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There is no doubt that the topic of legacy of sport events is becoming one of the critical issues in professional sports worldwide. Taxpayers’ money is used to support the staging of events and the...

Catechols are prone to oxidative polymerization as well as complex formation with metal ions. These two features of catechols have played an important role in the construction of functional films on various surfaces. For example, marine antifouling films and antibacterial films were successfully prepared by oxidative polymerization and metal complexation of catechol-containing molecules, respectively. However, the effect of simultaneous metal complexation and oxidative polymerization on functional film formation has not yet been fully investigated. Herein, as a derivative of 3-(3,4-dihydroxyphenyl)-l-alanine (DOPA), we synthesized an ethylene glycol-derivatized DOPA (OEG-DOPA) and formed OEG-DOPA thin films based on (1) oxidative polymerization and (2) the complexation between catechol groups of OEG-DOPA and iron(III) (FeIII) ions. Either or both approaches were used for the film formation. OEG-DOPA film formation was characterized by ellipsometry, contact angle goniometry, field emission scanning electron microscopy, and X-ray photoelectron spectroscopy. Among the conditions used, the formation of a uniform film was only achieved with the dual cross-linking system of FeIII complexation and oxidation-induced covalent bond formation. Compared to the uncoated substrate and other OEG-DOPA films prepared under different conditions, the uniform OEG-DOPA film strongly inhibited bacterial adhesion, showing excellent antibacterial capability. We think that our surface-coating strategy can be applied to medical devices, tools, and implants where bacterial adhesion and biofilm formation should be prevented. This work can also serve as a basis for the construction of functional thin films for other catechol-functionalized materials.

Playing with a soccer ball is not easy even for a real human because of dynamic foot contacts with the moving ball while chasing and controlling it. The problem of online full-body soccer motion synthesis is challenging and has not been fully solved yet. In this paper, we present a novel motion control system that produces physically-correct full-body soccer motions: dribbling forward, dribbling to the side, and shooting, in response to an online user motion prescription specified by a motion type, a running speed, and a turning angle. This system performs two tightly-coupled tasks: data-driven motion prediction and physics-based motion synthesis. Given example motion data, the former synthesizes a reference motion in accordance with an online user input and further refines the motion to make the character kick the ball at a right time and place. Provided with the reference motion, the latter then adopts a Model Predictive Control (MPC) framework to generate a physically-correct soccer motion, by solving an optimal control problem that is formulated based on dynamics for a full-body character and the moving ball together with their interactions. Our demonstration shows the effectiveness of the proposed system that synthesizes convincing full-body soccer motions in various scenarios such as adjusting the desired running speed of the character, changing the velocity and the mass of the ball, and maintaining balance against external forces.

Even though South Korea’s universal health care system was established in 1989, many South Koreans continue to encounter obstacles in their attempts to access health care. Previous studies have not investigated the relationship between health care access and utilization and perceived health in the context of a universal health care system that implements a mandatory social health insurance policy. The objective of this study was to evaluate the influence of health care access and use of preventive health care services on self-rated health among young and middle-aged adults in Korea. The sample consisted of 1242 young adults aged 20–39 years and 2389 middle-aged adults aged 40–64 years who had participated in the cross-sectional 2015 Korea National Health and Nutrition Examination Survey. Using multiple logistic regression analysis, the association between health care access and use of preventive health care services and perceived poor health among young adults and middle-aged adults was assessed. The main finding was that a history of unmet health care requirements during the past 12 months was strongly associated with fair and poor self-rated health, especially among young adults. Additionally, middle-aged adults who had attended medical check-ups during the preceding 2 years reported poorer self-rated health. This study’s findings suggest that, despite South Korea’s universal public insurance system, there remains the need to improve access to health care services, especially among young adults. As a health improvement strategy, it is imperative that measures be taken to promote the availability of health care services when they are required and to solve any of the various individual accessibility problems, such as cost, particularly with young adults in mind.

We synthesized a zwitterionic dopamine derivative ( ZW-DOPA) containing both catechol and amine groups, and we demonstrated an excellent marine antifouling surface by controlling the oxidation of ZW-DOPA. The oxidation was mediated by the deprotonation of catechol or the addition of an oxidant (ammonium persulfate (AP) or sodium periodate (NaIO4)). The oxidation and subsequent molecular transformation of ZW-DOPA was investigated over time by UV-vis spectroscopy. Among the different oxidation conditions tested, NaIO4-induced ZW-DOPA coating was the most efficient and successfully formed on various substrates, such as titanium dioxide, stainless steel, and nylon. Compared with uncoated substrates, ZW-DOPA-coated substrates showed high resistance to marine diatom adhesion. Considering the ease of use and substrate independence of the ZW-DOPA coating, this method shows promise as a basis for inhibiting marine fouling on a variety of substrates used in the marine industry and aquatic environments.

We present SketchiMo, a novel approach for the expressive editing of articulated character motion. SketchiMo solves for the motion given a set of projective constraints that relate the sketch inputs to the unknown 3 D poses. We introduce the concept of sketch space, a contextual geometric representation of sketch targets---motion properties that are editable via sketch input---that enhances, right on the viewport, different aspects of the motion. The combination of the proposed sketch targets and space allows for seamless editing of a wide range of properties, from simple joint trajectories to local parent-child spatiotemporal relationships and more abstract properties such as coordinated motions. This is made possible by interpreting the user's input through a new sketch-based optimization engine in a uniform way. In addition, our view-dependent sketch space also serves the purpose of disambiguating the user inputs by visualizing their range of effect and transparently defining the necessary constraints to set the temporal boundaries for the optimization.

In the paper, we present an online real-time method for automatically transforming a basic locomotive motion to a desired motion of the same type, based on biomechanical results. Given an online request for a motion of a certain type with desired moving speed and turning angle, our method first extracts a basic motion of the same type from a motion graph, and then transforms it to achieve the desired moving speed and turning angle by exploiting the following biomechanical observations: contact-driven center-of-mass control, anticipatory reorientation of upper body segments, moving speed adjustment, and whole-body leaning. Exploiting these observations, we propose a simple but effective method to add physical and behavioral naturalness to the resulting locomotive motions without preprocessing. Through experiments, we show that our method enables a character to respond agilely to online user commands while efficiently generating walking, jogging, and running motions with a compact motion library. Our method can also deal with certain dynamical motions such as forward roll. Copyright © 2016 John Wiley & Sons, Ltd.

Direct patterning of streptavidin and NIH 3T3 fibroblast cells was successfully achieved over a large-area pristine graphene sheet on Si/SiO2 by aryl azide-based photografting with the conventional UV lithographic technique and surface-initiated, atom transfer radical polymerization of oligo(ethylene glycol) methacrylate.

Numerous coating strategies are available to control the surface properties and confer new properties to substrates for applications in energy, environment, biosystems, etc., but most have the intrinsic limitations in the practical setting: (1) highly specific interactions between coating materials and target surfaces are required for stable and durable coating; (2) the coating of bulk substrates, such as fruits, is time-consuming or is not achievable in the conventional solution-based coating. In this respect, material-independent and rapid coating strategies are highly demanded. We demonstrate spray-assisted nanocoating of supramolecular metal-organic complexes of tannic acid and ferric ions. The spray coating developed is material-independent and extremely rapid (

We designed a perfluorinated dopamine derivative, which, upon oxidative polymerization, formed a structurally rough film of extremely low surface energy on various substrates. The static water contact angles larger than 150° and the low water sliding angles less than 7° confirmed the formation of superhydrophobic, self-cleaning surfaces.

Inspired by the iron gall ink that has been used since the Middle Ages, we formulated a hair-dyeing solution for blackening hair. The ingredients in the formulation have been approved as cosmetic ingredients, including tannic acid, gallic acid, and Fe(d-gluconate)2. The formulation does not require any harmful oxidizing agents, such as hydrogen peroxide&mdash, the Fe(II) cations bound to tannins are oxidized spontaneously upon exposure to air and form the blackish Fe(III)-tannin nanocomplex that coats hair firmly. In our study, we show that the dyed color did not fade under sunlight exposure for at least three months and after shampooing. This natural formulation for black hair-dyeing can have great impact in the hair cosmetic industry.

In this paper, carbamate-based self-assembled monolayers (SAMs) of alkanethiolates on gold were suggested as a versatile platform for release of amine-bearing molecules in response to the electrical signal. The designed SAMs underwent the electrochemical oxidation on the gold surface with simultaneous release of the amine molecules. The synthesis of the thiol compounds was achieved by coupling isocyanate-containing compounds with hydroquinone. The electroactive thiol was mixed with 11-mercaptoundecanol [HS(CH(2))(11)OH] to form a mixed monolayer, and cyclic votammetry was used for the characterization of the release behaviors. The mixed SAMs showed a first oxidation peak at +540 mV (versus Ag/AgCl reference electrode), indicating the irreversible conversion from carbamate to hydroquinone groups with simultaneous release of the amine molecules. The analysis of ToF-SIMS further indicated that the electrochemical reaction on the gold surface successfully released amine molecules.

We developed the educational purpose mobile application, named “Wild Flowers of Bukhansan National Park (version 1.0)”, aiming for easy identification of wildflowers for students and visitors in the park. When visitors find a flower or part of plant in the park, visitors can search for its name utilizing the pictures and characters provided in their own smartphone mobile devices or tablet PCs. The application provides pictures of wildflowers in the park and character-based searching system based on 12 diagnostic features (e.g., growth form, leaf arrangement, flower symmetry, petal color, petal number, sepal number, etc). We adopted the complete floristic survey of Chung and Lee (1962) and added species that we confirmed their distribution in the park during the development of this application. In summary, number of vascular plants in this park was estimated to be 428 taxa including 100 families, 280 genera, 327 species, 1 subspecies, 50 varieties, and 5 formas. We provided a total of 588 pictures representing 358 taxa and each taxon includes multiple pictures in many cases. Included identification quizzes can be an efficient educational tool as well as fun activity for students and visitors who are learning plant species in Korea. Our next step will include GPS function in the application for indicating visitor's location and for providing previously reported sites of the species that we interested in the map of the park. The future application which includes GPS function will be a valuable tool for the monitoring of rare plants, plant researches related to the climate changes, etc. We currently provide Korean iPhone version only, and English version and both of android versions will be serviced soon.

Using finite element analysis, this paper extends elastic stress solutions for 90° pipe elbows under in-plane bending, given in Marie et al. (2007) [1] , to cases of mean pipe radius-to-thickness ratio up to 50. It is found that for 90° elbows an in-plane bending moment produces not only an axial membrane stress component but also axial and hoop bending stress components. Furthermore, the magnitudes of these stress components depend strongly on the mean radius-to-thickness ratio, the circumferential location and the longitudinal location. Maximum stresses tend to occur in the centre of the elbow at or near the crown.

This paper presents closed-form approximations to elastic stresses in thick- and thin-walled elbows with attached straight pipes under internal pressure, based on three-dimensional elastic finite element analysis. Elastic stresses in the centre of an elbow are found to be close to an existing closed-form solution, suggesting that the hoop stress varies with the longitudinal position. The FE results indicate that the hoop stress varies linearly with the longitudinal position. Moreover, stresses in the junction of an elbow and straight pipe are shown to be the average of those in the centre of the elbow and in the straight pipe.

Solid-fuel conversion or gasification study of sewage sludge and energy recovery has become increasingly important because energy recovery and climate change are emerging issues. Various types of catalysts, such as dolomite, steel slag and calcium oxide, were tested for tar reduction during the sewage sludge gasification process. For the experiments on sewage sludge gasification reactions and tar reduction using the catalysts, a fixed bed of laboratory-scale experimental apparatus was set up. The reactor was made of quartz glass using an electric muffle furnace. The sewage sludge samples used had moisture contents less than 6%. The experimental conditions were as follows: sample weight was 20 g and reaction time was 10 min, gasification reaction temperature was from 600 to 800°C, and the equivalence ratio was 0.2. The quantity of catalysts was 2–6 g, and temperatures of catalyst layers were 500–700°C. As the reaction temperature increased up to 800°C, the yields of gaseous products and liquid products increased, whereas char and tar products decreased, showing effects on gas product compositions. These results were considered to be due to the increase of the water-gas reaction and Boudouard reaction. In the case of experiments with catalysts, dolomite (4 g), steel slag (6 g) and calcium oxide (6 g) were used. When the temperature of catalysts increased, the weight of the tar produced decreased with different cracking performances by different catalysts. Reforming reactions were considered to occur on the surface of dolomite, steel slag and calcium oxide, causing cracking of the hydrocarbon structure, which eventually showed reduced tar generation.

This paper quantifies the effect of internal pressure on plastic loads for elbows with circumferential through-wall and constant-depth part-through surface cracks under in-plane bending. Results are based on FE limit analyses using elastic–perfectly plastic materials and the non-linear geometry option. It is found that, for larger values of r / t , the pressure effect on plastic loads is more pronounced and plastic loads for combined loading cases could be much higher than those for pure bending cases. Full FE data of plastic loads are tabulated, and effects of crack geometries on interaction curves are discussed.

This paper provides approximate limit pressure solutions for circumferential cracked elbows, resulting from small strain finite element limit analyses using elastic–perfectly plastic materials. Circumferential through-wall and constant-depth surface cracks of which the circumferential lengths are limited to 50% of the circumference are considered. Two locations along the longitudinal direction are considered; one in the centre of the elbow, and the other in the junction between the elbow and the attached straight pipe. Along the circumference, either extrados or intrados cracks are considered. It is found that limit pressures of circumferential cracked elbows are not affected by the presence of the circumferential surface crack, unless it is sufficiently deep and long. Moreover, normalized limit pressures with respect to un-cracked limit pressures decrease almost linearly with increasing the relative crack depth and length. Based on finite element results, approximate closed-form solutions for limit pressures are proposed.

This paper provides closed-form plastic limit load solutions for elbows under in-plane bending and internal pressure, via three-dimensional (3D), geometrically linear FE limit analyses using elastic-perfectly plastic materials. Wide ranges of elbow and thinning geometries are considered. To investigate the effect of the axial thinning length on limit loads systematically, two limiting cases are considered; a sufficiently long thinning, and the circumferential part-through surface crack. Closed-form plastic limit load solutions for wall thinning with intermediate longitudinal extents are then obtained from these two limiting cases. The effect of the axial extent of wall thinning on plastic limit loads for elbows is highlighted by comparing that for straight pipes. Although the proposed solutions are developed for the case when wall thinning exists in the center of elbows, it is also shown that they can be applied to the case when thinning exists anywhere within the elbow.

This paper provides closed-form plastic limit load solutions for elbows with local wall thinning under in-plane bending, via three-dimensional (3-D), small strain FE limit analyses using elastic-perfectly plastic materials. Wide ranges of elbow and thinning geometries are considered.

This paper proposes closed-form plastic limit load solutions for elbows under in-plane bending, via three-dimensional (3-D), small strain FE limit analyses using elastic-perfectly plastic materials. A wide range of elbow and thinning geometries are considered. For systematic analyses of the effect of the axial thinning length on limit loads, two limiting cases are considered; a sufficiently long wall thinning, and the circumferential part-through surface crack. Closed-form plastic limit load solutions for wall thinning with intermediate longitudinal extents are then obtained from these two limiting cases. The effect of the axial extent of wall thinning on plastic limit loads for elbows is highlighted by comparing that for straight pipes. Although the proposed solutions are developed for the case when wall thinning exists in the center of elbows, it is also shown that they can be applied to the case when wall thinning exists anywhere within the elbow.

Although the programmed degradation of biocompatible films finds applications in various fields including biomedical and bionanotechnological areas, coating methods have generally been limited to be substrate-specific, not applicable to any kinds of substrates. In this paper, we report a dopamine derivative, which allows for both universal coating of various substrates and stimuli-responsive film degradation, inspired by mussel-adhesive proteins. Two dopamine moieties are linked together by the disulfide bond, the cleavage of which enables the programmed film degradation. Mechanistic analysis of the degradable films indicates that the initial cleavage of the disulfide linkage causes rapid uptake of water molecules, hydrating the films, which leads to rapid degradation. Our substrate-independent coating of degradable films provides an advanced tool for drug delivery systems, tissue engineering, and anti-fouling strategies.

The posttranslational modification of neural cell-adhesion molecule (NCAM) with polysialic acid (PSA) and the spatiotemporal distribution of PSA-NCAM play an important role in the neuronal development. In this work, we developed a tissue-based strategy for metabolically incorporating an unnatural monosaccharide, peracetylated N-azidoacetyl-d-mannosamine, in the sialic acid biochemical pathway to present N-azidoacetyl sialic acid to PSA-NCAM. Although significant neurotoxicity was observed in the conventional metabolic labeling that used the dissociated neuron cells, neurotoxicity disappeared in this modified strategy, allowing for investigation of the temporal and spatial distributions of PSA in the primary hippocampal neurons. PSA-NCAM was synthesized and recycled continuously during neuronal development, and the two-color labeling showed that newly synthesized PSA-NCAMs were transported and inserted mainly to the growing neurites and not significantly to the cell body. This report suggests a reliable and cytocompatible method for in vitro analysis of glycans complementary to the conventional cell-based metabolic labeling for chemical glycobiology.

In conclusion, we demonstrated that SI-ATRP could be utilized for generating CNT/glycopolymer hybrid nanocomposites. As a proof-of-concept, we grafted MAIpGlc, a monomer that carries protected glucose ring, onto s-MWCNTs. After coating s-MWCNTs with pMAIpGlc, the MAIpGlc moiety was deprotected to extrude the glucose group onto the surface of s-MWCNTs. LAMA (and its derivatives) would have advantages over MAIpGlc, because various monosaccharides and a sequence of saccharides could be incorporated into the polymer backbone and polymerization does not need protection/deprotection steps. Considering the biological importance of polysaccharides, the method described herein would be beneficial in many areas, such as pathogen detection and biosensors.

We present a novel approach for synthesizing human gait motions according to a range of input ages by transforming a given motion based on biomechanical observations. Given an original motion, our method first extracts gait cycles that are periodically defined by foot contact on the ground and then transforms the original motion to achieve a desirable posture and motions that respectively correspond to the input age. Among many biomechanical features that gradually change with aging, we mainly focus on spatiotemporal and kinematic features as well as postural changes. Exploiting these features, we formulate the biomechanical changes as continuous functions that reflect visually significant features corresponding to the input age. Finally, we demonstrate that our system can automatically generate plausible gait motions given a wide range of input ages.

The chemical control of cell division has attracted much attention in the areas of single cell-based biology and high-throughput screening platforms. A mussel-inspired cytocompatible encapsulation method for achieving a "cell-division control" with cross-linked layer-by-layer (LbL) shells is developed. Catechol-grafted polyethyleneimine and hyaluronic acid are chosen as polyelectrolytes for the LbL process, and the cross-linking of polyelectrolytes is performed at pH 8.5. Cell division is controlled by the number of the LbL nanolayers and cross-linking reaction. We also suggest a new measuring unit, t-2.0 OD 600, for quantifying "cell-division timing" based on microbial growth kinetics.

This paper provides closed-form plastic limit load solutions for elbows with local wall thinning under in-plane bending, via three-dimensional (3-D), small strain FE limit analyses using elastic-perfectly plastic materials. Wide ranges of elbow and thinning geometries are considered.