Search

Through interviews of 20 sitting politicians and water practitioners in New South Wales, Australia, this article explores the underlying perceptions of the viability of potable water reuse for Sydn...

The International Water Association (IWA) initiated a Task Force in April 2020 to serve as a leadership team within IWA whose role is to keep abreast and communicate the emerging science, technology, and applications for understanding the impact and the ability to respond to the COVID-19 pandemic and specifically designed for water professionals and industries. Expertise was nominated across the world with the purpose of collectively providing the water sector with knowledge products for the guidance on the control of COVID-19 and other viruses. This review paper developed by a working group of the IWA Task Force focuses on the control of COVID-19. The purpose of this review paper is to provide an understanding of existing knowledge with regards to COVID-19 and provide the necessary guidance of risk mitigation based on currently available knowledge of viruses in wastewater. This review paper considered various scenarios for both the developed world and the developing world and provided recommendations for managing risk. The review paper serves to pool the knowledge with regards to the pandemic and in relation to other viruses. The IWA Task Team envisage that this review paper provides the necessary guidance to the global response to the ongoing pandemic. HIGHLIGHTS Review of existing research of the virus, SARS-CoV-2, that causes COVID-19 and other viruses in relation to wastewater process control and risk mitigation.; Available techniques for wastewater process engineers to reduce health risks associated with COVID-19 within wastewater processes.; Risk mitigation for developing countries that are serviced by small wastewater treatment works.

This work examined the chiral inversion of 2-arylpropionic acids (2-APAs) under anaerobic conditions and the associated microbial community. The anaerobic condition was simulated by two identical anaerobic digesters. Each digester was fed with the substrate containing 11 either pure (R)- or pure (S)-2-APA enantiomers. Chiral inversion was evidenced by the concentration increase of the other enantiomer in the digestate and the changes in the enantiomeric fraction between the two enantiomers. Both digesters showed similar and poor removal of 2-APAs (≤30%, except for naproxen) and diverse chiral inversion behaviors under anaerobic conditions. Four compounds exhibited (S → R) unidirectional inversion [flurbiprofen, ketoprofen, naproxen, and 2-(4-tert-butylphenyl)propionic acid], and the remaining seven compounds showed bidirectional inversion. Several aerobic and facultative anaerobic bacterial genera (Candidatus Microthrix, Rhodococcus, Mycobacterium, Gordonia, and Sphingobium) were identified in both digesters and predicted to harbor the 2-arylpropionyl-CoA epimerase (enzyme involved in chiral inversion) encoding gene. These genera presented at low abundances

Water quality management has increasingly been based on the adoption of risk management frameworks as defined by Water Safety Plans (WSP), through the World Health Organization Guidelines for Drinking-water Quality. The potential application of such frameworks in Chile has not been fully explored, therefore it is necessary to identify aspects of water quality management which are currently not consistent with such an approach. A template for successful adaptation is provided by the framework for Management of Drinking Water Quality applied in Australia, through the Australian Drinking Water Guidelines (ADWG). This study employed the management framework presented in the ADWG, to evaluate gaps in risk management as it is applied in the drinking water sector in Chile. Substantial differences were detected in the assessment of the supply system, preventive measures, R&D, the needs for review and continual improvement, as well as concepts and tools including multiple barriers and critical control points.

The authors regret that the printed version of the above article contained a transcription error in the m/z 1048 peak area column for the branched GDGTs (Table S2). This error affected the GDGT-inferred summer air temperature presented in Figs. 3, 4 and 5, and some of the calibrations presented Fig. S2. The GDGT-inferred temperatures have been recalculated and are presented below. The authors would like to apologise for any inconvenience caused. The corrected GDGT-inferred summer air temperature (Fig. 3) is largely within the uncertainty of the temperature calibration (2.0 °C RMSE, Pearson et al., 2011). While the pattern of the temperature variations over the last 3500 years remains unchanged, the GDGT-inferred summer air temperature is between 0.4 and 3.3 degrees lower than was originally presented. The interpretations of Thomas et al. (2022) are unaffected, with reconstructed changes in temperature at Club Lake still associated with several other palaeoenvironmental proxies. Section 4.1 “Our reconstruction of MSAT varies between about 13 and 16 °C, and appears to display a long-term increase in temperature averaging ~0.1 °C per century (Fig. 3).” should be “Our reconstruction of MSAT varies between about 10 and 15 °C, and appears to display a long-term increase in temperature averaging ~0.13 °C per century (Fig. 3).” Section 4.2 “The reconstructed temperature of 16.2 ± 1 °C (which is higher than the contemporary Thredbo AWS mean summer temperature) must therefore be treated with caution.” should be “The reconstructed temperature of 15.7 ± 1 °C (which is higher than the contemporary Thredbo AWS mean summer temperature) must therefore be treated with caution.” The updated figures and Supplementary information table and figure related to this corrigendum are presented below. [Figure presented] [Figure presented] [Figure presented]

The chemical pollution crisis severely threatens human and environmental health globally. To tackle this challenge the establishment of an overarching international science–policy body has recently been suggested. We strongly support this initiative based on the awareness that humanity has already likely left the safe operating space within planetary boundaries for novel entities including chemical pollution. Immediate action is essential and needs to be informed by sound scientific knowledge and data compiled and critically evaluated by an overarching science–policy interface body. Major challenges for such a body are (i) to foster global knowledge production on exposure, impacts and governance going beyond data-rich regions (e.g., Europe and North America), (ii) to cover the entirety of hazardous chemicals, mixtures and wastes, (iii) to follow a one-health perspective considering the risks posed by chemicals and waste on ecosystem and human health, and (iv) to strive for solution-oriented assessments based on systems thinking. Based on multiple evidence on urgent action on a global scale, we call scientists and practitioners to mobilize their scientific networks and to intensify science–policy interaction with national governments to support the negotiations on the establishment of an intergovernmental body based on scientific knowledge explaining the anticipated benefit for human and environmental health., Environmental Sciences Europe, 34 (1), ISSN:2190-4715, ISSN:2190-4707

The stability of drinking water disinfectant residuals is known to be influenced by multiple variables. To evaluate the effects of various influencing variables on disinfectant stability, a multivariate analysis of chloramine decay and associated disinfection by-products (DBPs) formation was investigated in a series of bench-scale experiments. Of nine water quality variables previously identified, monochloramine dose, pH, and bromide concentration were selected as key water quality variables based on previous investigations and modelling. Co-effects of these key variables on monochloramine decay and formation of 33 halogenated and nitrogen-containing DBPs were investigated using response surface experimental design. Rechloramination conditions, including monochloramine dose, pH and bromide concentration, were optimised via a 3-factorial multivariate analysis of monochloramine stability in post-treatment drinking water. Effects of influencing variables on disinfectant decay and DBP formation were assessed and graphically presented as response surfaces with minimal experiments using Doehlert matrix experimental design compared to other multivariate experimental designs. Concentrations of trihalomethanes (THMs), haloacetic acids (HAAs), and N-nitrosamines were found to increase with water age, whereas opposite phenomenon was observed in the net production of haloacetonitriles (HANs). Increasing pH was found to stabilise monochloramine but it could cause DBP speciation to shift. Furthermore, increasing bromide concentration elevated Br-DBP formation. In bromide-containing water, pH = 7.8-8.0 should be considered as higher pH increases Br-THMs formations and lower pH increases formations of Br-HAAs and Br-HANs. However, water age or pH has insignificant impacts on DBP formation after significant monochloramine decay or at low initial monochloramine dose. These findings indicate that effective combined control measures to maintain monochloramine stability should include the application of high monochloramine dose (1.5 mg-Cl

Constantly changing and evolving social, economic, political, and environmental landscapes create new uncertainties in urban water supplies. These uncertainties surrounding urban water management have been captured using various scenario analysis techniques, which have been developed to envision plausible futures. Although past review papers have conducted broad reviews on water-related issues and water management generally, there has been a lack of attention to urban water management specifically. The growing uncertainty surrounding urban water management systems necessitates a focused review specifically aimed at the use of scenarios in urban water management. Using a comprehensive typology, a systematic review is presented to empirically investigate the necessary dimensions of urban water management scenario assessment. Urban water management scenario studies that exclusively employ qualitative methods, as well as urban water management studies that employ qualitative methods with quantitative techniques, are reviewed against the comprehensive typology. By aligning the reviewed scenarios with the dimensions in the typology, some important gaps in the current literature were identified. The need for: (i) transparency in scenario development and analysis processes, (ii) inclusion of surprises and extreme events, (iii) validation efforts and (iv) considering the impact phase of a scenario process. Recommendations are proposed to address the above gaps in current urban water scenarios literature, providing a path for future scenario analysis in urban water management.

The alpine area of the Australian mainland is highly sensitive to climate and environmental change, and potentially vulnerable to ecosystem tipping points. Over the next two decades the Australian alpine region is predicted to experience temperature increases of at least 1 °C, coupled with a substantial decrease in snow cover. Extending the short instrumental record in these regions is imperative to put future change into context, and potentially provide analogues of warming. We reconstructed past temperatures, using a lipid biomarker palaeothermometer technique and mercury flux changes for the past 3500 years from the sediments of Club Lake, a high-altitude alpine tarn in the Snowy Mountains, southeastern Australia. Using a multi-proxy framework, including pollen and charcoal analyses, high-resolution geochemistry, and ancient microbial community composition, supported by high-resolution 210Pb and AMS 14C dating, we investigated local and regional ecological and environmental changes occurring in response to changes in temperature. We find the region experienced a general warming trend over the last 3500 years, with a pronounced climate anomaly occurring between 1000 and 1600 cal yrs. BP. Shifts in vegetation took place during this warm period, characterised by a decline in alpine species and an increase in open woodland taxa which co-occurred with an increase in regional fire activity. Given the narrow altitudinal band of Australian alpine vegetation, any future warming has the potential to result in the extinction of alpine species, including several endemic to the area, as treelines are driven to higher elevations. These findings suggest ongoing conservation efforts will be needed to protect the vulnerable alpine environments from the combined threats of climate changes, fire and invasive species.

Stuart Khan and David Cwiertny provide the latest Environmental Science: Water Research & Technology ‘Editorial Perspective’ on how we define safe drinking water.

Increased water scarcity is driving water utilities to consider alternative water supply options (WSOs). Identifying the most sustainable WSOs that meet environmental, economic, and social objectives is challenging due to the overwhelming number of both assessment criteria and treatment configurations, including a growing number of potable reuse options. Conventional approaches using process-based life cycle assessments are data-intensive and site-specific, and therefore not suitable for the early stages of assessing WSOs. To address this gap, we have combined hybrid multi-regional input-output-based life cycle assessment (MRIO-LCA), social impact analysis, and multi-criteria decision analysis (MCDA) to develop a novel, flexible framework with unit process level resolution for the comprehensive evaluation of WSOs. Here we describe the formulation of the framework along with an application to two US utilities considering alternative WSOs. In both cases, given sufficient levels of community acceptance and optimum system design, the results favoured potable reuse WSOs due to their climatic resilience, cost effectiveness and lower environmental impacts (compared to other non-conventional options such as desalination). The generalised and globally applicable framework developed for this study can be used to assess sustainability trade-offs between diverse WSO configurations, providing valuable insights for decision-making processes at the early planning stage, as a complement to existing urban water supply scenario and optimisation models.

Secondary disinfectants, such as chlorine and chloramine, have been widely applied to minimise microbial risks in drinking water during distribution. Key challenges have included the maintenance of stable concentrations of disinfectant residuals and the control of disinfection by-products that may form as a consequence of residual decay processes. Many factors may influence disinfectant residual stability and the consequential formation of by-products. Thus predictions of disinfectant stability and by-product formation are multifactorial problems, complete with numerous complications of parameter co-dependence and feedback amplification of some key parameters. The aim of this review was to derive an understanding of how disinfectant residual stability in drinking water distribution systems is impacted by various influencing factors such as water quality and operational parameters. Factors known to influence disinfectant stability and by-product formation were critically reviewed. A systematic review method was applied to identify 1809 journal articles published in the two decades from January 1998 to December 2017. From the initial screening, 161 papers were selected for detailed assessment. Important factors were identified to include temperature, water age, piping material, corrosion products, pH, hydraulic condition, disinfectant residual type and dosage and microbial activity. Microbial activity is a particularly complex parameter on which to base predictions since many factors are known to influence the degree and nature of such activity. These include temperature, water age, piping material, corrosion products, nutrients, natural organic matter, hydraulic condition and disinfectant residual type and dosage. Disinfectant types and dosages were found to be among the most important factors. Many knowledge gaps and research needs still remain, including the need for a more complete understanding of the factors that influence the production of nitrogenous disinfection by-products.

© 2018 This study examined the occurrence of 49 micropollutants in reclaimed water and Silver Perch (Bidyanus bidyanus) living in a reclaimed water reservoir. The numbers of micropollutants detected in reclaimed water, Silver Perch liver, and Silver Perch flesh were 20, 23, and 19, respectively. Concentrations of all micropollutants in reclaimed water, except benzotriazole, were well below the Australian Guideline for Recycled Water (AGRW) values for potable purposes. The concentration of benzotriazole in reclaimed water was 675 ± 130 ng/L while the AGRW value for this compound was 7 ng/L. Not all micropollutants detected in the water phase were identified in the Silver Perch flesh and liver tissues. Likewise, not all micropollutants detected in the Silver Perch flesh and liver were identified in the reclaimed water. In general, micropollutant concentrations in the liver were higher than in the flesh. Perfluorooctane sulfonate (PFOS) was detected at a trace level in reclaimed water well below the AGRW guideline value for potable purposes, but showed a high and medium bioconcentration factor in Silver Perch liver and flesh, respectively. In addition, the risk quotient for PFOS was medium and high when considering its concentration in Silver Perch liver and flesh, respectively. Results reported here highlight the need to evaluate multiple parameters for a comprehensive risk assessment. The results also single out PFOS as a notable contaminant of concern for further investigation.

The growth of potable reuse as a planned water supply strategy has led to an increased focus on the presence and significance of trace chemical contaminants. By the use of reclaimed wastewater as a source, potable reuse projects require serious consideration to be given to the range and character of chemicals which may be present and may pose unacceptable risks to public health if not properly managed. The first step, required to assess and manage risks, is to consider the range of chemical contaminants which may be present. Although it is impossible to derive an exhaustive list, it is useful to consider broad categories and the specific types of challenges that may be posed by the chemicals within those categories. Such a broad categorisation of chemical contaminants is presented in this review and provides the basis for initial consideration by those tasked with assessing the water quality and treatment requirements of a potable reuse project. Chemicals, which may potentially be of concern in potable reuse projects, are diverse in terms of their (anthropogenic or natural) source, chemical characteristics and their likely human toxicity. Public health risk assessments are further complicated by the inevitable presence of unidentified chemicals and potential impacts of ‘mixture effects’ on the overall toxicity of complex, low-concentration chemical mixtures.

Membrane bioreactors (MBRs) have attracted attention in water reclamation as a result of the recent technical advances and cost reduction in membranes. However, the increasing occurrence of micropollutants in wastewaters has posed new challenges. Therefore, we reviewed the current state of research to identify the outstanding needs in this field. In general, the fate of micropollutants in MBRs relates to sorption, biodegradation and membrane separation processes. Hydrophobic, nonionized micropollutants are favorable in sorption, and the biological degradation shows higher efficiency at relatively long SRTs (30–40 days) and HRTs (20–30 h), as a result of co-metabolism, metabolism and/or ion trapping. Although the membrane rejection rates for micropollutants are generally minor, final water quality can be improved via combination with other technologies. This review highlights the challenges and perspectives that should be addressed to facilitate the extended use of MBRs for the removal of micropollutants in water reclamation.

Wastewater surveillance for pathogens using reverse transcription-polymerase chain reaction (RT-PCR) is an effective and resource-efficient tool for gathering community-level public health information, including the incidence of coronavirus disease-19 (COVID-19). Surveillance of Severe Acute Respiratory Syndrome Coronavirus-2 (SARS-CoV-2) in wastewater can potentially provide an early warning signal of COVID-19 infections in a community. The capacity of the world's environmental microbiology and virology laboratories for SARS-CoV-2 RNA characterization in wastewater is increasing rapidly. However, there are no standardized protocols or harmonized quality assurance and quality control (QA/QC) procedures for SARS-CoV-2 wastewater surveillance. This paper is a technical review of factors that can cause false-positive and false-negative errors in the surveillance of SARS-CoV-2 RNA in wastewater, culminating in recommended strategies that can be implemented to identify and mitigate some of these errors. Recommendations include stringent QA/QC measures, representative sampling approaches, effective virus concentration and efficient RNA extraction, PCR inhibition assessment, inclusion of sample processing controls, and considerations for RT-PCR assay selection and data interpretation. Clear data interpretation guidelines (e.g., determination of positive and negative samples) are critical, particularly when the incidence of SARS-CoV-2 in wastewater is low. Corrective and confirmatory actions must be in place for inconclusive results or results diverging from current trends (e.g., initial onset or reemergence of COVID-19 in a community). It is also prudent to perform interlaboratory comparisons to ensure results' reliability and interpretability for prospective and retrospective analyses. The strategies that are recommended in this review aim to improve SARS-CoV-2 characterization and detection for wastewater surveillance applications. A silver lining of the COVID-19 pandemic is that the efficacy of wastewater surveillance continues to be demonstrated during this global crisis. In the future, wastewater should also play an important role in the surveillance of a range of other communicable diseases.

During the summer of 2019-2020, more than 15 000 wildfires burned up to 19 million hectares of forest and woodland regions across Australia. These fires culminated in the worst Australian fire season on record, producing what has come to be known as the Australian "Black Summer." The fires have been described as an "ecological disaster," but the scale of the impacts is so extensive that the full ecological consequence may take years to assess. In the immediate aftermath of the Black Summer fires, two major national investigations were established by the Australian Commonwealth Government. By reviewing reports produced by these two investigations, high-level insights into the scale of the ecological consequences of the Black Summer fires have been obtained and are summarized here. Through these insights, the urgency for action to reduce the occurrence, and improve the management, of future comparable fire events is made clear. Integr Environ Assess Manag 2021;17:1136-1140. © 2021 SETAC.

© 2020 Elsevier B.V. Adsorption pre-treatment to enhance the nanofiltration (NF) removal of inorganic ions, dissolved organic carbon (DOC) and organic micropollutants (OMP) from microfiltered (MF) wastewater was investigated using NF 90 membrane (contact angle 79% and molecular weight cut off value of 90–200 Da). The NF showed greater rejection for divalent cations (Ca2+, Mg2+) and anions (SO42−) compared to monovalent cations (Na+, K+) and anions (Cl−, NO3−). The degree of total DOC removal was: GAC adsorption + NF (86%) > an ion exchange resin (Purolite) adsorption + NF (81%) > NF operation alone (72%). GAC + NF removed biopolymers and hydrophobic substances almost completely and the highest percentage of LMW neutral substances. In contrast, Purolite + NF almost completely removed humic substances. The degree of membrane fouling order was: LMW neutrals > building blocks > biopolymers > hydrophobics > humics. Adsorption pre-treatment reduced membrane fouling and increased solution flux, the outcome being better with GAC compared to Purolite. Of the 10 MOPs in the MF water, seven were rejected > 90% by NF without any pre-treatment. Conversely, Purolite and GAC pre-treatments rejected > 90% of all OMPs.

2020 is the year of wildfire records. California experienced its three largest fires early in its fire season. The Pantanal, the largest wetland on the planet, burned over 20% of its surface. More than 18 million hectares of forest and bushland burned during the 2019–2020 fire season in Australia, killing 33 people, destroying nearly 2500 homes, and endangering many endemic species. The direct cost of damages is being counted in dozens of billion dollars, but the indirect costs on water‐related ecosystem services and benefits could be equally expensive, with impacts lasting for decades. In Australia, the extreme precipitation (“200 mm day −1 in several location”) that interrupted the catastrophic wildfire season triggered a series of watershed effects from headwaters to areas downstream. The increased runoff and erosion from burned areas disrupted water supplies in several locations. These post‐fire watershed hazards via source water contamination, flash floods, and mudslides can represent substantial, systemic long‐term risks to drinking water production, aquatic life, and socio‐economic activity. Scenarios similar to the recent event in Australia are now predicted to unfold in the Western USA. This is a new reality that societies will have to live with as uncharted fire activity, water crises, and widespread human footprint collide all‐around of the world. Therefore, we advocate for a more proactive approach to wildfire‐watershed risk governance in an effort to advance and protect water security. We also argue that there is no easy solution to reducing this risk and that investments in both green (i.e., natural) and grey (i.e., built) infrastructure will be necessary. Further, we propose strategies to combine modern data analytics with existing tools for use by water and land managers worldwide to leverage several decades worth of data and knowledge on post‐fire hydrology., Wildfires are a source of socio‐hydrological extremes that increasingly threaten water security across the world; this situation may be referred to as wildfire‐watershed risks (WWR). WWR geographically vary and require locally‐adapted governance for efficient disaster risk reduction. A combination of watershed protection, forest restoration (including fire reintroduction), and adaptation of water infrastructures is the answer to reduce water supply vulnerability to wildfires.

We report a biocatalytic, buoyancy-propelled metal-organic framework (MOF) nanomotor system with boosted removal efficiency for both inorganic heavy metal ions and organic per- and poly-fluoroalkyl substances (PFAS). With the motion-induced convection and increased mass transfer of the target pollutants, the nano system exhibits excellent contaminants remediation capacity in both fresh water and sea water environments.

This study examined the removal and enantio-specific fate of a suite of eleven chiral 2-arylpropionic acids (2-APAs) during biological wastewater treatment simulated in a laboratory-scale membrane bioreactor (MBR). Using pure (R)- and (S)- enantiomers in the MBR influent, chiral inversion was determined through the increase in the concentration of the non-dominant enantiomer and changes in the enantiomeric fraction (EF) between the two enantiomers during the treatment process. Effective (> 90%) and similar removal rates between (R)- and (S)- enantiomers were confirmed for eight 2-APAs. In this study, 2-APAs exhibited diverse and distinctive chiral inversion behaviours: two 2-APAs showed (R→S) unidirectional inversion, three 2-APAs showed (S→R) unidirectional inversion, and six 2-APAs showed bidirectional inversion. This is the first study to report chiral inversion behaviours of a comprehensive suite of 2-APAs with a variety of functional groups substituted onto the aryl ring. A decrease in effluent EF over time was observed for two 2-APAs. This study shows that chiral inversion of 2-APAs varies significantly from compound to compound, despite the high similarity in their chemical structures.

Controlling disinfection by-products formation while ensuring effective drinking water disinfection is important for protecting public health. However, understanding and predicting disinfection by-product formation under a variety of conditions in drinking water distribution systems remains challenging as disinfection by-product formation is a multifactorial phenomenon. This study aimed to assess the application of Bayesian Network models to predict the concentration of trihalomethanes, the dominant halogenated disinfection by-product class, using various water quality parameters. Naive Bayesian and semi-naive Bayesian models were constructed from Sydney and South East Queensland datasets across 15 drinking water distribution systems in Australia. The targeted variable, total trihalomethanes concentration, was discretised into 3 bins ( 0.2 mg L−1). The Bayesian network structures were built using water quality parameters including concentrations of individual and total trihalomethanes, disinfectant species (free chlorine, monochloramine, dichloramine, total chlorine), nitrogen species (free ammonia, total ammonia, nitrate, nitrite), and other physical/chemical parameters (temperature, pH, dissolved organic carbon, total dissolved solids, conductivity and turbidity). Seven performance parameters, including predictive accuracy and the rates of true and false positive and negative results, were used to assess the accuracy and precision of the Bayesian network models. After evaluating the model performance, the optimum models were selected to be Bayesian network augmented naive models. These were observed to have the highest predictive accuracies for Sydney (78%) and South East Queensland (94%). Although disinfectant residuals are among the key variables that lead to trihalomethanes formation, potential concentrations of trihalomethanes in distribution systems can be more confidently predicted, in terms of probability associated with a wider range of water quality variables, using Bayesian networks. The modelling procedure developed in this work can now be applied to develop system-specific Bayesian network models for trihalomethanes prediction in other drinking water distribution systems.

Algal cells and algal organic matter (AOM) are a source of high dissolved organic carbon (DOC) and nitrogen (DON) concentrations. This poses a possible health risk due to their potential to form disinfection by-products (DBPs), some of which may be of health concern, after disinfection. While several studies have focussed on the formation of carbonaceous DBPs from AOM, only a few studies have focussed on the formation of nitrogen containing N-DBPs from AOM. Hence, the main aim of this study was to thoroughly investigate the N-DBP formation potential of the AOM from a species of cyanobacteria commonly found in natural waters, Microcystis aeruginosa. Three haloacetonitriles, two halonitromethanes, two haloacetamides, and eight N-nitrosamines were analysed by gas chromatography-mass spectrometry after chlorination and chloramination of the extracted AOM. To provide further insight into the influence of changing DON character on N-DBP formation potential, the AOM from three other species, Chlorella vulgaris, Dolichospermum circinale and Cylindrospermopsis raciborskii, were also tested. Dichloroacetonitrile (DCAN) was the DBP formed in the highest concentrations for both chlorination and chloramination of bulk AOM from all the species. Furthermore, during chlorination and chloramination, the high molecular weight fraction (1 kDa) of AOM from M. aeruginosa had a greater DCAN formation potential (normalised to DOC or DON) than the AOM in the low molecular weight fraction (1 kDa) of M. aeruginosa, regardless of growth stage. N-Nitrosamine formation from the bulk AOM of all species occurred only after chloramination. The molar concentration of N-nitrosodimethylamine (NDMA) was lower than the other N-nitrosamines detected. However, NDMA formation increased with culture age for all four species, in contrast to most other N-nitrosamines whose formation remained consistent or decreased with culture age. Overall, algal growth could result in elevated concentrations of N-DBPs due to the increasing concentrations of high molecular weight algal DON in the AOM. It is suggested that the AOM comprises precursors containing long C-chain amine (R

Australia has played an important role in the development of potable reuse internationally. Most significantly, Australia was the first country to develop national water quality guidelines specifically for this purpose. This has recently been followed-up with the development of detailed protocols for the validation of treatment performance for a number of key advanced water treatment processes. Nonetheless, the successes of potable reuse projects, which have been proposed for development in Australia, have been variable. An important groundwater replenishment project is now operational in Perth, Western Australia. However, what was to be a similarly important reservoir-augmentation project in South East Queensland is currently idle. A smaller scheme in Sydney, New South Wales, produces highly treated reclaimed water for river-flow augmentation upstream of a drinking water offtake. Each of these projects has contributed to technical skills and provided important research opportunities. Key research topics and outcomes are described here. Finally, prospects for the future role of potable reuse in Australia are considered.

© 2017 This study investigated the impact of sulphur content on the performance of an anaerobic membrane bioreactor (AnMBR) with an emphasis on the biological stability, contaminant removal, and membrane fouling. Removal of 38 trace organic contaminants (TrOCs) that are ubiquitously present in municipal wastewater by AnMBR was evaluated. Results show that basic biological performance of AnMBR regarding biomass growth and the removal of chemical oxygen demand (COD) was not affected by sulphur addition when the influent COD/SO42− ratio was maintained higher than 10. Nevertheless, the content of hydrogen sulphate in the produced biogas increased significantly and membrane fouling was exacerbated with sulphur addition. Moreover, the increase in sulphur content considerably affected the removal of some hydrophilic TrOCs and their residuals in the sludge phase during AnMBR operation. By contrast, no significant impact on the removal of hydrophobic TrOCs was noted with sulphur addition to AnMBR.

A two-stage hybrid Constructed Wetland (CW) integrated with a microbial fuel cell (MFC), and microbial electrolysis cell (MEC) has been assessed for treatment performance and clogging assessment and further compared with CW. The CW-MEC was operated with applied potential to the working electrode and compared with the performance of naturally adapted redox potential of the CW-MFC system. A complex synthetic municipal wastewater was used during the study, which was composed of trace metals, organics, inorganics, and dye. The study demonstrated that providing a constant potential to the working electrode in CW-MEC has resulted in high treatment performance and reduced sludge generation. The maximum chemical oxygen demand (COD), ammonium(NH4+), and phosphate (PO43−) removal achieved during treatment by CW-MEC at 24 h hydraulic retention time was 89 ± 6%, 72 ± 6% and 93 ± 2%, respectively. ICP-MS results indicated that trace metal removals were also higher in CW-MEC than in CW alone (p

Surface modification of nanofiltration (NF) membranes has great potential to improve the removal of organic micropollutants (OMs) by NF membranes. This study used polydopamine (PDA) as a model coating to comprehensively link the changes in membrane properties with the changes in transmission of 34 OMs. The membrane characterization demonstrated that a thicker, denser, and more hydrophilic PDA coating can be achieved by increasing the PDA deposition time from 0.5 to 4 hours. Overall, the transmissions of target OMs were reduced by PDA-coated NF membranes compared to unmodified NF membranes. The neutral hydrophobic compounds showed lower transmissions for longer PDA coating (PDA4), while the neutral hydrophilic compounds tended to show lower transmissions for shorter PDA coating (PDA0.5). To explain this, competing effects provided by the PDA coatings are proposed including sealing defects, inducing cake-enhanced concentration polarization in the coating layer for neutral hydrophilic compounds, and weakened hydrophobic adsorption for neutral hydrophobic compounds. For charged compounds, PDA4 with the greatest negative charge among the PDA-coated membranes showed the lowest transmission. Depending on the molecular size and hydrophilicity of the compounds, the transmission of OMs by the PDA4 coating could be reduced by 70% with only a 26.4% decline in water permeance. The correlations and mechanistic insights provided by this work are highly useful for designing membranes with specific surface properties via surface modification to improve the removal of OMs without compromising water production.

© 2017 Elsevier Ltd This study investigated the fate of trace organic contaminants (TrOCs) in an oxic-settling-anoxic (OSA) process consisting of a sequencing batch reactor (SBR) with external aerobic/anoxic and anoxic reactors. OSA did not negatively affect TrOC removal of the SBR. Generally, low TrOC removal was observed under anoxic and low substrate conditions, implicating the role of co-metabolism in TrOC biodegradation. Several TrOCs that were recalcitrant in the SBR (e.g., benzotriazole) were biodegraded in the external aerobic/anoxic reactor. Some hydrophobic TrOCs (e.g., triclosan) were desorbed in the anoxic reactor possibly due to loss of sorption sites through volatile solids destruction. In OSA, the sludge was discharged from the aerobic/anoxic reactor which contained lower concentration of TrOCs (e.g., triclosan and triclocarban) than that of the control aerobic digester, suggesting that OSA can also help to reduce TrOC concentration in residual biosolids.

Quantitative risk assessment (QRA) has been applied widely in environmental decision-making. Despite its advantage in taking locally specific details into consideration, problem shifting may occur due to its relatively narrow focus. To achieve a broader perspective, we propose that the combined use of QRA and life cycle assessment (LCA) may be beneficial. The feasibility and effectiveness of a hybrid approach of QRA and LCA were evaluated by considering alternative future air quality scenarios. Future air pollution emission scenarios based on different state-based environmental agency policies in Victoria, Australia, were considered to explore ways to reduce problem shifting. QRA was used to estimate human burden of disease (BoD) for the local population due to particulates and tropospheric ozone under ‘Low Impact’ and ‘Most Likely’ scenarios. To detect potential problem shifting, LCA was performed for other associated impact categories such as climate change potential. Disability-adjusted life years (DALYs) were used as a common metric to facilitate direct comparisons and aggregation between results of QRA and LCA. While the ‘Low Impact’ scenario was developed to project a scenario with reduced human health impacts (among other environmental impacts), the overall assessment revealed that BoD impacts may suffer a net increase under this scenario. The QRA suggested about 0.74 kilo DALYs (kDALYs) were saved annually; however, the LCA indicated that more impacts were expected, over 8 kDALYs per year. Hence, it was projected that reducing local impact by improving local air quality would shift more problems elsewhere. Therefore, using QRA alone that focuses on local impacts could result in an inappropriate scenario being preferred and improper policies being set. The outcomes of this study revealed the importance of applying a broad perspective in environmental decision-making. QRA appeared to be a suitable tool to assess local BoD impacts caused by ambient air pollutants. However, by also including LCA, impacts could be more comprehensively assessed. Combined use of QRA and LCA enables the analyst to account for locally specific considerations while reducing potential problem shifting to more distant receptors.

Chlorine disinfection of biologically treated wastewater is practiced in many locations prior to environmental discharge or beneficial reuse. The effectiveness of chlorine disinfection processes may be influenced by several factors, such as pH, temperature, ionic strength, organic carbon concentration, and suspended solids. We investigated the use of Bayesian multilayer perceptron (BMLP) models as efficient and practical tools for compiling and analysing free chlorine and monochloramine virus disinfection performance as a multivariate problem. Corresponding to their relative susceptibility, Adenovirus 2 was used to assess disinfection by monochloramine and Coxsackievirus B5 was used for free chlorine. A BMLP model was constructed to relate key disinfection conditions (CT, pH, turbidity) to observed Log Reduction Values (LRVs) for these viruses at constant temperature. The models proved to be valuable for incorporating uncertainty in the chlor(am)ination performance estimation and interpolating between operating conditions. Various types of queries could be performed with this model including the identification of target CT for a particular combination of LRV, pH and turbidity. Similarly, it was possible to derive achievable LRVs for combinations of CT, pH and turbidity. These queries yielded probability density functions for the target variable reflecting the uncertainty in the model parameters and variability of the input variables. The disinfection efficacy was greatly impacted by pH and to a lesser extent by turbidity for both types of disinfections. Non-linear relationships were observed between pH and target CT, and turbidity and target CT, with compound effects on target CT also evidenced. This work demonstrated that the use of BMLP models had considerable ability to improve the resolution and understanding of the multivariate relationships between operational parameters and disinfection outcomes for wastewater treatment.

The occurrence of five organophosphate flame retardants (PFRs) consisting of tributyl phosphate (TNBP), tris(2-chloroethyl) phosphate (TCEP), tris(1-chloro-2-propyl) phosphate (TCIPP), tris(1.3-dichloro-2-propyl) phosphate (TDCIPP) and triphenyl phosphate (TPHP) in swimming pools were investigated. Fifteen chlorinated public swimming pools were sampled, including indoor pools, outdoor pools and spa pools. The analyses were carried out using isotope dilution gas chromatography tandem mass spectrometry. All five PFRs were detected in swimming pool waters with concentrations ranging from 5-27ng/L (TNBP), 7-293ng/L (TCEP), 62-1180ng/L (TCIPP), 10-670ng/L (TDCIPP) and 8-132ng/L (TPHP). The concentrations of PFRs were generally higher in indoor swimming pools compared to outdoor swimming pools. In municipal water supplies, used to fill the swimming pools in three of the sampling locations, the five PFRs were all below the limit of quantifications, eliminating this as the source. Potential leaching of PFRs from commonly used swimming equipment, including newly purchased kickboards and swimsuits was investigated. These experiments revealed that PFRs leached from swimsuits, and may be a source of PFRs in swimming pools. A quantitative risk assessment revealed that the health risk to PFRs via swimming pools was generally low and below commonly applied health risk benchmarks.

This study elucidates the impact of draw solution chemistry (in terms of pH and draw solute species) and membrane fouling on water flux and the rejection of trace organic contaminants by forward osmosis. The results show that draw solution chemistry could induce a notable impact on both water flux and TrOCs rejection. In addition, the impact was further influenced by membrane fouling. The reverse flux of proton (or hydroxyl) could alter the feed solution pH, which governed the separation of ionisable TrOCs. In addition, charged compounds generally exhibited higher rejections than neutral ones by the clean membrane. Electrostatic interaction, rather than size exclusion, was therefore the dominant rejection mechanism for most compounds. There was also a weak correlation between rejection and molecular sizes of the 43 TrOCs. Compared with Na+, Li+ with a larger hydrated radius showed a significantly lower reverse salt flux, resulting in a lower ionic strength and therefore a stronger electrostatic interaction. A fouling cake layer consisted of low molecular weight neutral organics could also affect TrOC rejection due to pore blockage and cake-enhanced concentration polarisation.

Small and brief exceedances of chemicals above their guideline values in drinking water are unlikely to cause an appreciable increased risk to human health. As a result, short-term exposure values (STEV) can be derived to help decide whether drinking water can still be supplied to consumers without adverse health risks. In this study, three approaches were applied to calculate and compare STEV for pesticides. The three approaches included basing a STEV on the acute reference dose (ARfD) (Approach 1), removing conventional attribution rates and uncertainty factors from current guideline values (Approach 2) and extrapolating 1 d and 7 d no observed adverse effect levels (NOAEL) from existing toxicity data using a log-linear regression (Approach 3). Despite being very different methods, the three approaches produced comparable STEV generally within an order of magnitude, which often overlapped with other existing short-term exposure values such as short-term no adverse response levels (SNARL) and health advisories (HA). The results show that adjusting the current guideline value using standard extrapolation factors (Approach 2) often produced the most conservative values. Approach 2 was then applied to two other chemical classes, disinfection by-products (DBPs) and cyanotoxins, demonstrating the wider applicability of the approach.

A constructed wetland (CW) microcosm based on conductive graphite gravel was investigated for hexavalent chromium (Cr(VI)) treatment from synthetic wastewater. Its performance was evaluated and compared with a traditional gravel-based CW microcosm. The microcosms were operated at varying initial Cr(VI) concentrations (5−20 mg/L) and hydraulic retention times (HRT) (3–7.5 h). Near complete treatment (99.9 ± 0.06 %) was achieved in the graphite-based microcosm throughout the experiment. The performance was consistently high throughout with 42.9 % improvement in Cr (VI) treatment compared to a traditional gravel microcosm. Scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX) analysis indicated that chromium was adsorbed to microbial biofilms. Moreover, microbial diversity profiling suggested that the microbial population in both microcosms differed in diversity and communities. The results suggest that the use of conductive materials in CW significantly enhances the treatment of Cr(VI) and more importantly, allows microbial activity even at high levels of Cr(VI) in the CW.

This study provides a new approach of electrode dependent anaerobic ammonium oxidation (electroanammox) in microbial fuel cell (MFC) integrated hybrid constructed wetlands (CWs). The study was carried out in three CWs, each with a horizontal flow (HF) followed by a vertical upflow (VUF). Two of the CWs were integrated with MFC, one was operated in closed circuit (CL) mode and the other in open circuit (OP) mode to determine the influence of electron transfer through an external electrical circuit. The initial nitrogen and carbon concentration were 40 mg/l and 880 mg/l respectively. The total nitrogen (TN), NH4+-N, TOC and COD removal achieved in CW-MFC-CL were 90.0 ± 1.15%, 94.4 ± 0.75%, 64.8 ± 3.0% and up to 99.5 ± 3.4%, respectively. The TN and NH4+-N removal in CW-MFC-CL was 20.0% and 13.6% higher than normal CW. Maximum current density achieved in CW-MFC-HF was of 75 mA/m3 and in CW-MFC-VUF was 156 mA/m3. Furthermore, the study revealed that even at low microbiological biomass, an MFC integrated CW operating in closed circuit gave higher removal of NH4+-N and COD than the normal CW and open circuit CW-MFC. Microbiological analysis shows the presence of already known nitrifier and denitrifer which indicates their role in electrode dependent nitrogen removal.

Wastewater treatment plants are a major pathway for pharmaceuticals to the aquatic environment. Many pharmaceuticals, including non-steroidal anti-inflammatory drugs (NSAIDs), are chiral chemicals and the biological activity of their enantiomers can differ. Few studies have assessed the effects of different NSAID enantiomers on non-target organisms. However, this information is important for environmental risk assessment to ensure that the effects of more potent enantiomers are not overlooked. In the current study, enantiomers of naproxen, ibuprofen, ketoprofen and flurbiprofen were evaluated in bioassays with bacteria, algae and fish cells. All enantiomers induced bacterial toxicity, with (R)-naproxen more toxic than (S)-naproxen (EC50 0.75 vs 0.93 mg/L) and (S)-flurbiprofen more toxic than (R)-flurbiprofen (EC50 1.22 vs 2.13 mg/L). Both (R)-flurbiprofen and (S)-flurbiprofen induced photosystem II inhibition in green algae, with (R)-flurbiprofen having a greater effect in the assay after 24 h (EC10 5.47 vs 9.07 mg/L). Only the (R)-enantiomers of flurbiprofen and ketoprofen induced ethoxyresorufin-O-deethylase (EROD) activity in fish cells, while (S)-naproxen was 2.5 times more active than (R)-naproxen in the EROD assay. While enantiospecific differences were observed for all assays, the difference was less than an order of magnitude. This indicates that the risk of overlooking the effect of more potent NSAID enantiomers is minor for the studied test systems and supports the use of racemic (or single enantiomer) effect data for environmental risk assessment. However, further investigation of the (R)-enantiomer of commonly used NSAID ketoprofen is recommended as it was at least six times more potent in the EROD assay than the inactive (S)-ketoprofen.

The application of multimedia fugacity models is useful to facilitate understanding of the behaviour of emerging contaminants during wastewater treatment, as well as after their release to the environment. In this paper, twenty-two fugacity modelling applications (reported over 1995-2019) describing the distribution of organic micropollutants in wastewater treatment plants and surface water bodies were analysed in terms of model application and modelling strategy. Disparities and similarities in strategies including selection of micropollutants, data sources for internal and external model inputs, sensitivity and uncertainty analysis, as well as model validation were discussed. This review confirmed that fugacity modelling is very applicable for providing qualitative predictions of the fate and removal of organic micropollutants in the various aqueous systems. However, it was also noted that there are issues related to the uncertainties and sensitivities of fugacity models such as the sources of model inputs and selection of default settings. The issues associated with the uncertainties in the investigated fugacity models are pointed out. Recommendations are given regarding the selection of the sources of model inputs, sensitivity analysis strategies and model validation methods. This review presents the challenges and opportunities for improving multimedia fugacity models, and so paves the way for future research in this field.