1. Polarized radiative transfer through terrestrial atmosphere accounting for rotational Raman scattering.
- Author
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Lelli, Luca, Rozanov, Vladimir V., Vountas, Marco, and Burrows, John P.
- Subjects
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ATMOSPHERIC aerosols spectra , *RADIATIVE transfer equation , *ICE crystals , *RAMAN scattering , *LINEAR polarization , *FRAUNHOFER diffraction - Abstract
This paper is devoted to the phenomenological derivation of the vector radiative transfer equation (VRTE) accounting for first-order source terms of rotational Raman scattering (RRS), which is responsible for the in-filling of Fraunhofer and telluric lines by inelastic scattered photons. The implementation of the solution of the VRTE within the framework of the forward-adjoint method is given. For the Ca II and the oxygen A-band (O 2 A) spectral windows, values of reflectance, degree of linear polarization (DOLP) and in-filling, in zenith and nadir geometry, are compared with results given in literature. Moreover, the dependence of these quantities on the columnar loading and vertical layering of non-spherical dust aerosols is investigated, together with their changes as function of two habits of ice crystals, modeled as regular icosahedra and severely rough aggregated columns. Bi-directional effects of an underlying polarizing surface are accounted for. The forward simulations are performed for one selected wavelength in the continuum and one in the strong absorption of the O 2 A, as their combination can be exploited for the spaceborne retrieval of aerosol and cloud properties. For this reason, we also mimic seasonal maps of reflectance, DOLP and in-filling, that are prototypical measurements of the Ultraviolet-Visible-Near Infrared (UVN) sensor, at a nominal spectral resolution of 0.12 nm. UVN is the core payload of the upcoming European Sentinel-4 mission, that will observe Europe in geostationary orbit for air quality monitoring purposes. In general, in the core of O 2 A, depending on the optical thickness and altitude of the scatterers, we find RRS-induced in-filling values ranging from 1.3% to 1.8%, while DOLP decreases by 1%. Conversely, while negligible differences of RRS in-filling are calculated with different ice crystal habits, the severely rough aggregated column model can reduce DOLP by a factor up to 10%. The UVN maps of in-filling show values varying between 1% and 8%. These changes are mainly driven by surface type and seasonal observational geometry. However, accounting for RRS, differences in DOLP do not exceed ± 0.2% within the full instrumental field-of-view. [ABSTRACT FROM AUTHOR]
- Published
- 2017
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