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3. Effect of carbon oxygen functionalization on the activity of Pd/C catalysts in hydrogenation reactions.

Author

Stucchi, M., Capelli, S., Villa, A., Vandegehuchte, B. D., and Prati, L.

Subjects
*HYDROGENATION, *CATALYSTS, *CATALYTIC activity, *BENZYL alcohol, *OXYGEN, *CATALYTIC hydrogenation
Abstract

This paper presents a study on the effects of oxygen functionalities on a mesoporous and graphitized carbon support (GNP, Graphene Nanoplatelets), on the catalytic activity of Pd/GNP catalysts in hydrogenation reactions. A functionalization method in liquid phase has been employed, using different oxidants (HNO3, H2O2, KMnO4), with the aim to tune the amount and the type of introduced oxygen functionalities. Preformed Pd nanoparticles have been used as Pd‐precursor to limit differences in metal particle size and dispersion on differently functionalized carbon. The catalytic behaviour in benzaldehyde hydrogenation/hydrogenolysis to benzyl alcohol and toluene revealed that the introduction of oxygen functionalities has a generally detrimental effect. NMR relaxometry studies highlighted the weaker interaction between the carbonyl group and the functionalized Pd/GNP surface than the non–functionalized Pd/GNP demonstrating that the origin of the different catalytic activity lies on the first step of the reaction. O‐functionalities also impacted on the Pd0/Pd2+ ratio at the surface which is an established parameter correlated to the reaction rate. [ABSTRACT FROM AUTHOR]

Published
2024
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8. Anemia and acute coronary syndrome: current perspectives

Author

Stucchi M, Cantoni S, Piccinelli E, Savonitto S, and Morici N

Subjects
anemia, acute coronary syndrome, hemoglobin, red blood cell transfusion, Diseases of the circulatory (Cardiovascular) system, RC666-701
Abstract

Miriam Stucchi,1 Silvia Cantoni,2 Enrico Piccinelli,3 Stefano Savonitto,4 Nuccia Morici5,6 1Division of Cardiology, ASST Vimercate, Italy; 2Division of Hematology, ASST Grande Ospedale Metropolitano Niguarda Ca’ Granda, Milano, Italy; 3Health Science Department, Milano-Bicocca University, Milano, Italy; 4Division of Cardiology, A. Manzoni Hospital, Lecco, Italy; 5De Gasperis Cardio Center, ASST Grande Ospedale Metropolitano Niguarda Ca’ Granda, Milano, Italy; 6Department of Clinical Sciences and Community Health, Università degli Studi di Milano, Milano, Italy Abstract: Reference hemoglobin (Hb) values for the definition of anemia are still largely based on the 1968 WHO Scientific Group report, which established a cutoff value of

Published
2018

9. Block-level Evaluation and Optimization of Backside PDN for High-Performance Computing at the A14 node

Author

Sisto, G., primary, Preston, R., additional, Chen, R., additional, Mirabelli, G., additional, Farokhnejad, A., additional, Zhou, Y., additional, Ciofi, I., additional, Jourdain, A., additional, Veloso, A., additional, Stucchi, M., additional, Zografos, O., additional, Weckx, P., additional, Hellings, G., additional, and Ryckaert, J., additional

Published
2023
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12. C84 OUTCOME AND MORPHO–FUNCTIONAL CHANGES ON CARDIAC MAGNETIC RESONANCE IN PATIENT WITH ACUTE MYOCARDITIS FOLLOWING MRNA COVID 19 VACCINATION

Author

Palazzini, M, primary, Ammirati, E, additional, Lupi, L, additional, Garascia, A, additional, Gentile, P, additional, Pedrotti, P, additional, Giannattasio, C, additional, Ciabatti, M, additional, Rossi, V, additional, Ruschitzka, F, additional, Uribarri, A, additional, Vecchio, C, additional, Nassiacos, D, additional, Cereda, A, additional, Tumminiello, G, additional, Piriou, N, additional, Stucchi, M, additional, Peretto, G, additional, Galasso, M, additional, Sala, S, additional, Camici, P, additional, Huang, F, additional, Ianni, U, additional, Procopio, A, additional, Saponara, G, additional, Cimaglia, P, additional, Tomasoni, D, additional, Moroni, F, additional, Turco, A, additional, Di Tano, G, additional, Bollano, E, additional, Moro, C, additional, Abbate, A, additional, Dalla Bona, R, additional, Porto, I, additional, Carugo, S, additional, Campodonico, J, additional, Pontone, G, additional, Grosu, A, additional, Adamo, M, additional, Salamanca, J, additional, Ozieransky, K, additional, Sardo Infirri, L, additional, Cannatà, A, additional, Adler, E, additional, Sinagra, G, additional, Potena, L, additional, Foà, A, additional, Metra, M, additional, and Pieroni, M, additional

Published
2023
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13. Persistent ST-segment elevation with elevated myocardial necrosis markers: A case of myocardial contusion [Sopraslivellamento persistente del tratto ST con marcatori di miocardiocitonecrosi elevati: un caso di contusione cardiaca]

Author

Stucchi, M, Galasso, M, De Censi, L, Cirò, A, Pedrotti, P, Giannattasio, C, Stucchi, M, Galasso, M, De Censi, L, Cirò, A, Pedrotti, P, and Giannattasio, C

Abstract

Myocardial contusion is a rare and potentially fatal complication of chest trauma. There is no unique definition for this entity: some authors define myocardial contusion as a mild increase in cardiac biomarkers in the context of chest trauma, while for others the diagnosis requires evidence of pathologic findings at cardiac imaging. Consequently, the real incidence of myocardial contusion remains unknown, varying in reports between 8% and 71%. We describe a case of cardiac contusion secondary to a low-energy blunt chest trauma, manifesting as persistent ST-elevation associated with elevation of myocardial necrosis markers, with consequent myocardial stunning of the right ventricular free wall. As there is no consensus regarding the diagnostic pathway, it is essential to integrate first-level exams (ECG and laboratory findings) with cardiac magnetic resonance imaging, to define the presence of cardiac contusion and its extent, particularly if the echocardiographic data are unconclusive.

Published
2023

14. Outcome and Morphofunctional Changes on Cardiac Magnetic Resonance in Patients With Acute Myocarditis Following mRNA COVID-19 Vaccination

Author

Ammirati, E, Lupi, L, Palazzini, M, Ciabatti, M, Rossi, V, Gentile, P, Uribarri, A, Vecchio, C, Nassiacos, D, Cereda, A, Conca, C, Tumminello, G, Piriou, N, Lelarge, C, Pedrotti, P, Stucchi, M, Peretto, G, Galasso, M, Huang, F, Ianni, U, Procopio, A, Saponara, G, Cimaglia, P, Tomasoni, D, Moroni, F, Turco, A, Sala, S, Di Tano, G, Bollano, E, Moro, C, Abbate, A, Della Bona, R, Porto, I, Carugo, S, Campodonico, J, Pontone, G, Grosu, A, Bolognese, L, Salamanca, J, Diez-Villanueva, P, Ozieranski, K, Tyminska, A, Sardo Infirri, L, Bromage, D, Cannatà, A, Hong, K, Adamo, M, Quattrocchi, G, Foà, A, Potena, L, Garascia, A, Giannattasio, C, Adler, E, Sinagra, G, Ruschitzka, F, Camici, P, Metra, M, Pieroni, M, Ammirati, Enrico, Lupi, Laura, Palazzini, Matteo, Ciabatti, Michele, Rossi, Valentina A, Gentile, Piero, Uribarri, Aitor, Vecchio, Chiara R, Nassiacos, Daniele, Cereda, Alberto, Conca, Cristina, Tumminello, Gabriele, Piriou, Nicolas, Lelarge, Coline, Pedrotti, Patrizia, Stucchi, Miriam, Peretto, Giovanni, Galasso, Michele, Huang, Florent, Ianni, Umberto, Procopio, Antonio, Saponara, Gianluigi, Cimaglia, Paolo, Tomasoni, Daniela, Moroni, Francesco, Turco, Annalisa, Sala, Simone, Di Tano, Giuseppe, Bollano, Entela, Moro, Claudio, Abbate, Antonio, Della Bona, Roberta, Porto, Italo, Carugo, Stefano, Campodonico, Jeness, Pontone, Gianluca, Grosu, Aurelia, Bolognese, Leonardo, Salamanca, Jorge, Diez-Villanueva, Pablo, Ozieranski, Krzysztof, Tyminska, Agata, Sardo Infirri, Loren, Bromage, Daniel, Cannatà, Antonio, Hong, Kimberly N, Adamo, Marianna, Quattrocchi, Giuseppina, Foà, Alberto, Potena, Luciano, Garascia, Andrea, Giannattasio, Cristina, Adler, Eric D, Sinagra, Gianfranco, Ruschitzka, Frank, Camici, Paolo G, Metra, Marco, Pieroni, Maurizio, Ammirati, E, Lupi, L, Palazzini, M, Ciabatti, M, Rossi, V, Gentile, P, Uribarri, A, Vecchio, C, Nassiacos, D, Cereda, A, Conca, C, Tumminello, G, Piriou, N, Lelarge, C, Pedrotti, P, Stucchi, M, Peretto, G, Galasso, M, Huang, F, Ianni, U, Procopio, A, Saponara, G, Cimaglia, P, Tomasoni, D, Moroni, F, Turco, A, Sala, S, Di Tano, G, Bollano, E, Moro, C, Abbate, A, Della Bona, R, Porto, I, Carugo, S, Campodonico, J, Pontone, G, Grosu, A, Bolognese, L, Salamanca, J, Diez-Villanueva, P, Ozieranski, K, Tyminska, A, Sardo Infirri, L, Bromage, D, Cannatà, A, Hong, K, Adamo, M, Quattrocchi, G, Foà, A, Potena, L, Garascia, A, Giannattasio, C, Adler, E, Sinagra, G, Ruschitzka, F, Camici, P, Metra, M, Pieroni, M, Ammirati, Enrico, Lupi, Laura, Palazzini, Matteo, Ciabatti, Michele, Rossi, Valentina A, Gentile, Piero, Uribarri, Aitor, Vecchio, Chiara R, Nassiacos, Daniele, Cereda, Alberto, Conca, Cristina, Tumminello, Gabriele, Piriou, Nicolas, Lelarge, Coline, Pedrotti, Patrizia, Stucchi, Miriam, Peretto, Giovanni, Galasso, Michele, Huang, Florent, Ianni, Umberto, Procopio, Antonio, Saponara, Gianluigi, Cimaglia, Paolo, Tomasoni, Daniela, Moroni, Francesco, Turco, Annalisa, Sala, Simone, Di Tano, Giuseppe, Bollano, Entela, Moro, Claudio, Abbate, Antonio, Della Bona, Roberta, Porto, Italo, Carugo, Stefano, Campodonico, Jeness, Pontone, Gianluca, Grosu, Aurelia, Bolognese, Leonardo, Salamanca, Jorge, Diez-Villanueva, Pablo, Ozieranski, Krzysztof, Tyminska, Agata, Sardo Infirri, Loren, Bromage, Daniel, Cannatà, Antonio, Hong, Kimberly N, Adamo, Marianna, Quattrocchi, Giuseppina, Foà, Alberto, Potena, Luciano, Garascia, Andrea, Giannattasio, Cristina, Adler, Eric D, Sinagra, Gianfranco, Ruschitzka, Frank, Camici, Paolo G, Metra, Marco, and Pieroni, Maurizio

Published
2023

16. Scaled FinFETs Connected by Using Both Wafer Sides for Routing via Buried Power Rails

Author

Veloso, A., primary, Jourdain, A., additional, Radisic, D., additional, Chen, R., additional, Arutchelvan, G., additional, O'Sullivan, B., additional, Arimura, H., additional, Stucchi, M., additional, De Keersgieter, A., additional, Hosseini, M., additional, Hopf, T., additional, D'have, K., additional, Wang, S., additional, Dupuy, E., additional, Mannaert, G., additional, Vandersmissen, K., additional, Iacovo, S., additional, Marien, P., additional, Choudhury, S., additional, Schleicher, F., additional, Sebaai, F., additional, Oniki, Y., additional, Zhou, X., additional, Gupta, A., additional, Schram, T., additional, Briggs, B., additional, Lorant, C., additional, Rosseel, E., additional, Hikavyy, A., additional, Loo, R., additional, Geypen, J., additional, Batuk, D., additional, Martinez, G. T., additional, Soulie, J. P., additional, Devriendt, K., additional, Chan, B. T., additional, Demuynck, S., additional, Hiblot, G., additional, Van der Plas, G., additional, Ryckaert, J., additional, Beyer, G., additional, Litta, E. Dentoni, additional, Beyne, E., additional, and Horiguchi, N., additional

Published
2022
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20. Backside PDN and 2.5D MIMCAP to Double Boost 2D and 3D ICs IR-Drop beyond 2nm Node

Author

Chen, R., primary, Sisto, G., additional, Stucchi, M., additional, Jourdain, A., additional, Miyaguchi, K., additional, Schuddinck, P., additional, Woeltgens, P., additional, Lin, H., additional, Kakarla, N., additional, Veloso, A., additional, Milojevic, D., additional, Zografos, O., additional, Weckx, P., additional, Hellings, G., additional, Van Der Plas, G., additional, Ryckaert, J., additional, and Beyne, E., additional

Published
2022
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29. Recombinant LCAT (Lecithin:Cholesterol Acyltransferase) Rescues Defective HDL (High-Density Lipoprotein)-Mediated Endothelial Protection in Acute Coronary Syndrome

Author

Ossoli, A, Simonelli, S, Varrenti, M, Morici, N, Oliva, F, Stucchi, M, Gomaraschi, M, Strazzella, A, Arnaboldi, L, Thomas, M, Sorci-Thomas, M, Corsini, A, Veglia, F, Franceschini, G, Karathanasis, S, Calabresi, L, Ossoli A., Simonelli S., Varrenti M., Morici N., Oliva F., Stucchi M., Gomaraschi M., Strazzella A., Arnaboldi L., Thomas M. J., Sorci-Thomas M. G., Corsini A., Veglia F., Franceschini G., Karathanasis S. K., Calabresi L., Ossoli, A, Simonelli, S, Varrenti, M, Morici, N, Oliva, F, Stucchi, M, Gomaraschi, M, Strazzella, A, Arnaboldi, L, Thomas, M, Sorci-Thomas, M, Corsini, A, Veglia, F, Franceschini, G, Karathanasis, S, Calabresi, L, Ossoli A., Simonelli S., Varrenti M., Morici N., Oliva F., Stucchi M., Gomaraschi M., Strazzella A., Arnaboldi L., Thomas M. J., Sorci-Thomas M. G., Corsini A., Veglia F., Franceschini G., Karathanasis S. K., and Calabresi L.

Abstract

Objective- Aim of this study was to evaluate changes in LCAT (lecithin:cholesterol acyltransferase) concentration and activity in patients with an acute coronary syndrome, to investigate if these changes are related to the compromised capacity of HDL (high-density lipoprotein) to promote endothelial nitric oxide (NO) production, and to assess if rhLCAT (recombinant human LCAT) can rescue the defective vasoprotective HDL function. Approach and Results- Thirty ST-segment-elevation myocardial infarction (STEMI) patients were enrolled, and plasma was collected at hospital admission, 48 and 72 hours thereafter, at hospital discharge, and at 30-day follow-up. Plasma LCAT concentration and activity were measured and related to the capacity of HDL to promote NO production in cultured endothelial cells. In vitro studies were performed in which STEMI patients' plasma was added with rhLCAT and HDL vasoprotective activity assessed by measuring NO production in endothelial cells. The plasma concentration of the LCAT enzyme significantly decreases during STEMI with a parallel significant reduction in LCAT activity. HDL isolated from STEMI patients progressively lose the capacity to promote NO production by endothelial cells, and the reduction is related to decreased LCAT concentration. In vitro incubation of STEMI patients' plasma with rhLCAT restores HDL ability to promote endothelial NO production, possibly related to significant modification in HDL phospholipid classes. Conclusions- Impairment of cholesterol esterification may be a major factor in the HDL dysfunction observed during acute coronary syndrome. rhLCAT is able to restore HDL-mediated NO production in vitro, suggesting LCAT as potential therapeutic target for restoring HDL functionality in acute coronary syndrome.

Published
2019

30. The SHARE European Earthquake Catalogue (SHEEC) 1000–1899

Author

Stucchi, M., Rovida, A., Gomez Capera, A. A., Alexandre, P., Camelbeeck, T., Demircioglu, M. B., Gasperini, P., Kouskouna, V., Musson, R. M. W., Radulian, M., Sesetyan, K., Vilanova, S., Baumont, D., Bungum, H., Fäh, D., Lenhardt, W., Makropoulos, K., Martinez Solares, J. M., Scotti, O., Živčić, M., Albini, P., Batllo, J., Papaioannou, C., Tatevossian, R., Locati, M., Meletti, C., Viganò, D., and Giardini, D.

Published
2013
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32. A Pt-Mo hybrid catalyst for furfural transformation

Author

Stucchi, M. (Marta), Alijani, S. (Sharam), Manzoli, M. (Maela), Villa, A. (Alberto), Lahti, R. (Riikka), Galloni, M. (M.G), Lassi, U. (Ulla), Prati, L. (Laura), Stucchi, M. (Marta), Alijani, S. (Sharam), Manzoli, M. (Maela), Villa, A. (Alberto), Lahti, R. (Riikka), Galloni, M. (M.G), Lassi, U. (Ulla), and Prati, L. (Laura)

Abstract

Furfural is a high-value chemical, being the precursor of compounds such as furfuryl alcohol and tetrahydrofurfuryl alcohol. Pt is known as active for furfural hydrogenation, but the high price limits its exploitation and imposes the search for alternatives. Here we presented a Pt/Mo bimetallic system with enhanced catalytic activity for furfural hydrogenation. For comparison, monometallic Mo- and Pt-supported on activated carbon have been prepared by impregnation and sol-immobilization. The bimetallic Pt/Mo was prepared impregnating the Mo-AC catalyst with Pt, using Na2PtCl4 as a precursor, PVA, and NaBH4 as reducing agent. HR-TEM analyses on Pt/Mo catalyst showed Mo-containing agglomerates embedded in the carbon matrix, displaying diffraction fringes with spacing typical of Mo4O11 in the orthorhombic phase, as well as Pt nanoparticles more evenly dispersed in the Mo-AC system compared to bare AC. The Pt/Mo catalyst showed higher activity than both monometallic ones, and it converted 92% of furfural to furfuryl alcohol and ethyl furfuryl ether with 20% and 80% selectivity, respectively. However, despite a lower initial activity, the monometallic Mo/AC catalyst showed a complete selectivity to the ether.

Published
2020

42. The reliability margin of interconnects for advanced memory technologies

Author

Beyer, G., Demuynck, S., Stucchi, M., Ciofi, I., and Tokei, Zs.

Subjects
Market trend/market analysis, DRAM, Flash memory, Dynamic random access memory -- Usage, Flash memory -- Usage, Reliability (Engineering) -- Usage, Dynamic cell -- Usage, Dielectrics -- Quality management -- Forecasts and trends
Abstract

EXECUTIVE OVERVIEW The trends of decreasing dimensions and new materials motivated the investigation of how these may affect the dielectric reliability of the interconnect structures. We posit that for a […]

Published
2009

46. Characterisation of JSR’s spin-on hardmask FF-02

Author

Das, A., Le, Q.T., Furukawa, Y., Nguyen, V.H., Terzieva, V., de Theije, F., Whelan, C.M., Maenhoudt, M., Struyf, H., Tókei, Zs., Iacopi, F., Stucchi, M., Carbonell, L., Vos, I., Bender, H., Patz, M., Beyer, G., Van Hove, M., and Maex, K.

Published
2003
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48. Vasopressors and inotropes in cardiogenic shock: Is there room for 'adrenaline resuscitation'?

Author

Morici, N, Stucchi, M, Sacco, A, Bottiroli, M, Oliva, F, Carugo, S, Castini, D, Catena, E, Cipriani, M, Corrada, E, Frigerio, M, Gagliardone, M, Garascia, A, Gentile, F, Mafrici, A, Milazzo, F, Negrini, M, Pappalardo, F, Russo, C, Senni, M, Seregni, R, Morici N., Stucchi M., Sacco A., Bottiroli M. A., Oliva F., Carugo S., Castini D., Catena E., Cipriani M., Corrada E., Frigerio M., Gagliardone M. P., Garascia A., Gentile F., Mafrici A., Milazzo F., Negrini M., Pappalardo F., Russo C., Senni M., Seregni R. G., Morici, N, Stucchi, M, Sacco, A, Bottiroli, M, Oliva, F, Carugo, S, Castini, D, Catena, E, Cipriani, M, Corrada, E, Frigerio, M, Gagliardone, M, Garascia, A, Gentile, F, Mafrici, A, Milazzo, F, Negrini, M, Pappalardo, F, Russo, C, Senni, M, Seregni, R, Morici N., Stucchi M., Sacco A., Bottiroli M. A., Oliva F., Carugo S., Castini D., Catena E., Cipriani M., Corrada E., Frigerio M., Gagliardone M. P., Garascia A., Gentile F., Mafrici A., Milazzo F., Negrini M., Pappalardo F., Russo C., Senni M., and Seregni R. G.

Published
2016

50. Interconnect metals beyond copper: reliability challenges and opportunities

Author

Croes, K., primary, Adelmann, Ch., additional, Wilson, C.J., additional, Zahedmanesh, H., additional, Pedreira, O. Varela, additional, Wu, C., additional, Lesniewska, A., additional, Oprins, H., additional, Beyne, S., additional, Ciofi, I., additional, Kocaay, D., additional, Stucchi, M., additional, and Tokei, Zs., additional

Published
2018
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