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The Shapoling Mo deposit is located in the Xiong'er rock mass of the southern margin of the North China Craton. The deposit is hosted in a contact zone between granite and wallrocks of the Taihua Soupergroup, which is a recently found discovered vein dissemination type deposit in East Qinling. The ore-bodies are associated with quartz veins and controlled by subsidiary faults. The mineralization styles include veinlet and disseminated types. In order to determine the age of the Shapoling Mo deposit, Re-Os isotopic dating of molybdenite was conducted. Six molybdenite samples yielded Re-Os ages ranging from 158.3±1.5 Ma to 160.7±1.2 Ma, with a weighted mean age of 160±1 Ma (2σ, MSWD=2.1). The Re-Os age shows that the Mo mineralization occurred during the late Jurassic, earlier than the formation of Huashan rock mass (about 30 Ma). In addition, one molybdenite sample in Huashan rock mass yielded a Re-Os age of 130.5±1.0 Ma, which is in accordance with the age of the Huashan pluton and molybdenite age (125.4-129.4 Ma) reported by a previous study. In conclusion, the Shapoling deposit contains two episodes of Mo mineralization from the early Cretaceous and late Jurassic periods. Combining this with geological characteristics and tectonic-metallogenic evolution, it is suggested that Huashan rock mass, granite porphyry, and related hydrothermal deposits in the Xiong'er terrain are the products of extrusion to extension transition during continent-continent collision in the Qinling orogenic belt.

Using the Gleeble-1500D simulator, the high temperature plastic deformation behavior of SiCp/Al-Cu composite were investigated at 350-500℃ with the strain rate of 0.01-10s-1. The true stress-strain curves were obtained in the tests. Constitutive equation and processing map were established. The results show that the softening mechanism of dynamic recrystallization is a feature of high-temperature flow stress-strain curves of SiCp/A1-Cu composite, and the peak stress increases with the decrease of deformation temperature or the increase of strain rate.The flow stress behavior of the composite during hot compression deformation can be represented by a Zener-Hollomon parameter in the hyperbolic sine form. Its activation energy for hot deformation Q is 320.79kJ/mol. The stable regions and the instability regions in the processing map were identified and the microstructures in different regions of processing map were studied.There are particle breakage and void in the instability regions.

Three novel bis-cationic asphalt emulsifiers were synthesized by two steps reaction of N-tallow-1,3-diaminopropane, methyl acrylate, sodium hydroxide and chloroacetic acid. The structure of the product was confirmed by FTIR, 1H NMR and elemental analysis. The emulsifier exhibits satisfactory emulsification. The prepared bituminous emulsion showed higher storage stability. The emulsifier belongs to medium-set and slow-set asphalt emulsifier. It can be designed to perform in a wide variety of applications including tack coat, fog seal, chip seal and slurry seal in asphalt pavement construction.

An efficient composite adsorbent was prepared based on acryloyl starch/carboxymethyl cellulose grafting copolymerization for the adsorptive removal of methylene blue. The developed composite hydrogels were characterized by means of FTIR, SEM (EDS-SEM), and XRD. Various parameters affecting the removal of methylene blue such as the type of adsorbents, pHs, the amount of adsorbents dosage, initial methylene blue concentration, and contact time were optimized using a series of batch adsorption experiments. The experimental data of the adsorption process were more fitted to Langmuir isotherm (R2 = 0.9898) with a maximum adsorption capacity of 483.5 mg/g and batch kinetic experiments revealed that the adsorption process followed quasi-second-order kinetic model. The adsorption process was rapid and equilibrium was reached within 30 min. When the adsorption dosage is 0.2 g L−1, the adsorption yield for 100 mg L−1 methylene blue solution can reach 96.7 %. Therefore, acryloyl starch/carboxymethyl cellulose grafting copolymerization composite hydrogel present excellent adsorption efficiency, shows the potential application in future treatment of dyes wastewater. [ABSTRACT FROM AUTHOR]

In this study, a series of organic amine-intercalated α-ZrP were prepared. The crystal phase, structures and properties of these intercalated compounds were analyzed and characterized using several analysis methods. The interlayer distance of organic amine-intercalated α-ZrP has increased regularly along with the increase of chain elongation of organic amine. The composites were applied to adsorb phenol from wastewater. The adsorption equilibrium, kinetics, and dynamic adsorption of phenol onto intercalated α-ZrP were studied. Adsorption isotherms of phenol were determined at different temperatures, and they were well fitted to the Freundlich equation (R2 > 0.99), and the corresponding maximum adsorption capacity of phenol was 0.832 mmol/g. Batch kinetic experiments revealed that the adsorption process followed a quasi-second-order kinetic model. The dynamic adsorption revealed that the adsorption capacity for phenol increased with the increase in temperature. The adsorption process was rapid and equilibrium was reached within 30 min. When the adsorption dosage is 0.1 g/15 mL, the adsorption yield for 10 mmol/L phenol solution can reach 61.2%. [ABSTRACT FROM AUTHOR]