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6. Effects of counter-ion size on solid state structures of M2+(Nitrilotriacetate) complexes

Author

Lien, Nathan R., primary, Timmons, Mitchell A., additional, Belkin, Gloria J.H., additional, Holst, James R., additional, Janzen, Merryn L., additional, Kanthasamy, Ramasubramanian, additional, Lin, Wenjiao, additional, Mubayi, Anamika, additional, Perring, Mathew I., additional, Rupert, Lanell M., additional, Saha, Arindom, additional, Schoenfeldt, Nicholas J., additional, Sokolov, Anatoliy N., additional, and Telford, Jason R., additional

Published
2005
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8. Effects of counter-ion size on solid state structures of M2+(Nitrilotriacetate) complexes

Author

Lien, Nathan R., Timmons, Mitchell A., Belkin, Gloria J.H., Holst, James R., Janzen, Merryn L., Kanthasamy, Ramasubramanian, Lin, Wenjiao, Mubayi, Anamika, Perring, Mathew I., Rupert, Lanell M., Saha, Arindom, Schoenfeldt, Nicholas J., Sokolov, Anatoliy N., and Telford, Jason R.

Subjects
*INTERMEDIATES (Chemistry), *PROPERTIES of matter, *IONS, *METALLURGY
Abstract

Abstract: The crystal structure of Na[Co(NC6H6O6)]·H2O is reported. The structure is compared to similar transition-metal nitrilotriacetate complexes containing different alkali cations and transition metals (Cu2+ and Zn2+). Inner-sphere coordination of the metals is similar, but the arrangement of counter-ions and water molecules in the unit cells vary with the size of the alkali cation. [Copyright &y& Elsevier]

Published
2005
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