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In close association with Paleoproterozoic retroeclogite and accretionary prism-related mica-quartz schist, a 2.13 Ga (metamorphic titanite U-Pb age) lawsonite/barroisite-bearing E-MORB signature metagabbro associated with spinel metaperidotite is found in the Itaguara Sequence from southern São Francisco craton, Brazil. Petrography and pressure-temperature equilibrium phase diagrams suggest that the metagabbro experienced blueschist-facies metamorphism, attaining peak metamorphic conditions at ~16 kbar and ~450 °C during subduction. The retrograde metamorphic path crossed epidote amphibolite-facies, in which the mineral assemblage found in metaperidotite (olivine, clinopyroxene, spinel, serpentine, chlorite, talc, and tremolite) was stable during a ca. 2.1 Ga continental collision-related exhumation that occurred between the Archean Campo Belo/Bonfim and Divinópolis complexes. This geological framework suggests that the metagabbro and adjacent spinel metaperidotite represent a subducted and exhumed blueschist-facies fragment of a Paleoproterozoic oceanic Mohorovičić (Moho) discontinuity, thus establishing the Itaguara metagabbro as the oldest-known occurrence of retrogressed blueschist and providing evidence for the activity of the modern-style plate tectonics more than 2 Gyr ago. [ABSTRACT FROM AUTHOR]

The Lomagundi-Jatuli Event (LJE) is a significant positive δ13Ccarb anomaly in Paleoproterozoic carbonates globally. In the northeast São Francisco Craton (SFC), this event is documented in phosphorous (P)-rich marbles, along with subordinate graphite schists and iron formations, located in the Tanque Novo-Ipirá Complex (TNIC), Jacurici Valley (JV) and Rio Salitre Complex (RSC). Although the TNIC, JV, and RSC share comparable geological, geochronological, and mineralization characteristics, their connection and phosphogenic ties to the LJE are still uncertain. By combining new and reviewed C and O isotopes, cerium (Ce) anomalies relative to an array of rare earth elements, and yttrium (REY), we aim to constrain the paleoenvironmental conditions governing the phosphogenesis in the northeast SFC and its cause-and-effect relationship with the LJE. The Ce anomalies between 0.12 and 0.67 reveal a connection between the TNIC, JV, and RSC marbles and an oxic-suboxic shallow ocean influenced by detritus inflow. The remaining dataset links the carbonate protoliths to a continental margin of a paleocean and continental rift. Additionally, The positive δ13C excursions in the marbles, ranging from 5. 38 to 9.69‰, in conjunction with available geochronological data, indicate a maximum deposition age within 2.20 and 2.02 Ga. Our results indicate that the carbonate protoliths in the TNIC, JV, and RSC were deposited in similar paleoenvironmental conditions during the Paleoproterozoic. During this time, factors such as elevated oxygen levels, oceanic primary paleoproductivity, and organic matter burial played a crucial role in determining P supply, precipitation, and accumulation. These factors ultimately led to the positive δ13C excursions observed in the SFC, which are consistent with marine carbonates found around the world towards the end of the LJE. [ABSTRACT FROM AUTHOR]

The belt of basic-ultrabasic rocks within the Curaçá River Valley Province of the Bahia State, northeastern Brazil, has been known for enclosing several Cu-orebodies that helped sustain the industrial development of Brazil in the last five decades. Caraíba, Vermelhos, Surubim, Terra do Sal, Angicos, Sussuarana are the most prominent of these deposits. The Caraíba Cu-Orebody, so far the most important of all, is part of a body of Archean hypersthenites and norites that underwent poly-deformation and granulitization in the roots of the Paleoproterozoic Itabuna-Salvador-Curaçá orogen, which records the continental collisions responsible for building the São Francisco-Congo paleocontinent in Rhyacian times, ca 2.0 Ga ago. The Caraíba Mine setup happened during the 1970 decade, together with the rush to free the country's economy from the costs of importations, exactly when the first international oil crisis (1974-1978) was suffocating the economy in many countries. Although that time coincided with the boom of geological knowledge associated with the worldwide acceptance of plate tectonics, the study of high-grade metamorphic terrains was still embryonic. In particular, the meaning of the poly-phased tectonic structures in areas recording a high degree of plasticity during deformation remained unraveled. Due to the international economic crisis, everything necessary for running the Caraíba Mine was done under pressure. Nonetheless, the coeval geological studies required for deciphering the area's structural evolution and the mineralization controls, vital for the booming mining planning and profitable exploitation of the Cu ore, had to keep the academic standards for surviving the hurry. Part of this text is a historical novel as it describes in detail how the convenient geological knowledge of the Caraíba-Cu Orebody could be achieved progressively in the years 1980-1990, well in the middle of the rush affecting everything and everybody working in the Caraíba Mine Project.We emphasize thedetailed structural geology studies as the primary tool for guaranteeing timely technical accuracy during the ore's exploitation and profitability in the mine project.As such, it means a historical but profoundly scientific document necessary for those interested in academic and technical purposes related to large-scale mine projects everywhere. Moreover, it highlights the human drama lived by many fortunate professionals in that forgotten semi-desertic area of northeastern Brazil. The experience gained when studying several generations of tectonic structures and metamorphism at Caraíba transformed for the better and forever the lives of several geologists and other professionals equally in charge of operating the Caraíba Mine during those pioneer years.

Abstract The Rio dos Remédios Group comprises a supracrustal sequence that occupies the base of the Espinhaço Supergroup, São Francisco Craton, Brazil. Its basal formation, Novo Horizonte, crops out in the Paramirim region mainly as metavolcanic rocks that represent one of the fewer occurrences of blue quartz phenocrysts in South America. Their mineralogy consists of quartz and K-feldspar phenocrysts, whereas biotite, muscovite, fluorite, allanite, chlorite, sericite, zircon, and opaque phases occur immersed in a quartz-feldspar-rich groundmass. Such heterogeneous composition is also supported by x-ray diffraction and chemical data. Electron probe microanalysis in some samples revealed the presence of two distinct groups of biotite (magmatic and neoformed), in addition to the presence of iron-rich white mica and almost pure orthoclase feldspar. Our data suggest that the studied metavolcanic rocks have maintained their magmatic characteristics, which were progressively overprinted by hydrothermal fluids and ductile-to-brittle deformation. The magmatic mineralogy is akin to strongly peraluminous and alkaline magmas, common in anorogenic settings – a fertile site for the origin of blue quartz-bearing rocks worldwide.

The Rio dos Remédios Group comprises a supracrustal sequence that occupies the base of the Espinhaço Supergroup, São Francisco Craton, Brazil. Its basal formation, Novo Horizonte, crops out in the Paramirim region mainly as metavolcanic rocks that represent one of the fewer occurrences of blue quartz phenocrysts in South America. Their mineralogy consists of quartz and K-feldspar phenocrysts, whereas biotite, muscovite, fluorite, allanite, chlorite, sericite, zircon, and opaque phases occur immersed in a quartz-feldspar-rich groundmass. Such heterogeneous composition is also supported by x-ray diffraction and chemical data. Electron probe microanalysis in some samples revealed the presence of two distinct groups of biotite (magmatic and neoformed), in addition to the presence of iron-rich white mica and almost pure orthoclase feldspar. Our data suggest that the studied metavolcanic rocks have maintained their magmatic characteristics, which were progressively overprinted by hydrothermal fluids and ductile-to-brittle deformation. The magmatic mineralogy is akin to strongly peraluminous and alkaline magmas, common in anorogenic settings -- a fertile site for the origin of blue quartz-bearing rocks worldwide. [ABSTRACT FROM AUTHOR]

A robust stratigraphic framework for the Meso-Neoproterozoic transition is necessary for a better understanding of evolutionary and environmental changes during this critical geological time interval. Given the limited availability of radiometric and biostratigraphic data from late Mesoproterozoic to early Neoproterozoic strata, chemostratigraphic correlations have been used to build this framework. To contribute to Proterozoic chemostratigraphy, here we report new carbonate carbon isotope data from the Hunjiang Group in the Baishan area of Jilin Province in North China. The carbon isotope data (average 3.00 ‰ ± 1.15 ‰, 1 SD), together with existing detrital zircon constraints and microfossils, confirm a late Mesoproterozoic to early Neoproterozoic age of the Hunjiang Group. Using the dynamic time warping algorithm, we then constructed a global chemostratigraphic framework for the Meso-Neoproterozoic transition based on δ13C carb data from the North China, São Francisco, and Congo cratons. This exercise confirms the generally narrow range of δ13C carb fluctuations in the late Mesoproterozoic but also substantiates a negative δ13C carb excursion of notable magnitude (∼9 ‰) and of potential global extent at ca. 1 Ga. This negative excursion, known as the Majiatun excursion, likely marks the Meso-Neoproterozoic transition and the onset of the dynamic carbon cycle in the Neoproterozoic Era. • Carbonate δ13C from the Meso-Neoproterozoic Hunjiang Group of North China. • Global δ13C chemostratigraphic correlation using a dynamic time warping algorithm. • A global δ13C chemostratigraphic framework for the Meso-Neoproterozoic transition. • A potentially global δ13C excursion (the Majiatun excursion) at ca. 1 Ga. [ABSTRACT FROM AUTHOR]

The Campo do Meio Shear Belt (CMSB) is an approximately 200 × 25 km transcurrent area along the south-southwest margin of the São Francisco Craton. A comprehensive review of geology was performed in the western CMSB, where rocks from the Campos Gerais and Petúnia Complexes are predominant. The Campos Gerais Complex is relatively well positioned in the geotectonic context of the region. It corresponds to an Archean granite-greenstone belt lithological association related to the south-southwest part of the São Francisco Craton. The Petúnia Complex, in contrast, is unraveled in this contribution through the integration of aerogeophysical data from the western Campo do Meio Shear Belt (CMSB) with new fieldwork observations and zircon U–Pb (LA-MC-ICP-MS) dating. The Petúnia Complex has been restricted to two Mesoarchean gneissic units – Petúnia and Ribeirão da Conquista Gneiss, with crystallization ages of 2993 ± 11 Ma and 2870 ± 9 Ma, respectively. Although the ages are broadly coincident with those found in the Campos Gerais Complex, three characteristics suggest an evolutionary independent scenario (pre-S2) during the Archean for the Petúnia and Campos Gerais Complexes: i) the sharp contrast in gamma-ray emissions between these complexes; ii) the absence of komatiite affiliation in the meta-ultramafic rocks from the Petúnia Complex; and, iii) the absence of mafic dykes in the Petúnia Complex. These two complexes also can be distinguished by the frequency of Paleoproterozoic granitoid intrusions. The Petúnia Complex has only one occurrence, the Bom Jesus da Penha Metagranite, with a crystallization age of 2004 ± 11 Ma. On the other hand, several Paleoproterozoic granitoid intrusions (2.0–1.9 Ga) have been found in the Campos Gerais Complex. These Orosirian granitoids are restricted to CMSB and younger than those in the Mineiro Belt. We suggest that these Orosirian granitoids may represent remnants of a collision event that occurred after 2.1 Ga, leading to the integration of the Petúnia and Campo Gerais Complexes into the Columbia paleocontinent. During the Neoproterozoic, the evolution in the CMSBinvolved the cratonic basement and units related to the Southernmost Brasília Orogen. This set configures a tectonic mélange that underwent progressive deformation in a non-coaxial, partitioned transpressional regime. • The use of aerogeophysics data in Archean terrain exploration. • A new Mesoarchean terrain to be integrated into the paleogeographic reconstructions. • Orosirian accretion records on the southernmost São Francisco Craton. • Progressive deformation in the basement from Southernmost Brasília Orogen. [ABSTRACT FROM AUTHOR]

The Pitangui Synclinorium is located in the northwestern portion of the Quadrilátero Ferrífero mineral province, São Francisco Craton, in southeast Brazil. It corresponds to a NW-SE-trending synformal structure composed of an Archean greenstone belt sequence, which is covered by Paleoproterozoic metasedimentary rocks to Neoproterozoic sedimentary rocks, and surrounded by Archean granite-gneiss complexes. This study reports the first detailed 1:25.000 scale geological mapping in the Pitangui Synclinorium and provides cartographic, stratigraphic and petrographic improvements, allowing the formalization of its lithostratigraphic units and unraveling the sedimentary and volcanic depositional environments. The Archean Pitangui greenstone belt occurs in most parts of the homonymous synclinorium, and is subdivided into the Pitangui Group and the Antimes Formation. The metavolcano-sedimentary sequence of the Pitangui Group comprises basal mafic/ultramafic metavolcanic rocks with subordinate felsic/intermediate metavolcanic and metavolcaniclastic rocks of the Rio Pará Formation, suggesting a bimodal volcanism. It is followed by volcanogenic and chemical metasedimentary rocks of the Rio São João Formation, and pelitic to sandy metasedimentary rocks of the Onça do Pitangui Formation deposited in subaqueous environments mainly corresponding to submarine fan systems. The occurrence of clastic rocks increases towards the top of the sequence. The Antimes Formation comprises quartzites and metaconglomerates related to fluvial and fan delta depositional environments. The Pitangui greenstone belt is overlapped, in the central and northwest regions of the study area, by the Fazenda Tapera Formation, a Paleoproterozoic siliciclastic package containing arkosic metasandstones, metagreywackes and metarhythmites deposited in a shallow marine environment. Subordinated tuff layers occur as ash/fall deposits from distal volcanism. Neoproterozoic clastic-chemical sedimentary rocks of the Bambuí Group cover the northern portions of the synclinorium, and are mainly composed of diamictites, limestones, marls and rhythmites from the Carrancas (lacustrine or restricted marine), Sete Lagoas (shallow marine) and Serra de Santa Helena formations (deep water grading to prodelta and delta front).

This work is based on the unprecedented Tectonic-Geochronological Map of Bahia (TGMBA): metallogenic implications. In the TGMBA, sixteen tectonic domains were identified, and the main mineral occurrences and deposits in each were recorded. Of the Palaeo-Mesoarchean blocks, the Gavião (GB), Serrinha (SB) and Uauá (UB) blocks were highlighted. The southern GB was formed by plate tectonics, in two stages, at ca. 3403–3378 and 3259–3240 Ma. These rocks served as basement for the Umburanas Greenstone Belt, which comprises felsic metavolcanic rocks (3147 Ma) interspersed with ocean floor mafic metavolcanics and could have been the source of the recently found orogenic gold. This crust could also have formed the basal section of the Brumado metavolcanic-sedimentary sequence, which hosts one of the most important magnesite mines in the world. The northern part of the GB hosts TTGs with ages of ca. 3642–3520 Ma, the oldest known rocks in the whole São Francisco Craton. This region served as a passive margin for the Jacobina-Umburanas Sea, where quartzites and conglomerates (3305 Ma) with detrital gold were deposited and, in the deeper portions of this sea, Mesoarchean ocean floor or Island-arc basalts (3200 Ma) with pillow-lava structures were formed. On the platform of this basin, Mn deposits were formed in association with pelites and sandstones [ABSTRACT FROM AUTHOR]

The Sergipano Belt is located in the Southern Subprovince of Borborema Province in the Northeast of Brazil. Its tectonic framework was consolidated in the Pan-African-Brasiliano Orogeny at the end of the Neoproterozoic. The most recent geological models indicate that its evolution occurred over a complete Wilson cycle. Gravimetric and magnetic data profiles that crossed the Sergipano Belt from south to north were modeled jointly by the direct method to provide a 2D view of the crust framework. The modeling process was linked and supported by the use of geological data and models. The result revealed the deep structure of the crust and identified the geometry of the main geological domains to the depth of Moho's discontinuity. The folds and thrusts toward the São Francisco Craton are a persistent and deep feature in the Southern crust of the Sergipano Belt. The general tectonic context of the models is compatible with the subduction and collision of the São Francisco Paleo-Plate under the Pernambuco-Alagoas Superterrane, sutured in the Shear Zone of São Miguel do Aleixo. The presence of dense blocks at the base of the crust was interpreted as layers of ophiolites placed by obduction. The metasediments of the Vaza Barris and Macururé Domains are tabular bodies with thicknesses lower than 5 km, which dip horizontally or at a low angle on the flanks of the shear zones. Small vertical bodies of lower density within the Macururé Domain have correlation with granitic intrusions. In the Canindé Domain there is a dense layer in the lower crust that was interpreted as the relicts of the oceanic crust that based a back-arc basin. The granitic bodies modeled north of the Canindé Domain and correlated with the Serra do Catu batholith in Pernambuco-Alagoas Superterrane, may be the record of subduction of this crust to the north. The data and models revealed geophysical differences between the Jirau do Ponciano, Coruripe River Domains and the crust north of the Palmeira dos Índios Shear Zone. These terrains are separated by shear zones with evident expression in gravimetric and magnetic data. However, the existence of Neoproterozoic metasedimentary supracrustal rocks partially covering the domains and zones and borderline shear indicates that the junction among these blocks occurred before the deposition of Neoproterozoic sediments.

Coeval Neoproterozoic mafic dykes with a well‐constrained isotopic age of 925 Ma are distributed in the North China Craton (NCC) of China and São Francisco Craton (SFC) of Brazil. Several recent studies favor the hypothesis that these two cratons were connected during 925 Ma and constituted building cratons for the supercontinent Rodinia. However, the paleo‐positions of the two cratons in Rodinia have not yet been paleomagnetically resolved. This paper presents the paleomagnetic results of these dykes in both NCC and SFC. Detailed thermal and alternating‐field demagnetization revealed that these dykes record stable components of magnetization with unblocking temperatures below the Curie temperature of magnetite. Rock magnetic results and scanning electron microscope analysis further confirm that the major magnetic minerals in dyke samples are pseudo‐single domain titanomagnetites. The mean directions of the characteristic remanent magnetization (ChRM) of the dykes are distinct from those of rocks of different ages in the sampling localities, and are supported by positive baked contact tests, indicating primary remanent magnetization. The ChRM of the SFC dykes also exhibits dual polarity. Our results suggest that the NCC and SFC were in the moderate to high paleolatitudes of the Southern Hemisphere during approximately 925 Ma, suggesting a possible paleogeographic connection between the two cratons. A new paleogeographic reconstruction of both cratons during 925 Ma is proposed, which is supported by other geological evidence. Plain Language Summary: The formation and breakup of the supercontinent Rodinia have played crucial roles in the global tectonic evolution and paleoclimate changes during the Neoproterozoic which lasted from 1.0 billion to 541 million years ago. The exact configuration of the Rodinia remains debatable, including whether the North China Craton (NCC) and São Francisco Craton (SFC) were integral components of the Rodinia. In this paper, we present new results of an integrated investigation, including paleomagnetic and rock magnetic studies and scanning electron microscope analysis, on the well dated coeval 925 Ma mafic dykes in both NCC and SFC. The results of scanning electron microscope and magnetic measurements confirm the major magnetic minerals and the stability of characteristic remanence directions. The results imply that both NCC and SFC were located at moderate to high paleolatitudes of the Southern Hemisphere during approximately 925 Ma, suggesting the possibility of a paleogeographic connection between the two cratons in the Rodinia. The findings of this study help gain improved understanding of paleogeography of the early Earth. Key Points: Characteristic remanence for the 925 Ma dykes in North China Craton and São Francisco Craton is interpreted as primaryBoth cratons were located at moderate–high paleolatitudes, southwest of Rodinia's core at 925 Ma, suggesting a paleogeographic connectionThe possible paleogeographic connection between the two cratons is supported by new paleomagnetic and geological evidence [ABSTRACT FROM AUTHOR]

[Display omitted] • Argon dates show Neoproterozoic tectonothermal overprint on the Southern SFC. • Northwest to Southeast isochrons become younger towards Neoproterozoic thrust faults. • Dates older than 600 Ma represent 'mixed' crystals or partial mineral transformations. The Archean domain of the Southern São Francisco Craton (SFC) acted as a foreland for the docking of the Mineiro Belt (2.47–2.05 Ga) through soft-collision processes during the Paleoproterozoic. Much later, during the Neoproterozoic, the newly formed Archean-Paleoproterozoic protocraton again served as a foreland for the development of thrust belts that contributed to the formation of the Gondwana supercontinent. From the Paleoproterozoic to the Neoproterozoic, pressure–temperature (P-T) conditions in the SFC crust varied from prograde amphibolite to retrograde amphibolite-greenschist metamorphic facies. In this paper, we reinterpret past 40K/40Ar data and present new 40Ar/39Ar dates in biotite and amphibole—evaluating the P-T conditions affecting metagranitoids, orthogneisses, and metamafic rocks of the southern SFC basement—to reconstruct its tectonothermal history during the assembly of the Gondwana supercontinent. Recalculated 40K/40Ar* and new 'total fusion' 40Ar/39Ar dates facilitated the creation of a contour map with a 900 Ma isochron, roughly corresponding to the tectonic boundary between the Archean and Paleoproterozoic domains, with the Neoproterozoic tectonothermal imprint recorded south of the 900 Ma line. The younger 40Ar/39Ar plateau dates from 651 to 526 Ma obtained on biotite crystals delineate a 600 Ma isochron within the Mineiro Belt area, approximately coinciding with the Lenheiro Shear Zone (LSZ). This comprehensive dataset, encompassing dates from 900 to 526 Ma, underscores a polycyclic tectonothermal reactivation that either delimits the Mineiro Belt area or occurs along the LSZ. This prominent structure within the belt differentiates deeper plutonic rocks from shallower (sub)volcanic rocks to its north and south regions, respectively. These relatively deeper to shallower crustal positions suggest that Neoproterozoic collisional fronts developed progressively from northwest (earlier collisions) to southeast (later collisions), corresponding to older and younger dates, respectively. Additionally, Discordia lower-intercepts in Wetherill diagrams from 977 to 488 Ma, obtained in previous U-Pb investigations within the Mineiro Belt, align with our new 40Ar/39Ar plateau and 'total fusion' dates, providing further evidence for reheating and partial to complete resetting of magmatic biotite-amphibole crystals and neoformed metamorphic biotite. Our results confirm that the Mineiro Belt did not behave as a stable continental landmass during the Neoproterozoic Brasiliano Orogeny, instead experiencing significant tectonothermal overprinting. [ABSTRACT FROM AUTHOR]

The Early Tonian period in the São Francisco Craton represents the development of an intracontinental rift across the northern and central Espinhaço regions, playing a crucial role in understanding the tectonic evolution of the Neoproterozoic Period within this craton and its adjacent orogens. This rift is associated with the breakup of the São Francisco paleoplate, marked by the formation of several rifts, some of which were aborted (e.g. Santo Onofre Rift), and magmatism associated. Field investigations, coupled with petrographic, lithogeochemical, and U–Pb geochronological data of the Serra do Meio Suite, elucidate key characteristics and offer significant insights into the Tonian tectonic evolution of the São Francisco Craton and its relationship with Santo Onofre Rift. The suite comprises metagranitoids exhibiting a mineralogical composition spanning from alkali-feldspar granites to granites and its petrogenesis and tectonic characteristics reveal an alkaline to calc-alkalic signature, exhibiting extreme ferroan geochemistry and indications of moderate to high oxygen fugacity. Pressure estimations suggest low-pressure conditions during magma crystallization, implying shallow crustal emplacement. The suite's evolution involves complex petrogenetic processes, likely influenced by fractional crystallization and contamination by country rocks from a quartz-feldspathic crustal source, as well as a possible contribution from juvenile tholeiitic mantle sources associated with rift environments, showcasing a signature typical of A1-type granite. The U–Pb SHRIMP age, determined as 930 ± 2 Ma (MSWD = 0.34), is interpreted as the crystallization age of the rock and allows us to connect it to the opening of the Santo Onofre-Macaúbas Rift in the São Francisco Craton. • The Serra do Meio Suite (930 Ma) contains an A-type magmatism in the São Francisco Craton. • Origin tied to quartzofeldspathic partial melting, with mantle input and crustal assimilation. • Tonian rifting links A-type magmatism with São Francisco's paleoplate breakup. • This Suite represents a continental rifting stage within the precursor Santo Onofre basin. [ABSTRACT FROM AUTHOR]

This paper focuses on two rare types of blue-coloured, world-famous natural stones: the blue dumortierite quartzites ‘Blue Macaúbas’, ‘Blue Boquira’, and ‘Imperial Blue’, and the sodalite syenites ‘Blue Bahia’ and ‘Blue Sodalite’ — all from the Brazilian state of Bahia. The blue quartzites belong to a metasedimentary sequence, deposited in a lagoon-and-coastal environment around 1 Ga ago. Ranging from pure to slightly micaceous, they present cross laminations and bedding, and are mainly composed of quartz, kyanite, and dumortierite in acicular radial aggregates, either concentrated in lenses or disseminated in the matrix. The blue sodalite syenites are products of the differentiation of a nepheline–syenitic magma, occurring as stocks and dykes. Their main composition is sodalite, feldspar, biotite, and nepheline, with remarkable structural and textural differences amongst the two commercial lithotypes. ‘Blue Bahia’ is homogeneous, exhibiting a granite-resembling texture, while ‘Blue Sodalite’ has a gneissic–migmatitic structure and variable grain size. Several companies have exploited and exported these quartzites and syenites since the 1960s. These blue stones have technological properties suitable for any use as a natural stone but, due to their rarity, they are expensive and therefore consumed by an upscale international market, and especially used in interior-design projects and high-value artworks. The geological and technical characteristics together with the small but continuous international use, for more than 50 years, of these unique building materials make them good candidates for Global Heritage Stone Resource (GHSR) designation. [ABSTRACT FROM AUTHOR]

This work reports on the first identification of sapphirine‐bearing ultrahigh‐temperature (UHT) metamorphic rocks within the Borborema Province, in NE Brazil. The investigated UHT diatexites outcrop in the Arapiraca Complex, a high‐grade Palaeoproterozoic block embedded within the Neoproterozoic metavolcano‐sedimentary sequence of the Sergipano fold‐and‐thrust belt. A sapphirine‐bearing diatexite sample preserves two distinct residual mineral associations as inclusions in cordierite poikiloblasts: a volumetrically dominant silica‐saturated, garnet–sillimanite–orthopyroxene–quartz domain, and a restricted silica‐undersaturated, sapphirine–magnetite–spinel–corundum domain. Phase equilibrium modelling for the whole‐rock bulk composition constrains the reactions preserved in the silica‐saturated domain, which, coupled with reintegrated ternary feldspar thermometry and Al‐in‐orthopyroxene thermobarometry, indicates peak UHT metamorphism occurring at ~970°C/8.5 kbar followed by a clockwise near isobaric cooling stage crossing the H2O‐undersaturated solidus at ~910°C/7.7 kbar. The T–MSiO2 and P–T phase equilibrium models reveal that the stabilization of magnetite‐spinel in the silica‐undersaturated domain can be a product of domanial SiO2‐depletion ascribed to inherited compositional banding and progressive melt‐loss episodes. The appearance of sapphirine as thin coronae around previously formed magnetite‐spinel cores requires an increase in the bulk silica content during retrograde metamorphism. This was driven by variable degrees of chemical interaction between the silica‐undersaturated domain and trapped silica‐rich leucosomes. U–Pb dating of zircon coupled with trace element behaviour records the timing of melt crystallization between ca. 2.03 and 1.96 Ga, after peak UHT metamorphism and supporting a protracted, ca. 70 My period of melt presence in the crust. The UHT metamorphism in the Arapiraca Complex is related to a contemporaneous UHT event recorded within the São Francisco Craton and more broadly coincides with high geothermal gradients at ca. 2.0 Ga linked to the formation of the Columbia supercontinent. The integration of new petrological and geochronological data indicates that the Arapiraca Complex is a continental ribbon pulled away from the São Francisco–Congo palaeocontinent possibly during the early Neoproterozoic intermittent rifting events and opening of the Sergipano oceanic basin between ca. 0.98–0.74 Ga. During the late Neoproterozoic at ca. 0.63–0.57 Ga, the Arapiraca Complex continental ribbon was thrusted back onto the northern margin of the São Francisco Craton as an inlier of the Sergipano fold‐and‐thrust belt. [ABSTRACT FROM AUTHOR]

Abstract The Cr-rich Jacurici Complex is located at the limit between the Serrinha Block and the Salvador-Curaçá Belt, Northeastern São Francisco Craton. In order to better understand the age span of magmatism and tectonism, we have studied a basement high-grade charnockite orthogneiss, a metanorite of the Complex and a crosscuting undeformed quartz-feldspar pegmatite. For the orthogneiss, SHRIMP U-Pb ages of zircon cores and overgrowth rims yielded, 2966 ± 9 Ma for crystallization and 2091 ± 10 Ma for metamorphism, respectively. Zircons from the metanorite show internal textures consistent with high grade metamorphism. The U-Pb LA-ICP-MS age determination provided a 2099 ± 6 Ma metamorphic age for the Jacurici Complex, indicating it was already emplaced during amalgamation around 2.1 Ga. Zircons from the undeformed quartz-feldspar pegmatite provided a LA-ICP-MS U-Pb age of 2083 ± 11Ma, marking the end of the N-S transcurrence. The magmatic Jacurici Complex age remains undefined, but is equal to, or older than, 2.1 Ga. Therefore, possible correlations with other mafic-ultramafic intrusions, such as the Cu-rich Caraíba Complex, should be reassessed. Our results indicate that the N-S transcurrence ended earlier in the Jacurici Complex region than in the northwestern area of the Salvador-Curaçá belt.

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The Cr-rich Jacurici Complex is located at the limit between the Serrinha Block and the Salvador-Curaçá Belt, Northeastern São Francisco Craton. In order to better understand the age span of magmatism and tectonism, we have studied a basement high-grade charnockite orthogneiss, a metanorite of the Complex and a crosscuting undeformed quartz-feldspar pegmatite. For the orthogneiss, SHRIMP U-Pb ages of zircon cores and overgrowth rims yielded, 2966 ± 9 Ma for crystallization and 2091 ± 10 Ma for metamorphism, respectively. Zircons from the metanorite show internal textures consistent with high grade metamorphism. The U-Pb LA-ICP-MS age determination provided a 2099 ± 6 Ma metamorphic age for the Jacurici Complex, indicating it was already emplaced during amalgamation around 2.1 Ga. Zircons from the undeformed quartz-feldspar pegmatite provided a LA-ICP-MS U-Pb age of 2083 ± 11Ma, marking the end of the N-S transcurrence. The magmatic Jacurici Complex age remains undefined, but is equal to, or older than, 2.1 Ga. Therefore, possible correlations with other mafic-ultramafic intrusions, such as the Cu-rich Caraíba Complex, should be reassessed. Our results indicate that the N-S transcurrence ended earlier in the Jacurici Complex region than in the northwestern area of the Salvador-Curaçá belt. [ABSTRACT FROM AUTHOR]

The distribution of trace elements in pyrite has been documented for the first time in quartz veins hosted in the Mesoproterozoic metasedimentary sequence of the Tombador Formation, São Francisco Craton, northeast Brazil. In this study, Electron Microprobe Analyses (EPMA) were used to determine the trace-element compositions of pyrite in these hydrothermal quartz veins. Three pyrite types have been distinguished and interpreted from petrographical relationships and trace-element patterns. Pre-existing pyrite (Py1), derived from the host-rock quartzite, is Ni-poor with concentrations varying from 600 – 6,100 ppm. Elongated syn-tectonic pyrite (Py2) has similar trace-element composition to the Py1, with Ni amounts ranging between 830 and 7,870 ppm. In contrast, possibly post-tectonic, euhedral to subhedral hydrothermal pyrite (Py3), contains higher contents of Ni (7,970 – 26,120 ppm). Mafic and/or metasedimentary rocks from the Espinhaço Supergroup were probably the source of Ni for this fluid-flow event. Fluid generation is related to the devolatilization of the base of the thickened crust, with migration of fluids by preexisting structures. Several shear zones and large-scale NNW-trending folds were developed during the inversion of the Espinhaço basin, as a result of the ca. 0.6 Ga Brasiliano orogenic event. Regional fluid movement through the crust at this time is supported by several mineralized veins and hydrothermal deposits in the São Francisco Craton and adjacent Neoproterozoic belts.

The Gentio metagranitoid presents equigranular and porphyritic facies, modal composition ranging from tonalite to monzogranite with calculated TZr<800 °C for most samples. Its mineralogy is dominated by quartz and feldspar (77% to 95%), biotite is the only mafic mineral present (2% to 18%) and, titanite, zircon, apatite, allanite are important accessory phases. These rocks range from metaluminous to weakly peraluminous, and have large variation in major and trace elements, and high alkali contents (>6 wt.%). Zircon analyses by LA-ICP-MS and SHRIMP yielded a concordia age of 2 119±10 Ma for the porphyritic facies and an upper intercept age of 2 111±15 Ma for the equigranular facies. The whole-rock Sm-Nd TDM ages vary from 2.4 to 2.8 Ga with εNd(2.1) values between −0.7 and −5.3, indicating crustal derivation from distinct and/or heterogeneous protoliths. Field observations indicate that the Gentio metagranitoid was formed through different pulses of magma. Individual batches were subject to little or even no fractionation process after its emplacement. Although the Gentio metagranitoid crosscuts metamafic and metaultramafic rocks akin to an oceanic arc setting, this pluton is likely originated by partial melting of a more evolved quartz-feldspathic crustal igneous rock in a post-collisional environment, after the accretion of the arcs from the Mineiro belt and rocks of the Mantiqueira Complex. [ABSTRACT FROM AUTHOR]

Abstract This paper analyzes mineralogical, geochemical, and geochronological aspects, along with the effect of hydrothermal/metasomatic overprints, to identify the presence of primary phosphate as well as depositional and paleoenvironmental conditions in marble and calcsilicate sequences recrystallized under transitional amphibolite-granulite metamorphic conditions in the Tanque Novo-Ipirá Complex within the Salvador-Curaçá Orogen, northeastern São Francisco Craton, state of Bahia, Brazil. Petrographic studies have identified up to 10 vol.% disseminated apatite and whole-rock P2O5 contents up to 3.2 wt.%. Post-depositional events affected the lithofacies to varying degrees. Late hydrothermalism did not modify the rare earth element and yttrium (REEY) patterns considerably. When normalized to Post-Archean Australian Shale (PAAS), these lithofacies are marked by flat pattern REEY, true negative Ce anomalies, and positive Y and Gd. The highly variable Eu anomalies were inherited from the source composition but may have been affected by interaction with fluids. U-Pb LA-ICP-MS (laser ablation multicollector inductively coupled plasma mass spectrometry) ages indicate a maximum depositional age of 2128 Ga, as well as Paleoproterozoic and Neoarchean sources. Samples with anomalous phosphorus show Y/Ho ratios >30 and Ce/Ce* anomalies between 0.53 and 1.0 with an average of 0.70, suggesting a sub-oxic environment for phosphate precipitation.

This paper analyzes mineralogical, geochemical, and geochronological aspects, along with the effect of hydrothermal/metasomatic overprints, to identify the presence of primary phosphate as well as depositional and paleoenvironmental conditions in marble and calcsilicate sequences recrystallized under transitional amphibolite-granulite metamorphic conditions in the Tanque Novo-Ipirá Complex within the Salvador-Curaçá Orogen, northeastern São Francisco Craton, state of Bahia, Brazil. Petrographic studies have identified up to 10 vol.% disseminated apatite and whole-rock P2O5 contents up to 3.2 wt.%. Post-depositional events affected the lithofacies to varying degrees. Late hydrothermalism did not modify the rare earth element and yttrium (REEY) patterns considerably. When normalized to Post-Archean Australian Shale (PAAS), these lithofacies are marked by flat pattern REEY, true negative Ce anomalies, and positive Y and Gd. The highly variable Eu anomalies were inherited from the source composition but may have been affected by interaction with fluids. U-Pb LA-ICP-MS (laser ablation multicollector inductively coupled plasma mass spectrometry) ages indicate a maximum depositional age of 2128 Ga, as well as Paleoproterozoic and Neoarchean sources. Samples with anomalous phosphorus show Y/Ho ratios >30 and Ce/Ce* anomalies between 0.53 and 1.0 with an average of 0.70, suggesting a sub-oxic environment for phosphate precipitation. [ABSTRACT FROM AUTHOR]

The Porteirinha Block (PB) provides an important record of the origin and evolution of South American crust. The PB records the generation of Paleoarchean TTG, Mesoarchean anatexis, and Paleoproterozoic crustal reworking. It is exposed as a basement inlier in the Araçuaí Orogen as a result of a tectonic involvement of the continental margins of São Francisco Congo Paleocontinent (PSFC) during the collisional processes of Gondwana amalgamation at the Neoproterozoic. The PB basement unit is the Porteirinha Complex (PC), which consists of TTG orthogneisses, migmatites, amphibolites, metaultramafics rocks and Neoarchean granitoids. In this paper, we discuss the evolution of the TTG orthogneisses and migmatites from PC based on field, geochronological and whole-rock geochemistry data. Zircon U–Pb ages (LA-ICP-MS) show a complex and polycyclic evolution of these rocks. Concordant ages were obtained for crystallization of TTG magma at ca. 3.4 Ga and the geochemical signature supports the idea of TTG generation by partial melting of hydrated mafic crust under garnet-amphibolite facies conditions. Zircon U–Pb ages also suggest crustal reworking events at 3.1 Ga. Metatexite and diatexite domains related to partial melting of TTG orthogneisses are individualized. The migmatites record processes of crustal anatexis and melt generation that occurred between 2.8 and 2.9 Ga (LA-ICP-MS, U–Pb in zircon) and are linked to crustal reworking and heat generation events recognized regionally. The new data presented in this work allow us to establish correlations between Archean and Paleoproterozoic units of the PB and those that occur regionally, particularly those related to Gavião block, where a series of stages and events of early crustal evolution are shared. • Archean crustal evolution of TTG orthogneisses from the São Francisco Congo Paleocontinent. • Zircon U–Pb geochronology shows igneous ages of 3.4 Ga for the precursor TTG magma of the Porteirinha Complex orthogneisses. • The orthogneisses show a typical TTG signature and were generated by partial melt of thickened lower crust. • Meso-Neoarchean crustal anatexis are recorded in metatexites and diatexites domains. • Successive stages of magmatism and crustal reworking have been identified since the Paleoarchean. [ABSTRACT FROM AUTHOR]

The Minas-Bahia orogeny juxtaposed Archean crustal fragments and Paleoproterozoic magmatic arcs to form the São Francisco-Congo Paleocontinent by the Rhyacian (ca. 2.05 Ga). Unravelling the Minas segment of the Minas-Bahia Orogenic Belt (MBO) is an important key to understanding the role of the São Francisco-Congo Paleocontinent in the construction of the Columbia Supercontinent. The Orosirian (ca. 1.9 Ga) final amalgamation of Columbia was preceded by a complex history of accretion of Archean nuclei and Proterozoic magmatic arcs. We present new whole-rock element geochemistry and isotopic (Rb-Sr, Sm-Nd) data and U-Pb ages for granitoid rocks of the main basement complexes located in the southern part of the São Francisco cratonic tip, which displays varied degrees of Neoproterozoic reworking related to the Brasiliano orogeny. Published data for the Campo Belo Complex, the Mineiro Belt and the Piedade Block are combined with the new data set to propose an integrated model for the tectonic evolution of the Minas segment of the MBO. This evolutionary model documents a complete Paleoproterozoic orogenic cycle, from subduction with terrane accretion to collision, followed by late-orogenic collapse. Subduction started diachronously between ca. 2.4 Ga and 2.2 Ga involving various Archean nuclei and Paleoproterozoic magmatic arcs that were later amalgamated during two collisional events at ca. 2.10 and 2.05 Ga. The oldest tonalite-trondhjemite-granodiorite (TTG) to sanukitoid magmatic suites transition are of Neoarchean age in the Piedade block, and of Paleoproterozoic age in the Mineiro belt and Mantiqueira complex, apparently indicating a diachronous onset of plate tectonic processes in different crustal segments. The petrogenesis, geochronology and isotopic signatures of these granitoid rocks provide important evidence towards understanding the periodicity of tectonic processes associated with the supercontinent cycle throughout Earth history. Unlabelled Image • Diachronous Collision of the São Francisco Paleocontinent. • Protracted orogenic cycle, from pre-subduction to late orogenic collapse is recognized within the Minas-Bahia Orogen. • A large continental landmass amalgamated during the Rhyacian (ca. 2.1–2.05 Ga). • Archean-Paleoproterozoic basement units reworked during the Brasiliano Orogeny. [ABSTRACT FROM AUTHOR]

In Brazil, Paleoproterozoic khondalites were recognized in Ceará, Bahia, Goiás, Tocantins, and Minas Gerais. The Itapecerica supracrustal succession in the Southern São Francisco Craton (Minas Gerais) contains sillimanite-cordierite-garnet-biotite gneiss (khondalite) with an anatectic record. The high-grade khondalite preserve representative mineral assemblages of peak and orogen collapse after post-peak decompressional stage. Based on petrographic observations and P–T pseudosections of bulk rock compositions, a clockwise pressure-temperature-time (P–T-t) path was inferred. The metamorphic peak assemblage is liquid + plagioclase ± K-feldspar + garnet + biotite + ilmenite + sillimanite + quartz at 715–772ºC and 5.5–7.5 kbar. In addition, the precursor sediments had mixed pelitic-wacke compositions resulting from erosion of different sources. Sediment deposition would have occurred at active continental marginal setting. Surrounding the khondalite occurs a peraluminous metagranite named here as Água Rasa, formed in syn- to post-collisional setting, whose εNd(t) (−0.5 to −2.7) and 87Sr/86Sr(t) (1.04 to 1.08) and the data set indicate that the precursor magma of the Água Rasa metagranite originated from anatexis of the khondalitic rocks (crustal source) and associated amphibolites (mantle source) during the crustal thickening followed by tectonic exhumation at peak metamorphism and at decompressional stage during the orogenic collapse. The khondalite yielded ages from monazite U-Th-PbT dating of 2090 ± 26 Ma and 1937 ± 32 Ma, while the Água Rasa metagranite yielded ages of 2077 ± 24 Ma and 1941 ± 23 from monazite and 1934 ± 74 Ma from zircon U-Pb. The ages of >2.0 Ga are related to the metamorphic peak, while the younger ones (~1940 Ma) are related to the orogen collapse after post-peak decompressional stage. Similarities between the khondalite rocks of this study and of the North China Craton suggest that the São Francisco-Congo Craton was near the North China Craton in the supercontinent Columbia for the 2.1–1.9 Ga period. [ABSTRACT FROM AUTHOR]

TIMS Pb-Pb geochronological data allow determination of the timing and genesis of the Fazenda Coqueiro volcanic‑hosted massive sulfide (VHMS) Zn-Pb deposit hosted in the Neoarchean Mundo Novo greenstone belt (MNGB), NE São Francisco Craton. The deposit is inserted in the Rhyacian-Orosirian Contendas-Jacobina lineament between Archean cratonic blocks. The basement of the deposit is composed of Paleoarchean metagranite and metarhyolite nuclei tectonically emplaced within the supracrustal rocks. The volcanic-sedimentary rocks comprise the ocean floor western metabasalt, calcsilicate rock, aluminous schist, metachert, banded iron formation, and tremolitite of the middle sequence and metasedimentary siliciclastic rocks of the uppermost sequence of the MNGB. The western metabasalt is hydrothermally altered, which resulted in the formation of two alteration zones. They consist of carbonate zone, proximal, hosting massive sulfides composed mainly of sphalerite and galena with minor chalcopyrite; and sericite-chlorite zone, distal, hosting mainly disseminated chalcopyrite. Pb-Pb galena, chalcopyrite and sphalerite data from the massive and disseminated zones in the Fazenda Coqueiro deposit yielded model ages of 2,804 ± 11.15, 2,794 ± 11.2, and 2,767 ± 11.1 Ma, respectively, with the Pb sourced from the upper crust, based on the uranogenic and thorogenic diagrams. The Pb-Pb isochron mineralization age of 2,747 ± 16 Ma obtained from chalcopyrite and sphalerite samples from the massive and disseminated zones suggests that the sulfides were coeval and do not record later metamorphic-hydrothermal events. Therefore, the Fazenda Coqueiro deposit would have formed from Neoarchean ocean floor volcanic-exhalative processes. The Rhyacian-Orosirian tectonic event compressed the deposit between Archean blocks along the Contendas-Jacobina lineament, preserving the sulfides from remobilization processes.

Abstract The Quadrilátero Ferrífero metallogenetic province is located in the southernmost portion of the São Francisco craton, SE Brazil. The Tamanduá and Cambotas ridges stand out topographically in the northeastern portion of Quadrilátero Ferrífero and show NE-SW and N-S directions, respectively. Those ridges involve metasedimentary rocks of the Tamanduá Group bounded by a fault system. Due to stratigraphic and structural complexities, there is little consensus about the maximum sedimentation age and the stratigraphic position in which Tamanduá Group sediments were deposited. In this work, we took advantage of the excellent exposures in the Tamanduá and Cambotas ridges to present detailed stratigraphic observations combined with U-Pb zircon geochronological data from samples of different stratigraphic levels of Tamanduá Group. Furthermore, we provide U-Pb data from samples of the intrusive Pedra Formosa Suite that cut the whole Tamanduá sequence in the study area. Our observations showed that the Tamanduá Group represents a rift-sag basin-fill succession developed along the eastern border of the São Francisco paleoplate. The basal metaconglomerate and metasandstone package grades upward into marine metasandstone and phyllite. Detrital zircon obtained from the basal unit, Antônio dos Santos Formation, reveals maximum depositional ages between ca. 1981 and 1770 Ma. The upper succession, Cambotas Formation, shows a maximum depositional age from 1769 to 1740 Ma. The Pedra Formosa Suite shows zircons that crystallized at ca. 1740 Ma. The stratigraphic framework and the Orosirian-Statherian ages suggest a correlation with the first rifting event within the São Francisco paleoplate, the precursor of Paleo- to Mesoproterozoic Espinhaço basin.

Copyright of Anuario do Instituto de Geociencias is the property of Universidade Federal do Rio de Janeiro, Instituto de Geociencias and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Paleoproterozoic retrogressed eclogite (retroeclogite) occurs in the Itaguara Sequence included in the suture zone formed by collision between the Archean Divinópolis and Campo Belo/Bonfim Complexes in the southern São Francisco Craton, which represents the South American counterpart of the African Congo Craton. The Itaguara retroeclogite contains scarce omphacite and phengite but abundant garnet porphyroblasts embedded in a fine-grained, amphibole, biotite and quartz-bearing matrix. The 2.20 ± 0.05 Ga eclogitization event (garnet and whole rock Sm-Nd isochronic age) of the E-MORB protolith (T DM ~ 2.47 Ga) is recorded by omphacite formation during high-pressure prograde stage in amphibole eclogite facies due to ~70 km depth subduction process. Amphibole eclogite facies metamorphic peak stage of 17–20 kbar and 600–700 °C occurred during ~2.1 Ga continental collision. Tectonic exhumation-related decompression during collision probably triggered partial melting of the eclogitic rock. Finally, decompression late stage estimated between 5 and 8 kbar and 550–650 °C under amphibolite facies overprint during orogenic collapse was responsible for appearance of kelyphitic reaction rims (symplectite) around garnet crystals. As its Paleoproterozoic contemporary analogues from Congo Craton, the Itaguara retroeclogite is one of the oldest records of the modern-style plate tectonics. Unlabelled Image • Itaguara retroeclogite is one of the oldest records of modern-style plate tectonics. • Its E-MORB protolith (T DM ~ 2.47 Ga) became eclogite in 2.20 ± 0.05 Ga subduction. • Metamorphic peak stage conditions were 17–20 kbar and 600–700 °C. [ABSTRACT FROM AUTHOR]

The São Francisco Craton, in Brazil, together with adjacent orogenic systems formed during Gondwana assemblage, are well-suited for the study of crustal growth processes. The region's geological history is marked by a series of complete tectono-metamorphic cycles, from the Archean to late Neoproterozoic, comprising arc-related magmatism followed by continental collisions and ultimately post-tectonic igneous events and rifting. In this contribution, a comprehensive isotopic database was compiled from the literature, composed mainly of high-quality U-Pb magmatic and metamorphic ages (ca. 1000), together with Lu-Hf (ca. 1300) and Sm-Nd (ca. 300) data. Using this database, combined with a tectonic/geochemical synthesized review of the region, it is possible to test which of the available contending models can better explain the apparent periodicity in the formation of the continental crustal. Some interpreted the peaks and troughs in the crustal age record as periods of increased magmatic production, controlled by periodic mantellic events. Another hypothesis is that subduction-related rocks are shielded from tectonic erosion after continental amalgamation, the peaks thus reflecting enhanced preservation potential. The latter hypothesis is favored, as the variability regarding the timing of arc-related peak magmatic production (U-Pb age peaks) from different tectonic provinces around the globe and in the considered regions, coupled to the fact that peak arc-production is always closely followed in time by major continental amalgamations (supercontinent formation), precludes a unified global causation effect, such as mantellic overturns or slab avalanches, and supports the preservation bias hypothesis. Furthermore, the worldwide (including the São Francisco Craton) occurrence of plume-related magmatism is concentrated during the periods of supercontinent break-up (i.e. after major collisions), which better relates to a top-down control on mantle convection and opposes most of the models that advocate for the primary periodicity of magmatic production, which predict enhanced plume activity slightly prior or concomitant to supercontinent formation events. Unlabelled Image • Isotopic (U-Pb, Lu-Hf and Sm-Nd) compilation of the São Francisco Craton • Compiled data better fit the preservation bias model for the growth of continental crust. • Differences in age and crustal thickness during Neoproterozoic continental arc development [ABSTRACT FROM AUTHOR]

The Jacobina Basin has a well-preserved sedimentary record, including continental and marine deposits, and hosts Au-(U)-Py mineralization in metaconglomerate beds similar to the Witwatersrand gold province. Based on petrographic observations, in situ trace-elements, and multiple sulfur isotope analyses (32S, 33S, 34S, and 36S) on pyrite from alluvial and marine facies, several types of pyrite were recognized. The pyrite grains identified in the alluvial metaconglomerates resemble those found in several pre-GOE gold-bearing metaconglomerates, including detrital and epigenetic varieties. Detrital inclusion-bearing pyrite is enriched in several redox-sensitive trace-metals as well as Au, which indicate an association with carbonaceous shales. On the other hand, the sources of detrital massive pyrite are more variable and include igneous, metamorphic, and hydrothermal sources from the Paleoarchean hinterland of Jacobina Basin. Epigenetic pyrite in metaconglomerates formed during metamorphism by the recrystallization of detrital pyrite with negligible contributions from external hydrothermal fluids to the basin. Diagenetic and epigenetic pyrite are found in marine lithologies. In a metapelite sample, the pyrite grains formed near the sediment-water column interface, with S sourced from the photolytic sulfate (SO 4 2−, Δ33S < 0) dissolved in the water column. A quartzite sample, in turn, has detrital pyrite grains that were likely reworked from continental deposits, as well as pyrite formed by the assimilation of elemental sulfur (S 8 , Δ33S > 0) that accumulated in sediment pore water during diagenesis. Significantly, the pyrite associated with terrestrial metasediments shows a wide range in δ34S values but quite restricted ranges in Δ33S and Δ36S values, whereas pyrite associated with the marine metasedimentary rocks exhibits limited δ34S values but has a wide range in Δ33S values and correlated Δ36S values close to the Archean array. These data suggest distinct preservation routes for MIF-S from atmospheric SO 4 2− and S 8 in terrestrial and marine environments. Conditions on the terrestrial surface resulted in re-equilibration of distinct S sources, diminishing the amplitude of the Archean atmospheric signal. In contrast, SO 4 2− dissolved in shallow marine settings while S 8 settled to the floor, favoring the preservation of MIF-S isotopic signatures. Such processes may also explain the apparent differences in interpretations of atmospheric conditions derived from uncharacterized pyrites from Archean sources. Our data suggest that the Earth's atmosphere remained anoxic, and terrestrial conditions were such as to allow the syngenetic accumulation of gold, as recently proposed for the Witwatersrand gold deposits. [ABSTRACT FROM AUTHOR]

The Itareru tonalite is one of the Paleoproterozoic plutonic rock units that intruded the Serrinha block, an Archean-Paleoproterozoic crustal fragment of the São Francisco Craton (Bahia, Brazil). It is characterized by a ca. 80 km long, NW-SE elongated leaf-shaped body, mainly comprised of tonalite-diorite to granodiorite rocks with numerous dioritic enclaves. Magnetic studies were performed on 26 sites of the Itareru pluton (including country rocks). Anisotropy of low-field magnetic susceptibility (AMS) and anisotropy of anhysteretic remanent magnetization (AARM) are coaxial, indicating that all minerals have the same orientation, partially controlled by regional strain. Rock-magnetism measurements reveal that paramagnetic–matrix minerals contributed significantly to the magnetic susceptibility and AMS while magnetite grains in the range of 2–5 μm are responsible for AARM. Magnetic fabrics in the central region of the pluton are probably primary (magmatic), which was acquired when the rocks were crystallized, reflecting magma flow linked to a magma feeder zone (magma chamber). The moderated magnetic lineation plunges in the northern part of the pluton suggest that this region was close to the feeder zone. In contrast, the southern region should be far from it, since the magnetic lineations are horizontal to sub-horizontal. The Itareru tonalite emplacement was also controlled by regional strains related to the collision of the Paleoproterozoic Rio Itapicuru greenstone Belt with the Archean basement. • AMS and AARM are coaxial indicating that all minerals have the same orientation. • Magnetic fabrics in the central region of the pluton are probably magmatic acquired when the rocks were crystallized. • Magnetic fabrics in the central region of the pluton are related to magma flow. • The emplacement of the pluton was controlled by regional strains. • Itareru emplacement is related to the collision of the RIGB with the Archean basement. [ABSTRACT FROM AUTHOR]

ABSTRACT In the Southeastern Quadrilátero Ferrífero, a package of metapelitic rocks previously attributed to the Archean Rio das Velhas Supergroup crops out in Piranga locality. This study presents the mineral chemistry and U-Pb-Hf zircon geochronology on foliated staurolite-garnet mica schists. Garnet and staurolite index minerals are syn- to post-kinematic towards the main schistosity. Garnet porphyroblasts display well-developed compositional zoning of Mg-Fe-Mn-Ca, with increase of almandine and pyrope and decrease of spessartine towards the rim, implying in prograde metamorphic pattern. Estimates of P-T values for the metamorphic peak resulted in temperatures between 630 to 650ºC and pressure around 7 kbar. Pseudosections show well-defined stability fields in amphibolite facies, with a metamorphic path displaying progressive increase in P-T conditions. Maximum depositional age of 1,875 ± 51 Ma is established for the Piranga mica schists pointing to a depositional history that is younger than those previously described. Metamorphic Cambrian ages characterize the strong influence of deformational processes related to the final stages of Brasiliano Orogeny in the Southeastern Quadrilátero Ferrífero.

The presence of dome-and-keel provinces in Archean cratons has been connected with the initiation of plate tectonics on Earth as these features are most commonly observed in Archean rocks. The Quadrilátero Ferrífero in Brazil has been identified as a Paleoproterozoic dome-and-keel province for more than three decades. The prevailing model suggests that it formed during the Rhyacian Transamazonian orogeny, making it unique among dome-and-keel provinces. However, a lack of appropriate lithologies, datable minerals and the metamorphic overprint of later orogenesis has resulted in a cryptic metamorphic record for the formation of this dome-and-keel province. A clinopyroxene-bearing migmatite from the core of the Bação dome has peak P – T conditions of 5–7 kbar and 700–750 °C and a published age of ca. 2730 Ma based on U–Pb ages of zircon from leucosomes, suggesting that this age represents the migmatisation event. A fine-grained epidote-albite-titanite assemblage overprints the coarse-grained clinopyroxene and amphibole, giving P – T conditions of 8–9 kbar and 550 °C with an associated titanite age of ca. 2050 Ma. A garnet-bearing amphibolite sample also from the core of the dome has peak P – T conditions of 7–8 kbar and 650–700 °C, and texturally late titanite from this sample produces an age of ca. 2060 Ma. Three additional samples were collected from the edges of the dome. A garnet-gedrite bearing felsic schist produces peak P – T conditions of 8–9 kbar and 650–700 °C on a clockwise P – T evolution. This sample has a U–Pb zircon age of ca. 2775 Ma, which could date metamorphism or be the age of its volcaniclastic protolith. Texturally unconstrained titanite from the sample gives an age of ca. 2040 Ma. A garnet-bearing amphibolite that occurs as a boudin within the felsic schist gives both zircon and titanite ages of ca. 2050 Ma and has peak P – T conditions of 5–6 kbar and 650–700 °C on a near isobaric P – T path. An amphibolite dike, observed to cross-cut the felsic schist produces a zircon U–Pb age of ca. 2760 Ma. Altogether this data suggests that the samples were metamorphosed in the Archean (ca. 2775–2730 Ma) and again during the Transamazonian event. The most plausible explanation for this data is that dome-and-keel formation occurred in the Archean with migmatisation and high-temperature metamorphism occurring at this time. The Paleoproterozoic event is interpreted as a reactivation of the dome-and-keel formation structures, with Paleoproterozoic keels crosscutting Archean keels and producing metamorphic aureoles. The high radiogenic heat production and the presence of dense sedimentary successions in Archean terranes make dome-and-keel provinces a uniquely Archean feature, but they are susceptible to reworking, resulting in an enigmatic record of formation. Image 1 • The formation of a Proterozoic dome-and-keel province was investigated. • Samples record two metamorphic events at ca. 2730 and ca. 2000 Ma. • Dome-and-keel formation occurred in the Archean and reactivated in the Paleoproterozoic. • The properties of Archean rocks result in dome-and-keel formation. [ABSTRACT FROM AUTHOR]

• Characteristic remanence recorded by the Uauá tholeiitic dykes, Brazil, is primary. • A new ∼2.62 Ga paleomagnetic pole for the northern São Francisco craton is obtained. • The northern São Francisco craton was part of the Supervaalbara supercraton. The original connections of Archean cratons are becoming traceable due to an increasing amount of paleomagnetic data and refined magmatic barcodes. The Uauá block of the northern São Francisco craton may represent a fragment of a major Archean craton. Here, we report new paleomagnetic data from the 2.62 Ga Uauá tholeiitic mafic dyke swarm of the Uauá block in the northern São Francisco craton, Eastern Brazil. Our paleomagnetic results confirm the earlier results for these units, but our interpretation differs. We suggest that the obtained characteristic remanent magnetization for the 2.62 Ga swarm is of primary origin, supported by a provisionally-positive baked contact test. The corresponding paleomagnetic pole (25.2°N, 330.5°E, A 95 = 8.1°, N = 20) takes the present northern part of the São Francisco craton to moderate latitudes. Based on the comparison of the paleolatitudes of cratons with high-quality paleomagnetic data and magmatic barcodes, we suggest that the northern part of the São Francisco craton could have been part of the proposed Supervaalbara supercraton during the Archean. Supervaalbara is proposed as including (but not limited to) the part of the São Francisco craton as well as the Superior, Wyoming, Kola + Karelia, Zimbabwe, Kaapvaal, Tanzania, Yilgarn, and Pilbara cratons. [ABSTRACT FROM AUTHOR]

• Two-stage plutonism (2.47–2.41 and 2.35–2.33 Ga) in the Mineiro belt. • Juvenile-derived plutonism which underwent minor crustal contamination in evolved arc setting. • TTG suites formed by partial melting and minor fractional crystallization. • Geodynamics and temporal link among arc and intraplate magmatisms. The Cassiterita Orthogneiss is the oldest pluton so far found within the Mineiro belt. In situ zircon U-Pb ages constrain the crystallization of the Cassiterita Orthogneiss to between 2472 ± 11 and 2414 ± 29 Ma. Zircon overgrowths are dated at 2024 ± 54 Ma, which matches the timing of the regional metamorphic overprint in the main belt. One metatonalite dike yields a zircon U-Pb age of 2156 ± 17 Ma, while a single inherited core is concordant at 2426 ± 17 Ma. The studied rocks exhibit low to medium grade metamorphism, and show tonalitic and granodioritic composition akin to TTG suites (tonalite-trondhjemite-granodiorite). The trace element patterns suggest that partial melting and fractional crystallization operated in the genesis. The La/Yb N , Yb N , Sr/Y, Nb/Ta and Zr/Sm values point to a garnet amphibolite residue. The positive ε Nd(t) (+5.2 to +1.3) and low 87Sr/86Sr i (0.700–0.702) isotopic signatures suggest a LREE- and/or LILE LILE-enriched MORB mantle source. The zircon ε Hf(t) parameters (-8.0 to +2.9) of the studied samples indicate some crustal assimilation during magma genesis. The chemical and isotopic signatures of the Cassiterita Orthogneiss are similar to nearby (ca. 2.35 Ga) TTG plutons, interpreted as cogenetic. This peculiar plutonism (from 2.47 to 2.35 Ga) marks the earliest stage of a long-lived accretionary regime (2.47–2.00 Ga) that built the Mineiro belt. This earliest orogenic event is roughly coeval with the (chemical) sedimentary infill of the passive basin (Minas Supergroup), previously dated at ca. 2.42 Ga. The age matches suggest a geodynamic link between the oceanic arc magmatism and penecontemporaneous basin infill in the continental margin. Early Paleoproterozoic TTG plutons such as the Cassiterita Orthogneiss have been related to the earliest accretionary processes that developed away from continental margins, where roughly coeval dike swarms and A-type plutons are emplaced along with the onset of passive basins. We explore the potential association and temporal interplay between convergent and intraplate settings and other major changes beyond the Archean-Paleoproterozoic Transition. [ABSTRACT FROM AUTHOR]

In the Southeastern Quadrilátero Ferrífero, a package of metapelitic rocks previously attributed to the Archean Rio das Velhas Supergroup crops out in Piranga locality. This study presents the mineral chemistry and U-Pb-Hf zircon geochronology on foliated staurolite-garnet mica schists. Garnet and staurolite index minerals are syn- to post-kinematic towards the main schistosity. Garnet porphyroblasts display well-developed compositional zoning of Mg-Fe-Mn-Ca, with increase of almandine and pyrope and decrease of spessartine towards the rim, implying in prograde metamorphic pattern. Estimates of P-T values for the metamorphic peak resulted in temperatures between 630 to 650°C and pressure around 7 kbar. Pseudosections show well-defined stability fields in amphibolite facies, with a metamorphic path displaying progressive increase in P-T conditions. Maximum depositional age of 1,875 ± 51 Ma is established for the Piranga mica schists pointing to a depositional history that is younger than those previously described. Metamorphic Cambrian ages characterize the strong influence of deformational processes related to the final stages of Brasiliano Orogeny in the Southeastern Quadrilátero Ferrífero. [ABSTRACT FROM AUTHOR]

We present the first data on the geochemistry and isotopic age of zircons from rocks of the Roseta (lherzolite and olivine orthopyroxenite) and Córrego da Areia (olivine orthopyroxenite) ultramafic massifs localized among Archean-Proterozoic metamorphic strata in the southern folded framing of the São Francisco Craton. The examined zircons differ in crystal morphology, the intensity and type of cathodoluminescence, oscillatory zoning, the distribution of trace elements, and U-Pb isotopic age. Zircon crystals from the Roseta lherzolite have an age of 800-728 Ma and show negligible cathodoluminescence. Some of them have reaction rims with an age of 663-619 Ma. The crystal cores are enriched in rare earth elements (REE) but are often depleted in U as compared with the reaction rims. The age of zircons from the Roseta olivine orthopyroxenite showing moderate cathodoluminescence is within 622.6-596.9 Ma. Zircons from the Córrego da Areia olivine orthopyroxenite show moderate to intense cathodoluminescence and often have a rhythmic oscillatory zoning. They are characterized by an uneven distribution of REE and other trace elements and have high contents of U and Th. Most of these zircons have an ancient isotopic age (2558-2100 Ma). The examined zircons are of several types: relict, xenogenic, syngenetic, and epigenetic. The Roseta and Córrego da Areia massifs are considered to be protrusive outliers of a deep-seated Precambrian mafic-ultramafic complex, which were tectonically transferred along faults into the intensely metamorphosed Archean-Proterozoic strata in the southern folded framing of the São Francisco Craton. [ABSTRACT FROM AUTHOR]

Abstract The Quadrilátero Ferrífero in the São Francisco Craton, Brazil is known for its world-class gold deposits hosted by the Rio das Velhas greenstone belt (RdV). As in other greenstone belts, gold is also concentrated in late Archean/early Paleoproterozoic supracrustal units; in this case within the Moeda Formation. This unit has been compared to the Witwatersrand basin where there has been a long-term debate over the nature of the gold and whether it is detrital (placer), hydrothermal or hybrid (modified placer). Presently, links between gold in the Moeda Formation and RdV are tenuous. To enlighten this area of ambiguity, a new approach using chemical, isotopic and mineral inclusion data from detrital rutile found in the gold-bearing horizons of the Moeda Formation is presented. Grain textures and mineral inclusions have contributed to establishing a primary hydrothermal origin for the rutile, related to As-Fe-Cu-Sb-Pb-W rich mineralising fluids. Fe, Nb and V indicate that the likely source of the gold-related rutiles is the Archean banded iron formations within the RdV, where most of the lode-gold occurs. Average Nb/Ta values of these rutiles are lower than average continental crust ratios which suggests fractionation driven by fluid precipitation and/or competing mineral phases. U-Pb data yield primary crystallization ages older than deposition ages (>2.58 Ga), supporting the detrital nature of these rutiles. Rutiles record either resetting or new growth at 2.1 Ga and at ca. 500 Ma, during which gold was remobilised. Hence, this study supports a modified placer model for the gold-bearing horizons of the Moeda Formation. These fluid-assisted gold remobilisation events can be found in other correlated Paleoproterozoic gold-bearing horizon units that represent intracratonic basins related to the rifting of the Kenorland Supercontinent. This study reinforces the suitability of rutile and mineral inclusions as a powerful tool to elucidate processes and provenance. Graphical abstract Unlabelled Image Highlights • Multiple stages of fluid-induced gold remobilisation in Paleoproterozoic placer • Mineral inclusions in rutile can be used as an effective provenance tool. • Nb/Ta vs Zr/Hf values discriminate different types of rutile. [ABSTRACT FROM AUTHOR]

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The presence of diamonds of lherzolitic, eclogitic and websteritic paragenesis in proximal alluvial deposits on the southwestern edge of the São Francisco Craton documents the incorporation of subducted oceanic crust and associated metasomatism through slab dehydration fluids affecting the local SCLM. To better constrain the subduction-association of diamond substrates and metasomatic events, we conducted a combined study of the δ13C-δ15N-[N] characteristics of 81 diamonds and the δ18O values of four of their eclogitic garnet inclusions. Diamond carbon isotope compositions range from −25.5 to +0.5‰, with 13C-depleted diamonds (≤ −7‰) being exclusively of eclogitic/websteritic paragenesis while the 13C-enriched (≥ −2‰) tail of the distribution is related to diamonds with lherzolitic inclusions. Nitrogen isotope values range from −14.2 to +25.5‰, with about half of the values being positive. A general absence of coherent trends in δ13C-δ15N-[N] across growth zones implies that diamond formation did not occur under fluid-limited conditions. Instead, the observed heterogeneity in carbon and nitrogen isotope compositions reflects contributions of distinct source reservoirs hosted in both altered oceanic crust and Earth's mantle. Nitrogen contents peak around a δ15N value of −3.5‰, indicating that more N-rich fluids, presumably representing a primitive endmember composition, have a mantle-like δ15N signature. While positive and negative δ15N values occur equally near the δ13C mantle value (−5 ± 2‰), 13C-depleted diamonds have nitrogen isotope compositions skewed towards positive values. 13C depletion and 15N enrichment is a signature of biogenic carbonates/organic matter and low-T clays in uppermost, basaltic sections of oceanic crust that experienced low-temperature seawater alteration prior to subduction. Correspondingly, the oxygen isotope compositions of eclogitic garnet inclusions fall in a restricted range between +5.5‰ to +7.0‰. For three of the four samples, the stable isotope signatures of inclusions and host diamonds display perfect agreement, with the intensity of seawater alteration signatures, in the form of garnet inclusion 18O enrichment and host diamond 13C depletion and 15N enrichment, increasing together. For the fourth sample, the δ18O signature of the garnet inclusion (+5.5‰) and δ13C-δ15N signatures of the diamond host (−25 and + 19‰, respectively) are decoupled. While the mantle-like δ18O signature indicates a diamond substrate derived from deeper levels in oceanic crust (e.g., deep sheeted dikes), the diamond-forming fluids must have originated from sources that originally resided near the sea water interface. A viable mode of mixing such disparate isotopic signatures is the interaction of diamond-forming fluids derived from shallow oceanic crust altered at low-temperatures with eclogitized substrates originally formed in deeper levels of oceanic crust. This process likely occurred during diamond formation in a tectonic subduction mélange, which juxtaposes deeper and shallower levels of oceanic crust. In the lithospheric mantle above the subcreted oceanic slab, the elevated carbon isotope and highly variable nitrogen isotope compositions of diamonds formed in lherzolitic substrates likely relate to devolatilization and/or melting of principally oceanic sediments containing marine carbonates and clays and subsequent mixing with mantle-derived volatile components. In combination, our diamond and inclusion stable isotope data provide insight into multiple processes that promote diamond formation both inside subducted slabs accreted to the São Francisco cratonic keel and in adjacent subcontinental lithospheric mantle. • Diamonds record both mantle and crustal isotopic signatures. • Eclogitic and websteritic diamonds are 13C-depleted, lherzolitic diamonds are 13C-enriched. • Mantle fluids are more nitrogen-rich than subduction fluids. • Garnet inclusions δ18O reflects original stratigraphic position within oceanic crust. • Diamond formation within subduction mélange. [ABSTRACT FROM AUTHOR]