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Biochar amendment have been explored recently for improving hydro-mechanical properties of landfill cover system and enhancing the vegetation for the ecological restoration of post closure landfills. Existing studies have predominantly focused on the hydro-mechanical properties of biochar-amended rooted soils and yet few studies have comprehensively investigated their gas permeability functions in response to unsaturated conditions. The objective of this study is to experimentally and theoretically investigate the coupled effects of biochar and root intensity on CO2 gas permeability in unsaturated soil. Biochar-amended rooted soil was prepared by growing Chrysopogon zizanioides on granite residual soils with biochar at a mas ratio of 5 %. Gas permeability and unsaturated soil properties (i.e., suction and degree of saturation) were monitored simultaneously. Due to the presence of roots, the maximum gas permeability, hydraulic conductivity, and suction increased by 200 %, 600 %, and 50 %, respectively, compared with bare soil. This was attributed to preferential flow, micropore increasement and negative pressure induced by root growth. However, biochar addition decreased the maximum gas permeability and hydraulic conductivity by 21 % and 33 %, respectively. This was attributed to the pore filling function of biochar, increased capillarity due to intrapore of biochar, and presence of surface functional groups in biochar promoting CO2 adsorption. A newly developed model was proposed to predict gas permeability with respected to unsaturated soil properties. It was revealed that the gas permeability function of rooted soils showed a strong dependence on the measured root length density. This study highlights the significance of adopting biochar in mitigation of gas emissions in vegetated landfill cover system.

Streams of Wokha district, Nagaland were surveyed (2005-2006) to document the torrential fish fauna. Amblyceps apangi Nath & Dey (1989) was collected from seven of the 12 streams surveyed, and found to be abundant in those streams. Detailed description of the study area, habitat characteristics of the streams, habitat ecology of the fish and a morphological study (based on 20 males and 20 females), is discussed.

Wetlands, known as beels in Assam, harbour rich fish fauna. Documentation of fish fauna in two beels of Goalpara district, Assam has been taken up for the first time (2005-2007). So far a total of 59 species belonging to 40 genera, 20 families and 8 orders have been recorded and listed in this paper. Of the collected species 17 were lotic species and 42 were lentic habitat fishes. These fishes are categorized into 13 vulnerable, 5 endangered and 1 critically endangered species (CAMP 1998). The two beels Sidli and Seksekia are fed by a channel from the river Brahmaputra.

Wild edible plants are often found to be rich sources of nutrients and medicinally beneficial compounds with pharmacological activities. Gnetum gnemon is a nutritionally important plant and a popular food source in parts of Assam and North-East India. Various microRNAs (miRNAs) have been recently identified in many plants; how ever, there are no records of identification of miRNAs in any species of Gnetum. The prediction of miRNA-target associations in G. gnemon is an important step to facilitate functional genomics studies in this species. In the present study, all known miRNAs from plants available in public domain were used to search for the conserved G. gnemon miRNA homologues in publicly accessible expressed sequence tags (ESTs) in NCBI database. An aggregate of 20 new potential miRNAs belonging to two diverse miRNA families (miR399 and miR5021) were identified through a homology-based search by following stringent filtering criteria. To investigate the potential cross-king dom effects of the identified miRNAs, we further identified the putative target genes of G. gnemon miRNAs in hu man transcriptome and analyzed them against the NCBI non-redundant protein database. The KEGG analysis of the target genes indicated that these genes were involved in different metabolic pathways such as caffeine meta bolism, drug metabolism, and nitrotoluene degradation. The target genes of G. gnemon miRNAs in humans were found to be associated with various disorders of both hereditary and non-hereditary origin. These results could help to shed new light on understanding of miRNA-mRNAs functional networks in this species and its po tential use as a small RNA-based therapy against some human diseases.

Critical soil suctions (threshold, tipping point, and permanent wilting) corresponding to initial drought response, near-death stage, and complete mortality, respectively; is essential for formulating irrigation schemes of vegetation grown in compacted soil under drought conditions. The effect of soil types on these critical soil suctions are unexplored and is crucial in understanding the soil-specific plant water functions. This study aims to establish the drought response of Axonopus compressus (grass), based on stomatal conductance (g s ) and chlorophyll fluorescence parameters (CI) grown in different soil types. A. compressus were grown in six soil types (2 coarse-grained and 4 fine-grained soils) for 8 weeks, followed by continued drought condition. The g s and CI were monitored along with soil suction and moisture content. Both leaf and root growth were observed to be higher in coarse-grained soils than fine-grained soils, even though the water retention of the coarse-grained soils were comparatively less. Drought stress initiation in plants was captured by ψ threshold from the CI (especially in fine-grained soils) before the g s response. The three critical soil suctions estimated from the correlation between CI and ψ were found to be increasing with higher soil clay fraction. Corresponding plant available water contents (based on v/v volumetric water content) with each of three critical soil suctions were found to be dependent on the relative growth of canopy to root growth that occurred in different soil medias. Especially, plant available water in 'tipping suction' was dependent on the soil clay fraction (i.e., higher fraction could restrict root water uptake) and is presented with a simple empirical correlation for A. compressus., Competing Interests: Declaration of competing interest All authors state that they have no competing interest to declare., (Copyright © 2024 Elsevier B.V. All rights reserved.)

The aim of this paper is to investigate the impact of observing affordance-driven action during motor imagery. Affordance-driven action refers to actions that are initiated based on the properties of objects and the possibilities they offer for interaction. Action observation (AO) and motor imagery (MI) are two forms of motor simulation that can influence motor responses. We examined combined AO + MI, where participants simultaneously engaged in AO and MI. Two different kinds of combined AO + MI were employed. Participants imagined and observed the same affordance-driven action during congruent AO + MI, whereas in incongruent AO + MI, participants imagined the actual affordance-driven action while observing a distracting affordance involving the same object. EEG data were analyzed for the N2 component of event-related potential (ERP). Our study found that the N2 ERP became more negative during congruent AO + MI, indicating strong affordance-related activity. The maximum source current density (0.00611 μ A/mm 2 ) using Low-Resolution Electromagnetic Tomography (LORETA) was observed during congruent AO + MI in brain areas responsible for planning motoric actions. This is consistent with prefrontal cortex and premotor cortex activity for AO + MI reported in the literature. The stronger neural activity observed during congruent AO + MI suggests that affordance-driven actions hold promise for neurorehabilitation., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Competing Interests: The authors declared no potential conflicts of interest with respect to the research, authorship and/or publication of this article.

Arsenic contamination in groundwater poses a significant threat to human health, affecting millions worldwide. This study presents a novel approach for simultaneous remediation of both As(III) and As(V) by using iron-functionalized polythiophene (PTh@Fe) composites. The PTh@Fe composite was synthesized by a reduction process involving FeCl 2 /FeCl 3 byproducts of polymerization, resulting in a highly efficient adsorbent for both As(III) and As(V) species. The investigation systematically examined key parameters influencing arsenic removal, including adsorbent dosage, pH, initial arsenic concentration, and contact time. The composite exhibited exceptional adsorption capacities, with maximum removal percentages of 98.7% for As(III) and 98.8% for As(V) under the optimized conditions. Thermodynamic and kinetic analyses suggested endothermic and spontaneous adsorption processes following a pseudo 2nd-order mechanism. Furthermore, the Langmuir isotherm model provided an excellent fit to the experimental data, with maximum adsorption capacities of 8.62 mg/g for As(V) and 7.57 mg/g for As(III). Density functional theory (DFT) calculations confirmed the feasibility of arsenic adsorption onto iron species in various oxidation states, offering valuable theoretical insights into the process. Furthermore, the composite demonstrated good reusability over multiple adsorption-desorption cycles and tolerance to coexisting anions, highlighting its practical applicability for water purification. This research demonstrates the potential of iron-functionalized polythiophene composites as a promising solution for addressing arsenic contamination in water sources, bridging the gap between innovative materials and theoretical understanding in environmental science and water treatment technologies., Competing Interests: The authors declare no competing financial interest., (© 2024 The Authors. Published by American Chemical Society.)

Fly ash consists of a considerable amount of hazardous elements with high mobility, posing substantial environmental risks during storage in surface impoundments and landfills. This hinders its efficient reuse in construction or material industries. To enhance the versatility of fly ash applications, a novel surface modification technique, termed SuMo, has been developed to create a hydrophobic polysulfide polymer coating on the surface of fly ash particles. The physicochemical properties of SuMo fly ash samples were examined using atomic force microscopy (AFM), environmental scanning electron microscopy (ESEM), thermal gravimetric analysis (TGA), Fourier Transform Infrared spectroscopy (FTIR), and leaching of hazardous elements was tested under practical environmental conditions (pH 4-12) based on the EPA's leaching environmental assessment framework (LEAF). The successful coating of polysulfide polymer on fly ash surface was verified through an increased percentage of C, S, and O in elemental mapping, coupled with the identification of S-O, CO, and C-H functional groups consistent with the chemical structure of polysulfide polymer. While the SuMo fly ash particles maintained their spherical shape, they exhibited increased surface roughness, robust hydrophobicity, and thermal stability up to 250 °C. Notably, owing to the coating's resilience against water leaching, the SuMo fly ash demonstrated a substantial reduction (up to 60-fold) in leachate concentrations of multiple concerning elements, including B, Be, Ba, Mn, Zn, As, Cr, Hg, etc., under various pH conditions compared to the uncoated fly ash. Furthermore, the polysulphide polymer coating effectively prevented Hg volatilization from fly ash below 163 °C. This study highlights the efficacy of the developed polysulfide polymer coating in mitigating the diffusion of hazardous elements from fly ash, thereby enhancing its potential reutilization in material, construction, and agriculture industries., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)

Introduction: Inflammation can be defined as a complex biological response that is produced by body tissues to harmful agents like pathogens, irritants, and damaged cells and thereby acts as a protective response incorporating immune cells, blood vessels, and molecular mediators. Histamine, serotonin, bradykinin, leukotrienes (LTB4), prostaglandins (PGE2), prostacyclins, reactive oxygen species, proinflammatory cytokines like IL-1, IL-11, TNF- anti-inflammatory cytokines like IL-4, IL-10, IL-11, IL-6 and IL-13, etc. all have different effects on both pro and anti-inflammatory mediators. Incorporation of combinatorial chemistry and computational studies have helped the researchers to design xanthones moieties with high selectivity that can serve as a lead compound and help develop potential compounds that can act as effective COX-2 inhibitors. The study aims to design and develop different series of substituted hydroxyxanthone derivatives with anti-inflammatory potential., Methods: The partially purified synthetic xanthone derivatives were orally administered to the carrageenan induced paw oedemic rat models at the dose of 100 mg/kg, and their effect in controlling the degree of inflammation was measured at the time interval of 30 min, 1, 2, 3, 4 and 6 hrs. respectively. Further, these compounds were also subjected to modern analytical studies like UV, IR, NMR and mass spectrometry or their characterization., Results: The results drawn out of the in silico, in vitro, in vivo and analytical studies concluded that the hydroxyxanthone derivatives can obstruct the enzyme COX-2 and produce anti-inflammatory action potentially., Conclusion: With the aim to evaluate the compounds for their anti-inflammatory activity, it was observed that the newly designed xanthonic compounds also possess a safe toxicity margin and hence can be utilized by the researchers to develop hybrid xanthonic moieties that can specifically target the enzyme COX-2., (Copyright© Bentham Science Publishers; For any queries, please email at epub@benthamscience.net.)

Background: Information Education Communication (IEC) materials play a vital role in behavior change by raising awareness about health issues. In India, suicide is the leading cause of death in the age group of 15-39 years, exemplifying the pressing need for raising awareness about suicide prevention. This study aimed to develop a brochure on suicide prevention for young adults with the help of scientific methodology., Materials and Methods: A cross-sectional qualitative research design was used in the study, and purposive sampling was used to collect the data. The study analyzed the awareness level and existing knowledge gap about suicide prevention among college students with the help of focus group discussions (FGDs) conducted independently among mental health experts, college teachers, and college students. Based on the findings from the FGDs, a comprehensive brochure was developed. The qualitative data collected by FGDs were analyzed using direct content analysis., Results: The findings of the FGDs helped identify the knowledge gaps with regard to young adult suicide prevention, and a brochure was prepared to address the same., Conclusion: The development of young adult suicide prevention IEC resources pertinent to Indian settings is crucial. To bridge the knowledge gap on suicide prevention among college students and raise awareness, a brochure was developed based on scientific findings of the FGDs., Competing Interests: The authors declare that there are no potential conflicts of interest with respect to the research, authorship, and/or publication of this article., (Copyright: © 2023 Journal of Education and Health Promotion.)

Aspergillus fumigatus is an opportunistic pathogen that primarily affects the lungs and frequently elicits an allergic immune response in human hosts via inhalation of its airborne asexual spores (conidia). In immunocompromised individuals, the conidia of this fungus can germinate in the lung and result in severe systemic infections characterised by widespread tissue and organ damage. Conversely, in healthy hosts, the innate immune system is instrumental in eliminating the conidia and preventing disease progression. As with numerous other pathogenic fungi, A. fumigatus possesses a set of virulence factors that facilitate its infective mechanism and the circumvention of immune defences in susceptible hosts. The intrinsic capacity of A. fumigatus to form complex 3D-structured biofilms, both on biotic and abiotic surfaces, represents a key determinant of its evasion of the host immune system and resistance to antifungal drugs. This review delineates the pivotal role of A. fumigatus biofilm structure and function as a significant virulence factor in pathogenic infections, such as aspergilloma and invasive pulmonary aspergillosis (IPA). Additionally, we discuss the importance for the development of novel antifungal drugs as drug-resistant strains continue to evolve. Furthermore, co-infections of A. fumigatus with other nosocomial pathogens have a substantial impact on patient's health outcomes. In this context, we provide a brief overview of COVID-19-associated pulmonary aspergillosis (CAPA), a recently documented condition that has gained attention due to its associated high degree of severity., (© 2023 Wiley-VCH GmbH.)

Construction and Demolition (C&D) waste is solid wastes generated from the construction, demolition, and renovation activities that constitute almost 30-40 % of globally generated solid wastes. Improper disposal and management of these materials can cause negative impacts on the environment, economy, and human health. Most research on C&D waste is limited to reduction, recycling, and reuse of the wastes. However, there is no systematic review dedicated entirely to the applicability of C&D wastes as adsorbent for waste management. This review presents the utilization of C&D wastes-based adsorbents for removing contaminants from environmental matrices covering triple edge benefits in the viewpoints of waste treatment, solid waste management, and disposal. The properties, the capability of C&D waste adsorbents on contaminant removal, and the influence of various factors on the adsorptive removal is detailed. Further, the mechanisms involved in contaminant removal by C&D waste are summarized. The review revealed that, chemisorption is the prominent mechanism of contaminant removal by most C&D wastes. Among the three types of C&D waste reviewed; concrete-based adsorbents were the most efficient for contaminant removal. Limited studies are avaiable in the literature on binary and multiple contaminant systems, reusability studies, and high dependence on solution pH, therefore further studies are warrated. As C&D waste contain trace concentration of heavy metals and contaminants, its leaching potential at different pH levels and adsorbate concentration need to be conducted, which has been hitherto neglected. Finally, the approaches, obstacles, and potential solutions to build an industrially and economically efficient C&D adsorbent are discussed., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 The Author(s). Published by Elsevier B.V. All rights reserved.)

Background: The military environment is characterized by unpredictable situations, intensive training, demanding workload, and job-associated stressors, which make it highly stressful. Mentorship and mental well-being training could be beneficial to both officers and the new adolescent recruits of the Indian Air Force (IAF)., Aim: This study aimed at evaluating the effect of a multi-disciplinary structured training on mentoring and mental well-being among officers and instructors in the IAF., Methods: Seventy IAF officers/instructors underwent a week-long multi-disciplinary structured training program, which was conducted at a tertiary care neuro-psychiatric hospital in South India. A quasi-experimental design with a single-group pre- and post-test was adopted. Outcome measures included a) knowledge on mentorship and mental health and b) self-perceived competence in addressing mental health distress., Results: Post training, there was a statistically significant improvement in scores on mentorship/mental health knowledge and a significant increase in self-perceived competence in addressing mental distress., Conclusion: Mentorship and mental well-being training for officers and instructors in the IAF improved mental health knowledge and self-perceived competence. Therefore, administration of regular and in-depth structured mental health-related training interventions could be beneficial not only to the officers but also to the new recruits/mentees in the IAF., Competing Interests: There are no conflicts of interest., (Copyright: © 2023 Industrial Psychiatry Journal.)

Soil acidification in managed ecosystems such as agricultural lands principally results from the increased releasing of protons (H + ) from the transformation reactions of carbon (C), nitrogen (N) and sulphur (S) containing compounds. The incorporation of liming materials can neutralize the protons released, hence reducing soil acidity and its adverse impacts to the soil environment, food security, and human health. Biochar derived from organic residues is becoming a source of carbon input to soil and provides multifunctional values. Biochar can be alkaline in nature, with the level of alkalinity dependent upon the feedstock and processing conditions. This review covers the fundamental aspects of soil acidification and of the use of biochar to address constraints related to acidic soil. Biochar is increasingly considered as an effective soil amendment for reducing soil acidity owing to its liming potential, thereby enhancing soil fertility and productivity in acid soils. The ameliorant effect on acid soils is mainly because of the dissolution of carbonates, (hydro)-oxides of the ash fraction of biochar and potential use by microorganisms., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Biochar amended clay layer has emerged as a sustainable hydraulic barrier for hazardous municipal waste containment system. The effects of pore fluid salinity on soil shrinkage and water retention characteristics of biochar amended clay are unknown. This study aims to investigate the behavior of soil shrinkage and water retention of biochar amended kaolin under different pore fluid salinity. A series of volumetric shrinkage and water retention tests were conducted on biochar amended kaolin in sodium chloride solution at initial concentrations of 1 %, 5 %, and 10 %. Biochar addition increased the shrinkage limit and minimum void ratio of kaolin by up to 17 % and 11 %, respectively. Air entry value of kaolin increased by 6-88 times with an increase in pore fluid salinity, caused by interparticle aggregation. Micrographs showed that biochar intrapore was filled by kaolin particles, partially hindering the interparticle aggregation of clay in the salt solution. Biochar addition lowered zeta potential on the surface of kaolin particles by 50-75 %, indicating that the immobilisation of excess sodium ions was achieved by biochar. Correspondingly, osmotic suction of pore fluid decreased by 21-64 % due to biochar's ion absorption. The findings highlighted that biochar addition to kaolin specimens minimises NaCl-induced soil shrinkage and reduces the pore fluid salinity. This study indicates that biochar could be potentially helpful for desalinisation and mitigating volumetric change issues for geo-environmental infrastructures., Competing Interests: Declaration of competing interest All authors have approved the manuscript and agree with its submission to “Science of the Total Environment” and there is no conflict of interest., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Object affordance, a characterization of the different functionalities of an object, refers to an object's numerous possibilities of interaction. It has a significant part to play in priming motoric actions which depends on the actor's spontaneous neurological behaviour. Action Observation (AO) and Motor Imagery (MI) also lead to the stimulation of motor system. In fact, AO and MI result in activation of overlapping brain areas as the actual motor task. AO combined with MI (referred to as AO+MI) initiates higher cortical activity in comparison with either MI or AO alone. In this paper, we investigate the influence of affordance driven motor priming during AO, MI and AO + MI. Source current density as an EEG parameter is estimated by Low Resolution Electromagnetic Tomography (LORETA). Our results demonstrate that affordance driven motor priming during AO+MI indicates stronger electrophysiological and behavioural changes. This is evident from the N2 ERP component. Further, the current source density (in brain regions associated with motor planning) during affordance driven AO+MI is found to be maximum.

Soil is an integral part of the ecosystem because it serves as a habitat for various microorganisms and lays the foundation for supporting plant growth and development. Therefore, factors such as increased anthropogenic activities hand by hand with other natural processes that harm the ecosystem may eventually lead to a decline in soil quality and fertility, hindering the growth of plants and soil microbial communities. Given the current global scenario of increasing human intervention, it is essential to find effective measures and reliable technologies to restore soil quality. Biochar is an emerging soil ameliorant employed for soil health restoration and is primarily generated through the anoxygenic pyrolysis of biomass. The biochar application in soil remediation may be beneficial due to biochar's unique physicochemical properties, including high carbon and metal fixation abilities. In addition, biochar possesses abilities to reduce the plant's environmental stress injuries. This review briefly overviewed the ingredients and mechanism of biochar productions. We then emphatically reviewed the advances in biochar applications in soil bioremediation, soil microflora growth stimulation, and the alleviation of various biotic and abiotic stresses in plants., Competing Interests: Conflict of interestThe authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (© King Abdulaziz City for Science and Technology 2022.)

The current work represents the study on morphology and reproductive biology of two indigenous torrential fishes, Balitora brucei and Psilorhynchus balitora, for the first time. The Gray's stone loach Balitora brucei and balitora minnow Psilorhynchus balitora abound in the torrential water bodies of South East Asia. The current paper redescribes morphology based on the fresh collection. Specific parameters of reproductive biology on both the fishes have been studied for the first time. Both the species were adapted to the same ecological conditions of the river Ranganadi. Fish specimens were collected at a fortnightly interval from the river in the Lakhimpur district of Assam, India. The detailed study includes morphological data analyzed with Mann-Whitney U-test and specific reproductive parameters such as condition factor (K), gonado-somatic index (GSI), modified gonado-somatic index (MGSI), and Dobriyal index (DI). Progressive development of the gonads was confirmed with dissection and histological study. Both the species are multiple breeders with prolonged reproductive seasons ranging from 4 to 5 months. Both the fishes are found to be migrants from upstream, and a good number of individuals were recorded during the monsoon season, reflecting the sampling site as a breeding ground. During winter, the local people use various chemicals, piscicidal plants, and electric instruments for fishing resulting in a steep decline in the number of individuals for both the species. Moreover, the effect of the North Eastern Electric Power Corporation Limited (NEEPCO) dam is evident on the decline of the ichthyofaunal diversity of the river. The results of present study will provide the baseline information on these two species of fishes for planning conservation measures in future., (© 2021. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Organic entities like suitably functionalized naphthalene diimide (NDI) exhibited logical behaviours in response to various external stimuli and can be used to develop digital logic operations. The present findings include utilization of two congeners of NDI i.e. , N1 and N2 for the successive turning ON/OFF of fluorescence with inclusion of acid and base. The recognition of the switching phenomenon of the probes N1 and N2 are applied to construct fundamental digital logic gates such as NOT, YES, IMPLICATION, INHIBIT, etc. The inputs to each of the logic gates are defined by the presence or absence of acid and base. Accordingly, the outputs generated from the gates are in the form of fluorescence ON or OFF status denoted by "1" and "0" respectively. Likewise, we have adopted Boolean algebra and its associated De-Morgan's theorem to build the combined logic gates such as XOR and XNOR gates. The proposed logic gates are validated by the optical behaviour of the congeners N1 and N2 in response to acid as well as base and the experimental results are confirmed by the theoretical predictions. The proposed work can have potential applications in next-generation logic based analytical applications., Competing Interests: “There are no conflicts to declare”., (This journal is © The Royal Society of Chemistry.)

The municipal solid waste (MSW) dump in Boragaon, Guwahati, lies on the fringe areas of the wetland, Deepor Beel, which is a Ramsar site. The study was undertaken to analyze the impact the solid waste dump has on the adjoining wetland. Five sampling locations (S1, S2, S3, S4 and S5) in the wetland were selected within a distance of 3000 m from the MSW dump for the continuous monitoring of the surface water and sediment of the wetland. Nineteen physicochemical parameters (pH, EC, air and water temperature, total hardness, alkalinity, turbidity, DO, free CO 2 , TDS, BOD, Na + , K + , Ca 2+ , Cl - , NO 3 - , HCO 3 - , PO 4 3- , SO 4 2- ) were analysed in the surface water, and 7 physicochemical parameters (pH, EC, %OC, %N, PO 4 3- , K + , Na + ) were analysed in sediment. Heavy metals Cu, Ni, Cd, Cr, Mn, Zn and As were analysed in surface water and sediment samples. The results of the principal component analysis (PCA) and cluster analysis (CA) applied on the surface water data have aptly described the source of contamination in the study area to be from the adjoining MSW dump site. The surface spread of contamination from the MSW dump towards the wetland was evident from the regression equations drawn from the sediment data. The mean concentration of Mn, Cr, Ni, Cd and As in surface water exceeded the MPL (maximum permissible limit) of WHO 2011 (World Health Organization). The pollution load index (PLI) of sediment in the wetland shows that the study area is under the category of "progressive deterioration".

A multi-layered final cover system is constructed over the landfill after it reaches its full capacity to minimize water ingress into the underlying hazardous waste. Three layered landfill cover are designed for areas experiencing very humid climatic conditions. Under the effects of climate change, the occurrences of extreme rainfall events become more frequent and this has resulted in catastrophic floods and hence extreme ponding. This study investigates the seepage characteristics of three-layered capillary barrier cover systems under an extreme ponding condition of 1.5 m water head, through detailed laboratory column tests and finite-element seepage analysis. Four 1.2 m-tall columns having different configurations (C1-C4) were studied. Fly ash (FA) was used to amend the surface and barrier layers in columns C2 and C4, in line with the novel concept of "waste protect waste". Spatiotemporal variations of volumetric water content of the four columns were monitored for three years continuously. With FA amendment in the surface layer and an inclusion of a 0.01 m thick geosynthetic clay liner between the drainage and barrier layers, the onset of basal percolation was significantly delayed until 700 days of ponding, compared to 115 days without FA amendment. Capillary flow dominated the gravitational flow and perched water table was formed as waterfront advanced from the drainage to barrier layers. Further seepage analysis considering a realistic humid climate boundary condition showed that all four configurations were successful in preventing basal percolation for 800 days., Competing Interests: Declaration of competing interest There is no conflict of interest., (Copyright © 2020 Elsevier B.V. All rights reserved.)

Permanent wilting point (PWP) is generally used to ascertain plant resistance against abiotic drought stress and designated as the soil water content (θ) corresponding to soil suction (ψ) at 1500 kPa obtained from the soil water retention curve. Determination of PWP based on only pre-assumed ψ may not represent true wilting condition for soils with contrasting water retention abilities. In addition to ψ, there is a need to explore significance of additional plant parameters (i.e., stomatal conductance and photosynthetic status) in determining PWP. This study introduces a new framework for determining PWP by integrating plant leaf response and ψ during drought. Axonopus compressus were grown in two distinct textured soils (clayey loam and silty sand), after which drought was initiated till wilting. Thereafter, ψ and θ within the root zone were measured along with corresponding leaf stomatal conductance and photosynthetic status. It was found that coarse textured silty sand causes wilting at much lower ψ (≈ 300 kPa) than clayey loam (≈ 1600 kPa). Plant response to drought was dependent on the relative porosity and mineralogy of the soil, which governs the ease at which roots can grow, assimilate soil O 2 , and uptake water. For clay loam, the held water within the soil matrix does not facilitate easy root water uptake by relatively coarse root morphology. Contrastingly, fine root hair formation in silty sand facilitated higher plant water uptake and doubled the plant survival time.

Multi-layered engineered landfill consists of the bottom liner layer (mainly bentonite clay (B)) upon which the hazardous wastes are dumped. In current practice, sand (S) is mixed with bentonite to mitigate the adverse effects of using bentonite alone in the liner layer. Incorporation of waste and unutilized fly ash (FA) as an amendment material to B has been explored in terms of its hydro-mechanical properties, but not gauged its adsorption potential. Indian subcontinent primarily relies on the thermal power source, and FA dumps have already reached its full capacity. The objective of this study is to explore the adsorption characteristics of four B-FA composite mixes sourced within India, considering Pb 2+ as a model contaminant. The effect of fly ash type, fly ash amendment rate and adsorbate concentration was explored in the current study and juxtaposed with B-S mixes, based on 960 batch adsorption tests. Both B-FA and B-S mixes reached equilibrium adsorption capacity within 65 min. At higher adsorbate concentrations (commonly observed in the liner), B-FA mixes exhibited superior adsorption capacity, mainly one mixed with Neyvelli fly ash (NFA). The effect of higher amendment rate had little impact on the adsorption capacity at different concentration, but gradually decreased the percentage removal of Pb 2+ . The B-S mix showed a drastic decrease in percentage removal at higher adsorbate concentration among all tested mixes. Systematic characterization including geotechnical properties, microstructure and chemical analysis was also done to interpret the obtained results. Both Freundlich and Langmuir models fitted the isotherm data well for all B-FA mixes. The maximum adsorption capacity from the isotherm was correlated to easily measurable Atterberg limits by two empirical relationships., Competing Interests: Declaration of competing interest The authors declare no competing financial interests., (Copyright © 2020 Elsevier Ltd. All rights reserved.)

Low hydraulic conductivity and high chemical immobilization are the two characteristics that make bentonite a mandatory construction material for hazardous waste containment applications. We performed a comprehensive batch sorption study on Barmer bentonite (BB), an exclusive construction clay mined in India, using lead (Pb 2+ ) as a model contaminant. The maximum adsorption capacity of BB was obtained as 55 mg g -1 at pH 5 and 27 ± 2℃. Adsorption was extremely rapid, with equilibrium attained <5 min for the BB. Increased adsorbent dosage resulted in higher Pb 2+ percentage removal, while adsorption capacity decreased. Ionic strength, salt concentration, valency and ionic radius played a critical role in suppressing the adsorption of Pb 2+ . Clay fabric change was observed to be dispersed at low ionic strength and gradually attained aggregated face-to-face structures at high ionic strength. The simultaneous presence of other metals/salts strongly influenced Pb 2+ removal by BB, while divalent salt exhibited high suppression of adsorptive reaction at low concentrations. Sorption isotherm and kinetic modeling results indicated the possibility of chemisorption of Pb 2+ on BB. Based on the thermodynamic analysis, it was noted that Pb 2+ adsorption on BB is exothermic, spontaneous and adsorption reaction is less favorable at a higher temperature., Competing Interests: Declaration of Competing Interest The authors declare that there are no competing financial interests., (Copyright © 2020 Elsevier B.V. All rights reserved.)