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High-spin states in molecular systems hold significant interest for a wide range of applications ranging from optoelectronics to quantum information and singlet fission (SF). Quintet and triplet states play crucial roles, particularly in SF systems, necessitating a precise monitoring and control of their spin dynamics. Spin states in intramolecular SF (iSF) are of particular interest, but tuning these systems to control triplet multiplication pathways has not been extensively studied. Additionally, whilst studies in this context focus on participation of triplet pathways leading to photoluminescence, emission pathways via quintet states remain largely unexplored. Here, we employ a set of unique spin-sensitive techniques to investigate high-spin state formation and emission in dimers and trimers comprising multiple diphenylhexatriene (DPH) units. We demonstrate the formation of pure quintet states in all these oligomers, with optical emission via quintet states dominating delayed fluorescence up to room temperature. For triplet formation, we distinguish between SF and ISC pathways, identifying the trimer Me-(DPH)$_3$ as the only oligomer exhibiting exclusively the desired SF pathways. Conversely, linear (DPH)$_3$ and (DPH)$_2$ show additional or exclusive triplet pathways via ISC. Our comprehensive analysis provides a detailed investigation into high-spin state formation, control, and emission in intramolecular singlet fission systems.

The impacts of climate change are intensifying existing vulnerabilities and disparities within urban communities around the globe, as extreme weather events, including floods and heatwaves, are becoming more frequent and severe, disproportionately affecting low-income and underrepresented groups. Tackling these increasing challenges requires novel approaches that integrate expertise across multiple domains, including computer science, engineering, climate science, and public health. Urban computing can play a pivotal role in these efforts by integrating data from multiple sources to support decision-making and provide actionable insights into weather patterns, infrastructure weaknesses, and population vulnerabilities. However, the capacity to leverage technological advancements varies significantly between the Global South and Global North. In this paper, we present two multiyear, multidisciplinary projects situated in Chicago, USA and Niter\'oi, Brazil, highlighting the opportunities and limitations of urban computing in these diverse contexts. Reflecting on our experiences, we then discuss the essential requirements, as well as existing gaps, for visual analytics tools that facilitate the understanding and mitigation of climate-related risks in urban environments., Comment: Accepted at the Viz4Climate + Sustainability: IEEE VIS 2024 Workshop on Visualization for Climate Action and Sustainability (https://svs.gsfc.nasa.gov/events/2024/Viz4ClimateAndSustainability/)

This paper explores the critical issue of enhancing cybersecurity measures for low-cost, Wi-Fi-based Unmanned Aerial Vehicles (UAVs) against Distributed Denial of Service (DDoS) attacks. In the current work, we have explored three variants of DDoS attacks, namely Transmission Control Protocol (TCP), Internet Control Message Protocol (ICMP), and TCP + ICMP flooding attacks, and developed a detection mechanism that runs on the companion computer of the UAV system. As a part of the detection mechanism, we have evaluated various machine learning, and deep learning algorithms, such as XGBoost, Isolation Forest, Long Short-Term Memory (LSTM), Bidirectional-LSTM (Bi-LSTM), LSTM with attention, Bi-LSTM with attention, and Time Series Transformer (TST) in terms of various classification metrics. Our evaluation reveals that algorithms with attention mechanisms outperform their counterparts in general, and TST stands out as the most efficient model with a run time of 0.1 seconds. TST has demonstrated an F1 score of 0.999, 0.997, and 0.943 for TCP, ICMP, and TCP + ICMP flooding attacks respectively. In this work, we present the necessary steps required to build an on-board DDoS detection mechanism. Further, we also present the ablation study to identify the best TST hyperparameters for DDoS detection, and we have also underscored the advantage of adapting learnable positional embeddings in TST for DDoS detection with an improvement in F1 score from 0.94 to 0.99.

Real-world misinformation, often multimodal, can be partially or fully factual but misleading using diverse tactics like conflating correlation with causation. Such misinformation is severely understudied, challenging to address, and harms various social domains, particularly on social media, where it can spread rapidly. High-quality and timely correction of misinformation that identifies and explains its (in)accuracies effectively reduces false beliefs. Despite the wide acceptance of manual correction, it is difficult to be timely and scalable. While LLMs have versatile capabilities that could accelerate misinformation correction, they struggle due to a lack of recent information, a tendency to produce false content, and limitations in addressing multimodal information. We propose MUSE, an LLM augmented with access to and credibility evaluation of up-to-date information. By retrieving evidence as refutations or supporting context, MUSE identifies and explains content (in)accuracies with references. It conducts multimodal retrieval and interprets visual content to verify and correct multimodal content. Given the absence of a comprehensive evaluation approach, we propose 13 dimensions of misinformation correction quality. Then, fact-checking experts evaluate responses to social media content that are not presupposed to be misinformation but broadly include (partially) incorrect and correct posts that may (not) be misleading. Results demonstrate MUSE's ability to write high-quality responses to potential misinformation--across modalities, tactics, domains, political leanings, and for information that has not previously been fact-checked online--within minutes of its appearance on social media. Overall, MUSE outperforms GPT-4 by 37% and even high-quality responses from laypeople by 29%. Our work provides a general methodological and evaluative framework to correct misinformation at scale., Comment: 50 pages

Navigating certain communication situations can be challenging due to individuals' lack of skills and the interference of strong emotions. However, effective learning opportunities are rarely accessible. In this work, we conduct a human-centered study that uses language models to simulate bespoke communication training and provide just-in-time feedback to support the practice and learning of interpersonal effectiveness skills. We apply the interpersonal effectiveness framework from Dialectical Behavioral Therapy (DBT), DEAR MAN, which focuses on both conversational and emotional skills. We present IMBUE, an interactive training system that provides feedback 25% more similar to experts' feedback, compared to that generated by GPT-4. IMBUE is the first to focus on communication skills and emotion management simultaneously, incorporate experts' domain knowledge in providing feedback, and be grounded in psychology theory. Through a randomized trial of 86 participants, we find that IMBUE's simulation-only variant significantly improves participants' self-efficacy (up to 17%) and reduces negative emotions (up to 25%). With IMBUE's additional just-in-time feedback, participants demonstrate 17% improvement in skill mastery, along with greater enhancements in self-efficacy (27% more) and reduction of negative emotions (16% more) compared to simulation-only. The improvement in skill mastery is the only measure that is transferred to new and more difficult situations; situation specific training is necessary for improving self-efficacy and emotion reduction.

The emergence of ChatGPT and other large language models (LLMs) has greatly increased interest in utilizing LLMs as therapists to support individuals struggling with mental health challenges. However, due to the lack of systematic studies, our understanding of how LLM therapists behave, i.e., ways in which they respond to clients, is significantly limited. Understanding their behavior across a wide range of clients and situations is crucial to accurately assess their capabilities and limitations in the high-risk setting of mental health, where undesirable behaviors can lead to severe consequences. In this paper, we propose BOLT, a novel computational framework to study the conversational behavior of LLMs when employed as therapists. We develop an in-context learning method to quantitatively measure the behavior of LLMs based on 13 different psychotherapy techniques including reflections, questions, solutions, normalizing, and psychoeducation. Subsequently, we compare the behavior of LLM therapists against that of high- and low-quality human therapy, and study how their behavior can be modulated to better reflect behaviors observed in high-quality therapy. Our analysis of GPT and Llama-variants reveals that these LLMs often resemble behaviors more commonly exhibited in low-quality therapy rather than high-quality therapy, such as offering a higher degree of problem-solving advice when clients share emotions, which is against typical recommendations. At the same time, unlike low-quality therapy, LLMs reflect significantly more upon clients' needs and strengths. Our analysis framework suggests that despite the ability of LLMs to generate anecdotal examples that appear similar to human therapists, LLM therapists are currently not fully consistent with high-quality care, and thus require additional research to ensure quality care.

Self-guided mental health interventions, such as "do-it-yourself" tools to learn and practice coping strategies, show great promise to improve access to mental health care. However, these interventions are often cognitively demanding and emotionally triggering, creating accessibility barriers that limit their wide-scale implementation and adoption. In this paper, we study how human-language model interaction can support self-guided mental health interventions. We take cognitive restructuring, an evidence-based therapeutic technique to overcome negative thinking, as a case study. In an IRB-approved randomized field study on a large mental health website with 15,531 participants, we design and evaluate a system that uses language models to support people through various steps of cognitive restructuring. Our findings reveal that our system positively impacts emotional intensity for 67% of participants and helps 65% overcome negative thoughts. Although adolescents report relatively worse outcomes, we find that tailored interventions that simplify language model generations improve overall effectiveness and equity., Comment: CHI 2024 Camera Ready

Agency, the capacity to proactively shape events, is central to how humans interact and collaborate. While LLMs are being developed to simulate human behavior and serve as human-like agents, little attention has been given to the Agency that these models should possess in order to proactively manage the direction of interaction and collaboration. In this paper, we investigate Agency as a desirable function of LLMs, and how it can be measured and managed. We build on social-cognitive theory to develop a framework of features through which Agency is expressed in dialogue - indicating what you intend to do (Intentionality), motivating your intentions (Motivation), having self-belief in intentions (Self-Efficacy), and being able to self-adjust (Self-Regulation). We collect a new dataset of 83 human-human collaborative interior design conversations containing 908 conversational snippets annotated for Agency features. Using this dataset, we develop methods for measuring Agency of LLMs. Automatic and human evaluations show that models that manifest features associated with high Intentionality, Motivation, Self-Efficacy, and Self-Regulation are more likely to be perceived as strongly agentive., Comment: EACL 2024

A proven therapeutic technique to overcome negative thoughts is to replace them with a more hopeful "reframed thought." Although therapy can help people practice and learn this Cognitive Reframing of Negative Thoughts, clinician shortages and mental health stigma commonly limit people's access to therapy. In this paper, we conduct a human-centered study of how language models may assist people in reframing negative thoughts. Based on psychology literature, we define a framework of seven linguistic attributes that can be used to reframe a thought. We develop automated metrics to measure these attributes and validate them with expert judgements from mental health practitioners. We collect a dataset of 600 situations, thoughts and reframes from practitioners and use it to train a retrieval-enhanced in-context learning model that effectively generates reframed thoughts and controls their linguistic attributes. To investigate what constitutes a "high-quality" reframe, we conduct an IRB-approved randomized field study on a large mental health website with over 2,000 participants. Amongst other findings, we show that people prefer highly empathic or specific reframes, as opposed to reframes that are overly positive. Our findings provide key implications for the use of LMs to assist people in overcoming negative thoughts., Comment: Accepted for publication at ACL 2023

Visible Light Communication (VLC) systems have relatively higher security compared with traditional Radio Frequency (RF) channels due to line-of-sight (LOS) propagation. However, they still are susceptible to eavesdropping. The proposed solution of the papers have been built on existing work on hyperchaos-based security measure to increase physical layer security from eavesdroppers. A fourth-order Henon map is used to scramble the constellation diagrams of the transmitted signals. The scramblers change the constellation symbol of the system using a key. That key on the receiver side de-scrambles the received data. The presented modulation scheme takes advantage of a higher degree of the map to isolate the data transmission to a single dimension, allowing for better scrambling and synchronization. A sliding mode controller is used at the receiver in a master-slave configuration for projective synchronization of the two Henon maps, which helps de-scramble the received data. The data is only isolated for the users aware of the key for synchronization, providing security against eavesdroppers. The proposed VLC system is compared against various existing approaches based on various metrics. An improved Bit Error Rate and a lower information leakage are achieved for a variety of modulation schemes at an acceptable Signal-to-Noise Ratio.