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Quantum computational chemistry has emerged as an important application of quantum computing. Hybrid quantum-classical computing methods, such as variational quantum eigensolvers (VQE), have been designed as promising solutions to quantum chemistry problems, yet challenges due to theoretical complexity and experimental imperfections hinder progress in achieving reliable and accurate results. Experimental works for solving electronic structures are consequently still restricted to nonscalable (hardware efficient) or classically simulable (Hartree-Fock) ansatz, or limited to a few qubits with large errors. The experimental realisation of scalable and high-precision quantum chemistry simulation remains elusive. Here, we address the critical challenges {associated with} solving molecular electronic structures using noisy quantum processors. Our protocol presents significant improvements in the circuit depth and running time, key metrics for chemistry simulation. Through systematic hardware enhancements and the integration of error mitigation techniques, we push forward the limit of experimental quantum computational chemistry and successfully scale up the implementation of VQE with an optimised unitary coupled-cluster ansatz to 12 qubits. We produce high-precision results of the ground-state energy for molecules with error suppression by around two orders of magnitude. We achieve chemical accuracy for H$_2$ at all bond distances and LiH at small bond distances in the experiment, even beyond the two recent concurrent works. Our work demonstrates a feasible path towards a scalable solution to electronic structure calculation, validating the key technological features and identifying future challenges for this goal., Comment: 11 pages, 4 figures in the main text, and 29 pages supplementary materials with 17 figures

The development of high-fidelity two-qubit quantum gates is essential for digital quantum computing. Here, we propose and realize an all-microwave parametric Controlled-Z (CZ) gates by coupling strength modulation in a superconducting Transmon qubit system with tunable couplers. After optimizing the design of the tunable coupler together with the control pulse numerically, we experimentally realized a 100 ns CZ gate with high fidelity of 99.38%$ \pm$0.34% and the control error being 0.1%. We note that our CZ gates are not affected by pulse distortion and do not need pulse correction, {providing a solution for the real-time pulse generation in a dynamic quantum feedback circuit}. With the expectation of utilizing our all-microwave control scheme to reduce the number of control lines through frequency multiplexing in the future, our scheme draws a blueprint for the high-integrable quantum hardware design.

Classifying many-body quantum states with distinct properties and phases of matter is one of the most fundamental tasks in quantum many-body physics. However, due to the exponential complexity that emerges from the enormous numbers of interacting particles, classifying large-scale quantum states has been extremely challenging for classical approaches. Here, we propose a new approach called quantum neuronal sensing. Utilizing a 61 qubit superconducting quantum processor, we show that our scheme can efficiently classify two different types of many-body phenomena: namely the ergodic and localized phases of matter. Our quantum neuronal sensing process allows us to extract the necessary information coming from the statistical characteristics of the eigenspectrum to distinguish these phases of matter by measuring only one qubit. Our work demonstrates the feasibility and scalability of quantum neuronal sensing for near-term quantum processors and opens new avenues for exploring quantum many-body phenomena in larger-scale systems., Comment: 7 pages, 3 figures in the main text, and 13 pages, 13 figures, and 1 table in supplementary materials

Quantum error correction is a critical technique for transitioning from noisy intermediate-scale quantum (NISQ) devices to fully fledged quantum computers. The surface code, which has a high threshold error rate, is the leading quantum error correction code for two-dimensional grid architecture. So far, the repeated error correction capability of the surface code has not been realized experimentally. Here, we experimentally implement an error-correcting surface code, the distance-3 surface code which consists of 17 qubits, on the \textit{Zuchongzhi} 2.1 superconducting quantum processor. By executing several consecutive error correction cycles, the logical error can be significantly reduced after applying corrections, achieving the repeated error correction of surface code for the first time. This experiment represents a fully functional instance of an error-correcting surface code, providing a key step on the path towards scalable fault-tolerant quantum computing.

High-fidelity two-qubits gates are essential for the realization of large-scale quantum computation and simulation. Tunable coupler design is used to reduce the problem of parasitic coupling and frequency crowding in many-qubit systems and thus thought to be advantageous. Here we design a extensible 5-qubit system in which center transmon qubit can couple to every four near-neighbor qubit via a capacitive tunable coupler and experimentally demonstrate high-fidelity controlled-phase (CZ) gate by manipulating center qubit and one near-neighbor qubit. Speckle purity benchmarking (SPB) and cross entrophy benchmarking (XEB) are used to assess the purity fidelity and the fidelity of the CZ gate. The average purity fidelity of the CZ gate is 99.69$\pm$0.04\% and the average fidelity of the CZ gate is 99.65$\pm$0.04\% which means the control error is about 0.04\%. Our work will help resovle many chanllenges in the implementation of large scale quantum systems., Comment: 6 pages, 6 figures

To ensure a long-term quantum computational advantage, the quantum hardware should be upgraded to withstand the competition of continuously improved classical algorithms and hardwares. Here, we demonstrate a superconducting quantum computing systems \textit{Zuchongzhi} 2.1, which has 66 qubits in a two-dimensional array in a tunable coupler architecture. The readout fidelity of \textit{Zuchongzhi} 2.1 is considerably improved to an average of 97.74\%. The more powerful quantum processor enables us to achieve larger-scale random quantum circuit sampling, with a system scale of up to 60 qubits and 24 cycles. The achieved sampling task is about 6 orders of magnitude more difficult than that of Sycamore [Nature \textbf{574}, 505 (2019)] in the classic simulation, and 3 orders of magnitude more difficult than the sampling task on \textit{Zuchongzhi} 2.0 [arXiv:2106.14734 (2021)]. The time consumption of classically simulating random circuit sampling experiment using state-of-the-art classical algorithm and supercomputer is extended to tens of thousands of years (about $4.8\times 10^4$ years), while \textit{Zuchongzhi} 2.1 only takes about 4.2 hours, thereby significantly enhancing the quantum computational advantage.

Scaling up to a large number of qubits with high-precision control is essential in the demonstrations of quantum computational advantage to exponentially outpace the classical hardware and algorithmic improvements. Here, we develop a two-dimensional programmable superconducting quantum processor, \textit{Zuchongzhi}, which is composed of 66 functional qubits in a tunable coupling architecture. To characterize the performance of the whole system, we perform random quantum circuits sampling for benchmarking, up to a system size of 56 qubits and 20 cycles. The computational cost of the classical simulation of this task is estimated to be 2-3 orders of magnitude higher than the previous work on 53-qubit Sycamore processor [Nature \textbf{574}, 505 (2019)]. We estimate that the sampling task finished by \textit{Zuchongzhi} in about 1.2 hours will take the most powerful supercomputer at least 8 years. Our work establishes an unambiguous quantum computational advantage that is infeasible for classical computation in a reasonable amount of time. The high-precision and programmable quantum computing platform opens a new door to explore novel many-body phenomena and implement complex quantum algorithms.

We experimentally study the ergodic dynamics of a 1D array of 12 superconducting qubits with a transverse field, and identify the regimes of strong and weak thermalization with different initial states. We observe convergence of the local observable to its thermal expectation value in the strong-thermalizaion regime. For weak thermalization, the dynamics of local observable exhibits an oscillation around the thermal value, which can only be attained by the time average. We also demonstrate that the entanglement entropy and concurrence can characterize the regimes of strong and weak thermalization. Our work provides an essential step towards a generic understanding of thermalization in quantum systems., Comment: 6+6 pages, 4+8 figures

Quantum walks are the quantum mechanical analogue of classical random walks and an extremely powerful tool in quantum simulations, quantum search algorithms, and even for universal quantum computing. In our work, we have designed and fabricated an 8x8 two-dimensional square superconducting qubit array composed of 62 functional qubits. We used this device to demonstrate high fidelity single and two particle quantum walks. Furthermore, with the high programmability of the quantum processor, we implemented a Mach-Zehnder interferometer where the quantum walker coherently traverses in two paths before interfering and exiting. By tuning the disorders on the evolution paths, we observed interference fringes with single and double walkers. Our work is an essential milestone in the field, brings future larger scale quantum applications closer to realization on these noisy intermediate-scale quantum processors., Comment: 13 pages, 4 figures, and supplementary materials with 21 pages, 13 figures and 1 table

Understanding various phenomena in non-equilibrium dynamics of closed quantum many-body systems, such as quantum thermalization, information scrambling, and nonergodic dynamics, is a crucial for modern physics. Using a ladder-type superconducting quantum processor, we perform analog quantum simulations of both the $XX$ ladder and one-dimensional (1D) $XX$ model. By measuring the dynamics of local observables, entanglement entropy and tripartite mutual information, we signal quantum thermalization and information scrambling in the $XX$ ladder. In contrast, we show that the $XX$ chain, as free fermions on a 1D lattice, fails to thermalize, and local information does not scramble in the integrable channel. Our experiments reveal ergodicity and scrambling in the controllable qubit ladder, and opens the door to further investigations on the thermodynamics and chaos in quantum many-body systems., Comment: 5 pages, 4 figures, and supplementary materials with 10 pages, 3 tables and 14 figures

Quantum resetting protocols allow a quantum system to be sent to a state in the past by making it interact with quantum probes when neither the free evolution of the system nor the interaction is controlled. We experimentally verify the simplest non-trivial case of a quantum resetting protocol, known as the $\mathcal{W}_4$ protocol, with five superconducting qubits, testing it with different types of free evolutions and target-probe interactions. After projection, we obtained a reset state fidelity as high as $0.951$, and the process fidelity was found to be $0.792$. We also implemented 100 randomly-chosen interactions and demonstrated an average success probability of $0.323$ for $|1\rangle$ and $0.292$ for $|-\rangle$, experimentally confirmed the nonzero probability of success for unknown interactions; the numerical simulated values are about $0.3$. Our experiment shows that the simplest quantum resetting protocol can be implemented with current technologies, making such protocols a valuable tool in the eternal fight against unwanted evolution in quantum systems., Comment: 9 pages, 6 figures, 1 table + Supplementary Materials