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In recent years, nocturnal ozone enhancement (NOE) events have emerged as a prominent research focus in the field of the atmospheric environment. By using statistical analysis methods, we conducted a comparative investigation of nocturnal ozone concentrations and NOE events in Dongying, the central city of the Yellow River Delta, China, in 2022 and 2023, and further explored the effects of NOE events on O3 and PM2.5 on the same night and the subsequent day. The results showed that from 2022 to 2023, in Dongying, the annual average nocturnal ozone concentrations increased from 51 μg/m3 to 59 μg/m3, and the frequency of NOE events was higher in the spring, summer, and autumn, and lower in the winter. The NOE events not only exhibited promoting effects on nocturnal O3 and Ox, and on the daily maximum 8 h average concentration of O3 (MDA8-O3) on the same day (comparatively noticeable in summer and autumn), but also demonstrated a clear impact on nocturnal PM2.5 and PM2.5-bounded NO3− and SO42− (especially in winter). Additionally, the NOE events also led to higher concentrations of O3 and Ox, as well as higher MDA8-O3 levels during the subsequent day, with more observable impacts in the summer. The results could strengthen our understanding about NOE events and provide a scientific basis for the collaborative control of PM2.5 and O3 in urban areas in the Yellow River Delta in China. [ABSTRACT FROM AUTHOR]

In order to investigate the causes of complex air pollution in coastal cities in the Bohai Rim of China, a one-month intensive field observation combined with model simulation was carried out in a typical city named Dongying in September 2022. The results showed that two PM2.5 and O3 complex pollution episodes occurred in Dongying in the observation period, with the primary pollutant being O3. Atmospheric photochemical reactions occurring under unfavorable meteorological conditions led to the production of O3 while at the same time facilitating the generation of nitrate, sulfate, and other secondary components of PM2.5 by enhancing the atmospheric oxidizing capacity, which promoted the formation of complex air pollution. It was worth noting that in the context of high pollutants emission, the occurrence of complex air pollution was more sensitive to the variation in meteorological conditions than to the change in pollutants emission. To continuously improve air quality and protect human health in Dongying, it is recommended that an effective regional joint air pollution prevention and control mechanism with neighboring cities should be established in the premise of effective local pollutants reduction, and special attention should be paid to the adverse effect of the air mass transportation from Bohai Bay. [ABSTRACT FROM AUTHOR]

In this work, aluminum and iron existing in coal fly ash were extracted by the method of hydrochloric acid leaching. Effects of solid-liquid ratio, reaction temperature, reaction time, acid concentration, and raw ash mesh on recovery efficiencies of Al2O3 and Fe2O3 were investigated. X-ray diffraction analysis indicated that anhydrite, hematite, mullite and quartz were the dominant minerals in the raw fly ash sample. X-ray fluorescence technique was applied to determine the mass fractions of chemical components in the raw ash and leached residues, while the concentrations of Al2O3 and Fe2O3 in leaching solutions were measured by titration method. The optimal recovery efficiencies of Al2O3 and Fe2O3, obtained under the reaction condition of 95°C, 5 h, acid concentration of 20 wt.%, a solid-liquid ratio of 1:3.5 and raw ash mesh of 400, were 42.75% and 35.10%, respectively. After removing the leached residues, the leaching solutions were employed to manufacture flocculants of polymeric aluminum ferric chloride for treating the oil recovery wastewater from polymer flooding, which possessed high contents of suspended solids (SS) and oils. Microfiltration membrane and ultraviolet spectrophotometer were utilized to determine the contents of SS and oils in water samples. Through adjusting Al/Fe molar ratio to 20:1 and basicity to 70%, the maximum removing efficiencies of SS and oils can be achieved, respectively 96.1% and 91.5%. Moreover, increasing the iron content and basicity of flocculants within certain ranges contributed to improving the settling characteristic of flocs. [ABSTRACT FROM AUTHOR]