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Knowledge graphs can effectively organize and represent information related to emergency resources for unforeseen sudden events. In this study, we construct a model layer for the knowledge graph of emergency resources, focused on sudden events, through the classification and analysis of unforeseen disaster measures. This study defines eight interconnected entity types, each characterised by a set of attributes and engaging in one or more relationships with other entity types. Utilizing 121 incident investigation reports from the emergency management departments of various provinces and cities over the past five years, we select five entities with the highest frequency of occurrence along with their corresponding four relationships. We then design an extraction plan for these entities and relationships. Based on the completed knowledge graph data, we formulate 14 questions related to emergency resources for sudden events and construct 19 corresponding question-and-answer templates using a template-based question-answering (QA) approach. We retrieve the corresponding Cypher statement templates through template mapping and obtain the question answers through querying. Finally, we design a knowledge graph question-and-answer system using the Django web framework, which includes entity queries and knowledge QA functions, specifically for emergency resources related to sudden events. [ABSTRACT FROM AUTHOR]

A new ruthenium complex, Ru(bpbp)(pbb)Cl, based on 2,6-bis(1-(phenyl)-1H-benzo[d]imidazol-2-yl)pyridine (bpbp) and 2-(1-phenyl-1H-benzo[d]imidazol-2-yl)benzoate (pbb) was synthesized. The complex Ru(bpbp)(pbb)Cl could catalytically oxidize 1-(1H-benzo[d]imidazol-2-yl)ethanol to 1-(1H-benzo[d]imidazol-2-yl)ethanone with H2O2 as oxidant. Influence of temperature and catalyst amount on the oxidation reaction was evaluated. The reaction optimal conditions are as follows: molar ratio of catalyst to substrate to H2O2 is 1 : 1000 : 3000, the proper reaction temperature is 50°C and reaction time lasts 5 h, and the isolated yield of 1-(1H-benzo[d]imidazol-2-yl)ethanol to 1-(1H-benzo[d]imidazol-2-yl)ethanone under the optimal reaction conditions is 57%. [ABSTRACT FROM AUTHOR]