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Recent JWST observations of the sub-Neptune GJ 1214 b suggest that it hosts a high-metallicity (>100x solar), hazy atmosphere. Emission spectra of the planet show molecular absorption features, most likely due to atmospheric H2O. In light of this new information, we conduct a thorough reevaluation of the planet's internal structure. We consider interior models with mixed H/He/H2O envelopes of varying composition, informed by atmospheric constraints from the JWST phase curve, in order to determine possible bulk compositions and internal structures. Self-consistent atmospheric models consistent with the JWST observations are used to set boundary conditions for the interior. We find that a total envelope mass fraction of at least 8.1% is required to explain the planet's mass and radius. Regardless of H2O content, the maximum H/He mass fraction of the planet is 5.8%. We find that a 1:1 ice-to-rock ratio along with 3.4-4.8% H/He is also a permissible solution. In addition, we consider a pure H2O (steam) envelope and find that such a scenario is possible, albeit with a high ice-to-rock ratio of at least 3.76:1, which may be unrealistic from a planet formation standpoint. We discuss possible formation pathways for the different internal structures that are consistent with observations. Since our results depend strongly on the atmospheric composition and haze properties, more precise observations of the planet's atmosphere would allow for further constraints on its internal structure. This type of analysis can be applied to any sub-Neptune with atmospheric constraints to better understand its interior., Comment: Accepted for publication in ApJ Letters. 13 pages, 6 figures, 2 tables

Transmission spectroscopy has been a workhorse technique over the past two decades to constrain the physical and chemical properties of exoplanet atmospheres. One of its classical key assumptions is that the portion of the atmosphere it probes -- the terminator region -- is homogeneous. Several works in the past decade, however, have put this into question for highly irradiated, hot ($T_{eq}\gtrsim 1000$ K) gas giant exoplanets both empirically and via 3-dimensional modelling. While models predict clear differences between the evening (day-to-night) and morning (night-to-day) terminators, direct morning/evening transmission spectra in a wide wavelength range has not been reported for an exoplanet to date. Under the assumption of precise and accurate orbital parameters on WASP-39 b, here we report the detection of inhomogeneous terminators on the exoplanet WASP-39 b, which allows us to retrieve its morning and evening transmission spectra in the near-infrared ($2-5\ \mu$m) using JWST. We observe larger transit depths in the evening which are, on average, $405 \pm 88$ ppm larger than the morning ones, also having qualitatively larger features than the morning spectrum. The spectra are best explained by models in which the evening terminator is hotter than the morning terminator by $177^{+65}_{-57}$ K with both terminators having C/O ratios consistent with solar. General circulation models (GCMs) predict temperature differences broadly consistent with the above value and point towards a cloudy morning terminator and a clearer evening terminator., Comment: Published in Nature at https://www.nature.com/articles/s41586-024-07768-4. All code to produce plots (with data) can be found at https://github.com/nespinoza/wasp39-terminators

The recent inference of sulphur dioxide (SO$_2$) in the atmosphere of the hot ($\sim$1100 K), Saturn-mass exoplanet WASP-39b from near-infrared JWST observations suggests that photochemistry is a key process in high temperature exoplanet atmospheres. This is due to the low ($<$1 ppb) abundance of SO$_2$ under thermochemical equilibrium, compared to that produced from the photochemistry of H$_2$O and H$_2$S (1-10 ppm). However, the SO$_2$ inference was made from a single, small molecular feature in the transmission spectrum of WASP-39b at 4.05 $\mu$m, and therefore the detection of other SO$_2$ absorption bands at different wavelengths is needed to better constrain the SO$_2$ abundance. Here we report the detection of SO$_2$ spectral features at 7.7 and 8.5 $\mu$m in the 5-12 $\mu$m transmission spectrum of WASP-39b measured by the JWST Mid-Infrared Instrument (MIRI) Low Resolution Spectrometer (LRS). Our observations suggest an abundance of SO$_2$ of 0.5-25 ppm (1$\sigma$ range), consistent with previous findings. In addition to SO$_2$, we find broad water vapour absorption features, as well as an unexplained decrease in the transit depth at wavelengths longer than 10 $\mu$m. Fitting the spectrum with a grid of atmospheric forward models, we derive an atmospheric heavy element content (metallicity) for WASP-39b of $\sim$7.1-8.0 $\times$ solar and demonstrate that photochemistry shapes the spectra of WASP-39b across a broad wavelength range., Comment: Published in Nature

Hot Jupiters are among the best-studied exoplanets, but it is still poorly understood how their chemical composition and cloud properties vary with longitude. Theoretical models predict that clouds may condense on the nightside and that molecular abundances can be driven out of equilibrium by zonal winds. Here we report a phase-resolved emission spectrum of the hot Jupiter WASP-43b measured from 5-12 $\mu$m with JWST's Mid-Infrared Instrument (MIRI). The spectra reveal a large day-night temperature contrast (with average brightness temperatures of 1524$\pm$35 and 863$\pm$23 Kelvin, respectively) and evidence for water absorption at all orbital phases. Comparisons with three-dimensional atmospheric models show that both the phase curve shape and emission spectra strongly suggest the presence of nightside clouds which become optically thick to thermal emission at pressures greater than ~100 mbar. The dayside is consistent with a cloudless atmosphere above the mid-infrared photosphere. Contrary to expectations from equilibrium chemistry but consistent with disequilibrium kinetics models, methane is not detected on the nightside (2$\sigma$ upper limit of 1-6 parts per million, depending on model assumptions)., Comment: 61 pages, 13 figures, 4 tables. This preprint has been submitted to and accepted in principle for publication in Nature Astronomy without significant changes

Photochemical hazes are expected to form in hot Jupiter atmospheres and may explain the strong scattering slopes and muted spectral features observed in the transmission spectra of many hot Jupiters. Absorption and scattering by photochemical hazes have the potential to drastically alter temperature structure and atmospheric circulation of these planets but have previously been neglected in general circulation models (GCMs). We present GCM simulations of hot Jupiter HD 189733b that include photochemical hazes as a radiatively active tracer fully coupled to atmospheric dynamics. The influence of haze radiative feedback strongly depends on the assumed haze optical properties. For soot hazes, two distinct thermal inversions form, separated by a local temperature minimum around 10$^{-5}$ bar caused by upwelling on the dayside mixing air with low haze abundance upwards. The equatorial jet broadens and slows down. The horizontal distribution of hazes remains relatively similar to simulations with radiatively passive tracers. For Titan-type hazes, the equatorial jet accelerates and extends to much lower pressures, resulting in a dramatically different 3D distribution of hazes compared to radiatively passive or soot hazes. Further experimental and observational studies to constrain the optical properties of photochemical hazes will therefore be crucial for understanding the role of hazes in exoplanet atmospheres. In the dayside emission spectrum, for both types of hazes the amplitude of near-infrared features is reduced, while the emitted flux at longer wavelengths ($>$4 $\mu$m) increases. Haze radiative feedback leads to increased phase curve amplitudes in many infrared wavelength regions, mostly due to stronger dayside emission., Comment: 31 pages, 18 figures, accepted for publication in ApJ

There are no planets intermediate in size between Earth and Neptune in our Solar System, yet these objects are found around a substantial fraction of other stars. Population statistics show that close-in planets in this size range bifurcate into two classes based on their radii. It is hypothesized that the group with larger radii (referred to as "sub-Neptunes") is distinguished by having hydrogen-dominated atmospheres that are a few percent of the total mass of the planets. GJ 1214b is an archetype sub-Neptune that has been observed extensively using transmission spectroscopy to test this hypothesis. However, the measured spectra are featureless, and thus inconclusive, due to the presence of high-altitude aerosols in the planet's atmosphere. Here we report a spectroscopic thermal phase curve of GJ 1214b obtained with JWST in the mid-infrared. The dayside and nightside spectra (average brightness temperatures of 553 $\pm$ 9 and 437 $\pm$ 19 K, respectively) each show >3$\sigma$ evidence of absorption features, with H$_2$O as the most likely cause in both. The measured global thermal emission implies that GJ 1214b's Bond albedo is 0.51 $\pm$ 0.06. Comparison between the spectroscopic phase curve data and three-dimensional models of GJ 1214b reveal a planet with a high metallicity atmosphere blanketed by a thick and highly reflective layer of clouds or haze., Comment: Published online in Nature on May 10, 2023

The near-infrared transmission spectrum of the warm sub-Neptune exoplanet GJ 1214 b has been observed to be flat and featureless, implying a high metallicity atmosphere with abundant aerosols. Recent JWST MIRI LRS observations of a phase curve of GJ 1214 b showed that its transmission spectrum is flat out into the mid-infrared. In this paper, we use the combined near- and mid-infrared transmission spectrum of GJ 1214 b to constrain its atmospheric composition and aerosol properties. We generate a grid of photochemical haze models using an aerosol microphysics code for a number of background atmospheres spanning metallicities from 100 to 1000 $\times$ solar, as well as a steam atmosphere scenario. The flatness of the combined data set largely rules out atmospheric metallicities $\leq$300 $\times$ solar due to their large corresponding molecular feature amplitudes, preferring values $\geq$1000 $\times$ solar and column haze production rates $\geq$10$^{-10}$ g cm$^{-2}$ s$^{-1}$. The steam atmosphere scenario with similarly high haze production rates also exhibit sufficiently small molecular features to be consistent with the transmission spectrum. These compositions imply that atmospheric mean molecular weights $\geq$15 g mol$^{-1}$ are needed to fit the data. Our results suggest that haze production is highly efficient on GJ 1214 b and could involve non-hydrocarbon, non-nitrogen haze precursors. Further characterization of GJ 1214 b's atmosphere would likely require multiple transits and eclipses using JWST across the near and mid-infrared, potentially complemented by groundbased high resolution transmission spectroscopy., Comment: 21 pages, 10 figures, 4 tables. Accepted for publication by ApJ

With an increased focus on the observing and modelling of mini-Neptunes, there comes a need to better understand the tools we use to model their atmospheres. In this paper, we present the protocol for the CAMEMBERT (Comparing Atmospheric Models of Extrasolar Mini-neptunes Building and Envisioning Retrievals and Transits) project, an intercomparison of general circulation models (GCMs) used by the exoplanetary science community to simulate the atmospheres of mini-Neptunes. We focus on two targets well studied both observationally and theoretically with planned JWST Cycle 1 observations: the warm GJ~1214b and the cooler K2-18b. For each target, we consider a temperature-forced case, a clear sky dual-grey radiative transfer case, and a clear sky multi band radiative transfer case, covering a range of complexities and configurations where we know differences exist between GCMs in the literature. This paper presents all the details necessary to participate in the intercomparison, with the intention of presenting the results in future papers. Currently, there are eight GCMs participating (ExoCAM, Exo-FMS, FMS PCM, Generic PCM, MITgcm, RM-GCM, THOR, and the UM), and membership in the project remains open. Those interested in participating are invited to contact the authors., Comment: Accepted to PSJ

Carbon dioxide (CO2) is a key chemical species that is found in a wide range of planetary atmospheres. In the context of exoplanets, CO2 is an indicator of the metal enrichment (i.e., elements heavier than helium, also called "metallicity"), and thus formation processes of the primary atmospheres of hot gas giants. It is also one of the most promising species to detect in the secondary atmospheres of terrestrial exoplanets. Previous photometric measurements of transiting planets with the Spitzer Space Telescope have given hints of the presence of CO2 but have not yielded definitive detections due to the lack of unambiguous spectroscopic identification. Here we present the detection of CO2 in the atmosphere of the gas giant exoplanet WASP-39b from transmission spectroscopy observations obtained with JWST as part of the Early Release Science Program (ERS). The data used in this study span 3.0 to 5.5 {\mu}m in wavelength and show a prominent CO2 absorption feature at 4.3 {\mu}m (26{\sigma} significance). The overall spectrum is well matched by one-dimensional, 10x solar metallicity models that assume radiative-convective-thermochemical equilibrium and have moderate cloud opacity. These models predict that the atmosphere should have water, carbon monoxide, and hydrogen sulfide in addition to CO2, but little methane. Furthermore, we also tentatively detect a small absorption feature near 4.0 {\mu}m that is not reproduced by these models., Comment: 27 pages, 6 figures, Accepted for publication in Nature, data and models available at https://doi.10.5281/zenodo.6959427

We present analysis of XMM-Newton Optical Monitor observations in the near-ultraviolet of HD 189733, covering twenty primary transits of its hot Jupiter planet. The transit is clearly detected with both the UVW2 and UVM2 filters, and our fits to the data reveal transit depths in agreement with that observed optically. The measured depths correspond to radii of $1.059^{+0.046}_{-0.050}$ and $0.94^{+0.15}_{-0.17}$ times the optically-measured radius (1.187 R$_{\rm J}$ at 4950 \r{A}) in the UVW2 and UVM2 bandpasses, respectively. We also find no statistically significant variation in the transit depth across the 8 year baseline of the observations. We rule out extended broadband absorption towards or beyond the Roche lobe at the wavelengths investigated, although observations with higher spectral resolution are required to determine if absorption out to those distances from the planet is present in individual near-UV lines., Comment: 7 pages, 7 figures, 3 tables; accepted for publication in MNRAS

Photochemical hazes have been suggested as candidate for the high-altitude aerosols observed in the transmission spectra of many hot Jupiters. We present 3D simulations of the hot Jupiter HD 189733b to study how photochemical hazes are transported by atmospheric circulation. The model includes spherical, constant-size hazes particles that gravitationally settle and are transported by the winds as passive tracers, with particle radii ranging from 1 nm to 300 $\mu$m. We identify two general types of haze distribution based on particle size: In the small-particle regime (<30 nm), gravitational settling is unimportant, and hazes accumulate in two large mid-latitude vortices centered on the night side that extend across the morning terminator. Therefore, small hazes are more concentrated at the morning terminator than at the evening terminator. In the large-particle regime (>30 nm), hazes settle out quickly on the nightside, resulting in more hazes at the evening terminator. For small particles, terminator differences in haze mass mixing ratio and temperature considered individually can result in significant differences in the transit spectra of the terminators. When combining both effects for HD189733b, however, they largely cancel out each other, resulting in very small terminator differences in the spectra. Transit spectra based on the GCM-derived haze distribution fail to reproduce the steep spectral slope at short wavelengths in the current transit observations of HD 189733b. Differing optical properties of hazes, hotter temperatures at low pressures because of heating by hazes, enhanced sub-grid-scale mixing, or star spots might explain the mismatch between the model and observations., Comment: This version incorporates the corrected versions of equations (7) and (8), as described in the correction published in July 2024, available at \url{https://academic.oup.com/mnras/article/531/3/3444/7691150}

The James Webb Space Telescope (JWST) is expected to revolutionize the field of exoplanets. The broad wavelength coverage and the high sensitivity of its instruments will allow characterization of exoplanetary atmospheres with unprecedented precision. Following the Call for the Cycle 1 Early Release Science Program, the Transiting Exoplanet Community was awarded time to observe several targets, including WASP-43b. The atmosphere of this hot Jupiter has been intensively observed but still harbors some mysteries, especially concerning the day-night temperature gradient, the efficiency of the atmospheric circulation, and the presence of nightside clouds. We will constrain these properties by observing a full orbit of the planet and extracting its spectroscopic phase curve in the 5--12 $\mu$m range with JWST/MIRI. To prepare for these observations, we performed an extensive modeling work with various codes: radiative transfer, chemical kinetics, cloud microphysics, global circulation models, JWST simulators, and spectral retrieval. Our JWST simulations show that we should achieve a precision of 210 ppm per 0.1 $\mu$m spectral bin on average, which will allow us to measure the variations of the spectrum in longitude and measure the night-side emission spectrum for the first time. If the atmosphere of WASP-43b is clear, our observations will permit us to determine if its atmosphere has an equilibrium or disequilibrium chemical composition, providing eventually the first conclusive evidence of chemical quenching in a hot Jupiter atmosphere. If the atmosphere is cloudy, a careful retrieval analysis will allow us to identify the cloud composition., Comment: 26 pages, 16 figures, accepted in The Astrophysical Journal

On hot Jupiter exoplanets, strong horizontal and vertical winds should homogenize the abundances of the important absorbers CH$_4$ and CO much faster than chemical reactions restore chemical equilibrium. This effect, typically neglected in general circulation models (GCMs), has been suggested as explanation for discrepancies between observed infrared lightcurves and those predicted by GCMs: On the nightsides of several hot Jupiters, GCMs predict outgoing fluxes that are too large, especially in the Spitzer 4.5 $\mu$m band. We modified the SPARC/MITgcm to include disequilibrium abundances of CH$_4$, CO and H$_2$O by assuming that the CH$_4$/CO ratio is constant throughout the simulation domain. We ran simulations of hot Jupiter HD 189733b with 8 CH$_4$/CO ratios. In the more likely CO-dominated regime, we find temperature changes $\geq$50-100 K compared to the equilibrium chemistry case across large regions. This effect is large enough to affect predicted emission spectra and should thus be included in GCMs of hot Jupiters with equilibrium temperatures between 600K and 1300K. We find that spectra in regions with strong methane absorption, including the Spitzer 3.6 and 8 $\mu$m bands, are strongly impacted by disequilibrium abundances. We expect chemical quenching to result in much larger nightside fluxes in the 3.6 $\mu$m band, in stark contrast to observations. Meanwhile, we find almost no effect on predicted observations in the 4.5 $\mu$m band, as the opacity changes due to CO and H$_2$O offset each other. We thus conclude that disequilibrium carbon chemistry cannot explain the observed low nightside fluxes in the 4.5 $\mu$m band., Comment: 28 pages, 12 figures; accepted for publication in ApJ. Key changes since v1: updated introduction and discussion to include recent literature more thoroughly; added paragraph and figure to clarify change in water abundance; ran simulations for additional 600 days simulation time (leading to small quantitative changes in some figures but no qualitative changes)