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The over‐loading of heat‐resistant fillers in silicone rubber creates a contradiction between heat resistance and mechanical properties, thus greatly limiting the durability of silicone rubber products in cutting‐edge applications and complex scenarios. To address this issue, silicone rubber was filled with octavinyl polyhedral oligomeric silsesquioxane (POSS) and carbon nanotubes (CNT) and crosslinked with 2,5‐dimethyl‐2,5‐di(tert‐butylperoxy)hexane (DBPMH) in an attempt to obtain composites with excellent mechanical properties and great thermal stability. Optical microscopy and X‐ray diffraction analyses revealed the size of POSS crystals decreased and the characteristic peaks disappeared after the peroxide crosslinked the polymer at elevated temperature. Specifically, silicone rubber composite filled with 0.1 phr POSS and 1.0 phr CNT exhibited a tensile strength of 10.2 MPa and elongation at a break of 450%. Further, the strength and elongation could be kept after thermo‐oxidative aging at 250°C for 32 h. Thermogravimetric analysis results demonstrate that the addition of POSS and CNT into silicone rubber exhibits a synergistic effect, markedly improving the thermal stability of the material. This method provides a valuable reference for manufacturing silicone rubber products that possess both excellent mechanical properties and high thermal stability under extreme working conditions. Highlights: A novel silicone rubber composite with excellent mechanical properties and thermal stability was prepared.A small amount of octavinyl polyhedral oligomeric silsesquioxane (POSS) and carbon nanotubes exhibited a synergistic effect to improve thermal stability.The dependence of the morphological evolution of POSS crystals in SR on the 2,5‐dimethyl‐2,5‐di(tert‐butylperoxy)hexane and temperature was studied. [ABSTRACT FROM AUTHOR]

Hydraulic electrostatic actuators have become a research hotspot for their inherent flexibility and safety of human-machine interaction. This paper aims to combine the characteristics of dielectric elastomers and fluid actuators, enhancing the dielectric constant and breakdown field strength by modifying Al2O3 on the surface of nanostructured BaTiO3 and in order to develop a hydraulic electrostatic actuator with silicone rubber as the matrix material. Single-factor experiments were firstly conducted to confirm the range of three factors affecting the actuation strain of the actuator: BaTiO3@Al2O3 content, thickness of the silicone rubber elastomer film, and pre-stretching ratio coefficient. The response surface methodology was used to study the interactive influence of the above three influencing factors on the actuation strain. It was obtained that A has an insignificant influence on the actuation strain, AB has a significant influence on the actuation strain, and B, C, AC, and BC have a highly influence on the actuation strain. Maximizing actuation strain as the optimization objective yielded the combination results of each factor: BaTiO3@Al2O3 content of 2.57%, thickness of 0.60 mm, and pre-stretching ratio coefficient of 2.50. Actuation strain tests were conducted with optimized parameters under no-load. The experimental results of the actuation strain test show that the relative error between the test value and the model prediction value of 16.47% is less than 5%, and the optimization model results are reliable. The optimized hydraulic electrostatic actuator was tested for actuation strain and electrical performance under different loads. The experiment showed that the maximum actuation strain of the hydraulic electrostatic actuator was 17.20% under a load of 100 g. The critical breakdown current of the actuator ranged from 115 μA to 130 μA, and the maximum electromechanical conversion efficiency of the actuator under different loads was 67.93%. Finally, a joint actuating device was developed based on the structure of the actuator, amplifying the output displacement of the actuator to 30 mm, and the linear displacement of the soft electro-fluid actuator can be converted into a 20° rotation angle through the gear steering mechanism, thus validating the effectiveness of the hydraulic electrostatic actuator. [ABSTRACT FROM AUTHOR]

Dielectric elastomers (DEs), have attracted interest because they can replicate the behavior of muscles. They can change shape when subjected to an electric field. A novel DE is proposed in this study that incorporates silicon carbide (SiC) nanowires into silicone rubber (SR). The nanowires were propagated using polycarbosilane via a chemical vapor reaction (CVR). A boronate polymer was employed to promote compatibility between SR and SiC nanowires which modified the nanowire surfaces, leveraging a strong adhesive quality of the catechol moiety. Electrohydrodynamic (EHD) inkjet printing was then used to form the DEs into various shapes. These DEs had substantial dielectric constants of the order of 4.46. Significantly, one of the DEs achieved the highest actuated area strain of 20.36% in an electric field of 16.5 V/μm, demonstrating excellent driving performance. Furthermore, when used the fabricated DEs showed pronounced long‐term stability, meaning they are capable of finding applications in artificial intelligence, biomimetics, aerospace, and other disciplines. Highlights: The SiC nanowires were obtained through a chemical vapor reaction.A boronate polymer with catechol moiety was used to modify the SiC nanowires.DEs were formed various shapes by inkjet printing.DEs achieved very large actuated strains of up to 20.36% at 16.5 V/μm. [ABSTRACT FROM AUTHOR]

Wearable technology refers to the devices that are integrated with textiles, or implanted in the body or plants for smart monitoring. Hence, this wearable technology has attracted tremendous attention from researchers globally due to its smart functions to be useful for mankind. The key target of this review is to examine the potential of rubber composite materials for such wearable devices. The rubber composites reviewed explore silicone rubber as a rubber matrix (SR). Another objective includes the use of multi‐walled carbon nanotubes (MWCNTs) in pristine and functionalization forms explored as reinforcing fillers. Moreover, prospects of CNT including their structure, properties, and types are explored both in pristine and functionalized state are reviewed. Following this, the mechanical, and electrical, properties of such composites are reviewed. The reported results show that the reinforcing properties are strongly improved by adding functional groups to CNT in rubber composite. These improvements in reinforcing properties are assisted by the functional groups like carboxyl (OH), carbonyl (CO), epoxy, and alkoxy (CO) on the surface of filler are useful. They assist in improving the filler‐rubber compatibility thereby improving filler dispersion and thus finally mechanical and electrical properties. Following this, such improved properties are explored for specific real‐time wearable technologies. This real‐time monitoring includes nursing plant pulse growth monitoring, health monitoring, and humidity sensors. The review further proposes that the functionalized CNTs can be useful for obtaining robust real‐time strain‐sensing monitoring. Moreover, it assists in obtaining sharp response time, strain sensitivity, and good stretchability. Finally, the prospects and challenges are explored discussing the real‐time monitoring of these sensors. Highlights: Configurations for nursing plant growth and other monitoring parameters are reviewed.The properties of pristine and functionalized carbon nanotubes reinforced silicone rubber for wearable technology were reviewed.The mechanical, and electrical aspects of functionalized carbon nanotubes were comparatively reviewed.Applications such as wearable strain sensors, humidity sensors, and wearable plant pulse monitoring sensors were reported. [ABSTRACT FROM AUTHOR]

Observation of 2D cell migration is integral to understanding fundamental biological phenomena and disease progression. However, migratory dynamic analysis is often reliant on computational tools that vary in accessibility and data resolution. Therefore, we aim to improve the throughput and accessibility of analysis by considering alternative 2D migration assays in combination with a machine learning-based segmentation model and computational ImageJ tracking plugin to track cell-specific migratory dynamics. Altering the barrier materials and shapes of cell exclusion zone assays, we found that room-temperature-vulcanizing silicone rubber detached unpredictably, and circular barriers covered less than 87% of the true punch area. A pilot test indicated no significant difference in directed migration, directed migration ratio, mean instantaneous speed, and track displacement between a traditional scratch and polydimethylsiloxane wounding, signifying comparable migratory dynamics. We demonstrate a method capable of identifying, tracking, and analyzing 2D migration dynamics, which enhances access to high-resolution data and computational tools. [ABSTRACT FROM AUTHOR]

Although there have been many theoretical studies on the enhancement effect of nanofiller networks and their interaction with elastomer molecular chains on the mechanical properties of elastomers, its mechanism description is still not completely clear. One of the main obstacles is the lack of quantitative characterization techniques and corresponding theoretical models for the three-dimensional morphology of complex nanofiller networks. In this paper, the precipitated silica-filled silicone rubber was studied by fluorescence labeling combined with laser scanning confocal microscopy, and the real three-dimensional images of dispersion and aggregation structure of filled rubber systems were obtained. The microstructure evolution of nano-particle aggregates caused by the increase in the filler volume fraction was quantitatively described, and the reinforcement mechanism of elastomers with a distribution of aggregates and filler networks composed of nanoparticles was studied. Furthermore, a nano-composite reinforcement model based on volume fraction, particle shape, interaction, and filler dispersion has been proposed. [ABSTRACT FROM AUTHOR]

This study explores the impact of butadiene rubber (BR) crystallization on the low-temperature properties of butadiene/silicone (VMQ) rubber blends (BR/VMQ) designed for Martian applications. Two types of BR, semi-crystalline high-cis Buna CB24 and amorphous Buna CB550, were blended with VMQ, and their mechanical and thermal properties were evaluated. Kinetics of vulcanization, static mechanical properties, dynamical mechanical analysis, thermal shrinkage, and differential scanning calorimetry were utilized. The research demonstrates that the semi-crystalline BR improves mechanical properties but induces greater shrinkage at low temperatures. Conversely, using amorphous BR provided more consistent mechanical properties across the Martian temperature range and reduced material shrink by 6.71% for samples with carbon black, by 8.36% for samples with silica, and by 11.63% for unfilled samples. Future research will be required to evaluate the impact of volume change on the sealing properties of the BR/VMQ blends. [ABSTRACT FROM AUTHOR]

The kinetics of polymerization of epoxy resin ED-20 cured with a polyethylene polyamine hardener modified with silicone rubber, tris(trimethylsiloxy) phenylsilane, octamethyl cyclotetrasiloxane is studied. A more rapid decrease in the amount of epoxy groups in systems modified with silicon-contained additives during polymerization is observed. A differential equation describing the change in changes in the concentration of epoxy groups with the polymerization time is proposed. The found exact solution to the proposed equation describes adequately the experimental data. The modification of epoxy binder reduces the time and temperature of the maximum heat release during the curing. The modification with the addition of tris(trimethylsiloxy) phenylsilane leads to the maximum increase in heat release. A differential equation describing the change in the heat release temperature with the curing time is formulated. The exact solution to the equation formulated is found, which is applied to estimate the curing end time of the compositions. [ABSTRACT FROM AUTHOR]

To realize the great potential of silicone rubber in advanced electronics, high dielectric constant and low loss tangent are currently pursued. Adding a third phase to conductive filler/silicone rubber composites may enhance the properties of the composites, but the appropriate particle size of the third phase is an open question. Here, MoS2 was used as the third phase to prepare the Ti3C2Tx MXene/MoS2/methylvinyl silicone rubber (VMQ) ternary composites, and the influence of different sizes of MoS2 (200 nm and 2 μm) on the dielectric performance of the composites was investigated. The dielectric constant of the Ti3C2Tx MXene/VMQ composites with 5 wt% MoS2 nanoparticles shows a 279% enhancement from 2.78 to 7.75 at 103 Hz, better than that of the Ti3C2Tx MXene‐MoS2 hybrid fillers/VMQ composites. Compared with micron MoS2, nano MoS2 can significantly enhance the dielectric performance of conductive filler/polymer composites because of shorter interparticle distances and enhanced interfacial polarization. Meanwhile, the composites exhibit low loss tangent (lower than 0.0015) and good thermal stability (up to 400°C) because of the low filling amounts of Ti3C2Tx MXene and MoS2 nanoparticles. Excellent flexibility with Young's modulus of 285 kPa and elongations break of 446% was also obtained. The design of these ternary composites greatly improves the dielectric and mechanical properties, which means that the dielectric material has a broad application prospect in modern electronics industry. Highlights: High dielectric constant was gained in Ti3C2Tx MXene/5n‐MoS2/VMQ composites.The MXene/5n‐MoS2/VMQ composites exhibited excellent mechanical properties.Appropriate filler size can benefit the performance of polymer composites. [ABSTRACT FROM AUTHOR]

Photocatalyzed hydrosilication has the advantages of high reaction efficiency and environmental friendliness. However, the cost of photosensitive platinum catalysts is very high, hindering their applications. In this work, a novel and cost-effective photosensitive platinum catalyst is synthesized and can effectively catalyze the hydrosilylation reaction under ultraviolet light. It is found that Pt catalysts exhibit catalytic activity under ultraviolet light when the ratio of Platinum chloride bonding and cyclopentadienyl (Pt-Cl:Cp) is higher than 1:1.2. The cost is reduced by 50%. The structure of this platinum catalyst is characterized using FTIR and NMR techniques. Under ultraviolet light, the new photosensitive platinum catalyst's catalytic efficiency increases from approximately 5% to 60%. The viscosity of prepared silicone rubber was measured. Results show that the prepared silicone rubber has a storing time of over 30 days in shaded environments, and can be completely cured within 2 min under ultraviolet light. The thermal decomposition residual mass of photocured silicone rubber products is as high as 70%, having good thermal stability. As the content of the platinum catalyst increases from 20 to 100 ppm, the reaction conversion rate of the hydrosilylation reaction increases from 43 to 60%. The hardness of the silicone rubber also increases from the initial 11 degrees to 20 degrees. This novel photosensitive platinum catalyst has potential applications in 3D printing and electronic packaging. [ABSTRACT FROM AUTHOR]

In this work, different kinds of silane coupling agents modified expanded graphite (MEG) fillers were successfully prepared and then incorporated into silicon rubber matrix to fabricate flame‐retardant composite materials (SR/MEG). The inserted MEG fillers with siloxane chains exhibited good compatibility with the silicon rubber matrix, which cannot only reduce the negative impact of adding fillers on mechanical properties but also endow the silicon rubber composites with ideal flame retardancy. Subsequently, platinum (Pt) catalyst was incorporated into the SR/MEG composites to prepare SR/MEG/Pt composites, and the synergistic effects of MEG and Pt catalyst on the thermal stability, flame retardancy, and combustion behavior of silicon rubber composites were systematically investigated. The target SR/MEG/Pt composite with appropriate addition of MEG and Pt catalyst can obtain relatively high char residue of 41.9% and limiting oxygen index value of 29.6%, as well as achieve V‐0 rating in the vertical combustion test, owing to the formation of expanded and dense silicon–carbon protective layer under the catalysis of Pt catalyst. Moreover, the cone calorimeter test results showed that the peak of heat release rate and total heat release of SR/MEG composites were further reduced after the addition of an appropriate amount of Pt catalyst, manifesting the good synergistic effect of MEG and Pt catalyst on the flame retardancy performance of silicon rubber. The method proposed herein may provide a promising way for fabricating high‐performance flame‐retardant silicone rubber materials. [ABSTRACT FROM AUTHOR]

Silicone rubber (SiR) has become a reliable choice for outdoor high voltage (HV) insulation in recent years. However, the durability of these polymeric materials is affected by both electrical and environmental stresses, leading to aging. While prior research aimed at enhancing performance, little focus was placed on identifying the major root causes of aging in these insulators. To delve into the causes, we conducted inclined plane tracking (IPT) tests, varying voltage, flow rate, and contamination concentration. Samples with consistent alumina trihydrate (ATH) filler content were tested under the BSEN 60587 standard. The voltage ranged from 3.5-5.5 kV, flow rate from 0.3-0.9 ml/min, and contamination concentration from 500-4500 µS/cm. A Two-Level Factorial analysis with a design of experiment (DOE) approach was used. The study revealed that contaminant concentration significantly impacted leakage current (LC), followed by contamination flow rate and voltage. Additionally, optimization techniques are used to determine ideal LC values under specific conditions. This study explains how each factor affects LC values, allowing for predictive modelling, which improves our understanding of SiR insulators' durability, optimizes LC in real-world situations, and improves their performance and lifespan. [ABSTRACT FROM AUTHOR]

Highlights The influence of filling by iron‐containing fillers on the heat release kinetics and mechanical properties of industrial unsaturated polyester resin PN‐1 is investigated experimentally. The iron ore concentrate, electrostatic precipitator dust, high alumina cement grade HAC‐1, shavings made of cast iron, fine grade sand are used as fillers. To improve the strength characteristics of polyester resin composites the small amount (0.2–1.0 wt%) of organosilicon additives such as synthetic silicone rubber, tris(trimethylsiloxy) phenylsilane, octamethyl cyclotetrasiloxane are used. The heat release kinetics is studied for different ratios between accelerator (cobalt naphthenate) and initiator (cyclohexanone peroxide). The time to reach the maximum temperature of the heat release is significantly reduced when a large amount of iron ore concentrate is used as filler. The temperature of maximum heat release decreases and the time to reach it increases when adding electrostatic precipitator dust in small amount of 5 wt% to the high filled by iron ore concentrate (295 wt%) composite system. The optimum in strength indicators associated with the ratio of different fractions in systems consisting of two fillers of different properties and granulometric composition is found. The highest values of compressive strength in the cement–iron ore concentrate and sand–iron ore concentrate systems are observed. An increase in the strength characteristics of composites by 15%–20% with organosilicon additive introduction is observed. The addition of the silicone rubber increases the strength properties of samples the most among all additives considered. Effect of filling by iron‐containing fillers on the heat release kinetics and mechanical properties of polyester resin is found. The time to reach the maximum temperature of the heat release is significantly reduced when the resin is filled by a large amount of iron ore concentrate. The temperature of maximum heat release decreases when the electrostatic precipitator dust in small amount is added to the high filled by iron ore concentrate. An increase in the strength characteristics of composites by 15–20% with introduction of organosilicon additives is observed. [ABSTRACT FROM AUTHOR]

During the utilization of silicone rubber, excessive friction can cause damage to the contact surface and the material itself. Therefore, friction‐reducing modification of silicone rubber has attracted much attention. In this paper, hyperbranched polysiloxanes with different structures is synthesized for friction‐reducing modification of silicone rubber. Infrared spectroscopy, nuclear magnetic resonance spectroscopy, and amine titration tests reveal that hyperbranched polysiloxanes are successfully synthesized by the hydrolytic condensation of 3‐aminopropyltriethoxysilane and their Michael addition with four acrylates with different alkyl chains. The friction coefficients and mechanical properties of silicone rubber are evaluated. Hyperbranched polysiloxanes significantly reduces friction and maintained excellent mechanical properties of silicone rubber. Silicone rubber with butyl‐ester‐secondary‐amino hyperbranched polysiloxane displays the best overall performance, with static and dynamic friction coefficients decreasing by 33.99% and 43.16% compared with that of pure silicone rubber, respectively, and a tensile strength of 10.80 MPa. The friction‐reducing mechanism of hyperbranched polysiloxanes on silicone rubber is investigated by contact angle test and dynamic mechanical analysis. Hyperbranched polysiloxanes migrates to the surface due to the incompatibility of alkyl chains with silicone rubber matrix. Consequently, the shielding effect produced by hyperbranched polysiloxanes on the surface depresses the adsorption activity of silicone rubber surface thereby reducing friction. [ABSTRACT FROM AUTHOR]

In this study, we prepared electromagnetic cobalt-coated glass fiber (Co@GF) composites via an electroless plating method. Subsequently, a conductive sandwich flexible film consisting of Co@GF composites and liquid silicone rubber (RTV-2) was successfully formed using the tape casting method at room temperature. Based on the perfect coating and excellent electrical conductivity of the Co@GF composites, the resultant RTV-2/Co@GF/RTV-2 sandwich flexible film showed a low volume resistivity of 0.264 Ω·cm and could stretch to 100% (of 4.40 Ω·cm) without obvious fracture. When a magnetic field was applied during the curing process, the electromagnetic Co@GF composites were aligned automatically in the RTV-2 matrix because of their ferromagnetic nature. The as-prepared film exhibited anisotropy in its electrical performance. The volume resistivity parallel to the magnetic field direction is approximately two times lower than that in the perpendicular direction. The maximum difference in the volume resistivity (ρ∥ = 0.768 Ω·cm and ρ⊥ = 1.549 Ω·cm) was obtained at a magnetic field intensity of 800 mT. In addition, a magnetic field intensity of 100 mT helps improve the electrical conductivity of the as-obtained sandwich film. The anisotropic RTV-2/Co@GF/RTV-2 sandwich flexible film is considered a promising flexible electronic sensor, where discrepant inductive sensitivity is required in orthogonal directions. [ABSTRACT FROM AUTHOR]

Aiming at settling the critical problems of ecological and environmental safety caused by traditional halogen-containing and phosphorus-containing flame-retardant system, this paper has fabricated a transition metal manganese ion (Mn2+) loaded diatomite (Mn@DE) via a simple chemical modification process, which can be employed as raising the flame retardancy of silicone rubber (SR). Compared with traditional flame retardants, the unique lamellar shielding ability and Mn-enhanced catalytic charring ability from designed mineral-based flame retardants are conductive to upgrading the flame-retardant level of silicone rubber/Mn-modified diatomite (SR/Mn@DE) composites. The results demonstrate that when the amount of Mn@DE reaches 30 phr in the composites, the limiting oxygen index (LOI) and vertical combustion tests of SR/30 phr Mn@DE can reach 27.3% and UL-94 V-0 ratings, respectively. Simultaneously, the reduction for peak heat release rate (PHRR) and total heat rate (THR) of SR/Mn@DE can achieve 55.3% and 66.1%, revealing that the fire hazard of SR has been effectively decreased. Thermogravimetric analysis (TGA) has enlightened that the introduction of Mn onto diatomite can effectively reinforce the thermal stability and char-forming ability of SR composites. Through the systematic analysis for combustion residues, the condensed flame-retardant mechanism of SR/Mn@DE via restraining the heat transfer and fuel feedback can be primarily inferred. Therefore, this paper have provided a fast and practical flame-retardant strategy in order to discarding the halogen-/phosphorus-containing flame retardants, which will open up the key problem of limited application for SR composites in more fields. [ABSTRACT FROM AUTHOR]

Inspired by the natural thermal charring capacity of lacquer tree bark, a novel halogen-free, bio-based and two-component synergistic flame retardant system has been constructed by introducing transition metal (Fe3+)-modified tannic acid (TA) as char source and ammonium polyphosphate (APP) as acid source, which was employed for overcoming the severe flammability problem for silicone rubber (SR). By systematically investigating the effect of APP/TA@Fe system on the flame retardancy of SR composites, it has been found that when 40 mass% APP and TA@Fe in a ratio of 3:1 are added, the limited oxygen index (LOI) and vertical combustion tests of SR composites can reach 30% and UL-94 V-0 rating with a rapid self-extinguishing capacity. Through the comprehensive analysis of the residues of SR composites after complete burning, a gas/condensed flame retardant mechanism is primarily proposed in detail. Among these, the ammonia and water vapor released by the decomposition of APP and TA@Fe during combustion can dilute the combustible gases and tannic acid will act via the free radicals scavenging ability. Besides, the continuous, intumescent and dense charring residues from the thermal interaction between APP and TA will exert a prominent role in restricting the heat/mass exchange process and inhibiting the SR matrix from further flame attacking. Surprisingly, the mechanical strength of SR system is attained even if the combination of APP and TA@Fe is blended. Consequently, this article has developed a bionic, eco-friendly and effective approach to settle the flammability problem of SR and broaden their applications in the fields of construction and decoration materials. [ABSTRACT FROM AUTHOR]

The combined insulation interface of a high-voltage cable and accessories is the weakest part of a cable system. In this paper, the parameters of the dielectric constant, thermal conductivity, and elastic modulus of cross-linked polyethylene (XLPE) and silicone rubber (SIR) are obtained experimentally. On this basis, the model of a specific type of 110 kV cable and prefabricated insulation joint is established. A simulation of the electric–thermal–stress coupling field in the presence of typical defects in the main insulation–inner semi-conductive (SEMI) shielding layer (XLPE/SEMI interface) and the main insulation–silicone rubber insulation layer (XLPE/SIR interface) is studied. The simulation results show that at the XLPE/SIR interface, the electric field distortion caused by bubble defects reached 20.17 kV/mm, and the temperature rose to 56.15 °C. The effect of air-gap defects on the interface is similar to that of bubble defects. In addition, the semi-conductive impurity defects induced an increase in temperature to 56.82 °C and an increase in stress to 0.32 MPa. At the XLPE/SEMI interface, the electric field distortion induced by bubble defects was 19.98 kV/mm, and the temperature rose to 61.72 °C. The electric field distortion caused by metallic and semi-conductive defects was 8.44 kV/mm and 8.64 kV/mm, respectively. This study serves as a reference for the fault analysis and the operation and maintenance of cable accessories. [ABSTRACT FROM AUTHOR]

Silicone rubber (SR), as one kind of highly valuable rubber material, has been widely used in many fields, e.g., construction, transportation, the electronics industry, automobiles, aviation, and biology, owing to its attractive properties, including high- and low-temperature resistance, weathering resistance, chemical stability, and electrical isolation, as well as transparency. Unfortunately, the inherent flammability of SR largely restricts its practical application in many fields that have high standard requirements for flame retardancy. Throughout the last decade, a series of flame-retardant strategies have been adopted which enhance the flame retardancy of SR and even enhance its other key properties, such as mechanical properties and thermal stability. This comprehensive review systematically reviewed the recent research advances in flame-retarded SR materials and summarized and introduced the up-to-date design of different types of flame retardants and their effects on flame-retardant properties and other performances of SR. In addition, the related flame-retardant mechanisms of the as-prepared flame-retardant SR materials are analyzed and presented. Moreover, key challenges associated with these various types of FRs are discussed, and future development directions are also proposed. [ABSTRACT FROM AUTHOR]

The presence of oil-contaminated water due to oil spill disasters or improper industrial waste dumping is now a worldwide danger to both human health and the sustainability of the environment.The use of superhydrophobic materials has attracted considerable attention in the field of oil-water separation, owing to the increasing demand for effective and economical oil-water separation techniques.A new, easy, and inexpensive flame treatment method was used to make a nanocomposite (CuO-SiO2) in order to improve its hierarchical structure (micro-nano).The anodisation process produced copper oxide (CuO) nanostructures (NSs) on a copper mesh. Subsequently, the nanostructures were modified by dip coating with a solution of room-temperature vulcanised silicone rubber (RTV-SR).The coated mesh demonstrated remarkable characteristics of superhydrophobicity and superoleophilicity, with a water contact angle (WCA) of (160 ± 1°) and an oil contact angle (OCA) of (0°), as determined during the measurement of the surface's wetability. The coated mesh surface was characterised using X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and energy dispersive spectroscopy (EDS).The successful separation of kerosene-water and diesel oil-water mixtures is accomplished by using a coated mesh in a simple filtration procedure. Furthermore, it has the capability to separate oils with a high efficiency of (99.8%) for kerosene and (87%) for diesel oil. It also has flux values of (7352.9 L.m-2.h-1) for kerosene and (6112.9 L/m2.h) for diesel. [ABSTRACT FROM AUTHOR]

Lightweight, electrically insulating and high thermally conductive materials are highly desirable in electronic and power systems because they can effectively transfer heat and avoid temperature rise of the equipment and devices, thus guaranteeing normal operation. In this work, silica-coated spherical boron nitride (SiO2@s-BN) was successfully fabricated and prepared as a thermally conductive composite by blending with silicone rubber (SR). Due to the modulus matching, SiO2@BN could decrease the thermal resistance between the SR matrices and the thermally conductive fillers, thus achieving higher thermal conductivity compared with the original BN at the same filler loading. When the SR composite is filled with 40 wt% SiO2@BN, the thermal conductivity can reach 1.2 W m−1 K−1, which is 16.5% higher than that of the 40 wt% s-BN/SR composite. Simultaneously, the 40 wt% SiO2@BN/SR composite material not only exhibits excellent dielectric, thermal, and mechanical properties but also demonstrates outstanding processability, maintaining a low precursor viscosity of only 14.5 Pa·s. Overall, this work provides a novel strategy for developing high thermally conductive SR composites with good processability. [ABSTRACT FROM AUTHOR]

[Display omitted] Replicating the tactile sensing mechanisms, conformity, and feel of real skin is essential for next-generation human–machine interfaces. However, producing tissue-like multilayered geometries and integrating them as e-skin systems requires simplifying and standardizing their manufacture. Here, we present a scalable and cost-effective cure-on-demand strategy for 3D printing nanocomposite silicone rubbers and integrating them into complex soft structures with 1200 % enhanced pressure-strain sensitivity. By utilizing a controlled in-situ mixing of catalyst-cured silicones and shear-driven alignment of carbon nanofibers (CNF), we construct percolated networks with conductivities up to 130 S m−1 layer-by-layer. We investigate the influence of ink composition, printing parameters, geometrical design, and material density on the mechanical properties, stretchability, sensitivity, and antimicrobial activity of 3D printed piezoresistive sensors and build skin-like interfaces that detect minimal deformations like human physiological signs. This customizable, biocompatible, and robust e-skin holds promise for cost-effective integration in rehabilitation medicine, smart robotics applications, and extended reality (XR) interactive experiences. [ABSTRACT FROM AUTHOR]

The heat aging resistance of a peroxide-cured silicone rubber (VMQ) in the temperature range from 75 to 225 °C was investigated. Activation energies for the degradation process were calculated in order to understand the durability and lifetime of the rubber. The hardness, tensile stress at 10% elongation, and chemical cross-link density measured by solvent swell and double-quantum nuclear magnetic resonance increase as a function of thermal aging. The increase is due to the prevalence of cross-linking reactions over chain scission events which was confirmed by FTIR analysis. The unaged monomodal cross-link distribution becomes more heterogeneous with heat aging as its distribution significantly widens toward higher cross-link densities. Calculated activation energies for the heat-induced degradation process were between 70 and 101 kJ/mol. Activation energies depended on the experimental test used to probe the system. The FTIR analysis confirmed the loss of –CH bonds and gain of Si–O–Si linkages during thermal aging. Oxidative products were extracted and characterized from the degraded VMQ. Aerobic and non-aerobic degradation mechanisms have been proposed to explain the presence of cross-linking and chain scission reactions. Given the lack of data change during low-temperature aging, the results are suitable for use to predict the performance of VMQ in applications between 100 and 225 °C. [ABSTRACT FROM AUTHOR]

Copyright of Acta Materiae Compositae Sinica is the property of Acta Materiea Compositae Sinica Editorial Department and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Copyright of Silicone Material is the property of Silicone Material Editorial Office and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Copyright of Silicone Material is the property of Silicone Material Editorial Office and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Copyright of Silicone Material is the property of Silicone Material Editorial Office and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Liquid silicone rubber (LSR) is characterized by a wide range of advantageous properties and is therefore used in many branches and industries. However, the material is difficult to recycle due to the non‐reversible cross‐linking reaction. A promising approach to recycle the already cross‐linked (post‐industrial) waste is the mechanical recycling of LSR via grinding and addition of the powder as filler in virgin material. This research focused on the processing of such LSR‐powder‐compounds via injection molding and the influence of the powder content on mechanical properties. Compounds of virgin LSR and ambient ground powder were prepared and injection molded. Both the processability and the mechanical properties were analyzed. Compounds of up to 40 wt% powder content could be processed with standard injection molding machine equipment without any noticeable issues. The results show a similar compression set for the virgin as for the recycled compounds. Hardness decreases slightly but constantly. Tensile strength and elongation at break are at similar levels for all powder added compounds and drop only by 16.6% and 12.6% compared with the virgin LSR. The results are promising and should be the basis for further and more detailed investigations to industrialize the mechanical recycling of LSR. Highlights: Processing on standard injection molding machine with standard parameters.Up to 40 wt% recycled silicone powder content.Using recycled silicone particles has no effect on compression set.Tensile strength and elongation at break decrease only by 16.6% and 12.6%. [ABSTRACT FROM AUTHOR]

The vibrations generated in the two-wheeled vehicles like motorcycles due to road irregularities such as cracks, potholes, and bumps on the road cause discomfort for the rider as well as the pillion. These vibrations are reported to cause lower back pains, musculoskeletal effects, fatigue, and long-term health issues. Particularly, electric two-wheelers are more susceptible to these vibrations caused by the road and need attention. This paper presents an innovative technique for the reduction of vibrations at prominent locations in the electric two-wheeler to improve the rider's comfort. All measured accelerations are about vertical direction (along z-axis as per ISO 2631-1 standard). Passive and Semi-active damping treatments namely, Room temperature vulcanizing Silicone rubber and Magnetorheological elastomer (MRE) were applied on the test vehicle at strategic locations of vibration. Both were compared for their effectiveness in reducing the vibrations. Results showed that MRE based damping technique proved better vibration isolation at the strategic locations. The weighted root mean square acceleration as well as vibration dose values were found to decrease with the help of damping treatments thus improving the rider's overall comfort level. [ABSTRACT FROM AUTHOR]

The diverse applications of magnetorheological elastomer (MRE) drive efforts to understand consistent performance and resistance to failure. Stress relaxation can lead to molecular chain deterioration, degradation in stiffness and rheological properties, and ultimately affect the life cycle of MRE. However, quantifying the energy and molecular dynamics during stress relaxation is challenging due to the difficulty of obtaining atomic-level insights experimentally. This study employs molecular dynamics (MD) simulation to elucidate the stress relaxation in MRE during constant strain. Magnetorheological elastomer models incorporating silicone rubber filled with varying magnetic iron particles (50–80 wt%) were constructed. Experimental results from an oscillatory shear rheometer showed the linear viscoelastic region of MRE to be within 0.001–0.01% strain. The simulation results indicated that stress relaxation has occurred, with stored energies decreased by 8.63–52.7% in all MRE models. Monitoring changes in energy components, the highest final stored energy (12,045 kJ) of the MRE model with 80 wt% Fe particles was primarily attributed to stronger intramolecular and intermolecular interactions, revealed by higher potential energy (3262 kJ) and van der Waals energy (− 2717.29 kJ). Stress relaxation also altered the molecular dynamics of this MRE model as evidenced by a decrease in kinetic energy (9362 kJ) and mean square displacement value (20,318 Å2). The MD simulation provides a promising quantitative tool for elucidating stress relaxation, preventing material failure and offering insights for the design of MRE in the nanotechnology industry. [ABSTRACT FROM AUTHOR]

Copyright of China Plastics / Zhongguo Suliao is the property of Journal Office of CHINA PLASTICS and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

To enhance the low‐temperature toughness and resistance of the engineering plastic polyamide PA12, this study introduces novel PA12/MVQ@POE‐g‐MAH ternary composites using a two‐step process and dynamic curing. Analytical results indicate that incorporating MVQ@POE‐g‐MAH into the PA12 matrix markedly enhances its toughness and heat resistance. As the MVQ@POE‐g‐MAH content increases, the elongation at break of PA12 composites significantly expands from 52.83% to 204.69%, and the notch impact strength escalates from 8.69 to 74.34 kJ m−2. In addition, the brittleness temperature of PA12 decreases from −59.5 to −67.0 °C. Experimental findings confirm that POE‐g‐MAH is dispersed at the interface between MVQ and PA12, creating an encapsulated structure of MVQ@POE‐g‐MAH. This enhancement significantly broadens the potential applications of PA12 by improving its toughness, and resistance to both low and high temperatures, as well as impact endurance. [ABSTRACT FROM AUTHOR]

Three-dimensional-printed silicone rubber foams, with their designable and highly ordered pore structures, have shown exceptional potential for engineering applications, particularly in areas requiring energy absorption and cushioning. However, optimizing the mechanical properties of these foams through structural design remains a significant challenge. This study addresses this challenge by formulating the research question: How do different 3D-printed topologies and printing parameters affect the mechanical properties of silicone rubber foams, and how can we design a novel topological structure? To answer this, we explored the mechanical behavior of two common structures–simple cubic (SC) and face-centered tetragonal (FCT)–by varying printing parameters such as filament spacing, filament diameter, and layer height. Furthermore, we proposed a novel two-level 3D-printed structure, combining SC and FCT configurations to enhance performance. The results demonstrated that the two-level SC-SC structure exhibited a specific energy absorption of 8.2 to 21.0 times greater than the SC structure and 2.3 to 7.2 times greater than the FCT structure. In conclusion, this study provides new insights into the design of 3D-printed silicone rubber foams, offering a promising approach to developing advanced cushioning materials with superior energy absorption capabilities. [ABSTRACT FROM AUTHOR]

The material parameters required to describe material behavior can change with the age of the components due to chemical and physical aging processes. The finite element method (FEM) is a tool for designing components for later use. The aim of this study is to correlate the change in the mechanical properties of silicone elastomers from standard tests over a longer period of time with the parameters of the Mooney–Rivlin model. To date, there are no publications on the development of the Mooney–Rivlin parameters of silicone elastomers over a storage period. For this purpose, the Shore A hardness, rebound elasticity, compression set and tensile properties were investigated over an aging period of approx. 200 days on two liquid silicone rubbers (LSRs) and one room-temperature-vulcanizing (RTV) silicone rubber. Depending on the silicone elastomer used, different trends in the characteristic values can be observed over the storage period. In general, increases in the Shore A hardness, rebound resilience and stress at a 100% strain with a decrease in the compression set can be determined. In addition to standard tensile tests, the material's multiaxial behavior under tension was probed, and it was found that the similarly stress at a 100% strain increased. Finite element simulations verified the standard tensile test and corresponding Mooney–Rivlin model parameters. These parameters from the uniaxial tensile were validated in the multiaxial behavior, and the model's accuracy in representing material properties and the influence of aging on the FEM simulation were affirmed. [ABSTRACT FROM AUTHOR]

The insulation of high-voltage direct-current (HVDC) cables experiences a short period of voltage polarity reversal when the power flow is adjusted, leading to sever field distortion in this situation. Consequently, improving the insulation performance of the composite insulation structure in these cables has become an urgent challenge. In this paper, SiC-SR (silicone rubber) and TiO2-SR nanocomposites were chosen for fabricating HVDC cable accessories. These nanocomposites were prepared using the solution blending method, and an electro-acoustic pulse (PEA) space charge test platform was established to explore the electron transfer mechanism. The space charge characteristics and field strength distribution of a double-layer dielectric composed of cross-linked polyethylene (XLPE) and nano-composite SR at different concentrations were studied during voltage polarity reversal. Additionally, a self-built breakdown platform for flake samples was established to explore the effect of the nanoparticle doping concentration on the breakdown field strength of double-layer composite media under polarity reversal. Therefore, a correlation was established between the micro electron transfer process and the macro electrical properties of polymers (XLPE/SR). The results show that optimal concentrations of nano-SiC and TiO2 particles introduce deep traps in the SR matrix, significantly inhibiting charge accumulation and electric field distortion at the interface, thereby effectively improving the dielectric strength of the double-layer polymers (XLPE/SR). [ABSTRACT FROM AUTHOR]

Associating molecular structure and mechanical properties is important for silicone rubber design. Although silicone rubbers are widely used due to their odourless, non-toxic, and high- and low-temperature resistance advantages, their application and development are still limited by their poor mechanical properties. The mechanical properties of silicone rubbers can be regulated by designing the cross-link density and cross-linking structure, and altering the molar contents of vinyl in the side groups of methyl vinyl silicone rubber (MVQ) leads to different cross-linking structures and cross-linking densities in the vulcanized rubber. Therefore, this study investigated the differences in molecular parameters and molecular chain structures of unprocessed MVQ rubbers with different vinyl contents. The results showed that MVQ rubbers with high vinyl contents were branched polymers, better facilitating the cross-linking reaction than MVQ rubbers with low vinyl contents. In addition, silicone rubbers with different vinyl contents were co-cross-linked to introduce an inhomogeneous cross-linked network in the silicone rubber to improve its mechanical properties. The cross-linked network properties were analysed by the Flory–Rehner model and Mooney–Rivlin plots, and it was found that the long chains in the sparsely cross-linked domains of the network favoured high elongation at break and the short chains in the densely cross-linked domains contributed to high modulus, which could satisfy the functions of reinforcing and toughening the rubber materials at the same time. It was also found by analysing the filler network and aggregate morphology that the inhomogeneous cross-linked network led to an improvement in the dispersion of silica in the rubber and a significant improvement in the mechanical properties of silicone rubber. [ABSTRACT FROM AUTHOR]

Silicone rubber is a good candidate as a carrier of small molecules in such applications as drug, fragrance and semiochemical delivery. When one matrix is loaded, the molecular interactions between the molecules and the matrix may affect their release rates. For this reason, it is important to investigate the effects of molecular interactions on release to better develop delivery systems with desirable release rates. In this study, the mass transfer and diffusion coefficients of three model molecules (i.e., octanol, octyl acetate, and octyl butyrate) were determined by monitoring their release from silicone rubber sheets loaded using headspace gas chromatography–mass spectrometry. Differential scanning calorimetry was used to characterize the plasticizing effects and Fourier transform infrared spectroscopy was used to characterize the molecular interactions. It was found that the release of octanol conformed to the Fickian diffusion pattern at 1 wt% initial concentration but deviated as the concentration increased due to hydrogen bonding between octanol and the silanol group of the silica filler. When two small molecules were released simultaneously, the effects of one molecule on the diffusion coefficient of the other differed, a result explained by the competing effects of plasticizing and hydrogen bonding. [ABSTRACT FROM AUTHOR]

This paper considers the design, manufacture, and testing of a prototype "soft–stiff" worm-inspired robot referred to herein, as the PneumaticallyActuated PeristaLtic Advancing Modular (PALAM) robot. The robot has a modular structure, mimicking the segmented nature of earthworms, and each segment is individually actuated by a set of three pneumatic artificial muscles (PAMs). The PAMs contract when inflated by pressurised air, generating a pulling force and fulfilling the role of biological muscles in the robot. The PAMs are made from the elastomer silicone rubber, which affords the robot flexibility and enables a wide range of real-life applications. A control-system is designed which can inflate any PAM on demand, and hence replicate the peristaltic motion of earthworms in the PALAM robot. Finally, this paper discusses a successful, low-cost, and widely accessible approach for the manufacture of the PAMs utilised herein. The PAMs can be scaled dimensionally and made from different materials with varying mechanical properties and behaviours, meaning that they are suitable for use in a wide range of robotics applications. [ABSTRACT FROM AUTHOR]

WO3 and silicone rubber (SR)-based gasochromic composites were fabricated to detect hydrogen leaks at room temperature. WO3 rod-like nanostructures were uniformly distributed in the SR matrix, with a particle size of 60–100 nm. The hydrogen permeability of these composites reached 1.77 cm3·cm/cm2·s·cmHg. At a 10% hydrogen concentration, the visible light reflectance of the composite decreased 49% during about 40 s, with a color change rate of 6.4% s−1. Moreover, the composite detected hydrogen concentrations as low as 0.1%. And a color scale was obtained for easily assessing hydrogen concentrations in the environment based on the color of composites. Finally, the composite materials as disposable sensors underwent testing at several Sinopec hydrogen refueling stations. [ABSTRACT FROM AUTHOR]

To enhance mechanical, adhesive, and thermal properties of Room Temperature Vulcanized (RTV) silicone rubber, a silicon-containing polyurethane/epoxy resin modifier (ESiPU) was developed. A three-phase system of polyurethane/epoxy resin/silicone rubber was prepared through blending, modification, and co-curing. FT-IR and 1H-NMR were employed to characterize the chemical structure of ESiPU. Microscopic analysis revealed improved compatibility between modified epoxy resin and silicone rubber. Mechanical testing showed significant enhancements in tensile strength, elongation at break, and adhesive strength, with RTV-20phr exhibiting increases of 236, 266, and 259%, respectively. Thermogravimetric analysis indicated higher initial decomposition temperature compared to pure RTV. At the same time, the char residue at 800 °C increased to 8.67%. TG-IR analysis demonstrated ESiPU's ability to delay thermal degradation. Contact angle test confirmed improved hydrophobicity. Overall, the developed silicone rubber system exhibits promising mechanical and thermal properties, suggesting potential for aerospace heat protection applications. [ABSTRACT FROM AUTHOR]

In practical applications, polyurethane (PU) foam must be rigid to meet the demands of various industries and provide comfort and protection in everyday life. PU foam components are extensively used in structural foam, thermal insulation, decorative panels, packaging, imitation wood, and floral foam, as well as in models and prototypes. Conventional technology for producing PU foam parts often leads to defects such as deformation, short shots, entrapped air, warpage, flash, micro-bubbles, weld lines, and voids. Therefore, the development of rigid PU foam parts has become a crucial research focus in the industry. This study proposes an innovative manufacturing process for producing rigid PU foam parts using silicone rubber molds (SRMs). The deformation of the silicone rubber mold can be predicted based on its wall thickness, following a trend equation with a correlation coefficient of 0.9951. The volume of the PU foam part can also be predicted by the weight of the PU foaming agent, as indicated by a trend equation with a correlation coefficient of 0.9824. The optimal weight ratio of the foaming agent to water, yielding the highest surface hardness, was found to be 5:1. The surface hardness of the PU foam part can also be predicted based on the weight of the water used, according to a proposed prediction equation with a correlation coefficient of 0.7517. The average surface hardness of the fabricated PU foam part has a Shore O hardness value of approximately 75. Foam parts made with 1.5 g of water added to 15 g of a foaming agent have the fewest internal pores, resulting in the densest interior. PU foam parts exhibit excellent mechanical properties when 3 g of water is added to the PU foaming agent, as evidenced by their surface hardness and compressive strength. Using rigid PU foam parts as a backing material in the proposed method can reduce rapid tool production costs by about 62%. Finally, an innovative manufacturing process for creating large SRMs using rigid PU foam parts as backing material is demonstrated. [ABSTRACT FROM AUTHOR]

Liquid‐metal embedded elastomers (LMEEs) have been demonstrated to show a variety of excellent properties, including high toughness, dielectric constant, and thermal conductivity, with applications across soft electronics and robotics. However, within this scope of use cases, operation in extreme environments – such as high‐temperature conditions – may lead to material degradation. While prior works highlight the functionality of LMEEs, there is limited insight on the thermal stability of these soft materials and how the effects of liquid metal (LM) inclusions depend on temperature. Here, the effects on thermal stability, including mechanical and electrical properties, of LMEEs are introduced. Effects are characterized for both fluoroelastomer and other elastomer‐based composites at temperature exposures up to 325 °C, where it is shown that embedding LM can offer improvements in thermo‐mechanical stability. Compared to elastomer like silicone rubber that has been previously used for LMEEs, a fluoroelastomer matrix offers a higher dielectric constant and significant improvement in thermo‐mechanical stability without sacrificing room temperature properties, such as thermal conductivity and modulus. Fluoroelastomer‐LM composites offer a promising soft, multi‐functional material for high‐temperature applications, which is demonstrated here with a printed, soft heat sink and an endoscopic sensor capable of wireless sensing of high temperatures. [ABSTRACT FROM AUTHOR]

In this paper, the silicone rubber (SR)/thermoplastic polyurethane (TPU) composites and its compatibilizers were studied by molecule dynamics simulation and experiment. Three compatibilizers, fluorosilicone rubber (FSR), dendritic hydroxyl-terminated silicone oil (DHSO), and fluorinated modified tetraethyl orthosilicate grafted silicone rubber (FTEOS-g-SR) were introduced into the SR/TPU composites. The simulation results showed that the cohesion density of pure SR was 3.072 × 108 J/m3, the solubility parameter was 17.504 (J/cm3)0.5, the Young's modulus was 4.0139 GPa, the shear modulus was 1.4493 GPa, and the bulk modulus was 5.8061 GPa. Moreover, the cohesion density of SR/TPU/FSR and SR/TPU/DHSO increased to 4.693 × 108 and 3.459 × 108 J/m3, solubility parameter increased to 21.662 and 18.597 (J/cm3)0.5, the Young's modulus increased to 6.6399 and 6.0020 GPa, shear modulus increased to 2.4377 and 2.2060 GPa, and bulk modulus increased to 8.0148 and 7.1653 GPa, respectively. However, the cohesion density, solubility, and young's modulus of SR/TPU/FTEOS-g-SR decreased to 2.617 × 108 J/m3, 16.174 (J/cm3)0.5, 3.872 GPa, 1.7510 Gpa, and 1.6365 GPa. These results demonstrated that both FSR and DHSO can improve the mechanical properties of the SR/TPU composites, while the FTEOS-g-SR reduced their mechanical properties. The compatibility and mechanical properties of SR/TPU composites modified by FSR and DHSO were verified and compared. The factors such as blending temperature, blending ratio, and TPU types of SR/TPU composites were considered. Compared to composites cured at 185 °C, those cured at 175 °C exhibited better mechanical properties. The dynamically vulcanized SR/TPU (3:7, mass ratio) materials showed superior tensile strength and elongation at break when compared to the SR/TPU (5:5, mass ratio) composites. Moreover, the polyether type of TPU was found to be more favorable than the polyester type for obtaining a blended composite with good tensile properties. The experimental results demonstrated that both compatibilizers contributed to improving the mechanical properties of the composites to a certain extent. The scanning electron microscope (SEM) test revealed that FSR enhanced the dispersion of SR in the TPU matrix. Additionally, charge distribution simulation analysis indicated the presence of abundant intermolecular hydrogen bonds between FSR and TPU, which played a significant role in the excellent compatibility and mechanical properties observed in this blend system. [ABSTRACT FROM AUTHOR]

UV ray is an unavoidable environmental factor in the operation of outdoor cable accessories, which is easy to cause the cable accessories flashover and breakdown faults. In this paper, the changes of insulation properties of silicone rubber (SiR) after UV radiation treatment were studied from the aspects of microstructure, dielectric properties, surface properties and discharge properties. Combined with the analysis of molecular chain damage and surface trap, the influence mechanism of UV radiation on the insulation properties of SiR was revealed. The experimental results show that the dielectric constant of SiR after UV radiation treatment first decreases and then increases, it decreases to 3.06 at 240 h and increases to 3.93 at 1000 h. UV radiation can reduce the surface resistance of SiR, it decreases by 48% after 1000 h radiation. With the extension of UV radiation time, the surface trap level corresponding to the peak of the trap density is about 0.95 eV, the trap density decreases to 2.32 × 1022 eV−1 m−3 at 240 h. Short-term UV radiation can promote the secondary cross-linking of SiR, resulting in the increase of flashover voltage from 6.32 to 7.64 kV. Long-term radiation can destroy the molecular chain structure, resulting in a slight decrease in the flashover voltage. With the extension of UV radiation time, the breakdown strength decreases by about 14% at 1000 h. This work has guiding significance for the radiation performance and life evaluation of cable accessories. [ABSTRACT FROM AUTHOR]

Strategies for synthesis and processing of silicone rubber materials in three-dimensional (3D) structures are of significant interest based on their exceptional potential in many applications including flexible electronics and biomedical devices. Here, we present a synthetic approach of crosslinked polydimethylsiloxane (PDMS) exhibiting dynamic siloxane bond exchange for sufficient stress relaxation capability to enable versatile processabilities including reprocessing, remolding, self-healing, and hot-melt extrusion 3D printing. Considering the significant potential of recyclable silicone materials and their 3D structures, presented approaches enabled by dynamic exchangeable PDMS can provide a new pathway to replace conventional unrecyclable silicone used in diverse industrial sectors. [ABSTRACT FROM AUTHOR]

Copyright of China Rubber Industry is the property of Editorial Office of China Rubber Industry and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)