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Organic features lead to two distinct types of Class 0/I low-mass protostars: hot corino sources, and warm carbon-chain chemistry (WCCC) sources. Some observations suggest that the chemical variations between WCCC sources and hot corino sources are associated with local environments, as well as the luminosity of protostars. We conducted gas-grain chemical simulation in collapsing protostellar cores, and found that the fiducial model predicts abundant carbon-chain molecules and COMs, and reproduces WCCC and hot corino chemistry in the hybrid source L483. By changing values of some physical parameters, including the visual extinction of ambient clouds ($A_{\rm V}^{\rm amb}$), the cosmic-ray ionization rate ($\zeta$), the maximum temperature during the warm-up phase ($T_{\rm max}$), and the contraction timescale of protostars ($t_{\rm cont}$), we found that UV photons and cosmic rays can boost WCCC features by accelerating the dissociation of CO and CH$_4$ molecules. On the other hand, UV photons can weaken the hot corino chemistry by photodissociation reactions, while the dependence of hot corino chemistry on cosmic rays is relatively complex. The $T_{\rm max}$ does not affect WCCC features, while it can influence hot corino chemistry by changing the effective duration of two-body surface reactions for most COMs. The long $t_{\rm cont}$ can boost WCCC and hot corino chemistry, by prolonging the effective duration of WCCC reactions in the gas phase and surface formation reactions for COMs, respectively. Subsequently, we ran a model with different physical parameters to reproduce scarce COMs in prototypical WCCC sources. The scarcity of COMs in prototypical WCCC sources can be explained by insufficient dust temperature in the inner envelopes to activate hot corino chemistry. Meanwhile, the High $\zeta$ and the long $t_{\rm cont}$ favors the explanation for scarce COMs in these sources., Comment: Accepted for publication in A&A, 18 pages, 10 figures

Whether SiC$_2$ is a parent species, that is formed in the photosphere or as a by-product of high-temperature dust formation, or a daughter species, formed in a chemistry driven by the photodestruction of parent species in the outer envelope, has been debated for a long time. Here, we analyze the ALMA observations of four SiC$_2$ transitions in the CSEs of three C-rich AGB stars (AI Vol, II Lup, and RAFGL 4211), and found that SiC$_2$ exhibits an annular, shell-like distribution in these targets, suggesting that SiC$_2$ can be a daughter species in the CSEs of carbon-rich AGB stars. The results can provide important references for future chemical models., Comment: Accepted in Frontiers in Astronomy and Space Sciences

To study the chemical evolution during the formation of molecular clouds, we model three types of clouds with different density structures: collapsing spherical, collapsing ellipsoidal, and static spherical profiles. The collapsing models are better than the static models in matching the observational characteristics in typical molecular clouds. This is mainly because the gravity can speed up the formation of some important molecules (e.g., H$_2$, CO, OH) by increasing the number density during collapse. The different morphologies of prolate, oblate, and spherical clouds lead to differences in chemical evolution, which are mainly due to their different evolution of number density. We also study the effect of initial chemical compositions on chemical evolution, and find that H atoms can accelerate OH formation by two major reactions: O + H $\rightarrow$ OH in gas phase and on dust grain surfaces, leading to the models in which hydrogen is mainly atomic initially better match observations than the models in which hydrogen is mainly molecular initially. Namely, to match observations, initially hydrogen must be mostly atomic. The CO molecules are able to form even without the pre-existence of H$_2$. We also study the influence of gas temperature, dust temperature, intensity of interstellar radiation field and cosmic-ray ionization rate on chemical evolution in static clouds. The static CO clouds with high dust temperature, strong radiation field, and intensive cosmic rays are transient due to rapid CO destruction., Comment: Accepted by RAA. 28 pages, 16 figures, and 4 tables

We attempt to visually classify the morphologies of 18190 molecular clouds, which are identified in the $^{12}$CO(1-0) spectral line data over $\sim$ 450 deg$^{2}$ of the second Galactic quadrant from the Milky Way Imaging Scroll Painting project (MWISP). Using the velocity-integrated intensity maps of the $^{12}$CO(1-0) emission, molecular clouds are first divided into unresolved and resolved ones. The resolved clouds are further classified as non-filaments or filaments. Among the 18190 molecular clouds, $\sim$ 25 $\%$ are unresolved, $\sim$ 64$\%$ are non-filaments, and $\sim$ 11$\%$ are filaments. In the terms of the integrated flux of $^{12}$CO(1-0) spectra of the whole 18190 molecular clouds, $\sim$ 90$\%$ are from filaments, $\sim$ 9$\%$ are from non-filaments, and the rest $\sim$ 1$\%$ are from unresolved sources. Although non-filaments are dominant in the number of the discrete molecular clouds, filaments are the main contributor of $^{12}$CO emission flux. We also present the number distributions of physical parameters of the molecular clouds in our catalog, including their angular sizes, velocity spans, peak intensities of $^{12}$CO(1-0) emission, and $^{12}$CO(1-0) total fluxes. We find that there is a systematic difference between the angular sizes of the non-filaments and filaments, with the filaments tending to have larger angular scales. The H$_{2}$ column densities of them are not significantly different. We also discuss the observational effects, such as those induced by the finite spatial resolution, beam dilution and line-of-sight projection, on the morphological classification of molecular clouds in our sample., Comment: 17 pages, 8 figures, 3 tables, appendix: 7 figures, accepted for publication in ApJS