited by an industrial 12-pulse thyristor bridge. The results show that the effective electrolyzer cell area should be up to five times as high as an ideal DC power supply when powered by the 12-pulse thyristor rectifier supply to match the specific energy consumption between the two power supply configurations. Therefore, the improvement of power quality is crucial for industrial PEM water electrolyzer systems. The presented approach is applicable to simulate the effect of power quality for different proton exchange membrane electolyzers. [ABSTRACT FROM AUTHOR]

Industrial water electrolyzers apply direct current in kiloampere ranges. Therefore, rectifiers are typically based on thyristors despite the high amplitude current fluctuation excited by the rectifier. This paper studies the effect of thyristor rectifiers on the power quality of the electrolyzer stack and the supplying AC grid. The thyristor bridge excites high current and power fluctuation causing additional losses in the electrolytic cells. Further, the both AC supply side and DC output power factors are low especially under partial load conditions. The reactive power is divided into phase shift and distortion components. In the case of thyristor rectifier without any passive filter components the distortion reactive power component is dominating. The simulated results are supported by the power factor measurements of an industrial alkaline water electrolyzer. It is proposed that electrolyzer stack manufacturers should give requirements for the DC power quality to maximize the stack energy efficiency and lifetime. • DC current harmonics increase the specific energy consumption of water electrolyzers. • Thyristor rectifier has poor input and output power factor at partial loads. • Thyristor rectifier has high distortion reactive power component. • High AC reactive power component indicates poor DC quality. [ABSTRACT FROM AUTHOR]

The ripple of the supplied direct current has a significant effect on the energy efficiency of the water electrolyzer cell. Hydrogen production is defined by the current mean value, but current harmonics generate additional losses in the electrolyzer cell. However, the direct measurement of the DC current in the kiloampere range may be a challenging task compared with the voltage, which is practically in the range of a few hundreds volts in the electrolyzer stack. The effect of current harmonics on the energy efficiency and the voltage mean and root-mean-square (RMS) values is analyzed analytically based on the measured polarization curve of the PEM electrolyzer cell. The results show that both in the case of a theoretical sinusoidal current ripple and a practical thyristor bridge supply, the voltage mean or RMS values do not give a reliable estimate of the power quality. Instead, the voltage waveform as a function of time or the difference between the current mean and RMS values should be monitored. • Current quality has significant effect on the energy efficiency of electrolytic cells. • Sinusoidal and thyristor rectifier-induced current ripples cause additional losses. • Current RMS value differing from the mean value indicates poor power quality. • Cell voltage mean or RMS values do not indicate power quality. [ABSTRACT FROM AUTHOR]

This paper proposes a parameter adjustable dynamic mass and energy balance simulation model for an industrial alkaline water electrolyzer plant that enables cost and energy efficiency optimization by means of system dimensioning and control. Thus, the simulation model is based on mathematical models and white box coding, and it uses a practicable number of fixed parameters. Zero-dimensional energy and mass balances of each unit operation of a 3 MW, and 16 bar plant process were solved in MATLAB functions connected via a Simulink environment. Verification of the model was accomplished using an analogous industrial plant of the same power and pressure range having the same operational systems design. The electrochemical, mass flow and thermal behavior of the simulation and the industrial plant were compared to ascertain the accuracy of the model and to enable modification and detailed representation of real case scenarios so that the model is suitable for use in future plant optimization studies. The thermal model dynamically predicted the real case with 98.7 % accuracy. Shunt currents were the main contributor to relative low Faraday efficiency of 86 % at nominal load and steady-state operation and heat loss to ambient from stack was only 2.6 % of the total power loss. [Display omitted] • Dynamic mass and energy balance simulation of a 3 MW industrial alkaline water electrolyzer. • Results are verified with measurements of an industrial plant. • Faraday efficiency at nominal operation was estimated at 86 %. • Contribution of each Faraday loss parameter was approximated. • 97 % of the stacks heat is extracted through the electrolyte circulation with heat exchangers. [ABSTRACT FROM AUTHOR]

Domestic hot water (DHW) heating is one of the most energy-consuming activities in a typical household. Photovoltaics (PV) connected with a ground source heat pump (GSHP) offers a low-emission method for DHW heating. This paper studies four different control methods for DHW heating in a building with a GSHP and a PV system. The main control method aims to minimize DHW heating costs by utilizing Nord Pool Spot market information together with a PV production output forecast. The results of this control method, implemented with a perfect PV output forecast and assessed over three years of hourly data, indicate that annual cost savings over other methods are achievable. Results with the real-world actual PV output forecast, evaluated between June–September 2020, demonstrate DHW heating cost savings up to 36–53%, even though forecasting errors are present. The heating costs are 9–11% higher compared against the perfect forecast case. The suggested control method thereby effectively reduces the costs when compared with all other methods, and its performance is not significantly affected even when an actual imperfect forecast is implemented. The results also indicate that minimizing energy consumption does not offer the lowest cost. • A solar PV production forecast is verified with measurements in a Nordic context. • A Cost optimal control method for domestic hot water heating is developed. • The control logic is based on PV forecast, electricity price, and COP curve data. • Clock control has 15–21% higher energy costs than the cost optimal control. [ABSTRACT FROM AUTHOR]

The electrodeposition process of carbon in molten lithium carbonate electrolysis and the associated gas-liquid flow hydrodynamics characteristics are for the first time investigated using computational fluid dynamics (CFD). The high-temperature (750 °C) process is challenging for conducting measurements, making CFD a valuable tool for providing insights into the novel coaxial-type cell design. The CFD simulation addresses the electric field distribution, oxygen gas evolution, and electrodeposition of carbon. The effect of gas bubble sizes (1, 0.8, and 0.6 mm) on the electrolysis process was examined at different electrical current densities (0.15 ± 0.01 A c m – 2 ). The CFD results reveal that gas holdup increases by decreasing the bubble size and that the bubble size significantly impacts the current density distribution by affecting the two-phase flow dynamics. The study highlights the potential of CFD for optimization of molten salt processes, while also suggesting the need for further improvements in the model. [Display omitted] • CFD simulation of bubble behavior and carbon deposition in molten salt electrolysis. • Computational modeling of two-phase flow in molten salt electrolysis processes. • Understanding the impact of gas bubbles on current density and carbon deposition. [ABSTRACT FROM AUTHOR]

The practical dynamic properties and operational limitations of a commercial differential pressure 1 Nm 3 h −1 proton exchange membrane (PEM) water electrolyzer are studied from the viewpoint of renewable power production. Measured values from a 5 kW p solar photovoltaic (PV) power plant and PEM electrolyzer are analyzed to study factors affecting the control of PEM water electrolyzers operating as a part of renewable power production systems. Specific energy consumption of the PEM stack as a function of stack hydrogen outlet pressure is estimated based on measured values from two different measurement systems. Electrical energy consumption of the stack does not show any notable increase as the hydrogen outlet pressure is increased from 2.0 MPa to 4.0 MPa. However, the stack specific energy consumption increases by a maximum of 0.2 kWh/Nm 3 when hydrogen outlet pressure is increased from 2.0 MPa to 4.0 MPa. The increase in specific energy consumption at high differential pressure operation is due to a decrease in Faraday efficiency. Selection and control of the hydrogen outlet pressure can minimize the specific energy consumption and maximize the real hydrogen production in dynamic PEM water electrolyzer operation. [ABSTRACT FROM AUTHOR]

A comprehensive literature review of current water electrolyzer modelling research was conducted and presented models critically evaluated. Based on the literature review this paper presents an open-source MATLAB toolbox for water electrolyzer polarisation curve parametrization and modelling. The modelling capabilities of the tooling were verified using measured PEM and alkaline water electrolyzer polarisation data. As real-world measurement data is rarely ideal, tests were also conducted using suboptimal data, first with data sets that have a low number of measurement points and secondly with data sets that have low or high current densities missing. The tooling is shown to work with a wide variety of use cases and provides an automated method for modelling and parametrization of electrolyzer polarisation curves. • Critical review of the water electrolyzer polarisation curve modelling is conducted. • Open source MATLAB toolbox for automated parametrization of models is presented. • Measured alkaline and PEM water electrolyzer data is used to verify fit accuracy. • Data sets of variable quality are used to verify fitting robustness. [ABSTRACT FROM AUTHOR]

The aim of this paper is to analyze through simulation how the energy efficiency of a single electrolysis stack at various loads is affected by shunt currents and to determine the energy-optimal load distribution between lines in a multiline electrolysis system under various magnitudes of shunt current losses. A dynamic energy and mass balance model of an industrial 3 MW , 16 bar alkaline water electrolyzer (AWE) process was developed using MATLAB. The optimization goal is to determine the power supply for each AWE line so that it can meet any hydrogen demand while minimizing the global specific energy consumption (SEC). The Particle Swarm Optimization (PSO) algorithm is used to minimize the objective function. According to the results of the single stack investigation, shunt current reduction could significantly improve the energy efficiency of partial-load operation. In addition, the optimization study revealed that whenever two or more lines are required to run in order to satisfy the hydrogen demand, the global SEC is minimized when the lines operate at equal loads. [ABSTRACT FROM AUTHOR]

The design process of direct-driven permanent-magnet (PM) synchronous machines (PMSMs) for a full electric 4 \times 4 sports car is presented. The rotor structure of the machine consists of two PM layers embedded inside the rotor laminations, thus resulting in some inverse saliency, where the q-axis inductance is larger than the d-axis one. An integer slot stator winding was selected to fully take advantage of the additional reluctance torque. The performance characteristics of the designed PMSMs were calculated by applying a 2-D finite-element method. Cross saturation between the d- and q-axes was taken into account in the calculation of the synchronous inductances. The calculation results are validated by measurements. [ABSTRACT FROM PUBLISHER]

In the present research work, an electrical resistance tomography (ERT) system is utilized as a means for real-time fault detection and diagnosis (FDD) during a reactive crystallization process. The calcium carbonate crystallization is part of the carbon capture and utilization scheme where process monitoring and malfunction diagnostics strategies are presented. The graphical logic representation of the fault tree analysis methodology is used to develop the system failure states. The measurement consistency due to the use of a single electrode from a set of ERT electrodes for malfunction identification is experimentally and quantitatively investigated based on the sensor sensitivity and standard deviation criteria. Electrical current measurements are employed to develop a LabVIEW-based process automation program by using the process-specific knowledge and historical process data. Averaged electrical current is correlated to the mechanical failure of the stirrer through standard deviation evaluation, and slopes of the measured data are used to monitor the pump and concentrations status. The performance of the implemented methodology for detecting the induced faults and abnormalities is tested at different operating conditions, and a basic signal-based alarming technique is developed. [ABSTRACT FROM AUTHOR]

Owing to the ongoing energy crisis, increasing shares of renewables, and climate mitigation targets, a green hydrogen economy through water electrolysis has gained interest. Hydrogen can be directly utilised or converted via different Power-to-X pathways to produce fossil-free substitutable products; therefore, their life-cycle emissions were studied to determine whether these solutions could provide sustainable alternatives. Thus, understanding which Power-to-X solution can provide the greatest greenhouse gas emission reduction is crucial. This study provides nine meta-analyses of different pathways to compare climate emissions reductions based on the literature. The minimum, maximum, and average values were estimated for each investigated Power-to-X pathway. The direct use of hydrogen or its service to produce steel, biogas upgrading, protein, or ammonia resulted in over 10 kg CO2 kg H2 −1 reductions on average while using low-carbon energy sources. Co-electrolysis can potentially provide higher emission savings owing to lower electricity consumption compared with low-temperature electrolysers. In addition, the possibility of integrating electrochemical synthesis with hydrogen production has great potential, but the usability depends on the advancement of the technology in the future. Selections of carbon dioxide sources, substitutable products, and other assumptions of the investigated studies significantly impact the reduction potential. Low-emission-factor electric grid mixes containing fossil sources can result in emission savings in many Power-to-X systems. However, using grid mixes that result in emission savings is system-dependent, and the largest emission savings are achieved through renewables or nuclear energy. • Emission reductions were evaluated in the different pathways using hydrogen. • Power-to-X solutions using carbon dioxide resulted in the least reductions. • Co-electrolysis is an interesting option but is unmatured technology. • Green hydrogen is not the only hydrogen source capable of emission reduction. • LCA studies using primary data are desirable. [ABSTRACT FROM AUTHOR]

Bipolar configuration electrochemical stacks with a common or circulating electrolyte supply usually embody a high amount of shunt currents that escape from the main current path to the manifold nozzles. This paper suggests a novel and simplified semiempirical model to reasonably predict the total shunt currents in industrial alkaline water electrolyzers (AWE). The aim of the study is to perform a sensitivity analysis of the model parameters and the process conditions that affect the shunt currents and the plant's specific energy consumption (SEC), and to determine the most important ones by analyzing the thermodynamic and fluidic properties of the stack. An in-house MATLAB dynamic energy and mass balance model of an industrial 3 M W , 16 b a r AWE plant process was developed. The semiempirical dynamic process model is updated with the essential shunt currents and electrochemical, fluidic, and circulation impurity models. The study revealed the influence of the supplied current, the electrolyte temperature, the process pressure, the electrolyte flow rate, and the potassium hydroxide concentration on the shunt currents and the plant's SEC. • Simulation of a validated 3 MW industrial-scale AWE semi-empirical transient model. • Sensitivity analysis of the process conditions affecting the shunt currents in bipolar-configuration stacks. • Effect of the current supply, stack temperature, and electrolyte flow rate on the plant SEC. • Plant model parametrization and uncertainty analysis for the electrochemical model. • At partial loads, the shunt currents are the major source of energy loss in the system. [ABSTRACT FROM AUTHOR]

• 3 Å molecular sieve is mixed with methanol synthesis catalyst to adsorb water. • Significant temporary improvement in efficiency is achieved due to water removal. • The process is studied for wide range of industrially relevant conditions. • Mechanistic process model is developed for investigating temporal process changes. • Downstream processing can be simplified as methanol is the only liquid product. Synthesis of methanol from carbon dioxide is affected by thermodynamic limitations and excessive formation of water that might have a detrimental impact on methanol production rate and catalytic activity. To overcome these effects, sorption enhanced (SE) carbon dioxide hydrogenation to methanol with selective in-situ adsorption of water is investigated both experimentally and via process simulation. A significant improvement in the process performance due to the thermodynamic equilibrium shift, achieved as a result of selective water removal, is reported. Depending on the process conditions, during the SE phase, outlet methanol concentration is ca. 150–290% of the steady state values recorded after the adsorbent saturation. For carbon monoxide this factor is ca. 220–510%. The effect of process parameters such as reactor pressure, temperature, overall gas flowrate and catalyst-to-adsorbent ratio is thoroughly addressed. Reactor pressure is demonstrated to affect methanol production during the SE phase to the greatest extent. Particularly, increasing reactor pressure above 40 bar enhances methanol formation during the SE phase at the cost of decreasing carbon monoxide production, thus improving process selectivity. Although increasing reactor temperature above 250 °C favors carbon monoxide formation, it results in suppressed methanol production and considerable shortening of the SE phase duration. Because of the RWGS reaction fast kinetics, the variations in gas hourly space velocity and amount of the adsorbent loaded in the reactor affect production of methanol more than carbon monoxide. The parameters describing kinetics of the involved reactions and water adsorption are adjusted based on the acquired experimental data. [ABSTRACT FROM AUTHOR]

The demand for green hydrogen is growing as the increasing production of pure hydrogen can no longer be based on fossil hydrocarbons. As water electrolysis would move from niche to a significant consumer of emission-free electricity, the efficiency of electrolytic gas production, lifetime of water electrolysis systems, and balance in the electricity grid become essential. The operational and investment costs of an industrial-scale alkaline water electrolyzer with four practical rectifier topologies are investigated. The results show thyristor-based rectifiers provide poor quality for the AC and DC sides, which leads to nonoptimal specific energy consumption (SEC) of the water electrolyzer and a notable reactive power component. Transistor-based topologies may offer up to 4.5% lower SEC of the electrolyzer than the conventional 6-pulse thyristor bridge. The reactive power results in additional costs in either investments in compensation equipment or regular allowance costs. An additional DC/DC converter can be installed to improve the power quality for the electrolyzer, but the second conversion stage adds to the system complexity and cost without eliminating reactive power. A modular single-stage rectifier based on insulated-gate bipolar transistor (IGBT) bridges is suggested as an alternative to provide improved power quality for both the electrolyzer and the electricity grid. • Four power supply topologies are studied in industrial green hydrogen production. • Thyristor rectifiers have poor AC power factor especially at partial loads. • Transistor-based topologies can minimize the stack SEC at wider partial loads. • A novel modular single-stage IGBT rectifier is presented for electrolysis applications. • The novel rectifier can be the most competitive solution in green hydrogen production. [ABSTRACT FROM AUTHOR]

The operating expenditures of electric vehicles (EVs) consist mainly of the electricity used to charge the EV battery and of the replacement of wearing parts. This paper aims to optimize the EV battery charging as cost-effectively as possible for a household with a small-scale photovoltaic (PV) power plant. The optimization is carried out by problem-based optimization to closely match the average Finnish user behavior. For reference, an optimization was also performed disregarding the user behavior to make EV charging as cost-effective as possible. Cost minimization was done by using Nord Pool Spot market data to find the cheapest grid electricity prices, employing a perfect PV forecast, and using only surplus PV electricity for EV charging. Six years' worth of data were analyzed, and it was found that the annual savings with average user behavior ranged between 25.4% and 51.9% when comparing optimized charging with uncontrolled charging. When disregarding the typical user behavior and having the EVs chargeable at all times, the annual savings ranged between 38.3% and 54.5%. The results show that the more the user uses the EV daily, the more cost-effective the optimization becomes compared with uncontrolled charging methods. The results also show that depending on daily fluctuations in the electricity prices, it is sometimes more beneficial to sell the produced PV power rather than use it to charge the EV and instead charge the EV with grid electricity at nighttime. • Benefits of solar photovoltaic use for electric vehicle charging are emphasized. • Over 50% cost reduction for electric vehicle charging can be achieved. • Methods of this study can be applied anywhere with fluctuating electricity market. • Multiple benefits of smart charging are presented. [ABSTRACT FROM AUTHOR]

Green hydrogen production systems will play an important role in the energy transition from fossil-based fuels to zero-carbon technologies. This paper investigates a concept of an off-grid alkaline water electrolyzer plant integrated with solar photovoltaic (PV), wind power, and a battery energy storage system (BESS). The operation of the plant is simulated over 30 years with 5 min time resolution based on measured power generation data collected from a solar photovoltaic installation and a wind farm located in southeastern Finland. Levelized cost of hydrogen (LCOH) is calculated based on the capital expenditures (CAPEX), the operating expenses (OPEX), and the respective learning curves for each of the components. Component degradation and replacements during the operational lifetime are included in the model, and the capacity of the components and the system control are simultaneously optimized to obtain the minimum LCOH. A sensitivity analysis performed over different installation years and discount rates reveals that for the off-grid alkaline system, the implementation of a wind farm as the sole power supply is the most economical solution until the installation years 2035–2040. Solar PV and a BESS are found to increase the full-load hours of the electrolyzer and reduce the electricity curtailed in the off-grid plant to less than 8%. However, with the current component prices and the climate in the studied region, they are not economically beneficial. It is found that the cost of hydrogen can be reduced to 2 €/kg by the year 2030. • Optimal control and component capacities for a green hydrogen production plant. • Simulations use measured power from a solar PV installation and a wind farm. • Levelized cost of hydrogen is less than 2 €/kg by the year 2030. • Purely wind based system is the most cost-effective solution until the years 2035–2040. [ABSTRACT FROM AUTHOR]

The worldwide spread of the SARS-CoV-2 virus has continued to accelerate, putting a considerable burden on public health, safety, and the global economy. Taking into consideration that the main route of virus transmission is via respiratory particles, the face mask represents a simple and efficient barrier between potentially infected and healthy individuals, thus reducing transmissibility per contact by reducing transmission of infected respiratory particles. However, long-term usage of a face mask leads to the accumulation of significant amounts of different pathogens and viruses onto the surface of the mask and can result in dangerous bacterial and viral co-infections. Zeolite imidazolate framework-8 (ZIF-8) has recently emerged as an efficient water-stable photocatalyst capable of generating reactive oxygen species under light irradiation destroying dangerous microbial pathogens. The present study investigates the potential of using ZIF-8 as a coating for face masks to prevent the adherence of microbial/viral entities. The results show that after 2 h of UV irradiation, a polypropylene mask coated with ZIF-8 nanostructures is capable of eliminating S. Aureus and bacteriophage MS2 with 99.99% and 95.4% efficiencies, respectively. Furthermore, low-pathogenic HCoV-OC43 coronavirus was eliminated by a ZIF-8-modified mask with 100% efficiency already after 1 h of UV irradiation. As bacteriophage MS2 and HCoV-OC43 coronavirus are commonly used surrogates of the SARS-CoV-2 virus, the revealed antiviral properties of ZIF-8 can represent an important step in designing efficient protective equipment for controlling and fighting the current COVID-19 pandemic. [Display omitted] • ZIF-8 is applied as a coating to different face masks. • ZIF-8-based coating exhibited good stability in boiling water. • ZIF-8-based coating exhibited high antimicrobial properties against S. Aureus. • ZIF-8-based coating exhibited high antiviral properties against SARS-CoV-2's surrogates including Bacteriophage MS2 and HCoV-OC43. [ABSTRACT FROM AUTHOR]

The capacity of each component in an off-grid water electrolyzer hydrogen production plant integrated with solar photovoltaics and a battery energy storage system represents a significant factor affecting the viability and reliability of the system. This paper describes a novel method that optimizes simultaneously the component capacities and finite-state machine based control of the system to minimize the cost of green hydrogen production. The components and control in the system are referenced to a proton exchange membrane water electrolyzer stack with a fixed nominal power of 4.5 kW. The end results are thus scalable by changing the nominal power of the electrolyzer. Simulations are carried out based on data collected from a residential solar photovoltaic installation with 300 s time resolution. Optimization of the system is performed with particle swarm optimization algorithm. A sensitivity analysis performed over the prices of the different components reveals that the price of the water electrolyzer has the greatest impact on the green hydrogen production cost. It is found that the price of the battery has to be below 0.3 €/Wh to become a feasible solution as overnight energy storage. • System components and control are optimized simultaneously using PSO algorithm. • Simulations are based on data collected from an existing solar PV installation. • Electrolyzer price has the strongest effect on off-grid hydrogen production cost. • Overnight hydrogen production becomes economic below 0.3 €/Wh battery system price. [ABSTRACT FROM AUTHOR]

• Only 60 °C coupled with purge gas regenerates amine-based adsorbent by over 85%. • Coupling purge gas with TVSA is beneficial in terms of CO 2 productivity. • TVSA with purge gas can have lower specific energy requirement than closed TVSA. • Using air and 100 °C during regeneration significantly decreases adsorbent capacity. • Mild temperature TVSA with purge gas is a viable direct air capture process option. Comparison of different regeneration options for direct air capture (DAC) has usually been limited to only consider pure CO 2 production, limiting the process options to e.g. temperature-vacuum swing adsorption (TVSA) or steam-stripping. In this work, detailed experimental comparison is conducted of temperature swing adsorption (TSA/TCSA) and TVSA for DAC. Particularly, TVSA is assessed with air or inert gas purge flow (TVCSA) and without purge flow. The working capacity, regeneration specific energy requirement (SER) and adsorbent regenerability of these processes was compared. For all other studied regeneration options except TVSA without purge flow, over 85% regeneration was obtained already at 60 °C. Isobaric TSA at 60 °C had the lowest regeneration SER of 4.2 MJ/kg CO2. Coupling TSA with mild vacuum improved desorption rate and increased working capacity from 0.47 to 0.51 mmol CO2 /g sorbent , requiring 7.5 MJ/kg CO2 for regeneration. Without purge flow, TVSA resulted in only 0.39 mmol CO2 /g sorbent with the SER of 8.6 MJ/kg CO2 at 100 °C. Due to lower allowable regeneration temperature of 60 °C, mild vacuum TVSA with air flow also had a lower cyclic capacity decrease rate of 0.26%/cycle compared to 0.38%/cycle with TVSA without purge flow at 100 °C. However, using 100 °C with air flow in the TVSA process lead to a significant capacity decrease of 0.6%/cycle. Therefore, using either air or inert purge flow below 100 °C coupled with mild vacuum has benefits over the TVSA process with no inflow in terms of CO 2 productivity, specific energy requirement and adsorbent regenerability. For utilization purposes that require low-concentration CO 2 , TVSA with purge flow should thus be considered as a viable regeneration option for direct air capture along with isobaric TSA. [ABSTRACT FROM AUTHOR]