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Columnar structures have been exposed by preferential weathering in non-welded, non-vapor-phase-altered zones of the 1.2 to 1.8 Ma Bandelier Tuff ignimbrites around Valles Caldera, New Mexico. These long, largely vertical cylindrical features are similar in composition and texture to the host ignimbrite but represent areas that underwent alteration to make them more resistant to erosion. Analyses show that the column ignimbrite was altered by the addition of the zeolite mordenite as a mineral cement into pore spaces. This, and the presence of illite and, to a lesser extent, chlorite, suggests alteration at ~120–125°C. We map column geometry, spacing, stratigraphic location, and spatial distribution. Columns are mostly vertical, there is a correlation between the diameters and spacing, and they exist in linear to rounded clusters of a few to 30 columns. Based on the location within the ignimbrites, the shape and form of column groups, and the temperature of formation of the columns, we propose that slumping of over-steepened valley walls exposed friable, warm, unaltered ignimbrite that enabled ponded meteoritic water to permeate into the deposit, which allowed localized convective chimney cells to form. We develop an analytical model to show that infiltrating water is convectively unstable, and, for reasonable permeabilities, we can explain the observed column spacing and alteration temperature. This model permits columns to form within parts of the deposits perched in ignimbrite deposited against pre-existing valley walls. An abundant supply of water from high precipitation is implied, reflecting a syn-glacial, pluvial climate in the southwestern United States at that time (1–2 Ma ago).

Late Cretaceous records of environmental change suggest that Deccan Traps (DT) volcanism contributed to the Cretaceous-Paleogene boundary (KPB) ecosystem crisis. However, testing this hypothesis requires identification of the KPB in the DT. We constrain the location of the KPB with high-precision argon-40/argon-39 data to be coincident with changes in the magmatic plumbing system. We also found that the DT did not erupt in three discrete large pulses and that >90% of DT volume erupted in

A few square kilometers of the Bishop Tuff in eastern California (USA) have evenly spaced columns that are more resistant to erosion than the surrounding tuff owing to the precipitation of mordenite, a low-temperature (100-130 °C) zeolite. We hypothesize that the columns are a result of instabilities at the liquid water and steam interface as cold water seeped into the still-cooling Bishop Tuff. We use two methods to quantitatively assess this hypothesis. First, scaling shows which hydrodynamic instabilities exist in the system. Second, to account for the effects of multiphase flow, latent heat, and the finite amplitude and temporal evolution of these instabilities we use two-dimensional numerical models of liquid water infiltrating hot tuff. These tests highlight several features of boiling hydrothermal systems. (1) The geometry of at least some convection appears to be broadly captured by linear stability theory that neglects reactive transport, heterogeneity of the host rock, and the finite amplitude of instabilities. (2) Slopes > 10% set the wavelength of convection, meaning that these columns formed somewhere with relatively gentle topography. (3) For permeabilities of > 10-13 m2, the wavelength of the instability changes through time, slowing infiltration, while for permeabilities < 10-15 m2, cooling is dominated by conduction. The spacing and stability of columns increase with higher vertical permeability and decrease with higher horizontal permeability. These columns are a rare window into hydrothermal processes that may be widespread.

New constraints on the timing of the Cretaceous- Paleogene mass extinction and the Chicxulub impact, together with a particularly voluminous and apparently brief eruptive pulse toward the end of the "main-stage" eruptions of the Deccan continental flood basalt province suggest that these three events may have occurred within less than about a hundred thousand years of each other. Partial melting induced by the Chicxulub event does not provide an energetically plausible explanation for this coincidence, and both geochronologic and magnetic-polarity data show that Deccan volcanism was under way well before Chicxulub/Cretaceous-Paleogene time. However, historical data document that eruptions from existing volcanic systems can be triggered by earthquakes. Seismic modeling of the ground motion due to the Chicxulub impact suggests that the impact could have generated seismic energy densities of order 0.1-1.0 J/m3 throughout the upper ~200 km of Earth's mantle, sufficient to trigger volcanic eruptions worldwide based upon comparison with historical examples. Triggering may have been caused by a transient increase in the effective permeability of the existing deep magmatic system beneath the Deccan province, or mantle plume "head." It is therefore reasonable to hypothesize that the Chicxulub impact might have triggered the enormous Poladpur, Ambenali, and Mahabaleshwar (Wai Subgroup) lava flows, which together may account for >70% of the Deccan Traps main-stage eruptions. This hypothesis is consistent with independent stratigraphic, geochronologic, geochemical, and tectonic constraints, which combine to indicate that at approximately Chicxulub/Cretaceous- Paleogene time, a huge pulse of mantle plume-derived magma passed through the crust with little interaction and erupted to form the most extensive and voluminous lava flows known on Earth. High-precision radioisotopic dating of the main-phase Deccan flood basalt formations may be able either to confirm or reject this hypothesis, which inturn might help to determine whether this singular outburst within the Deccan Traps (and possibly volcanic eruptions worldwide) contributed significantly to the Cretaceous-Paleogene extinction.

Bolide impact and flood volcanism compete as leading candidates for the cause of terminal-Cretaceous mass extinctions. High-precision (40)Ar/(39)Ar data indicate that these two mechanisms may be genetically related, and neither can be considered in isolation. The existing Deccan Traps magmatic system underwent a state shift approximately coincident with the Chicxulub impact and the terminal-Cretaceous mass extinctions, after which ~70% of the Traps' total volume was extruded in more massive and more episodic eruptions. Initiation of this new regime occurred within ~50,000 years of the impact, which is consistent with transient effects of impact-induced seismic energy. Postextinction recovery of marine ecosystems was probably suppressed until after the accelerated volcanism waned.

New magnetostratigraphic data from seven Western Ghats sections in the Deccan Volcanic Province are presented. These are combined with an established geochemically defined stratigraphy, and volcanological logs, to provide a correlated, chronological eruptive framework. We identify two magnetic polarities in five of the sections, and these are assigned to chrons 29r and 29n. Importantly, the reversal boundary represents an identifiable isochronous surface within the volcanic pile. This surface occurs at different elevations, as does the altitude of the geochemically defined formation boundary (i.e. Ambenali-Mahabaleshwar Fms), which defines a second isochronous surface. Inspection reveals significant differences in the number and thickness of lava units preserved between these two surfaces. This indicates that there was significant local topography (c. 80 m) across Deccan Volcanic Province lava fields during their development; an interpretation consistent with topographies observed across modern and historical examples (e.g. Hawaii, Iceland). These data also indicate that the geochemical stratigraphies of continental flood basalt provinces can mask local and sub-regional detail in lava stacking patterns when applied at smaller spatial scales (

Research from biological and geological sources has highlighted the role of volcanoes in the outgassing of P, and thermal fixation and subsequent atmospheric oxidation of N[O.sub.x] in volcanic environments. The impact of these nutrient fluxes on biological systems has been demonstrated on present-day Hawai'i, and here we consider the impact on the plant communities within a large igneous province (LIP). The Miocene Columbia River Basalt Province, the youngest LIP on Earth, contains many sedimentary interbeds between the flows of the major extrusive phase, and these interbeds preserve variable but often diverse palynofloras. By integration of palynofloral analysis with analysis of macronutrient levels in the interbeds it can be suggested that there may have been significantly elevated levels of P within the lava field proximal to the source vents, a distribution mirrored by Ca and Mg. Evidence for potential volcanogenic eutrophication is restricted to >[10.sup.3] year duration interbeds, contemporary with eruptive activity elsewhere in the LIP. The geochemistry and palynology of other interbeds demonstrate nutrient deficiency, with a potential route to nutrient sufficiency available from long-term symbiotic N-fixation. Elsewhere within the Columbia River Basalt Province, this process is short-circuited by the imput of felsic ash from the nearby Cascades Range of volcanoes.

Flood lavas are major geological features on all the major rocky planetary bodies. They provide important insight into the dynamics and chemistry of the interior of these bodies. On the Earth, they appear to be associated with major and mass extinction events. It is therefore not surprising that there has been significant research on flood lavas in recent years. Initial models suggested eruption durations of days and volumetric fluxes of order [10.sup.7] [m.sup.3] [s.sup.-1] with flows moving as turbulent floods. However, our understanding of how lava flows can be emplaced under an insulating crust was revolutionized by the observations of actively inflating pahoehoe flows in Hawaii. These new ideas led to the hypothesis that flood lavas were emplaced over many years with eruption rates of the order of [10.sup.7] [m.sup.3] [s.sup.-1]. The field evidence indicates that flood lava flows in the Columbia River Basalts, Deccan Traps, Etendeka lavas, and the Kerguelen Plateau were emplaced as inflated pahoehoe sheet flows. This was reinforced by the observation of active lava flows of [greater than or equal to] 100 km length on Io being formed as tube-fed flows fed by moderate eruption rates ([10.sup.2] [10.sup.3] [m.sup.3] [s.sup.-1]). More recently it has been found that some flood lavas are also emplaced in a more rapid manner. New high-resolution images from Mars revealed 'platy-ridged' flood lava flows, named after the large rafted plates and ridges formed by compression of the flow top. A search for appropriate terrestrial analogues found an excellent example in Iceland: the 1783-1784 Laki Flow Field. The brecciated Laki flow top consists of pieces of pahoehoe, not aa clinker, leading us to call this 'rubbly pahoehoe'. Similar flows have been found in the Columbia River Basalts and the Kerguelen Plateau. We hypothesize that these flows form with a thick, insulating, but mobile crust, which is disrupted when surges in the erupted flux are too large to maintain the normal pahoehoe mode of emplacement. Flood lavas emplaced in this manner could have (intermittently) reached effusion rates of the order of [10.sup.6] [m.sup.3] [s.sup.-1]