1. Multiferroic Bi 0.65 La 0.35 Fe 0.5 Sc 0.5 O 3 perovskite: Magnetic and thermodynamic properties
- Author
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Yu. V. Radyush, A. Baran, Andrius Stanulis, Erik Čižmár, Anatoli V. Pushkarev, N. M. Olekhnovich, Alexander Feher, Andrei N. Salak, Alexey V. Fedorchenko, E. L. Fertman, O. V. Kotlyar, Vladimir Desnenko, Dmitry D. Khalyavin, Aivaras Kareiva, A.I. Vaisburd, and E.S. Syrkin
- Subjects
Heat capacity ,Materials science ,Magnetic domain ,Condensed matter physics ,Demagnetizing field ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Magnetic hysteresis ,Magnetization ,01 natural sciences ,Electronic, Optical and Magnetic Materials ,Condensed Matter::Materials Science ,Paramagnetism ,Magnetic anisotropy ,Multiferroic perovskites ,0103 physical sciences ,Superdiamagnetism ,Condensed Matter::Strongly Correlated Electrons ,010306 general physics ,0210 nano-technology ,Saturation (magnetic) - Abstract
Magnetic and thermodynamic properties of polycrystalline multiferroic Bi 0.65 La 0.35 Fe 0.5 Sc 0.5 O 3 synthesized under high-pressure and high-temperature conditions are reported. Magnetic properties were studied using a SQUID magnetometer technique over the temperature range of 5−300 K in magnetic fields up to H =10 kOe. The field dependent magnetization M(H) was measured in magnetic fields up to 50 kOe at different temperatures up to 230 K after zero-field cooling procedure. A long-range magnetic ordering of the AFM type with a weak FM contribution occurs below the Neel temperature T N ~237 K. Magnetic hysteresis loops taken below T N show a huge coercive field up to H c ~10 kOe. A strong effect of magnetic field on the magnetic properties of the compound has been found. Derivative of the initial magnetization curves demonstrates a temperature-dependent anomaly in fields of H =15−25 kOe. Besides, an anomaly of the temperature dependent zero-field cooled magnetization measured in magnetic fields of 6−7 kOe has been found. Origin of both anomalies is associated with inhomogeneous magnetic state of the compound. The heat capacity has been measured from 2 K up to room temperature and a significant contribution from the magnon excitations at low temperatures has been detected. From the low-temperature heat capacity, an anisotropy gap of the magnon modes of the order 3.7 meV and Debye temperature T D =189 K have been determined.
- Published
- 2017