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Based on the analysis of statistical and information sources, scientific publications, and the authors’ personal experience, the article analyzes the peculiarities of Japanese minimarkets that rank among amazing Japanese inventions, creations, and practices and have become an integral part of the Japanese way of life and a trademark of the country. In the academic literature, there have been no comprehensive works revealing this phenomenon so far, and their regional peculiarities, especially the geography of stores operated by different chains, are almost completely neglected. The purpose of this article is to highlight the key scientific discourse, to characterize the unique character and universality, which, in fact, constitutes the phenomenon of konbini, as well as to identify their regional features. The study clearly shows that these stores, which came to Japan from the United States in 1973, have been completely transformed and are constantly evolving, changing the store concept and presenting a globally unique phenomenon. It describes the characteristics of the leading chains of these stores in their endeavor to gain even greater popularity among consumers and the innovations that have emerged in recent years, including those caused by the Covid-19 pandemic. In revealing the phenomenon of konbini, the authors, on the one hand, note their transformation into an important element of social infrastructure, that meets the needs of modern society and is especially necessary in the context of rapidly progressing aging of the population, and, on the other hand, their certain negative impact, especially on the younger generation. The paper features an analysis of the regional characteristics of these stores and the copyrighted cartographic material illustrating them. It is revealed that, within prefectures, the location of konbini correlates with the number of inhabitants (the number of stores is proportional to the population of municipalities), and each of the 20 konbini chains operating in Japan is located in its own specific area. The authors conclude that konbini are in the interest of the development of the country’s regions as a whole, and their role in Japanese society cannot be overemphasized. The Japanese experience can be relevant to other countries, including Russian chain stores.

Potential contribution from gamma-ray sources to the Galactic diffuse gamma rays observed above 100 TeV (sub-PeV energy range) by the Tibet AS γ experiment is an important key to interpreting recent multimessenger observations. This paper reveals a surprising fact: none of the 23 Tibet AS γ diffuse gamma-ray events above 398 TeV within the Galactic latitudinal range of ∣ b ∣ < 10° come from the 43 sub-PeV gamma-ray sources reported in the 1LHAASO catalog, which proves that these sources are not the origins of the Tibet AS γ diffuse gamma-ray events. No positional overlap between the Tibet AS γ diffuse gamma-ray events and the sub-PeV LHAASO sources currently supports the diffusive nature of the Tibet AS γ diffuse gamma-ray events, although their potential origin in the gamma-ray sources yet unresolved in the sub-PeV energy range cannot be ruled out.

Abstract Ocean swell activities excite body‐wave microseisms that contain information on the Earth's internal structure. Although seismic interferometry is feasible for exploring structures, it faces the problem of spurious phases stemming from an inhomogeneous source distribution. This paper proposes a new method for inferring seismic discontinuity structures beneath receivers using body‐wave microseisms. This method considers the excitation sources of body‐wave microseisms to be spatially localized and persistent over time. To detect the P‐s conversion beneath the receivers, we generalize the receiver function analysis for earthquakes to body‐wave microseisms. The resultant receiver functions are migrated to the depth section. The detected 410‐ and 660‐km mantle discontinuities are consistent with the results obtained using earthquakes, thereby demonstrating the feasibility of our method for exploring deep‐earth interiors. This study is a significant step toward body‐wave exploration considering the sources of P‐wave microseisms to be isolated events.

Aerosol optical depths (AODs) used for the Edition 4.1 Clouds and the Earth's Radiant Energy System (CERES) Synoptic 1∘ (SYN1deg) product are evaluated. AODs are derived from Moderate Resolution Imaging Spectroradiometer (MODIS) observations and assimilated by an aerosol transport model (the Model for Atmospheric Transport and Chemistry – MATCH). As a consequence, clear-sky AODs closely match with those derived from MODIS instruments. AODs under all-sky conditions are larger than AODs under clear-sky conditions, which is supported by ground-based AErosol RObotic NETwork (AERONET) observations. When all-sky MATCH AODs are compared with Modern-Era Retrospective analysis for Research and Applications (Version 2; MERRA-2) AODs, MATCH AODs are generally larger than MERRA-2 AODs, especially over convective regions (e.g., the Amazon, central Africa, and eastern Asia). This variation is largely due to the differing methods of assimilating the MODIS AOD data product and the use of quality flags in our assimilation. Including AODs with larger retrieval uncertainty makes AODs over the convective regions larger. When AODs are used for clear-sky irradiance computations and computed downward shortwave irradiances are compared with ground-based observations, the computed instantaneous irradiances are 1 %–2 % larger than observed irradiances. The comparison of top-of-atmosphere clear-sky irradiances with those derived from CERES observations suggests that AODs used for surface radiation observation sites are 0.01–0.03 larger, which is within the uncertainty of instantaneous MODIS AODs. However, the comparison with AERONET AODs suggests that AODs used for computations over desert sites are 0.08 larger. The cause of positive biases in downward shortwave irradiance and in AOD for the desert sites is possibly due to the dust particle size and distribution, as defined by the MATCH transport model, and the transfer of that information into the radiative transfer model.

Clouds warm the surface in the longwave (LW), and this warming effect can be quantified through the surface LW cloud radiative effect (CRE). The global surface LW CRE has been estimated over more than 2 decades using space-based radiometers (2000–2021) and over the 5-year period ending in 2011 using the combination of radar, lidar and space-based radiometers. Previous work comparing these two types of retrievals has shown that the radiometer-based cloud amount has some bias over icy surfaces. Here we propose new estimates of the global surface LW CRE from space-based lidar observations over the 2008–2020 time period. We show from 1D atmospheric column radiative transfer calculations that surface LW CRE linearly decreases with increasing cloud altitude. These computations allow us to establish simple parameterizations between surface LW CRE and five cloud properties that are well observed by the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) space-based lidar: opaque cloud cover and altitude and thin cloud cover, altitude, and emissivity. We evaluate this new surface LWCRE–LIDAR product by comparing it to existing satellite-derived products globally on instantaneous collocated data at footprint scale and on global averages as well as to ground-based observations at specific locations. This evaluation shows good correlations between this new product and other datasets. Our estimate appears to be an improvement over others as it appropriately captures the annual variability of the surface LW CRE over bright polar surfaces and it provides a dataset more than 13 years long.

Iodine compounds destroy ozone (O3) in the global troposphere and form new aerosols, thereby affecting the global radiative balance. However, few reports have described the latitudinal distribution of atmospheric iodine compounds. This work reports iodine monoxide (IO) measurements taken over unprecedented sampling areas from the Arctic to the Southern Hemisphere and spanning sea surface temperatures (SSTs) of approximately 0 to 31.5 ∘C. The highest IO concentrations were observed over the Western Pacific warm pool (WPWP), where O3 minima were also measured. There, a negative correlation was found between O3 and IO mixing ratios at extremely low O3 concentrations. This correlation is not explained readily by the O3-dependent oceanic fluxes of photolabile inorganic iodine compounds, which is the dominant source in recent global-scale chemistry transport models representing iodine chemistry. Actually, the correlation rather implies that O3-independent pathways can be similarly important in the WPWP. The O3-independent fluxes result in a 15 % greater O3 loss than that estimated for O3-dependent processes alone. The daily O3 loss rate related to iodine over the WPWP is as high as approximately 2 ppbv (parts per billion by volume) despite low O3 concentrations of approximately 10 ppbv, with the loss being up to 100 % greater than that without iodine. This finding suggests that warming SST driven by climate change might affect the marine atmospheric chemical balance through iodine–ozone chemistry.

In this paper, the performance of the methylammonium bismuth iodide (MBI) solar cells device fabricated using the hot immersion method (HIM) is evaluated for the first time. The hot immersion time (HIT) varied between 1 h and 24 h to obtain a compact MBI film. The scanning electron microscopy images visually depicted that the compact MBI film was fabricated at 24 h. The cross-sectional SEM image confirmed the uniformity and smoothness of the film, while the Dektak measurement revealed that the surface roughness decreased as the HIT was increased to 24 h. The crystallinity of the MBI film showed much improvement and UV–vis showed the extended absorption of light towards the visible region. The performance of MBI solar cells indicates five times and four times increment in the voltage and the efficiency, respectively. Our findings provide a new route to design a better absorber film in the bismuth-perovskite solar cells (Bi-PeSCs) device development using a simple method in the future.

Cloud optical properties such as optical thickness along with surface albedo are important inputs for deriving the shortwave radiative effects of clouds from spaceborne remote sensing. Owing to insufficient knowledge about the snow or ice surface in the Arctic, cloud detection and the retrieval products derived from passive remote sensing, such as from the Moderate Resolution Imaging Spectroradiometer (MODIS), are difficult to obtain with adequate accuracy – especially for low-level thin clouds, which are ubiquitous in the Arctic. This study aims at evaluating the spectral and broadband irradiance calculated from MODIS-derived cloud properties in the Arctic using aircraft measurements collected during the Arctic Radiation-IceBridge Sea and Ice Experiment (ARISE), specifically using the upwelling and downwelling shortwave spectral and broadband irradiance measured by the Solar Spectral Flux Radiometer (SSFR) and the BroadBand Radiometer system (BBR). This starts with the derivation of surface albedo from SSFR and BBR, accounting for the heterogeneous surface in the marginal ice zone (MIZ) with aircraft camera imagery, followed by subsequent intercomparisons of irradiance measurements and radiative transfer calculations in the presence of thin clouds. It ends with an attribution of any biases we found to causes, based on the spectral dependence and the variations in the measured and calculated irradiance along the flight track. The spectral surface albedo derived from the airborne radiometers is consistent with prior ground-based and airborne measurements and adequately represents the surface variability for the study region and time period. Somewhat surprisingly, the primary error in MODIS-derived irradiance fields for this study stems from undetected clouds, rather than from the retrieved cloud properties. In our case study, about 27 % of clouds remained undetected, which is attributable to clouds with an optical thickness of less than 0.5. We conclude that passive imagery has the potential to accurately predict shortwave irradiances in the region if the detection of thin clouds is improved. Of at least equal importance, however, is the need for an operational imagery-based surface albedo product for the polar regions that adequately captures its temporal, spatial, and spectral variability to estimate cloud radiative effects from spaceborne remote sensing.

Gamma rays from HESS J1849−000, a middle-aged TeV pulsar wind nebula (PWN), are observed by the Tibet air shower array and the muon detector array. The detection significance of gamma rays reaches 4.0 σ and 4.4 σ levels above 25 TeV and 100 TeV, respectively, in units of the Gaussian standard deviation σ . The energy spectrum measured between 40 TeV < E < 320 TeV for the first time is described with a simple power-law function of ${dN}/{dE}={(2.86\pm 1.44)\times {10}^{-16}(E/40\,\mathrm{TeV})}^{-2.24\pm 0.41}\,{\mathrm{TeV}}^{-1}\,{\mathrm{cm}}^{-2}\,{{\rm{s}}}^{-1}$ . The gamma-ray energy spectrum from the sub-TeV ( E < 1 TeV) to sub-PeV (100 TeV < E < 1 PeV) ranges, including the results of previous studies, can be modeled with the leptonic scenario, i.e., inverse Compton scattering by high-energy electrons accelerated by the PWN of PSR J1849−0001. On the other hand, the gamma-ray energy spectrum can also be modeled with the hadronic scenario in which gamma rays are generated from the decay of neutral pions produced by collisions between accelerated cosmic-ray protons and the ambient molecular cloud found in the gamma-ray-emitting region. The cutoff energy of cosmic-ray protons E _p,cut is estimated as ${\mathrm{log}}_{10}({E}_{{\rm{p}},\mathrm{cut}}/\mathrm{TeV})={3.73}_{-0.66}^{+2.98}$ , suggesting that protons are accelerated up to the PeV energy range. Our study thus proposes that HESS J1849−000 should be further investigated as a new candidate as a Galactic PeV cosmic-ray accelerator, or “PeVatron.”

In this paper, we report the successful fabrication of compact and high crystallinity methylammonium bismuth iodide (MBI) layers by using a new method named as hot immersion method (HIM) for the first time. This novel method is proposed to improve the surface morphology and structural properties of MBI film. The substrate is dipped in the hot solution while the hot immersion time was varied. The scanning electron microscopy images showed that the compact MBI layer was fabricated at a longer immersion time, while the x-ray diffraction characterization showed that the crystallinity of the MBI layer was improved. The compactness and uniformity of MBI layer were further confirmed using Dektak measurement. Our findings suggest the enhanced performance of bismuth-perovskite solar cells (Bi-PeSC’s) device by the simple process in the future.

Constraints from ozone (O3) observations over oceans are needed in addition to those from terrestrial regions to fully understand global tropospheric chemistry and its impact on the climate. Here, we provide a large data set of ozone and carbon monoxide (CO) levels observed (for 11 666 and 10 681 h, respectively) over oceans. The data set is derived from observations made during 24 research cruise legs of R/V Mirai during 2012 to 2017, in the Southern, Indian, Pacific, and Arctic oceans, covering the region from 67∘ S to 75∘ N. The data are suitable for critical evaluation of the over-ocean distribution of ozone derived from global atmospheric chemistry models. We first give an overview of the statistics in the data set and highlight key features in terms of geographical distribution and air mass type. We then use the data set to evaluate ozone mixing ratio fields from the tropospheric chemistry reanalysis version 2 (TCR-2), produced by assimilating a suite of satellite observations of multiple species into a global atmospheric chemistry model, namely CHASER. For long-range transport of polluted air masses from continents to the oceans, during which the effects of forest fires and fossil fuel combustion were recognized, TCR-2 gave an excellent performance in reproducing the observed temporal variations and photochemical buildup of O3 when assessed from ΔO3∕ΔCO ratios. For clean marine conditions with low and stable CO mixing ratios, two focused analyses were performed. The first was in the Arctic (> 70∘ N) in September every year from 2013 to 2016; TCR-2 underpredicted O3 levels by 6.7 ppbv (21 %) on average. The observed vertical profiles from O3 soundings from R/V Mirai during September 2014 had less steep vertical gradients at low altitudes (> 850 hPa) than those obtained by TCR-2. This suggests the possibility of a more efficient descent of the O3-rich air from above than assumed in the models. For TCR-2 (CHASER), dry deposition on the Arctic ocean surface might also have been overestimated. In the second analysis, over the western Pacific equatorial region (125–165∘ E, 10∘ S to 25∘ N), the observed O3 level more frequently decreased to less than 10 ppbv in comparison to that obtained with TCR-2 and also those obtained in most of the Atmospheric Chemistry Climate Model Intercomparison Project (ACCMIP) model runs for the decade from 2000. These results imply loss processes that are unaccounted for in the models. We found that the model's positive bias positively correlated with the daytime residence times of air masses over a particular grid, namely 165–180∘ E and 15–30∘ N; an additional loss rate of 0.25 ppbv h−1 in the grid best explained the gap. Halogen chemistry, which is commonly omitted from currently used models, might be active in this region and could have contributed to additional losses. Our open data set covering wide ocean regions is complementary to the Tropospheric Ozone Assessment Report data set, which basically comprises ground-based observations and enables a fully global study of the behavior of O3.

We report the development of filterless deep ultraviolet photoconductive detectors using cerium fluoride (CeF3) thin films fabricated by pulsed laser deposition (PLD). By varying the PLD laser power during thin film growth, we observed that CeF3 breaks down to CeF2 at PLD laser powers greater than 100 mW. This consequently leads to the formation of fluorine defects that effectively narrowed the optical bandgap of the thin films, resulting in the decreased resistivity of the photoconductive detector. Under ultraviolet irradiation, the detector using a thin film grown at 5 mW PLD laser power exhibited close to four orders of magnitude increase in photocurrent compared to the dark current. The spectral response of the photoconductive detectors can be tuned from 300 nm to 400 nm when PLD laser powers ranging from 5 mW to 400 mW are used to fabricate the thin films. The filterless nature of the detectors simplifies their production, and their tunability can extend their use to a wider range of applications.

In this study, we integrate recent in situ measurements with satellite retrievals of dust physical and radiative properties to quantify dust direct radiative effects on shortwave (SW) and longwave (LW) radiation (denoted as DRESW and DRELW, respectively) in the tropical North Atlantic during the summer months from 2007 to 2010. Through linear regression of the CERES-measured top-of-atmosphere (TOA) flux versus satellite aerosol optical depth (AOD) retrievals, we estimate the instantaneous DRESW efficiency at the TOA to be −49.7±7.1 W m−2 AOD−1 and −36.5±4.8 W m−2 AOD−1 based on AOD from MODIS and CALIOP, respectively. We then perform various sensitivity studies based on recent measurements of dust particle size distribution (PSD), refractive index, and particle shape distribution to determine how the dust microphysical and optical properties affect DRE estimates and its agreement with the above-mentioned satellite-derived DREs. Our analysis shows that a good agreement with the observation-based estimates of instantaneous DRESW and DRELW can be achieved through a combination of recently observed PSD with substantial presence of coarse particles, a less absorptive SW refractive index, and spheroid shapes. Based on this optimal combination of dust physical properties we further estimate the diurnal mean dust DRESW in the region of −10 W m−2 at TOA and −26 W m−2 at the surface, respectively, of which ∼  30 % is canceled out by the positive DRELW. This yields a net DRE of about −6.9 and −18.3 W m−2 at TOA and the surface, respectively. Our study suggests that the LW flux contains useful information on dust particle size, which could be used together with SW observations to achieve a more holistic understanding of the dust radiative effect.

How bacteria migrate collectively despite individual phenotypic variation is not understood. Here, the authors show that cells spontaneously sort themselves within moving bands such that variations in individual tumble bias, a determinant of gradient climbing speed, are compensated by the local gradient steepness experienced by individuals.

According to climate model simulations, the changing altitude of middle and high clouds is the dominant contributor to the positive global mean longwave cloud feedback. Nevertheless, the mechanisms of this longwave cloud altitude feedback and its magnitude have not yet been verified by observations. Accurate, stable, and long-term observations of a metric-characterizing cloud vertical distribution that are related to the longwave cloud radiative effect are needed to achieve a better understanding of the mechanism of longwave cloud altitude feedback. This study shows that the direct measurement of the altitude of atmospheric lidar opacity is a good candidate for the necessary observational metric. The opacity altitude is the level at which a spaceborne lidar beam is fully attenuated when probing an opaque cloud. By combining this altitude with the direct lidar measurement of the cloud-top altitude, we derive the effective radiative temperature of opaque clouds which linearly drives (as we will show) the outgoing longwave radiation. We find that, for an opaque cloud, a cloud temperature change of 1 K modifies its cloud radiative effect by 2 W m−2. Similarly, the longwave cloud radiative effect of optically thin clouds can be derived from their top and base altitudes and an estimate of their emissivity. We show with radiative transfer simulations that these relationships hold true at single atmospheric column scale, on the scale of the Clouds and the Earth's Radiant Energy System (CERES) instantaneous footprint, and at monthly mean 2° × 2° scale. Opaque clouds cover 35 % of the ice-free ocean and contribute to 73 % of the global mean cloud radiative effect. Thin-cloud coverage is 36 % and contributes 27 % of the global mean cloud radiative effect. The link between outgoing longwave radiation and the altitude at which a spaceborne lidar beam is fully attenuated provides a simple formulation of the cloud radiative effect in the longwave domain and so helps us to understand the longwave cloud altitude feedback mechanism.

To provide a better representation of natural ice clouds, a novel ice cloud model is developed by assuming an ice cloud to consist of an ensemble of hexagonal columns and 20-element aggregates with specific habit fractions at each particle size bin. The microphysical and optical properties of this two-habit model (THM) are compared with both laboratory and in situ measurements, and its performance in downstream satellite remote sensing applications is assessed. The ice water contents and median mass diameters calculated based on the THM closely agree with in situ measurements made during 11 field campaigns. In this study, the scattering, absorption, and polarization properties of ice crystals are calculated with a combination of the invariant imbedding T matrix, pseudo-spectral time domain, and improved geometric-optics methods over an entire practical range of particle sizes. The phase functions, calculated based on the THM, show close agreement with counterparts from laboratory and in situ measurements and from satellite-based retrievals. When the THM is applied to the retrievals of cloud microphysical and optical properties from MODIS (the Moderate Resolution Imaging Spectroradiometer) observations, excellent spectral consistency is achieved; specifically, the retrieved cloud optical thicknesses based on the visible/near infrared bands and the thermal infrared bands agree quite well. Furthermore, a comparison between the polarized reflectivities observed by the PARASOL satellite and from theoretical simulations illustrates that the THM can be used to represent ice cloud polarization properties.

Washcoated catalysts on honeycomb substrates are widely used as automotive catalysts, and it is well known that their catalytic performance is limited by gas transport resistance. In order to reduce the gas transport resistance, understanding the relationship between gas transport and pore properties is essential. Since a washcoat layer consists of porous metal oxide particles (e.g., Al2O3), the washcoat layer has two types of pores: primary pores, which are located inside the porous metal oxide particles themselves, and secondary pores, which are located among the porous metal oxide particles. We recently studied the effect of secondary pore connectivity on gas permeability by synchrotron X-ray computed tomography. Based on the results, we proposed a new model to predict the effective gas permeability of a washcoat layer by using parameters of the pore connectivity; however, the pore properties did not vary enough for this model to be validated. Therefore, in this research, we attempted to validate the model using a wide range of pore properties. In order to access various pore properties, 8 real washcoat layers and 12 virtual 3D structures were used. The pore properties of the real washcoat layers were determined using synchrotron X-ray computed tomography. The pore properties varied more widely in this study than in our previous study, thus allowing the model to be validated.

Biogenic emissions supply the largest fraction of non-methane volatile organic compounds (VOC) from the biosphere to the atmospheric boundary layer, and typically comprise a complex mixture of reactive terpenes. Due to this chemical complexity, achieving comprehensive measurements of biogenic VOC (BVOC) in air within a satisfactory time resolution is analytically challenging. To address this, we have developed a novel, fully automated Fast Gas Chromatography (Fast-GC) based technique to provide higher time resolution monitoring of monoterpenes (and selected other C9-C15 terpenes) during plant emission studies and in ambient air. To our knowledge, this is the first study to apply a Fast-GC based separation technique to achieve quantification of terpenes in ambient air. Three chromatography methods have been developed for atmospheric terpene analysis under different sampling scenarios. Each method facilitates chromatographic separation of selected BVOC within a significantly reduced analysis time compared to conventional GC methods, whilst maintaining the ability to quantify individual monoterpene structural isomers. Using this approach, the C9-C15 BVOC composition of single plant emissions may be characterised within a 14.5 min analysis time. Moreover, in-situ quantification of 12 monoterpenes in unpolluted ambient air may be achieved within an 11.7 min chromatographic separation time (increasing to 19.7 min when simultaneous quantification of multiple oxygenated C9-C10 terpenoids is required, and/or when concentrations of anthropogenic VOC are significant). These analysis times potentially allow for a twofold to fivefold increase in measurement frequency compared to conventional GC methods. Here we outline the technical details and analytical capability of this chromatographic approach, and present the first in-situ Fast-GC observations of 6 monoterpenes and the oxygenated BVOC (OBVOC) linalool in ambient air. During this field deployment within a suburban forest ~30 km west of central Tokyo, Japan, the Fast-GC limit of detection with respect to monoterpenes was 4–5 ppt, and the agreement between Fast-GC and PTR-MS derived total monoterpene mixing ratios was consistent with previous GC/PTR-MS comparisons. The measurement uncertainties associated with the Fast-GC quantification of monoterpenes are ≤ 12%, while larger uncertainties (up to ~25%) are associated with the OBVOC and sesquiterpene measurements.

We conducted an intensive field campaign at the summit of Mt. Tai (36.26° N, 117.11° E, 1534 m above sea level), Shandong Province, located at the center of central East China, during the period 28 May to 30 June 2006, to study seasonal maxima of regional air pollution with respect to ozone (O3) and aerosols. The specific objectives, campaign design, and major findings are summarized. High concentrations of O3 and its precursors, and aerosols, were detected and studied in the context of annual variations. Most importantly, we identified that emissions from regional-scale open crop residue burning after the harvesting of winter wheat, together with photochemical aging, strongly increased the concentrations of O3, aerosols, and primary pollutants in this month of year. Studies of in situ photochemical activity, regional source attribution of O3, O3–aerosol interactions, validation of satellite observations of tropospheric NO2, behaviors of volatile organic compounds and organic/inorganic aerosol species, loss rates of black carbon (BC), and instrument inter-comparisons are also summarized. The observed BC levels must have a strong impact on the regional climate.

In this study we examine the performance of 31 global model radiative transfer schemes in cloud-free conditions with prescribed gaseous absorbers and no aerosols (Rayleigh atmosphere), with prescribed scattering-only aerosols, and with more absorbing aerosols. Results are compared to benchmark results from high-resolution, multi-angular line-by-line radiation models. For purely scattering aerosols, model bias relative to the line-by-line models in the top-of-the atmosphere aerosol radiative forcing ranges from roughly −10 to 20%, with over- and underestimates of radiative cooling at lower and higher solar zenith angle, respectively. Inter-model diversity (relative standard deviation) increases from ~10 to 15% as solar zenith angle decreases. Inter-model diversity in atmospheric and surface forcing decreases with increased aerosol absorption, indicating that the treatment of multiple-scattering is more variable than aerosol absorption in the models considered. Aerosol radiative forcing results from multi-stream models are generally in better agreement with the line-by-line results than the simpler two-stream schemes. Considering radiative fluxes, model performance is generally the same or slightly better than results from previous radiation scheme intercomparisons. However, the inter-model diversity in aerosol radiative forcing remains large, primarily as a result of the treatment of multiple-scattering. Results indicate that global models that estimate aerosol radiative forcing with two-stream radiation schemes may be subject to persistent biases introduced by these schemes, particularly for regional aerosol forcing.

Owing to recent industrialization, Central East China has become a significant source of air pollutants. To examine the processes controlling the chemistry and transport of tropospheric ozone, we performed on-line measurements of non-methane volatile organic compounds (NMVOCs) as part of an intensive field campaign at Mount Tai, China, in June 2006 (MTX2006), using proton transfer reaction mass spectrometry (PTR-MS). Temporal variations of NMVOCs were recorded in mass-scan mode from m/z17 to m/z 300 during 12–30 June 2006. More than thirty kinds of NMVOCs were detected up to m/z 160, including alkenes, aromatics, alcohols, aldehydes, and ketones. In combination with non-methane hydrocarbon data obtained by a gas chromatography with flame ionization detection, it was found that oxygenated VOCs were the predominant NMVOCs. Diurnal variations depending mainly on local photochemistry were observed during 24–28 June. During the night of 12 June, we observed an episode of high NMVOCs concentrations attributed to the burning of agricultural biomass. The ΔNMVOCs/ΔCO ratios derived by PTR-MS measurements for this episode (with biomass burning (BB) plume) and during 16–23 June (without BB plume) are compared to emission ratios from various types of biomass burning as reviewed by Andreae and Merlet (2001) and to ratios recently measured by PTR-MS in tropical forests (Karl et al., 2007) and at urban sites (Warneke et al., 2007).

The measurement of volatile organic compounds (VOCs) was carried out at the summit of Mount Tai, located in the center of the Central East China (CEC) region, in June 2006 as part of the Mount Tai Experiment 2006 (MTX2006), which focused on the ozone and aerosol chemistry in the region. Temporal variations of simple VOCs between 2 June and 28 June revealed the characteristics of an aged air mass with minimum local influence. A comparison of VOCs observed at Mount Tai with other Chinese sites revealed relatively similar VOC levels to remote sites and, as expected, a lower level compared to more polluted sites. However, relatively high acetylene and benzene levels at Mount Tai were evidently indicated from comparison with normalized VOC profile by ethane suggested for Beijing. Owing to a shift in boundary layer height, we observed considerable differences between daytime and nighttime VOC mixing ratios. This suggests that the site potentially has a very useful characteristic of being able to measure regional polluted air and the free troposphere regional background air quality. Influence of emissions from biomass burning in the region was evidently found to be extensive during the first half of the campaign (2–15 June), using fire spot data coupling with backward trajectory analysis. Agricultural residue burning was suggested as the primary source of emissions elucidated by the slope of the correlation plot between CH3Cl and CO obtained during the first half of the campaign.

OH reactivity is one of key indicators which reflect impacts of photochemical reactions in the atmosphere. An observation campaign has been conducted in the summer of 2007 at the heart of Tokyo metropolitan area to measure OH reactivity. The total OH reactivity measured directly by the laser-induced pump and probe technique was higher than the sum of the OH reactivity calculated from concentrations and reaction rate coefficients of individual species measured in this campaign. And then, three-dimensional air quality simulation has been conducted to evaluate the simulation performance on the total OH reactivity including "missing sinks", which correspond to the difference between the measured and calculated total OH reactivity. The simulated OH reactivity is significantly underestimated because the OH reactivity of volatile organic compounds (VOCs) and missing sinks are underestimated. When scaling factors are applied to input emissions and boundary concentrations, a good agreement is observed between the simulated and measured concentrations of VOCs. However, the simulated OH reactivity of missing sinks is still underestimated. Therefore, impacts of unidentified missing sinks are investigated through sensitivity analyses. In the cases that unknown secondary products are assumed to account for unidentified missing sinks, they tend to suppress formation of secondary aerosol components and enhance formation of ozone. In the cases that unidentified primary emitted species are assumed to account for unidentified missing sinks, a variety of impacts may be observed, which could serve as precursors of secondary organic aerosols (SOA) and significantly increase SOA formation. Missing sinks are considered to play an important role in the atmosphere over Tokyo metropolitan area.

An observation-based box model approach was undertaken to estimate concentrations of OH, HO2, and RO2 radicals and the net photochemical production rate of ozone at the top of Mount Tai, located in the middle of Central East China, in June 2006. The model calculation was constrained by the measurements of O3, H2O, CO, NO, NO2, hydrocarbon, HCHO, and CH3CHO concentrations, and temperature and J values. The net production rate of ozone was estimated to be 6.4 ppb h−1 as a 6-h average (09:00–15:00 CST), suggesting 58±37 ppb of ozone is produced in one day. Thus the daytime buildup of ozone recorded at the mountain top as ~23 ppb on average is likely affected by in situ photochemistry as well as by the upward transport of polluted air mass in the daytime. On days with high ozone concentrations (hourly values exceeding 100 ppb at least once), in situ photochemistry was more active than it was on low ozone days, suggesting that in situ photochemistry is an important factor controlling ozone concentrations. Sensitivity model runs for which different NOx and hydrocarbon concentrations were assumed suggested that the ozone production occurred normally under NOx-limited conditions, with some exceptional periods (under volatile-organic-compound-limited conditions) in which there was fresh pollution. We also examined the possible influence of the heterogeneous loss of gaseous HO2 radicals in contact with aerosol particle surfaces on the rate and regimes of ozone production.

The pore structure of a simulated washcoat layer was evaluated using the Mean Transport Pore Model (MTPM). The MTPM provides the mean diffusive pore radius (rm) of a simulated washcoat layer from the experimentally measured effective diffusion coefficient (De). However, data previously published in the literature indicated that the value of rm depended on the choice of diffusive gas for the measurement of De. Therefore, a new, more efficient method was developed to estimate rm. To obtain base data, De was measured in a binary gas diffusion system using a modified Wicke-Kallenbach diffusion cell at room temperature, 473 K, and 673 K. The diffusive gases tested were H2, He, CH4, Ne, N2, O2, C3H6, CO2, and C3H8, and a simulated washcoat layer was used. The results confirmed that the value of rm depended on the type of diffusive gas used. However, many measurements of De are required to avoid problems. In the catalytic R&D process, the measurement of many De values for every experiment is impractical. To balance validity against efficiency for estimating rm, a combination of experimentally measured De and predicted De was used. This method is effective for predicting De using the mean molecular speed instead of a porous structure, and is more efficient than the conventional method of using MTPM. This method also can contribute to investigations of automotive catalysts.

The 3-GeV rapid cycling synchrotron (RCS) of the Japan Proton Accelerator Research Complex (J-PARC) is now in the final beam commissioning phase, aiming for a design output beam power of 1 MW. With a series of injector linac upgrades in 2013 and 2014, RCS developed a high-intensity beam test, and launched 1-MW beam tuning in October 2014. The most important issues in realizing such a high-power continuous beam operation are to control and minimize beam loss for maintaining machine activations within permissible levels. In RCS, numerical simulation was successfully utilized along with experimental approaches to isolate the mechanism of beam loss and find its solution. By iteratively performing actual beam experiments and numerical simulations, and also by several hardware improvements, we have recently established a 1-MW beam operation with very low fractional beam loss of a couple of 10^{-3}. In this paper, our recent efforts toward realizing such a low-loss high-intensity beam acceleration are presented as a follow-up of our previous article, H. Hotchi et al. Phys. Rev. ST Accel. Beams 12, 040402 (2009)PRABFM1098-440210.1103/PhysRevSTAB.12.040402, in which the initial beam commissioning status of RCS has been reported.

In the 3-GeV rapid cycling synchrotron of the Japan Proton Accelerator Research Complex, transverse injection painting is utilized not only to suppress space-charge induced beam loss in the low energy region but also to mitigate foil scattering beam loss during charge-exchange injection. The space-charge induced beam loss is well minimized by the combination of modest transverse painting and full longitudinal painting. But, for sufficiently mitigating the foil scattering part of beam loss, the transverse painting area has to be further expanded. However, such a wide-ranging transverse painting had not been realized until recently due to beta function beating caused by edge focusing of pulsed injection bump magnets during injection. This beta function beating additionally excites random betatron resonances through a distortion of the lattice superperiodicity, and its resultant deterioration of the betatron motion stability causes significant extra beam loss when expanding the transverse painting area. To solve this issue, we newly installed pulse-type quadrupole correctors to compensate the beta function beating. This paper presents recent experimental results on this correction scheme for suppressing the extra beam loss, while discussing the beam loss and its mitigation mechanisms with the corresponding numerical simulations.

The construction of axially symmetric soliton solutions with non-zero Hopf topological charges according to a theory known as the extended Skyrme-Faddeev model, was performed in [1]. In this paper we show how masses of glueballs are predicted within this model.