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The Cassini spacecraft orbiting Saturn carries the composite infrared spectrometer (CIRS) designed to study thermal emission from Saturn and its rings and moons. CIRS, a Fourier transform spectrometer, is an indispensable part of the payload providing unique measurements and important synergies with the other instruments. It takes full advantage of Cassini's 13-year-long mission and surpasses the capabilities of previous spectrometers on Voyager 1 and 2. The instrument, consisting of two interferometers sharing a telescope and a scan mechanism, covers over a factor of 100 in wavelength in the mid and far infrared. It is used to study temperature, composition, structure, and dynamics of the atmospheres of Jupiter, Saturn, and Titan, the rings of Saturn, and surfaces of the icy moons. CIRS has returned a large volume of scientific results, the culmination of over 30 years of instrument development, operation, data calibration, and analysis. As Cassini and CIRS reach the end of their mission in 2017, we expect that archived spectra will be used by scientists for many years to come.

We use the existing thirteen Cassini radio'occultation soundings to construct a meridional cross section of geopotential height vs. pressure and latitude. The assumption of balanced flow permits the construction of a similar cross section of zonal winds, from near the surface to the 0.1'mbar level. In the lower troposphere, the winds are approx.10 m/s, except within 20deg of the equator, where they are much smaller. The winds increase higher up in the troposphere to nearly 40 m/s in the tropopause region, but then decay rapidly in the lower stratosphere to near'zero values at 20 mbar (approx.80 km), reminiscent of the Huygens Doppler Wind Experiment result. This null zone extends over most latitudes, except for limited bands at mid'latitudes. Higher up in the stratosphere, the winds become larger. They are highest in the northern (winter) hemisphere. We compare the occultation results with the DWE and CIRS retrievals and discuss the similarities and differences among the data sets.

Equatorial oscillations in the zonal-mean temperatures and zonal winds have been well documented in Earth's middle atmosphere. A growing body of evidence from ground-based and Cassini spacecraft observations indicates that such phenomena also occur in the stratospheres of Jupiter and Saturn. Earth-based midinfrared measurements spanning several decades have established that the equatorial stratospheric temperatures on Jupiter vary with a cycle of 4-5 years and on Saturn with a cycle of approximately 15 years. Spectra obtained by the Composite Infrared Spectrometer (CIRS) during the Cassini swingby at the end of 2000, with much better vertical resolution than the ground-based data, indicated a series of vertically stacked warm and cold anomalics at Jupiter's equator; a similar structurc was seen at Saturn's equator in CIRS limb measurements made in 2005, in the early phase of Cassini's orbital tour. The thermal wind equation implied similar patterns of mean zonal winds increasing and decreasing with altitude. On Saturn the peak-to-pcak amplitude of this variation was nearly 200 meters per second. The alternating vertical pattern of wanner and colder cquatorial tcmperatures and easterly and westerly tendencies of the zonal winds is seen in Earth's equatorial oscillations, where the pattern descends with time, The Cassini Jupiter and early Saturn observations were snapshots within a limited time interval, and they did not show the temporal evolution of the spatial patterns. However, more recent Saturn observations by CIRS (2010) and Cassini radio-occultation soundings (2009-2010) have provided an opportunity to follow the change of the temperature-zonal wind pattern, and they suggest there is descent, at a rate of roughly one scale height over four years. On Earth, the observed descent in the zonal-mean structure is associated with the absorption of a combination of vertically propagating waves with easlerly and westerly phase velocities. The peak-to-peak zonal wind amplitude in the oscillation pattern and the rate of descent constrain the absorbed wave flux of zonal momentum. On Saturn this is approximately 0.05 square meters per square seconds, which is comparable to if not greater than that associated with the terrestrial oscillations. We discuss possible candidates for the absorbed waves on Saturn. On Earth the wave forcing of the equatorial oscillation generales secondary circulations that can affcct the temperature and wind structure at latitudes well away from the equator, and we discuss possible evidence of that on Saturn.

A series of near-equatorial radio occultations of Cassini by Saturn occurred in 2005 and again in 2009-2010. Comparison of the temperature-pressure profiles obtained from the two sets of occultations shows evidence of a descending pattern in the stratosphere that is similar to those associated with equatorial oscillations in Earth's middle atmosphere. This is the first time that this descent has been observed in another planetary atmosphere. If absorption of upwardly propagating waves drives the descent, the implied absorbed flux is 0.05 square meters per square second at least as large if not greater than on Earth.

The thermal structure of Titan's atmosphere is reviewed, with particular emphasis on recent Cassini-Huygens results. Titan's has a similar troposphere-stratosphere-mesosphere pattern like Earth, but with a much more extended atmosphere, because of the weaker gravity, and also much lower temperatures, because of its greater distance from the sun. Titan's atmosphere exhibits an unusually large range in radiative relaxation times. In the troposphere, these are long compared to seasonal time scales, but in the stratosphere they are much shorter than a season. An exception is near the winter pole, where the stratospheric relaxation times at 100-170 km become comparable to the seasonal time scale; at the warm stratopause, they are comparable to a Titan day. Hence, seasonal behavior in the troposphere should be muted, but significant in the stratosphere. This is reflected in the small meridional contrast observed in temperatures in the troposphere and the large stratospheric contrasts noted above. A surprising feature of the vertical profiles of temperature is the abrupt transition between these regimes in at high northern latitudes in winter, where the temperatures in the lower stratosphere exhibit a sudden drop with increasing altitude. This could be a radiative effect, not associated with spatial variations in gaseous opacity, but rather from an optically thick condensate at thermal-infrared wavelengths. A curious aspect of Titan's middle atmosphere is that the axis of symmetry of the temperature field is tilted by several degrees relative to the rotational axis of the moon itself. Whether this is driven by solar heating or gravitational perturbations is not known. Titan's surface exhibits weak contrasts in temperature, approximately 3 K in the winter hemisphere. At low latitudes, there is evidence of a weak nocturnal boundary layer on the morning terminator, which is not radiatively controlled, but can be explained in terms of vertical mixing with a small eddy viscosity.

The intensity of the received signal at Earth in the radio occultations of Titan is attenuated both by refractive defocusing and pressure-induced absorption from N2-N2 and CH4-N2 pairs. Because the absorption strength is different for the two sets of pairs, matching the retrieved absorptivity profile can in principle yield the vertical variation in gaseous methane in the troposphere. There are two factors that make this difficult. The first is the propagation of noise in the phase and amplitude of the received signal in the absorption retrieval. The phase data is first inverted to retrieve vertical profiles of refractivity, from which the refractive defocusing is calculated. This is then subtracted from the observed. intensity attenuation of the received signal to generate a profile of atmospheric absorption. The second problem is the uncertainty in the pressure-induced absorption coefficients. Laboratory data at radio wavelengths is only available near room temperature (see, e.g., [1] for N2-N2), and the extrapolation to the low temperatures in Titan's troposphere is not well established. Ab initio calculations by Borysow et al. [2, 3] provide absorption coefficients at low temperatures and long wavelengths, but their accuracy has come into question. We present examples from Cassini radio occultations of Titan to illustrate the difficulties. For methane mole fractions in the lower troposphere comparable to that inferred from the Huygens probe (approximately 0.05), it will be difficult to separate the contributions of N2-N2 collisions from those of N2-CH4, collisions to the retrieved absorption. However, higher concentrations of CH4 and/or a higher signal-to-noise ratio from a future uplink experiment could result in a successful separation of the two components. However, key to this are highly accurate estimates of the absorption from a combination of laboratory measurements at love temperatures and long wavelengths, and possibly improved theoretical calculations.

The radiative response of Titan's atmosphere varies by several orders of magnitude with altitude. This presents an interesting situation in which most of the stratosphere---at least that part above 100km is characterized by radiative relaxation times that are short compared to the length of a Titan season, and the troposphere and tropopause region by times that are larger than seasonal timescales. Consistent with this, Cassini CIRS spectra indicate stratospheric temperatures at 100-170 kin that are 20-30 K cooler at high northern latitudes in winter than those at equatorial and southern latitudes. Given the expectation that the situation will largely reverse in southern winter, the observed large meridional contrast is likely indicative of the expected seasonal variation at polar latitudes in both hemispheres. CIRS spectra do not as easily yield temperatures below 100 km in the lower stratosphere and tropopause region, because of the contribution of heterogeneously distributed aerosols and condensates to the infrared opacity. However, Cassini radio occultations probe both the stratosphere and troposphere, and below 80 km they show the thermal contrast with latitude to be muted, e.g, approx.5 K near the tropopause at 40-50 km and approx.3 K just above the surface. This is consistent with the large radiative relaxation times at these altitudes and with efficient meridional heat transport. What is curious is the manner in which temperatures in the north winter polar atmosphere make the transition between the troposphere and lower stratosphere, where seasonal variations are relatively small, and higher altitudes, where they are large. Temperatures at all latitudes sounded by the radio occultations exhibit similar behavior in the lower stratosphere, increasing with altitude. Between 80 and 100 kin, however, the temperatures at high northern latitudes exhibit a sudden drop with increasing altitude, producing the meridional contrast in the upper stratosphere described above. While the radiative relaxation time associated with infrared gaseous coolants decreases with altitude in the stratosphere, it is not likely to account for the abrupt transition observed. Possible mechanisms for this transition are discussed, including the presence of an optically thick. cloud at thermal-infrared wavelengths.

Radio-occultation and thermal-infrared measurements are complementary investigations for sounding planetary atmospheres. The vertical resolution afforded by radio occultations is typically approximately 1 km or better, whereas that from infrared sounding is often comparable to a scale height. On the other hand, an instrument like CIRS can easily generate global maps of temperature and composition, whereas occultation soundings are usually distributed more sparsely. The starting point for radio-occultation inversions is determining the residual Doppler-shifted frequency, that is the shift in frequency from what it would be in the absence of the atmosphere. Hence the positions and relative velocities of the spacecraft, target atmosphere, and DSN receiving station must be known to high accuracy. It is not surprising that the inversions can be susceptible to sources of systematic errors. Stratospheric temperature profiles on Titan retrieved from Cassini radio occultations were found to be very susceptible to errors in the reconstructed spacecraft velocities (approximately equal to 1 mm/s). Here the ability to adjust the spacecraft ephemeris so that the profiles matched those retrieved from CIRS limb sounding proved to be critical in mitigating this error. A similar procedure can be used for Saturn, although the sensitivity of its retrieved profiles to this type of error seems to be smaller. One issue that has appeared in inverting the Cassini occultations by Saturn is the uncertainty in its equatorial bulge, that is, the shape in its iso-density surfaces at low latitudes. Typically one approximates that surface as a geopotential surface by assuming a barotropic atmosphere. However, the recent controversy in the equatorial winds, i.e., whether they changed between the Voyager (1981) era and later (after 1996) epochs of Cassini and some Hubble observations, has made it difficult to know the exact shape of the surface, and it leads to uncertainties in the retrieved temperature profiles of one to a few kelvins. This propagates into errors in the retrieved helium abundance, which makes use of thermal-infrared spectra and synthetic spectra computed with retrieved radio-occultation temperature profiles. The highest abundances are retrieved with the faster Voyager-era winds, but even these abundances are somewhat smaller than those retrieved from the thermal-infrared data alone (albeit with larger formal errors). The helium abundance determination is most sensitive to temperatures in the upper troposphere. Further progress may include matching the radio-occultation profiles with those from CIRS limb sounding in the upper stratosphere.