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ZnO/Cu2S nanotube arrays are fabricated firstly by a facile and capping-agent-free method, and the photo-electrochemical performance has been studied systematically. The results show that ZnO/Cu2S nanotube arrays achieve enhanced photo-electrochemical water splitting performance and the photocurrent densities of ZnO/Cu2S are 7.9 times than that of ZnO at 0 V versus Ag/AgCl. The performance of the ZnO/Cu2S nanotube arrays can be adjusted by changing the amount of Cu2S microcrystals. The results confirm that the enhanced photo-electrochemical performance of ZnO/Cu2S is due to the significantly improved visible light absorption, effective separation of photo-induced carriers due to the well band energy match and the formed p-n junction between ZnO and Cu2S.

Tandem Diels-Alder reactions of masked porphyrindienes (i.e., sulfolenoporphyrins) with benzoquinones and stilbenes, followed by aromatization, have been developed to load porphyrin with mixed annulation units (i.e., terphenyl and naphthoquinone), furnishing the low-symmetry π-extended porphyrins (

Aeolian process is the most active and extensive contemporary geomorphological process on the Mars, bearing rich information on surface processes, environment and evolution history. High-resolution remote sensing images covering the whole planet are interpreted and processed by GIS software to analyze the morphological characteristics of the Martian dunes on global basis, and discuss their aeolian geomorphological implications. A tentative dune classification scheme is proposed for the Mars. Dunes types on the Mars mainly include sand sheet, dome dune, barchan, barchanoid ridge, transverse ridge, linear ridges, seif dune, raked linear dune, nail dune, square dune network, ladder-like dune network, scaled dune network, honeycomb dune network, star dune, and obstacle dune. It is suggested that the Mars shares similar dune types with the Earth to a large extent, but is dominated by simple dune types. Complex and compound dunes are rarely seen on the Mars so that the cumulative probability curves of dune morphological parameters are characterized by a single section. Barchans, barchanoid ridges and transverse ridges are the most popular, but linear dunes that account for about 50% on the Earth only have 10% on the Mars. The simplicity of dune geomorphology on the Mars is also manifested by the small patches of the dune fields the Martian dune-fields. The Martian dunes are generally smaller on the Mars, in contradiction with theoretical inferences that the scale of dunes increases the ratio of particle/air density. The morphological parameters of the Martian dunes are well correlated, similar to the Earth dunes, but the correlationship is different, implying the similar formation mechanism but different development conditions. It is also suggested that the Martian analogues of terrestrial aeolian landforms, such as those found on the Tibetan Plateau, are good examples to study the Martian aeolian geomorphology. The simplicity of dune geomorphology on the Mars probably suggests that dunes on the Mars are developed with insufficient sediment availability and short development history. Inactive recent exogenic processes are probably responsible for insufficient sediment availability on the Mars. Insufficient sediment availability would be an interesting topic for future research, which may have extensive earth science significances.

We have combined ferroelectric BaTiO3 nanostructures with α-Fe2O3 nanoparticles to prepare BaTiO3@α-Fe2O3 core@shell heterojunction photoelectrodes. The effects of α-Fe2O3 nanoparticle loadings on ...

The ZnO nanotube arrays were obtained by a simple three-step method, and then Au nanoparticles and Cu2O nanocrystals were decorated onto ZnO nanotube arrays successively. The composition, morphology, optical properties and photoelectrochemical performance of the as-prepared ZnO@Au@Cu2O nanotube arrays were characterized by X-ray diffraction, scanning electron microscopy, UV–vis diffuse reflectance spectra, X-ray photoelectron spectroscopy, and photocurrent densities. The results confirmed that ZnO@Au@Cu2O nanotube arrays showed enhanced response to visible light and achieved an excellent photocurrent under visible light due to the localized surface plasmon resonance effect, visible light harvesting of Cu2O nanocrystals, effective transfer and separation of photo-generated charge carriers induced by p-n junction and well band energy match of the ZnO@Au@Cu2O nanotube arrays.

The application of single-phase ZnO in hydrogen production through photoelectrochemical (PEC) water reduction is limited because of its unability to utilize photon energy of visible light and high carrier recombination rate. Herein, a three-dimensional (3D) plasmonic photoanode consisting of Au nanoparticles/ZnFe2O4 nanosheets coated onto ZnO nanotube arrays (Au/ZnFe2O4/ZnO NTAs) is rationally designed for hydrogen generation via PEC water splitting. The measurements preformed under simulated solar light and visible light irradiation show that the hot-electron injection of Au nanoparticles (NPs) significantly enhances PEC water splitting for hydrogen generation of 3D plasmonic Au/ZnFe2O4/ZnO NTAs photoanode. Benefiting from the outstanding visible light harvesting ability of ZnFe2O4 nanosheets, efficient suppression of carrier recombination by a favorable band alignment, hot-electron injection of Au NPs and large surface area of 3D architecture, the 3D plasmonic Au/ZnFe2O4/ZnO NTAs photoanode exhibits enhanced PEC water splitting for hydrogen generation. The hydrogen generation rate obtained by 3D plasmonic Au/ZnFe2O4/ZnO NTAs photoanode is 1.5 and 5.7-fold of ZnO/ZnFe2O and ZnO NTAs photoanodes, respectively, at 0.6 V versus reference electrode (Ag/AgCl) under simulated solar light irradiation.

Reliable attribution of changes in streamflow is fundamental to our understanding of the hydrological cycle and is needed to enable decision makers to manage water resources in a sustainable way. Here, we used a new attribution method based on the Budyko framework (complementary method) to quantify the contributions of climate change and human activities to the changes in annual streamflow in 22 catchments on China's Loess Plateau during the past three decades. Our results showed that after the Grain-for-Green (GFG) project, the annual streamflow decreased by 36% on average (3–72%), with reductions being more intense in northern catchments. The sensitivity of streamflow to precipitation and potential evapotranspiration also decreased, with a mean rate of −0.7 mm yr−1/mm yr−1 and −0.2 mm yr−1/mm yr−1, respectively. Using the upper and lower bounds of the human effects on streamflow from the complementary method as a reference, we found that these effects at half of the stations were under- or over-estimated by the total differential method. The contribution analysis from the complementary method showed that although human activities decreased streamflow by 26% (or 54% as a relative value) on average, the contribution of potential evapotranspiration alone to the decrease in streamflow was 9% (42%), highlighting the important role of increasing atmospheric moisture demand in the water cycle. In addition, the 5-year incremental analysis showed that the impacts of climate and human activities on streamflow had strong spatiotemporal variability.

In this study, we show for the first time a hierarchical ZnO/ZnFe2O4 nanotube array photoanode for water splitting to produce hydrogen. In this photoanode, the wrinkle-like ZnFe2O4 nanosheets (NSs) are grown onto ZnO nanotube arrays through adsorption and annealing reaction. The hierarchical ZnO/ZnFe2O4 nanotube array photoanode exhibits outstanding PEC water splitting to produce hydrogen due to the remarkable visible-light harvesting ability and the large surface area of wrinkle-like ZnFe2O4 NSs. Under simulated solar light irradiation, the hierarchical ZnO/ZnFe2O4 nanotube arrays (NTAs) achieve a remarkably enhanced photocurrent density of 1.3 mA/cm2, which is 2.2-fold higher than that of pristine ZnO NTAs at 0 V vs Ag/AgCl. Moreover, the hydrogen production rate of the hierarchical ZnO/ZnFe2O4 nanotube array photoanode is 3.6-fold higher than that of pristine ZnO nanotube array photoelectrode at 0.6 V vs Ag/AgCl.

Superhydrophilic membranes with simultaneous underwater superoleophobicity are highly desirable and worth exploring for separation of emulsified oil from water. In this work, combining the strong negative charges of phytic acid (PA) and the high cationic charge density of polyethyleneimine (PEI), an eco-friendly PA@PEI polyelectrolyte complex was synthetized in aqueous solution. And then the polyelectrolyte complex was deposited onto hydrophobic PVDF membranes through a one-step assembly approach with high convenience, endowing the membranes with superhydrophilic and underwater superoleophobic property. The as-prepared PA@PEI/PVDF membrane shows outstanding static and dynamic water stability, and was successfully used to separate multiple oil-in-water emulsions, with an average rejection rate exceeding 98.5% and a water flux up to 12203.6 L m−2∙h−1∙bar−1. Furthermore, the water flux can be recovered to a high level after four separation-washing cycles, showing excellent antifouling performance and recovery capability. Together with its natural raw materials and environmentally friendly preparation strategy, the PA@PEI/PVDF membrane shows great potential in practical treatment of emulsified oily wastewater.

A novel Janus sponge with the ability to remove complex contaminants from water is reported. Firstly, a superhydrophilic sponge (PA@PEI-sponge) is prepared via synthesizing negatively charged phytic acid@polyethyleneimine (PA@PEI) nanoparticles and assembling them on the surface of polydopamine (PDA) and PEI-modified polyurethane (PU) sponge through electrostatic adsorption. The Janus sponge is generated by modifying one side of the PA@PEI-sponge with PDMS, which exhibits superior separation efficiency and high filtration flux toward both water-in-oil and oil-in-water emulsions due to its multiplex selective wettability and the interconnected and tortuous 3D porous channels. The numerous negatively charged active sites of PA@PEI nanoparticles and PDA layer impart the superhydrophilic PA@PEI-sponge with the removal efficiency of 39.95 ± 0.27% for malachite green (MG) via simple flow-through filtration, which can be improved to 99.92 ± 0.07% by Janus modification. More importantly, the Janus sponge exhibits an excellent treatment capacity for complex mixtures containing emulsified oil and dye, with the separation efficiency above 99.59%. The Janus sponge also demonstrates the effective separation of real industrial wastewater collected from an acrylic dyeing plant. Together with a facile and green preparation strategy, this Janus sponge shows excellent application potential for simultaneous dye removal and oil/water emulsion separation.

Recently, relationship between vegetation activity and temperature variability has received much attention in China. However, vegetation-induced changes in water resources through changing land surface energy balance (e.g. albedo), has not been well documented. This study investigates the underlying causes of vegetation change and subsequent impacts on runoff for the Northern Shaanxi Loess Plateau. Results show that satellite-derived vegetation index has experienced a significantly increasing trend during the past three decades, especially during 2000-2012. Large-scale ecological restorations, i.e., the Natural Forest Conservation project and the Grain for Green project, are found to be the primary driving factors for vegetation increase. The increased vegetation coverage induces decrease in surface albedo and results in an increase in temperature. This positive effect can be counteracted by higher evapotranspiration and the net effect is a decrease in daytime land surface temperature. A higher evapotranspiration rate from restored vegetation is the primary reason for the reduced runoff coefficient. Other factors including less heavy precipitation, increased water consumption from town, industry and agriculture also appear to be the important causes for the reduction of runoff. These two ecological restoration projects produce both positive and negative effects on the overall ecosystem services. Thus, long-term continuous monitoring is needed.

Agricultural water resource, mainly consumed through evapotranspiration, plays a critical role in agricultural production of arid and semiarid regions. Quantifying the changes of evapotranspiration in cropland (ETc), and its driving factors, may provide rich information for improving human land-use and water resource management. Here we first investigated the multi-year (2000–2015) changes in the ETc (mm yr−1) and associated driving factors of the Loess Plateau (LP), using a combination of the Vegetation Interfaces Processes model and a factorial analysis of variance. We found that the ETc of the LP showed a significant upward trend of 0.31 km3 yr−2 (3.33 mm yr−2) (p

In this study, we show for the first time a hierarchical ZnO/ZnFe