254 results on '"Sub critical"'
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2. Catalytic Dehydrogenation of Cyclohexanone to Phenol Over the Ru, Rh, Pd and Pt Surfaces in Sub-critical Water
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Santosh Agrawal, Pradip Munshi, Kshudiram Mantri, Vipul Sharma, and Raksh V. Jasra
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Inorganic chemistry ,Cyclohexanone ,General Chemistry ,Catalysis ,Metal ,chemistry.chemical_compound ,chemistry ,visual_art ,Zeta potential ,visual_art.visual_art_medium ,Phenol ,Sub critical ,Dehydrogenation ,Organometallic chemistry - Abstract
With the overview of different kinds of phenol synthesis routes, dehydrogenation of cyclohexanone to phenol under sub-critical water condition using Pt, Pd, Rh, Ru and Re immobilized heterogeneous catalysts have been reported. Surface properties and characterizations of the catalysts were done. Binding of metal on a support and their relationship with zeta potential (ζ) and their effect on catalytic activity are discussed. Importance of sub-critical water reaction conditions in terms of thermodynamic favourability and phase equilibrium are evaluated through ASPEN simulator. Based on the results obtained, possible reaction pathways for the formation of product and the by-products are illustrated. The feasibility of a metal acting as a dehydrogenation catalyst according to M0/MII (E0) couple is also explained.
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- 2021
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3. Experimental Study of Sub-critical Velocity in Longitudinally Ventilated Tunnels
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Y. O. Tong, Xinyu Yang, Dongli Gao, Peng Lin, and Xingchao Chen
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law ,Airflow ,Ventilation (architecture) ,Environmental science ,Sub critical ,General Materials Science ,Upstream (networking) ,Mechanics ,Safety, Risk, Reliability and Quality ,Critical ionization velocity ,law.invention - Abstract
The critical velocity is the minimum velocity blowing towards the fire seat in tunnels to reduce the length of back-layering to zero, and it has been extensively adopted in the design of longitudinal smoke control in tunnels. A new concept, i.e., sub-critical velocity, is proposed in lieu of critical velocity for longitudinally ventilated tunnels. The sub-critical velocity allows the presence of back-layering upstream of the fire, provided that the back-layering is kept above the heads of motorists, thus posing no detrimental impact on them during evacuation. Experiments with propane fires with heat release rates of 3.7–25.5 kW were conducted in a 1/20 reduced-scale model tunnel. Both the lengths and the heights of back-layering at varying HRRs and longitudinal velocities were studied. Subsequently, the relationship of critical velocity and sub-critical velocity were developed. The results showed that sub-critical velocity is around 45–60% of the critical velocity. The adoption of sub-critical velocity in the design of longitudinally ventilated tunnels not only significantly reduces the cost of fans to drive the airflow, but also minimizes the impact of ventilation on heat release rates.
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- 2021
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4. Effect of high temperatures on the efficiency of sub-critical CO2 cycle
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Attila R. Imre and Aram Mohammed Ahmed
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Modeling and Simulation ,Nuclear engineering ,Sub critical ,Environmental science ,General Materials Science ,Software ,Computer Science Applications ,Civil and Structural Engineering ,Carbon cycle - Abstract
Thermodynamic efficiency is a crucial factor of a power cycle. Most of the studies indicated that efficiency increases with increasing heat source temperature, regardless of heat source type. Although this assumption generally is right, when the heat source temperature is close to the critical temperature, increasing the heat source temperature can decrease efficiency. Therefore, in some cases, the increase in the source temperature, like using improved or more collectors for a solar heat source can have a double negative effect by decreasing efficiency while increasing the installation costs. In this paper, a comparison of the CO2 subcritical cycle and the Trilateral Flash Cycle will be presented to show the potential negative effect of heat source temperature increase.
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- 2021
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5. Measurement of reactivity in a source driven deep sub-critical system using neutron noise methods.
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Kumar, Rajeev, Degweker, S.B., Roy, Tushar, Singh, K.P., Samanta, Sudipta, Bajpai, Shefali, Ray, Nirmal, Yakub Ali, M., Patel, Tarun, Shukla, Mayank, and Sinha, Amar
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NEUTRON transport theory , *REACTIVITY (Fission reactors) , *ACCELERATOR-driven systems , *DATA analysis , *AUTOCORRELATION (Statistics) - Abstract
Measurement of reactivity in deep sub critical system using neutron noise method is challenging due to the modal effect. This paper addresses the issue of modal effect in such system in a new and better way. The measurements were carried out in the ADS experimental facility BRAHMMA commissioned recently at Bhabha Atomic Research Centre (BARC), India. The BRAHMMA assembly is a deep sub critical system having multiplication factor (K eff ) ∼ 0.9. The data analysis was carried out using two commonly used neutron noise techniques namely the Feynman alpha and the auto correlation function methods. The modal effect was eliminated by placing the neutron detectors at strategically chosen locations in the core. The detector locations were decided on the basis of the detailed modal analysis of the core. The modal analysis and calculations of the kinetic parameters of the core were carried out using a diffusion theory code. The measured reactivity was found to be in good agreement with the theoretical estimate. [ABSTRACT FROM AUTHOR]
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- 2017
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6. A model of capillary phenomena in RN with subcritical growth
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Calogero Vetro and Vetro C.
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Capillary phenomena ,Dirichlet boundary value problem ,Settore MAT/05 - Analisi Matematica ,Capillary action ,General Mathematics ,Sub critical ,Mechanics ,Sobolev space ,P-Laplacian-like operator ,Mathematics - Abstract
This paper deals with the nonlinear Dirichlet problem of capillary phenomena involving an equation driven by the p-Laplacian-like di¤erential operator in RN. We prove the existence of at least one nontrivial nonnegative weak solution, when the reaction term satisfies a sub-critical growth condition and the potential term has certain regularities. We apply the energy functional method and weaker compactness conditions.
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- 2020
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7. Measurement of sub-critical reactivity in a heavy water reactor by neutron noise methods using a time stamping data acquisition system.
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Kumar, Rajeev, Degweker, S.B., Singh, K.P., and Ali, M. Yakub
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REACTIVITY (Fission reactors) , *HEAVY water reactors , *NEUTRONS , *DATA acquisition systems , *NUCLEAR physics experiments - Abstract
Experiments were performed to measure the sub critical reactivity in a zero power heavy water moderated reactor by neutron noise methods. The measurements were carried out using a time stamping data acquisition system developed for this purpose. This system has the advantage that it gives the complete time history of the detected neutron pulse train and a single set of data so acquired can be used for analysis by any of the noise techniques. The data obtained in the course of the experiments were analyzed using two commonly used neutron noise techniques namely the Feynman alpha and the auto correlation function methods. Noise analysis in heavy water reactors is more cumbersome than in light water reactors due to an overlap of the prompt neutron and delayed neutron time scales and consequently an unavoidable contribution from delayed neutrons and photo neutrons. Measurements were done at various levels of sub criticality by varying the moderator level height. The measured sub-critical reactivities were found to be in good agreement with theoretical estimates. [ABSTRACT FROM AUTHOR]
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- 2016
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8. Misdiagnosis prevents accurate monitoring of transmission and burden for sub-critical pathogens: a case study of Plasmodium knowlesi malaria
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John H. Huber
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medicine.medical_specialty ,biology ,business.industry ,biology.organism_classification ,medicine.disease ,law.invention ,Transmission (mechanics) ,law ,Plasmodium knowlesi ,medicine ,Sub critical ,Intensive care medicine ,business ,Basic reproduction number ,Malaria - Abstract
Maintaining surveillance of emerging infectious diseases presents challenges for monitoring their transmission and burden. Incomplete observation of infections and imperfect diagnosis reduce the observed sizes of transmission chains relative to their true sizes. Previous studies have examined the effect of incomplete observation on estimates of pathogen transmission and burden. However, each study assumed that, if observed, each infection was correctly diagnosed. Here, I leveraged principles from branching process theory to examine how misdiagnosis could contribute to bias in estimates of transmission and burden for emerging infectious diseases. Using the zoonotic Plasmodium knowlesi malaria as a case study, I found that, even when assuming complete observation of infections, the number of misdiagnosed cases within a transmission chain for every correctly diagnosed case could range from 0 (0 – 4) when R0 was 0.1 to 86 (0 – 837) when R0 was 0.9. Data on transmission chain sizes obtained using an imperfect diagnostic could consistently lead to underestimates of R0, the basic reproduction number, and simulations revealed that such data on up to 1,000 observed transmission chains was not powered to detect changes in transmission. My results demonstrate that misdiagnosis may hinder effective monitoring of emerging infectious diseases and that sensitivity of diagnostics should be considered in evaluations of surveillance systems.
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- 2021
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9. Performance of Various Turbulence Models for Simulating Sub-critical High-Reynolds Number Flows over a Smooth Cylinder
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Sylvain Lardeau, Sylvain Laizet, and Michael D. Mays
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Physics ,symbols.namesake ,Turbulence ,symbols ,Cylinder ,Reynolds number ,Sub critical ,Mechanics - Published
- 2021
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10. Non‐linear rheological response as a tool for assessing dispersion in polypropylene/polycaprolactone/clay nanocomposites and blends made with sub‐critical gas‐assisted processing
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Galip Yilmaz, Thomas Ellingham, and Lih-Sheng Turng
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Polypropylene ,Materials science ,Nanocomposite ,Polymers and Plastics ,General Chemistry ,Nonlinear system ,chemistry.chemical_compound ,chemistry ,Rheology ,Polycaprolactone ,Dispersion (optics) ,Materials Chemistry ,Sub critical ,Composite material - Published
- 2019
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11. Physical model simulation of surface subsidence under sub-critical condition
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Supattra Khamrat, Kittitep Fuenkajorn, and Suratwadee Sartkaew
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021110 strategic, defence & security studies ,0211 other engineering and technologies ,Excavation ,Subsidence ,02 engineering and technology ,Geotechnical Engineering and Engineering Geology ,Physical modelling ,Representativeness heuristic ,Model simulation ,Groundwater-related subsidence ,Sub critical ,Geotechnical engineering ,Geology ,021101 geological & geomatics engineering - Abstract
Physical modelling and numerical analyses are performed to assess the representativeness of some widely used profile functions developed to describe the subsidence configurations under sub-critical conditions. Synthetic gel is used to simulate the overburden. The surface profile measurements are used to calculate the maximum subsidence, slope and curvature angle. The model results agree well with those obtained from numerical analyses with discrepancies of less than 3%. Both suggest that the subsidence components increase with opening width-to-depth ratio. Under the same trough width, the trigonometric function slightly underpredicts the subsidence components, particularly for those induced by deep and small openings. The subsidence components predicted by the hyperbolic function are about 10% greater than those of the physical models. The exponential function underestimates the model measurements by about 5% for all cases. A set of empirical equations is derived to fit with the test results, which can be used to predict the subsidence components induced by the mine opening. Based on the scale law, the gel properties and the opening depths and widths can be correlated with those of the prototypes representing overburden above salt and potash mines in the Maha Sarakham formation.
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- 2019
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12. Sugar Recovery from Food Waste via Sub-critical Water Treatment
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Rozita Omar, Farah Saleena Taip, Siti Mazlina Mustapa Kamal, Nurfatimah Mohd Thani, Shamsul Izhar, and Alifdalino Sulaiman
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chemistry.chemical_classification ,0303 health sciences ,030309 nutrition & dietetics ,Chemistry ,General Chemical Engineering ,fungi ,digestive, oral, and skin physiology ,food and beverages ,04 agricultural and veterinary sciences ,Carbohydrate ,040401 food science ,03 medical and health sciences ,Hydrolysis ,Food waste ,0404 agricultural biotechnology ,Sub critical ,Monosaccharide ,Water treatment ,Food science ,Sugar ,Food Science - Abstract
Large quantities of food are wasted globally. Sugars such as monosaccharides and oligosaccharides are valuable carbohydrate compounds that can be hydrolyzed from food waste, particularly from carbo...
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- 2019
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13. Moderate deviations for the total population arising from a nearly unstable sub-critical Galton-Watson process with immigration
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Haotian Chen and Yong Zhang
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Statistics and Probability ,021103 operations research ,media_common.quotation_subject ,Immigration ,0211 other engineering and technologies ,02 engineering and technology ,Total population ,01 natural sciences ,Galton–Watson process ,010104 statistics & probability ,Statistics ,Sub critical ,Moderate deviations ,0101 mathematics ,media_common ,Mathematics - Abstract
In this paper, we consider the moderate deviation of the nearly unstable sub-critical Galton-Waston process with immigration for the centered total population arising. We discuss the main influence...
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- 2019
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14. Design and thermal performance of spoke cavity prototype cryomodule of the Chinese Accelerator Driven Sub-critical system Injector-I
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Jiyuan Zhai, Hongyan Zhu, Ruixiong Han, Shaopeng Li, Zhengze Chang, Minjing Sang, Jian-Qing Zhang, Zhuo Zhang, Rui Ye, Rui Ge, L. T. Sun, Miaofu Xu, Zhengping Zou, Xiangzhen Zhang, Jiehao Zhang, and Lin Bian
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Physics ,Nuclear and High Energy Physics ,010308 nuclear & particles physics ,Mechanical engineering ,Peak current ,Injector ,01 natural sciences ,Linear particle accelerator ,law.invention ,Proton (rocket family) ,law ,Cryomodule ,0103 physical sciences ,Thermal ,Sub critical ,010306 general physics ,Instrumentation ,Beam (structure) - Abstract
The Chinese Accelerator Driven Sub-critical system (C-ADS) Injector-I is designed and constructed by the Institute of High Energy Physics (IHEP) of the Chinese Academy of Sciences (CAS) in Beijing, China. The test cryomodule (TCM), housing two 325 MHz spoke cavities and two solenoids and operating at 2 K, has been designed, assembled and commissioned since the beginning of 2012. The C-ADS Injector-I linac with the TCM successfully accelerated the proton beam to 3.68 MeV with the peak current of 10.1 mA in pulse mode. It is the world’s first prototype of spoke cavity cryomodule with beam, and is an important step in the qualification of the cryomodule before series productions. This paper describes the detail of the design, operation and thermal performances of the prototype cryomodule. The analysis takes into account the heat loads of the main components (support posts, multilayer insulation and cavities) at various cryogenic temperature levels. The estimated heat loads of the cryomodule have been compared with the available experimental measurements, and the cryogenic deformations by simulation is verified by the experimental measurements by the wire position monitors (WPMs). The operation experiences including the cool down, alignment and heat load measurement are reported.
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- 2019
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15. Scaling and Fractality in Sub-critical Fatigue and Creep Crack Growth
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Alberto Carpinteri
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Materials science ,Creep ,Range (statistics) ,Sub critical ,Statistical physics ,Scaling ,Simple correlation - Abstract
More than 50 years ago, Paris and Erdogan [107] suggested to use the stress-intensity factor range, ΔK, to obtain the rate of crack advancement per cycle, da/dN, proposing a very general and simple correlation.
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- 2021
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16. Phenomenological reduced-order modeling of subcritical combustion in cryogenic rocket engines: an application to the prediction of high-frequency combustion instabilities
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Guillaume Storck, Sébastien Ducruix, Luc-Henry Dorey, Marie Théron, DMPE, ONERA, Université Paris Saclay [Palaiseau], ONERA-Université Paris-Saclay, Laboratoire d'Énergétique Moléculaire et Macroscopique, Combustion (EM2C), CentraleSupélec-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), and Centre National d’Études Spatiales [Paris] (CNES)
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[PHYS]Physics [physics] ,Materials science ,business.product_category ,business.industry ,02 engineering and technology ,Combustion ,01 natural sciences ,7. Clean energy ,010305 fluids & plasmas ,Reduced order ,Physics::Fluid Dynamics ,[SPI]Engineering Sciences [physics] ,020401 chemical engineering ,Rocket ,0103 physical sciences ,Sub critical ,0204 chemical engineering ,Aerospace engineering ,business - Abstract
International audience; The set of equations governing reacting two-phase flows in liquid-propellant rocket engines is simplified and linearized around a steady base flow. In the particular case of a liquid/gas coaxial injector, models for the atomization, evaporation and combustion source terms are derived from a simplified physical description of both the oxidizer liquid core and spray. The resulting equations are projected onto a modal basis, leading to a quasi-linear dynamic description of the evolution of the system. In this paper, detailed model reduction focuses on the evaporation of polydisperse sprays and on the propagation of acoustic waves within the gas.
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- 2020
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17. PRODUCTION AND PROPERTIES OF SOLID BIOCHAR FROM OIL PALM TRUNK WASTE USING SUB-CRITICAL WATER TECHNOLOGY
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Noor Azura Muda
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Biomaterials ,Renewable Energy, Sustainability and the Environment ,Biochar ,Palm oil ,Environmental science ,Sub critical ,Production (economics) ,Pulp and paper industry ,Agronomy and Crop Science ,Trunk ,Food Science - Published
- 2020
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18. A Boundary Estimate for Singular Sub-Critical Parabolic Equations
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Naian Liao and Ugo Gianazza
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General Mathematics ,010102 general mathematics ,Mathematical analysis ,Boundary (topology) ,Type (model theory) ,01 natural sciences ,Parabolic partial differential equation ,Modulus of continuity ,Domain (mathematical analysis) ,Range (mathematics) ,Mathematics - Analysis of PDEs ,0103 physical sciences ,FOS: Mathematics ,35K67 ,Sub critical ,010307 mathematical physics ,0101 mathematics ,Mathematics ,Analysis of PDEs (math.AP) - Abstract
We prove an estimate on the modulus of continuity at a boundary point of a cylindrical domain for local weak solutions to singular parabolic equations of $p$-laplacian type, with $p$ in the sub-critical range $(1,\frac{2N}{N+1}]$. The estimate is given in terms of a Wiener-type integral, defined by a proper elliptic $p$-capacity., Comment: arXiv admin note: text overlap with arXiv:1703.04907
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- 2020
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19. Application of the respiratory 'critical care-sub-critical care-rehabilitation integrated management model' in severe stroke associated pneumonia
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Kai Wang, Li-Jun Ma, Cheng Jianjian, Hu Xingang, and Xue-Lin Wang
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Male ,Pulmonary and Respiratory Medicine ,Respiratory Therapy ,medicine.medical_specialty ,Time Factors ,Stroke-associated pneumonia ,Critical Care ,Severe stroke ,Patient satisfaction ,Humans ,Medicine ,Sub critical ,Respiratory system ,Integrated management ,APACHE ,Aged ,lcsh:RC705-779 ,APACHE II ,business.industry ,Stroke Rehabilitation ,lcsh:Diseases of the respiratory system ,Pneumonia ,Severe pneumonia ,Respiratory “Critical Care-Sub-critical Care-Rehabilitation Integrated Management Model” ,Length of Stay ,Middle Aged ,medicine.disease ,Stroke ,Intensive Care Units ,Patient Satisfaction ,Emergency medicine ,Feasibility Studies ,Female ,Blood Gas Analysis ,business ,Research Article ,Care rehabilitation - Abstract
Background This study aimed to explore the feasibility of applying the respiratory “critical care-sub-critical care-rehabilitation integrated management model” in severe stroke-associated pneumonia and evaluate its effect. Methods From January to September 2018, 24 patients with severe stroke-associated pneumonia, who were admitted to the Respiratory Intensive Care Unit of the Respiratory and Critical Care Medicine Department of Henan Provincial People’s Hospital, were randomly divided into two groups: integrated management group and control group. According to the admission criteria of the respiratory “critical care-sub-critical care-rehabilitation integrated model” prescribed by the above-mentioned hospital, patients were grouped. The professional respiratory therapy team participated in the whole treatment. The acute physiology and chronic health evaluation II (APACHE II) score, clinical pulmonary infection score (CPIS) and oxygenation index of these two groups were dynamically observed, and the average hospital stay, 28-day mortality and patient satisfaction were investigated. Results Patients in the integrated management group and control group were similar before treatment (P > 0.05). After treatment, the main indicators, the APACHE II score, CPIS score and oxygenation index, were significantly different between the integration group and control group (P P < 0.05). However, the 28-day mortality wasn’t significantly different (P > 0.05). Conclusions For patients with severe stroke-associated pneumonia, it was feasible to implement the respiratory “critical care-sub-critical care-rehabilitation integrated management model”, which could significantly improve the treatment effect, shorten average hospitalization days and improve patient/family satisfaction.
- Published
- 2020
20. Finitary coding for the sub-critical Ising model with finite expected coding volume
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Yinon Spinka
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Statistics and Probability ,finite expected coding volume ,82B20 ,01 natural sciences ,010104 statistics & probability ,Ising model ,FOS: Mathematics ,Sub critical ,Finitary ,0101 mathematics ,Mathematics ,Discrete mathematics ,Random field ,Markov chain ,Probability (math.PR) ,010102 general mathematics ,finitary coding ,60K35 ,28D99, 60K35, 82B20, 82B26, 37A60 ,82B26 ,37A60 ,Statistics, Probability and Uncertainty ,28D99 ,Mathematics - Probability ,Coding (social sciences) - Abstract
It has been shown by van den Berg and Steif that the sub-critical Ising model on $\mathbb{Z}^d$ is a finitary factor of a finite-valued i.i.d. process. We strengthen this by showing that the factor map can be made to have finite expected coding volume (in fact, stretched-exponential tails), answering a question of van den Berg and Steif. The result holds at any temperature above the critical temperature. An analogous result holds for Markov random fields satisfying a high-noise assumption and for proper colorings with a large number of colors., Comment: 24 pages, 1 figure. Renumbered theorems, minor improvements to text
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- 2020
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21. The oscillator technique for cross-section measurements in a sub-critical system
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G.R. Imel and D. Coll Segarra
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Physics ,Cross section (physics) ,Nuclear Energy and Engineering ,Sub critical ,Computational physics - Published
- 2022
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22. ASSESSMENT OF FAST-SPECTRUM BLANKET LATTICES FOR BREEDING FISSILE FUEL FROM THORIUM AND DEPLETED URANIUM IN AN EXTERNALLY DRIVEN SUB-CRITICAL GAS-COOLED PRESSURE TUBE REACTOR
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Blair P. Bromley and Jude S. Alexander
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Materials science ,chemistry ,Fissile material ,Pressure tube ,Nuclear engineering ,Depleted uranium ,Sub critical ,Thorium ,chemistry.chemical_element ,Ocean Engineering ,Blanket - Abstract
To ensure long-term nuclear energy security, it is advantageous to consider the use of externally driven sub-critical systems for producing fissile fuel to supply fleets of thermal-spectrum reactors as an alternative to using fast-spectrum or thermal-spectrum breeder reactors. Computational/analytical neutronics and heat transfer studies have been carried out for gas-cooled fuel bundle lattices with mixtures of fertile thorium and depleted uranium (DU) that could be used in the blanket region of a sub-critical fast reactor driven either by a fusion reactor in a hybrid fusion-fission reactor (HFFR) system, or an accelerator-based spallation neutron source in an accelerator driven system (ADS). The HFFR or ADS concept envisioned is one with a simple cylindrical geometry. The annular-cylindrical blanket is approximately 10 m long, can be made 2–5 m thick (1.0 m ≤ Rblanket ≤ 3.0 m to 6.0 m), and is filled with a repeating square lattice of pressure tubes filled with 0.5 m long fuel bundles that are made of (DU,Th)O2, with various mixtures of Th and DU, and refuelled periodically online. Although using blankets made of pure DUO2or ThO2are viable options to analyze, mixing DUO2with ThO2can help alleviate any potential proliferation concerns, since any233U produced from breeding will be denatured by the presence of238U in (DU, Th)O2.Lattice calculations demonstrate that the total fissile content in the fuel after an extended period of burnup (50 MWd/kg) will be approximately the same, regardless of the mixture of DU and thorium used, and that the content of americium and232U in the irradiated fuel will be
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- 2018
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23. High-Pressure and High-Temperature NMR Observation of Synthetic Polymers: High-Resolution Measurement Taking Advantage of Motional Narrowing in Sub-Critical Fluids
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Ken Yoshida, Koichi Ute, Tomohiro Hirano, and Miyuki Oshimura
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chemistry.chemical_classification ,Materials science ,chemistry ,Chemical physics ,High pressure ,High resolution ,Sub critical ,General Materials Science ,General Chemistry ,Polymer ,Condensed Matter Physics ,Motional narrowing - Published
- 2018
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24. Exergy analysis of sub-critical organic Rankin cycle for the energy utilization of biomass
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S Sandira Eljšan and I Nurdin Ćehajić
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Exergy ,Rankine cycle ,law ,020209 energy ,0202 electrical engineering, electronic engineering, information engineering ,Environmental engineering ,Sub critical ,Biomass ,Environmental science ,02 engineering and technology ,Energy (signal processing) ,law.invention - Published
- 2018
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25. Effect of water addition to super/sub-critical fluid mobile-phases for achiral and chiral separations
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Daipayan Roy, Larry Miller, and Abhijit Tarafder
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Work (thermodynamics) ,Chemical physics ,Polarity (physics) ,Chemistry ,Supercritical fluid chromatography ,Polar ,Sub critical ,Retention time ,Spectroscopy ,Analytical Chemistry - Abstract
Use of water as an additive in sub/supercritical fluid chromatography (SFC) is becoming more common. Water can significantly modify mobile-phase properties by increasing the polarity and also acting as an additional source of H-bonding - resulting in novel selectivities. Addition of water to SFC mobile-phases increases its solvating power allowing the technique to work with highly polar analytes previously thought to be out-of-scope. A lesser discussed but equally important consequence of water addition is the role it plays in modulating analyte interactions with the stationary-phase. These interactions can be beneficial in terms of having better peak shape, increased efficiency and lesser retention time. Early studies that used water in neat CO2 bear testimony to this observation. This review discusses all these aspects of incorporating water in SFC mobile-phases and aims to elucidate the topic for wider acceptance and further investigation.
- Published
- 2021
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26. Sub-critical limits are viable alternatives to critical thermal limits
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Grant A. Duffy, Brigitte Braschler, and Steven L. Chown
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0106 biological sciences ,Physiology ,Acclimatization ,Climate change ,010603 evolutionary biology ,01 natural sciences ,Biochemistry ,03 medical and health sciences ,Species Specificity ,Abundance (ecology) ,Thermal ,Statistics ,Animals ,Sub critical ,Phylogeny ,030304 developmental biology ,0303 health sciences ,Ants ,Temperature ,food and beverages ,Conversion factor ,Critical limit ,15. Life on land ,Explained variation ,13. Climate action ,Environmental science ,General Agricultural and Biological Sciences ,Developmental Biology - Abstract
Thermal traits are frequently used to explain variation in species distributions, abundance, and sensitivity to climate change. Due to their utility and ease of measurement, critical thermal limits in particular have proliferated across the ecophysiological literature. Critical limit assays can, however, have deleterious or even lethal effects on individuals and there is growing recognition that intermediate metrics of performance can provide a further, nuanced understanding of how species interact with their environments. Meanwhile, the scarcity of data describing sub-critical or voluntary limits, which have been proposed as alternatives to critical limits and can be collected under less extreme conditions, reduces their value in comparative analyses and broad-scale syntheses. To overcome these limitations and determine if sub-critical limits are viable proxies for upper and lower critical thermal limits we measured and compared the critical and sub-critical thermal limits of 2023 ants representing 51 species. Sub-critical limits in isolation were a satisfactory linear predictor for both individual and species critical limits and when species identity was also considered there were substantial gains in variance explained. These gains indicate that a species-specific conversion factor can further improve estimates of critical traits using sub-critical proxies. Sub-critical limits can, therefore, be integrated into broader syntheses of critical limits and confidently used to calculate common ecological metrics, such as warming tolerance, so long as uncertainty in estimates is explicitly acknowledged. Although lower thermal traits exhibited more variation than their upper counterparts, the stronger phylogenetic signal of lower thermal traits indicates that appropriate conversions for lower thermal traits can be inferred from congenerics or other closely related taxa.
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- 2021
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27. Pore Structural Characterization of Shales Treated by Sub-Critical and Supercritical CO2 Exposure
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Yiwen Ju, Xuefu Xian, Jingqiang Tan, Hong Yin, Qili Liu, Junping Zhou, and Yongdong Jiang
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Materials science ,Chemical engineering ,020209 energy ,0202 electrical engineering, electronic engineering, information engineering ,Biomedical Engineering ,Sub critical ,General Materials Science ,Bioengineering ,02 engineering and technology ,General Chemistry ,Condensed Matter Physics ,Supercritical fluid ,Characterization (materials science) - Published
- 2017
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28. Exergy and thermoeconomic analyses of 500 MWe sub critical thermal power plant with solar aided feed water heating
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S.C. Kaushik and Sairam Adibhatla
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Exergy ,Engineering ,Water heating ,Waste management ,business.industry ,020209 energy ,Boiler (power generation) ,Energy Engineering and Power Technology ,Thermal power station ,02 engineering and technology ,Industrial and Manufacturing Engineering ,020401 chemical engineering ,Heat exchanger ,0202 electrical engineering, electronic engineering, information engineering ,Exergy efficiency ,Capital cost ,Sub critical ,0204 chemical engineering ,business - Abstract
In this paper, an attempt has been made to integrate solar aided feed water heating with a 500 MWe sub critical coal fired thermal power plant. Complete bleed steam substitution in high pressure heaters (HPH) has been attained by placing a feed water heat exchanger (FWHE) in parallel to the HPH group for solar aided feed water heating. Exergy and thermo economic analyses have been performed on both reference 500 MWe and conceptual solar aided 500 MWe thermal power plants. The exergy analysis has revealed that the solar field followed by boiler have the maximum exergy destruction ratios of 78.90% and 56.52% respectively. The corresponding second law efficiencies of solar field and boiler are 21.10% and 43.48% respectively. Thermoeconomic analysis has been performed on both the plants by developing physical and productive structures for them. A set of linear equations have been developed and solved for finding the cost rates of different product streams.
- Published
- 2017
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29. Co-liquefaction of mixed culture microalgal strains under sub-critical water conditions
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Nilusha Sudasinghe, Peter J. Lammers, Kodanda Phani Raj Dandamudi, Tanner Schaub, Shuguang Deng, Tapaswy Muppaneni, and F. Omar Holguin
- Subjects
Environmental Engineering ,020209 energy ,Batch reactor ,Bioengineering ,02 engineering and technology ,010501 environmental sciences ,01 natural sciences ,Mixed culture ,Biochar ,Botany ,Microalgae ,0202 electrical engineering, electronic engineering, information engineering ,Sub critical ,Biomass ,Food science ,Waste Management and Disposal ,0105 earth and related environmental sciences ,biology ,Renewable Energy, Sustainability and the Environment ,Galdieria sulphuraria ,Temperature ,Water ,Liquefaction ,General Medicine ,biology.organism_classification ,Cyanidioschyzon merolae ,Yield (chemistry) ,Oils - Abstract
We report the co-liquefaction performance of unicellular, red alga Cyanidioschyzon merolae and Galdieria sulphuraria under sub-critical water conditions within a stainless-steel batch reactor under different temperatures (150-300°C), residence time (15-60min), and Cyanidioschyzon merolae to Galdieria sulphuraria mass loading (0-100%). Individual liquefaction of C. merolae and G. sulphuraria at 300°C achieved maximum biocrude oil yield of 18.9 and 14.0%, respectively. The yield of biocrude oil increased to 25.5%, suggesting a positive synergistic effect during the co-liquefaction of 80-20mass loading of C. merolae to G. sulphuraria. The biocrude oils were analyzed by FT-ICR MS which showed that co-liquefaction did not significantly affect the distribution of product compounds compared to individual oils. The co-liquefied biocrude and biochar have a higher-heating-value of 35.28 and 7.96MJ/kg. Ultimate and proximate analysis were performed on algae biomass, biocrude and biochar.
- Published
- 2017
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30. Conceptual design of a sub-critical Pb-cooled Accelerator Driven System (ADS) fuelled by (Th-LEU)
- Author
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G. Glinatsis, D. Gugiu, Mario Carta, and Carta, M.
- Subjects
ADS ,Sub-criticality ,Computer science ,Fuel cycle ,Nuclear engineering ,Monte Carlo methods ,Monte Carlo method ,Core design ,Reactivity coefficients ,Nuclear Energy and Engineering ,Conceptual design ,Criticality ,Sub critical ,Boundary value problem - Abstract
The target of this study is to provide information on the actual boundary conditions encountered in the conceptual design of an ADS fuelled by (Th, LEU), as well as their impact on the design itself, on the performances of the system and on the possible solutions from the point of view of the choice of materials, the operating conditions, the neutron design optimization, etc. In this paper rationales and consequences of the (Th, U) fuel cycle adoption, together with the design constraints, are discussed. Identified reference core configuration and the steady state criticality results are also discussed. Stochastic approach for the neutronic evaluations has been adopted. © 2017 Elsevier Ltd
- Published
- 2017
- Full Text
- View/download PDF
31. Vibration analysis of a multi-fault transient rotor passing through sub-critical resonances
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Y.K. Younes and Heba H. El-Mongy
- Subjects
Computer science ,Rotor (electric) ,Mechanical Engineering ,Aerospace Engineering ,02 engineering and technology ,Fault (power engineering) ,01 natural sciences ,law.invention ,Vibration ,020303 mechanical engineering & transports ,0203 mechanical engineering ,Safe operation ,Mechanics of Materials ,Vibration response ,Control theory ,law ,0103 physical sciences ,Automotive Engineering ,Sub critical ,General Materials Science ,Transient (oscillation) ,Transient response ,010301 acoustics - Abstract
Various faults may simultaneously occur in a rotor dynamic system. It is crucial to detect and monitor these faults to ensure the safe operation of machinery. Usually, vibration response is utilized for fault diagnosis; however, the identification process becomes more challenging when multiple faults exhibit similar symptoms in the vibration response. In this paper, the vibrational transient response of a cracked rotor is analyzed in the presence of unbalance and coupling misalignment. The study focuses on investigating the possibility, advantages and limitations of using the sub-critical startup response in solving the fault identification problem. Numerical simulations using finite element modeling and experimental investigations are carried out for different individual and multi-fault conditions. Various factors are taken into consideration, including sub-critical limit speed, crack parameters, unbalance parameters and misalignment severity. Numerical and experimental investigations showed that the sub-critical transient response is suitable for the fault detection and diagnosis of the simultaneously existing faults studied. Compared to the critical response, the sub-critical response is more informative and each fault shows a unique feature that can be extracted without the need for sophisticated post signal processing. The study provides useful insights on the interaction between the various fault effects on the vibratory response and presents a simple method for condition monitoring of industrial equipment.
- Published
- 2017
- Full Text
- View/download PDF
32. Scattering of solutions to the defocusing energy subcritical semi-linear wave equation in 3D
- Author
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Ruipeng Shen
- Subjects
Scattering ,Applied Mathematics ,010102 general mathematics ,Mathematical analysis ,Space (mathematics) ,Wave equation ,01 natural sciences ,0103 physical sciences ,Sub critical ,010307 mathematical physics ,0101 mathematics ,Analysis ,Energy (signal processing) ,Linear wave equation ,Mathematics - Abstract
In this paper, we consider a semi-linear, energy sub-critical, defocusing wave equation in the three-dimensional space with p∈[3,5). We prove that if initial data are radial so that , where...
- Published
- 2017
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- View/download PDF
33. 2D Quasi-Geostrophic equation; sub-critical and critical cases
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Tomasz Dlotko and Chunyou Sun
- Subjects
Applied Mathematics ,010102 general mathematics ,Mathematical analysis ,01 natural sciences ,Task (project management) ,010101 applied mathematics ,Alpha (programming language) ,Viscosity (programming) ,Sub critical ,Uniqueness ,0101 mathematics ,Analysis ,Geostrophic wind ,Mathematics - Abstract
Our task here is to use a version of the 'vanishing viscosity technique' to study the critical 2D Quasi-Geostrophic equation. The present paper extends and specializes the results reported in Dlotko et al. (2015). We treat now in more detail the solutions of the critical problem (alpha = 1/2); in particular their uniqueness, regularity and long time behavior. (C) 2016 Elsevier Ltd. All rights reserved.
- Published
- 2017
- Full Text
- View/download PDF
34. Unsteady Multi-hole Probe Measurements of the Near Wake of a Circular Cylinder at Sub-critical Reynolds Numbers
- Author
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Christian Breitsamter, Daniel Iglesias, and Florian M. Heckmeier
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Physics ,Reynolds number ,Mechanics ,Wake ,Vortex shedding ,Spectral line ,law.invention ,Physics::Fluid Dynamics ,symbols.namesake ,Pressure measurement ,Lateral velocity ,law ,symbols ,Sub critical ,Cylinder - Abstract
Unsteady multi-hole probe measurements are conducted to investigate the near wake of a circular cylinder at Reynolds numbers which vary between 3000 and 10000. Besides the pressure measurements, data with a triple-wire probe are recorded to validate the multi-hole probe results. The streamwise and lateral velocity components and their higher order statistical moments are investigated. Furthermore, frequency spectra of the velocity components are shown. Experimental results of the unsteady multi-hole probe demonstrate a good match with the hot-wire results as well as numerical and experimental data from the literature.
- Published
- 2019
- Full Text
- View/download PDF
35. Analysis of Sub-Critical Cracking in a Ti-5Al-2.5Sn Liquid Hydrogen Control Valve
- Author
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R. A. Bayles and D. A. Meyn
- Subjects
Control valves ,Cracking ,Materials science ,Sub critical ,Composite material ,Liquid hydrogen - Abstract
A liquid hydrogen main fuel control valve for a rocket engine failed by fracture of the Ti-5Al-2.5Sn body during the last of a series of static engine test firings. Fractographic, metallurgical, and stress analyses determined that a combination of fatigue and unexpected aqueous stress-corrosion cracking initiated and propagated the crack which caused failure. The failure analysis approach and its results are described to illustrate how fractography and fracture mechanics, together with a knowledge of the crack initiation and propagation mechanisms of the valve material under various stress states and environments, helped investigators to trace the cause of failure.
- Published
- 2019
- Full Text
- View/download PDF
36. The Little Things that Matter:Detonation Manipulation through Sub-Critical Diameter Structure in High Explosives
- Author
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Alexander H. Mueller
- Subjects
Materials science ,Explosive material ,Detonation ,Sub critical ,Mechanics - Published
- 2019
- Full Text
- View/download PDF
37. Failed self-reformation of a sub-critical fast magnetosonic shock in collisionless plasma
- Author
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Mark E Dieckmann, Rolf Walder, Q. Moreno, Doris Folini, Xavier Ribeyre, Emmanuel d'Humières, V. T. Tikhonchuk, Centre de Recherche Astrophysique de Lyon (CRAL), École normale supérieure de Lyon (ENS de Lyon)-Université Claude Bernard Lyon 1 (UCBL), and Université de Lyon-Université de Lyon-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)
- Subjects
Physics ,Nuclear and High Energy Physics ,010504 meteorology & atmospheric sciences ,sub-critical shock ,proto-shock ,Astrophysics::High Energy Astrophysical Phenomena ,fast magnetosonic waves ,collisionless plasma ,Mechanics ,Plasma ,Condensed Matter Physics ,01 natural sciences ,Shock (mechanics) ,Nuclear Energy and Engineering ,Physics::Plasma Physics ,[SDU]Sciences of the Universe [physics] ,Physics::Space Physics ,0103 physical sciences ,Perpendicular ,Astrophysics::Solar and Stellar Astrophysics ,Sub critical ,010306 general physics ,Astrophysics::Galaxy Astrophysics ,0105 earth and related environmental sciences ,self-reformation - Abstract
International audience; We study with a 1D particle-in-cell (PIC) simulation the evolution of a subcritical perpendicular fast magnetosonic shock. The shock propagates at 1.5 times the fast magnetosonic speed. Some upstream protons are reflected by the shock's electric potential. They form a beam which carries less energy than those that are reflected magnetically by super-critical shocks. The beam triggers the growth of a fast magnetosonic solitary wave upstream of the shock, which reflects the beam protons back to the shock. Extracting the momentum and energy of this beam allows the solitary wave to grow into a proto-shock that is trailed by a short downstream region. Protons from the shock-reflected proton beam increase the density of the plasma between the shock and the proto-shock reducing its potential difference relative to both surrounding structures. Bulk protons, which cross the proto-shock, react to the decreased potential jump. The plasma behind the proto-shock accelerates and so does the shock. The trailing end of the proto-shock speeds up in order to continue reflecting the beam protons and eventually it catches up with its front; the proto-shock collapses and the self-reformation fails. A more energetic proton beam could decrease the potential jump across the shock, let it collapse and replace it with the proto-shock.
- Published
- 2019
- Full Text
- View/download PDF
38. Sub-critical gas-assisted processing of ethylene vinyl alcohol + nanoclay composites
- Author
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Thomas K. Ellingham Jr., Zhutong Li, Lukas Duddleston, Galip Yilmaz, and Lih-Sheng Turng
- Subjects
Materials science ,Sub critical ,Composite material - Published
- 2019
- Full Text
- View/download PDF
39. Realising bio-inspired impact damage-tolerant thin-ply CFRP Bouligand structures via promoting diffused sub-critical helicoidal damage
- Author
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Lorenzo Mencattelli, Silvestre T. Pinho, and European Research Council
- Subjects
Materials science ,Failure strain ,Delamination ,General Engineering ,02 engineering and technology ,Fibre-reinforced plastic ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Compression (physics) ,01 natural sciences ,09 Engineering ,0104 chemical sciences ,Residual strength ,Ceramics and Composites ,Sub critical ,Pitch angle ,Composite material ,0210 nano-technology ,Materials ,Damage tolerance - Abstract
In this work, we manufactured bio-inspired thin-ply Carbon Fibre Reinforced Plastic (CFRP) laminates, mimicking the helicoidal architecture of the mantis shrimp's dactyl club periodic region, with the smallest inter-ply (pitch) angle in the literature (2.5 ∘ ), thus better mimicking the actual micro-structure of the dactyl club. We conducted Low Velocity Impact (LVI) tests on a wide range of pitch angles (2.5 ∘ , 5 ∘ , 10 ∘ , 20 ∘ , 45 ∘ ), thus demonstrating that decreasing the pitch angle leads to a progressively smoother double helicoidal evolution of damage, reduces delamination areas, diffuses sub-critical damage, and enhances damage tolerance. We then conducted Compression After Impact (CAI) tests, thereby demonstrating that the residual strength and failure strain are preserved as the pitch angle is reduced, even though there is a steep decrease in the proportion of 0 ∘ -plies (plies aligned with the loading direction) as the pitch angle decreases. Via detailed modelling, we then developed and proposed an explanation for why very small pitch angles are required to achieve the beneficial damage mechanisms exhibited by biological Bouligand structures.
- Published
- 2019
- Full Text
- View/download PDF
40. A multiparameter fractional Laplace problem with semipositone nonlinearity
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Sweta Tiwari and R. Dhanya
- Subjects
Physics ,Applied Mathematics ,media_common.quotation_subject ,Boundary (topology) ,General Medicine ,Type (model theory) ,Infinity ,Lambda ,Omega ,Combinatorics ,Bounded function ,Laplace problem ,Sub critical ,Analysis ,media_common - Abstract
In this paper we prove the existence of at least one positive solution for nonlocal semipositone problem of the type \begin{document}$ (P_\lambda^\mu)\left\{ \begin{array}{rcl} (-\Delta)^s u& = & \lambda(u^{q}-1)+\mu u^r \text{ in } \Omega\\ u&>&0 \text{ in } \Omega\\ u&\equiv &0 \text{ on }{\mathbb R^N\setminus\Omega}. \end{array}\right. $\end{document} when the positive parameters \begin{document}$ \lambda $\end{document} and \begin{document}$ \mu $\end{document} belong to certain range. Here \begin{document}$ \Omega\subset \mathbb{R}^N $\end{document} is assumed to be a bounded open set with smooth boundary, \begin{document}$ s\in (0, 1), N> 2s $\end{document} and \begin{document}$ 0 First we consider \begin{document}$ (P_ \lambda^\mu) $\end{document} when \begin{document}$ \mu = 0 $\end{document} and prove that there exists \begin{document}$ \lambda_0\in(0, \infty) $\end{document} such that for all \begin{document}$ \lambda> \lambda_0 $\end{document} the problem \begin{document}$ (P_ \lambda^0) $\end{document} admits at least one positive solution. In fact we will show the existence of a continuous branch of maximal solutions of \begin{document}$ (P_\lambda^0) $\end{document} emanating from infinity. Next for each \begin{document}$ \lambda>\lambda_0 $\end{document} and for all \begin{document}$ 0 we establish the existence of at least one positive solution of \begin{document}$ (P_\lambda^\mu) $\end{document} using variational method. Also in the sub critical case, i.e., for \begin{document}$ 1, we show the existence of second positive solution via mountain pass argument.
- Published
- 2021
- Full Text
- View/download PDF
41. Sub-critical and critical stochastic quasi-geostrophic equations with infinite delay
- Author
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Yejuan Wang and Tongtong Liang
- Subjects
Physics ,Pure mathematics ,Quasi-geostrophic equations ,Multiplicative white noise ,Applied Mathematics ,010102 general mathematics ,01 natural sciences ,010101 applied mathematics ,Dissipative system ,Local martingale ,Discrete Mathematics and Combinatorics ,Sub critical ,Uniqueness ,0101 mathematics ,Fractional Laplacian - Abstract
In this paper, we investigate a stochastic fractionally dissipative quasi-geostrophic equation driven by a multiplicative white noise, whose external forces contain hereditary characteristics. The existence and uniqueness of both local martingale and local pathwise solutions are established in \begin{document}$ H^s $\end{document} with \begin{document}$ s\geq2-2\alpha $\end{document} , where \begin{document}$ \alpha\in(\frac{1}{2}, 1) $\end{document} . For the critical case \begin{document}$ \alpha = \frac12 $\end{document} , we obtain the similar results in \begin{document}$ H^s $\end{document} with \begin{document}$ s>1 $\end{document} .
- Published
- 2021
- Full Text
- View/download PDF
42. The Effect of Sub-Critical Heat Treatment on Hardness, Retained Austenite and Abrasive Wear Resistance of Hypoeutectic 16 mass% Cr-2 mass% Mo Cast Iron with Varying Vanadium Content
- Author
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Sudsakorn Inthidech, Keartisak Sriprateep, Yasuhiro Matsubara, and Pisizchai Kosasu
- Subjects
010302 applied physics ,Austenite ,Materials science ,Mechanical Engineering ,Abrasive ,Metallurgy ,Vanadium ,chemistry.chemical_element ,02 engineering and technology ,engineering.material ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,Wear resistance ,chemistry ,Mechanics of Materials ,0103 physical sciences ,engineering ,Sub critical ,General Materials Science ,Cast iron ,0210 nano-technology ,Eutectic system - Published
- 2016
- Full Text
- View/download PDF
43. A PROPOSAL OF THE EXTRACTION TEST OF ASPHALT USING SUB-CRITICAL WATER
- Author
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Kengo Akatsu, Katsumi Sato, Shoichi Akiba, and Yosuke Kanou
- Subjects
Engineering ,Asphalt ,business.industry ,Extraction (chemistry) ,Sub critical ,Geotechnical engineering ,Water pressure ,business - Abstract
The authors have already showed the possibility of the application as the asphalt extractant of the high temperature and high pressure water. And they have suggested an extraction test of asphalt considering environment balance type by using the sub-critical water that is 350°C and 16MPa. However, as for this test, the examination for the different asphalt of the property and the various asphalt mixtures was not accomplished, and the applicability and the reproducibility for them were unconfirmed. Therefore, in this study, the authors confirmed the adaptability for a representative asphalt mixture for the development of the sub-critical water method, and examined for the device, conditions and method of test to improve measurement precision. As a result, this sub-critical water method was systematized that was available for the new mixture which contained straight asphalt or modified asphalt and reproduction aggregate, and the usefulness became clear. 著者らは,これまで高温高圧水のアスファルト抽出溶媒としての応用の可能性を明らかにしており,実用を視座にした基礎研究から,350°C・16MPaの亜臨界水を抽出溶媒とした環境調和型アスファルト抽出試験法を提案している.しかし,本手法は,性質の異なるアスファルトや種々のアスファルト混合物に対する検討がなされておらず,多様な供試体に対する適用性や再現性についての信頼性が不明であった.本研究では,亜臨界水を用いた抽出試験法の開発に向けて,代表的なアスファルト混合物に対する適応性を確認し,測定精度を向上させるための試験装置,試験条件・方法について検討した.この結果,ストレートアスファルト,改質アスファルトを含有する新規混合物,ならびに再生骨材に適応可能な亜臨界水抽出法を体系化し,その有用性を明らかにした.
- Published
- 2016
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44. Analysis On Optimization Operation Of Cold End Of 600MW Wet Cooling Sub-critical Air Cooling Unit
- Author
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Bai Wei, li Qianyu, Zhang Jinsong, Zhang Qi, Xiao Yu, Wang Liuhu, Jin Shengxiang, He Chuan, li Daming, and Zhou Yong
- Subjects
Air cooling ,History ,Nuclear engineering ,Environmental science ,Sub critical ,Computer Science Applications ,Education ,Unit (housing) - Abstract
Due to its remarkable water-saving characteristics, direct air cooling device has been widely used in carbon rich and water deficient areas in China. However, in the high temperature period in summer, the exhaust pressure of air cooling unit will rise greatly, the exhaust steam temperature will be high and the condensate temperature will be high. In this paper, Daihai Power Plant Phase I unit transformation as the research object, the cold end optimization of air cooling unit is analyzed, in order to improve the unit operation economy.
- Published
- 2020
- Full Text
- View/download PDF
45. Sub critical water-methanol condition of rice bran oil for biodiesel production
- Author
-
Lidya Elizabeth and G. Prihandini
- Subjects
Chemistry ,Biodiesel production ,Rice bran oil ,Sub critical ,Water methanol ,Pulp and paper industry - Abstract
Biodiesel produced in conventional way by using catalyst make environment harmful. Subcritical water is a new method, green technology which can be employed to convert rice bran with water and methanol to fatty acid methyl ester (FAMEs) or biodiesel with adding CO2 and N2 gas as co-solvent. The aim of this study to investigates the influence of operation condition of biodiesel production from rice bran oil. Some solvents concentrated, range of temperature, pressurized gas and reaction time were applied in this research. Rice bran, water, and ethanol were put into subcritical water reactor in a certain ratio at 40bar to carried out the reaction under subcritical condition. The best condition 30/10 methanol-water (v/v), t = 7 h, T = 200 °C, CO2 as co-solvent was highest yield oil obtained 18% with oleic acid methyl ester as the major identified biodiesel.
- Published
- 2020
- Full Text
- View/download PDF
46. Large-eddy simulation of sub-, critical and super-critical Reynolds number flow past a circular cylinder
- Author
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Seong Mo Yeon
- Subjects
Reynolds number flow ,Shear layer instability ,Cylinder ,Mechanical engineering ,Sub critical ,Mechanics ,Large eddy simulation ,Mathematics - Published
- 2018
- Full Text
- View/download PDF
47. Numerical Framework for Simulation of Propulsive Systems at Sub-Critical Conditions
- Author
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Kevin Brinckman, Ashvin Hosangadi, Vineet Ahuja, and Andrea C. Zambon
- Subjects
Materials science ,business.industry ,Sub critical ,Aerospace engineering ,business - Published
- 2018
- Full Text
- View/download PDF
48. Numerical Simulations of CO2 Compressors at Near-Critical and Sub-Critical Inlet Conditions
- Author
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Z. Liu, J. Busby, V. Ahuja, T. Weathers, and A. Hosangadi
- Subjects
geography ,Impeller ,geography.geographical_feature_category ,Near critical ,Environmental science ,Sub critical ,Engineering simulation ,Mechanics ,Inlet ,Gas compressor - Abstract
An advanced real-fluid numerical framework for transcritical CO2 spanning both the supercritical and sub-critical regime near the critical point is presented. The numerical algorithm is specifically designed to faithfully model sharp variations of thermodynamic derivatives near the critical point. Numerical results for compressor performance in the Sandia test loop [1] at near critical inlet conditions have been presented over a range of flow rates from the choke point to the stall line. The analysis identifies the shift in the flow losses from the impeller to the diffuser as the flow rate increases from the stall to choke limit. The simulations have been compared with both the Sandia performance curves as well as raw data from Barber Nichols Inc. (BNI); the results compare well with the raw data and provide good qualitative comparisons with Sandia’s performance curves [1]. The numerical framework has also been extended to sub-critical conditions by solving for separate transport equations for each phase. Methodology for NIST table lookup at sub-critical conditions to identify liquid and vapor properties has been developed. Phase change is triggered when local conditions go sub-critical and do not require the phase to be specified a priori. Calculations at both near critical inlet temperatures as well as a two-phase inlet condition at lower temperatures were modeled. Significant difference in the phase change characteristics at these two conditions have been identified and discussed in the paper.
- Published
- 2018
- Full Text
- View/download PDF
49. Life Cycle Analysis: Sub-Critical Pulverized Coal (SubPC) Power Plants
- Author
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Greg Schivley, Greg Cooney, Matt Jamieson, Michele Mutchek, Michelle Krynock, James Littlefield, Chung Shih, Joe Marriott, and Timothy J. Skone
- Subjects
Pulverized coal-fired boiler ,business.industry ,Environmental science ,Sub critical ,Process engineering ,business ,Power (physics) - Published
- 2018
- Full Text
- View/download PDF
50. Nanoplasmonic ('Sub-Critical') Silver as Optically Absorptive Layers in Solar-Control Glasses
- Author
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Paul A. Medwick and Vitro Architectural Glass
- Subjects
Optics ,Materials science ,business.industry ,Sub critical ,Optoelectronics ,business - Published
- 2018
- Full Text
- View/download PDF
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