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378 results on '"SUN, Shiyong"'

26. Piezo‐Photocatalytically Induced Dual‐Channel Pathway of CdxZn1‐xS Solid‐Solution Nanorods for Hydrogen Peroxide Evolution.

Author

Lin, Sen, Sun, Shiyong, Zhang, Xueyan, Tang, Haoming, Liu, Jun, and Li, Xiang

Subjects
*PIEZORESPONSE force microscopy, *ELECTRON paramagnetic resonance, *PIEZOELECTRICITY, *HYDROGEN peroxide, *CLEAN energy
Abstract

As a class of clean oxidants, the hydrogen peroxide (H2O2) has shown great application potential in a variety of fields due to its high energy density and convenient storage condition, while the synthesis of H2O2 by the utilization of green energy technology has currently become one of the attentions in energy field. In this paper, the CdxZn1‐xS (x = 0, 0.2, 0.4, 0.6, 0.8, 1) solid solutions with different zinc‐cadmium molar ratios are prepared by a simple solvothermal route, and the H2O2 evolution performances of materials under illumination and ultrasound conditions are explored. The results show that Cd0.4Zn0.6S has the highest H2O2 yield rate of 2866 µmol/g/h under the synergistic effect of ultrasound and illumination without any sacrificial agent, which is higher than those in ultrasonic or light condition alone, showing piezo‐photocatalytic coupling characteristic. The characterizations including piezoresponse force microscopy (PFM), finite element simulation, in situ electron spin resonance (ESR) reveal that the excellent H2O2 production property of the material should be mainly ascribed to its nanorod structure and e−‐h+ dual‐channel reactivity formed by the bending of its energy band under the piezoelectric effect. This work provides reference and enlightenment for the preparation of H2O2 through the green energy avenue. [ABSTRACT FROM AUTHOR]

Published
2024
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34. Binary anorthite‐cordierite ceramic composite from kaolin and dolomite rock with improved characteristics.

Author

Ponaryadov, Alexey, Kotova, Olga, Sun, Shiyong, and Kotova, Elena

Subjects
DIFFERENTIAL thermal analysis, CERAMIC engineering, HEAT treatment, CORDIERITE, SCANNING electron microscopy
Abstract

Binary CaO‐MgO‐Al2O3‐SiO2 (CMAS) ceramics composites of anorthite‐cordierite composition were synthesized from natural raw materials (kaolin and dolomite rock). The change of SiO2/Al2O3 ratio in kaolin/dolomite mixtures (12, 24, and 36 wt.%) and synthesized composites along with analysis of their phase composition transformations (X‐ray diffraction) during heat treatment (thermogravimetric and differential thermal analysis) give the controlled design of aluminosilicate matrices. The obtained ceramic composites are represented by anorthite, a cordierite‐like phase whose ratio varies from 1.3:1 to 2.8:1. Mullite crystals, also included in the composition, reinforce the anorthite‐cordierite matrix. The morphostructural features of the samples were studied using optical and scanning electron microscopy. The porosity ranges from 7.8% to 24.2% depending on dolomite content. The impurities of iron and titanium interfering with obtaining a qualitative product are leveled by the presented technique including the heat treatment scheme justified by thermogravimetric analysis. Obtained CMAS‐ceramics of anorthite‐cordierite composition correspond to industrial international standards by their technical characteristics and exceed the requirements for heat‐insulating and chemically resistant materials by compressive strength. [ABSTRACT FROM AUTHOR]

Published
2024
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45. Efficient immobilization of iodide from aqueous solution by Cu2O/Cu modified shungite.

Author

Tang, Haoming, Zhang, Mingzhu, Ran, Fengya, Sun, Shiyong, Golubev, Yevgeny Aleksandrovich, Zhao, Qian, Lin, Sen, Duan, Tao, and Kotova, Olga Borisovna

Subjects
LANGMUIR isotherms, IODINE isotopes, AQUEOUS solutions, ADSORPTION capacity, IODIDES, SUPERABSORBENT polymers, COPPER ions
Abstract

The Cu2O/Cu modified shungite (ShC) absorbent (Cu2O/Cu-ShC) was synthesized by hydrothermal method, benefiting from the mineral backbone and Cu2O/Cu particles, Cu2O/Cu-ShC can remove ~ 96% of I− within 60 min, the batch experiments showed that the I− adsorption process follows pseudo-second-order model and Langmuir model with maximum adsorption capacity of 10.99 mg/g. The high binding affinity between Cu+ and I− contributes effective removal of I− and excellent selectivity at high concentrations of competing ions. This work highlights the feasibility of Cu2O/Cu-ShC for the radioactive iodine separation, and provides a promising sorbent material for large-scale purification of radioactive iodine anions in wastewater. [ABSTRACT FROM AUTHOR]

Published
2024
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47. Service Mechanism for the Cloud–Edge Collaboration System Considering Quality of Experience in the Digital Economy Era: An Evolutionary Game Approach

Author

Sun, Shiyong Li, Min Xu, Huan Liu, and Wei

Subjects
digital economy, digital transformation, cloud–edge collaboration, quality of experience, evolutionary stable strategy
Abstract

In the digital economy era, cloud–edge collaboration technology provides the necessary technical support for the digital transformation of enterprises, which can improve the quality of services (QoS), and it attracts extensive attention from scholars and entrepreneurs from all fields. Under the bounded-rationality hypothesis, this paper investigates the service mechanism for the cloud–edge collaboration system considering the quality of experience (QoE) and presents a dynamic evolutionary game model between cloud service providers and edge operators by applying the evolutionary game theory. Then, this paper analyzes the equilibrium and stability conditions for the decision-making of both parties involved to guarantee the QoE reaches the ideal state. In addition, we investigate the factors that influence the stable cooperation between the two evolutionary stable strategies and validate the theoretical analytical results with numerical simulations. The research results show that the final evolution of the cloud–edge collaboration system depends on the benefits and costs of the game matrix between the two parties and the initial state values of the system. Under a specific condition, the cloud–edge collaboration system can eventually be driven to be an ideal state by reducing the collaboration cost and improving the collaboration benefit. The more both parties focus on the QoE, the more conducive it will be for the formation of a cloud–edge collaboration, thus effectively promoting long-term stability and better serving enterprises’ digital transformation.

Published
2023
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