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Phosphide anions PX 2 - with electron-withdrawing substituents display ambiphilic properties. The use of P(V) thiophosphorane substituents enables the coordination of the resulting bis(thiophosphoranyl)phosphide anion ( BTPP = L ) to a variety of transition metals from groups 7 to 10. A series of homoleptic and heteroleptic complexes was synthesized and X-ray diffraction analysis revealed that, depending on the metal, L may adopt three coordination modes (κ 3 -(S, P, S); κ 2 -(S, S); κ 2 -(S, P)) supporting three distinct geometries (octahedral; tetrahedral; square planar). Complex L 2 Co displays Single Molecule Magnet (SMM) properties, and complex LRh(COD) (COD = 1,5-cyclooctadiene) catalyzes the hydrosilylation of terminal alkynes. more...

Two rare two-dimensional Ln-radical networks, namely, [{Ln(tfa) 3 } 3 (NIT-4Py) 2 ] n [Ln III = Gd 1 and Tb 2 ; tfa - = trifluoroacetylacetonato; and NIT-4Py = 2-(4-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide], have been successfully constructed and characterized. In these complexes, each NIT-4Py radical functions as a tridentate ligand to ligate three Ln ions, creating a 2D network with linear five-spin [Ln 3 (NIT) 2 ] nodes. Ferromagnetic Ln-NO interactions govern the characteristic magnetic behavior of a finite spin system. The Tb complex is shown to exhibit SMM behavior in a zero DC field, with an energy barrier for spin flipping of 53 K and hysteretic M-H behavior at 2.3 K, with a coercive field H coer = 110 Oe. This complex represents the first example of a Ln-nitronyl nitroxide SMM-based network. more...

With the aim of tuning the magnetic anisotropy, a series of Co(ii) complexes with the general formula of complex cations [Co(L)X] + , where X = Br -ipt> (1); I - (2); NCO - (3); NCS - (4a); N 3 - (5), and [Co(L)(NCS) 2 ] (4b), (L = a 17-membered pyridine-based N 3 O 2 -macrocyclic ligand containing two pyridin-2-ylmethyl pendant arms) were prepared and thoroughly characterized. The molecular structures for all complexes showed strongly distorted geometry in between octahedral and trigonal prismatic. The magnetic studies confirmed substantial magnetic anisotropy with positive values of D , the axial zero-field splitting parameter, but E / D ratios close to 1/3. This was supported by theoretical CASSCF calculations showing no significant effect of the co-ligands. Complex 4b was found to behave as a field-induced SMM., Competing Interests: There are no conflicts to declare., (This journal is © The Royal Society of Chemistry.) more...

Purpose: Listeria monocytogenes causes severe bacterial infections with the highest mortality rate among foodborne pathogens in Europe. Combination treatment with ampicillin and gentamicin is recommended for invasive manifestations. However, evidence to support this treatment approach remains limited due to a lack of randomised controlled trials. To explore this critical issue further, we conducted this retrospective, single-center study., Methods: We identified all patients hospitalized with invasive listeriosis at the University Medical Center Hamburg-Eppendorf between 2009 and 2020 and analyzed the effect of gentamicin combination treatment versus monotherapy on 90-day mortality., Results: In total, 36 patients with invasive listeriosis were included, of which 21 patients received gentamicin combination treatment and 15 received monotherapy. The mean age-adjusted Charlson Comorbidity Index (aaCCI) value was lower in the gentamicin combination treatment group (5.4 vs. 7.4). Neurolisteriosis was more common in the gentamicin group (81% vs. 20%). The 90-day mortality was with significantly lower in the gentamicin combination treatment group (10%) compared to the monotherapy group (60%). Multivariable cox regression analysis, adjusted for a propensity score computed based on neurolisteriosis, aaCCI and sex, revealed a significantly reduced hazard ratio of 0.07 (95% CI: 0.01-0.53, p = 0.01) for 90-day mortality for the gentamicin combination treatment., Conclusion: This retrospective study highlights the benefit of gentamicin combination treatment in reducing the 90-day mortality rate among patients with invasive listeriosis. The high prevalence of monotherapy in this study cohort raises concerns about the adequacy of antibiotic therapy in clinical practice., (© 2024. The Author(s).) more...

A novel series of one-dimensional coordination polymers (CPs) is achieved via a facile one-pot synthesis strategy employing the nitrate salts of trivalent lanthanides, a pentadentate chelating ligand, and triphenylphosphine oxide at a controlled stoichiometry under ambient conditions. All the CPs are characterized comprehensively using spectroscopic, X-ray crystallographic and magnetometric studies. The CPs are found to be thermally stable up to a significantly high temperature and resistant to water for an indefinite time. They are photoactive and exhibit selective fluoride ion (F - ) sensing with excellent efficiency both colorimetrically and fluorimetrically in the solid-state as well as in solution. The presence of F - concomitantly sensitizes the photoluminescence enhancement and visual decolourization of the CPs in solution owing to the ground-state intra-molecular proton transfer. The photophysical response of the CPs to F - in solution was found to be instantaneous (<30 s). The sensitivity of detection is observed to be significantly high over a wide range of F - concentrations, covering the beneficial and detrimental domains of F - concentrations in drinking water. The limit of detection (LoD) under ambient conditions was found to be in the micromolar (μM) range-the best being 0.22 μM found using UV-vis spectrometry and 7.5 μM using fluorimetry. In comparison, the USEPA standard cut-off for the upper limit of F - concentration in drinking water is 211 μM, and the LoD of measuring F - concentration using the USEPA standard method using a fluoride-selective electrode is 26.3 μM. The CPs display markedly high selectivity toward F - with negligible-to-no interference from the commonly abundant ions (Cl - , Br - , I - , CH 3 CO 2 - , CO 3 2- , SO 4 2- , HPO 4 2- , NH 4 + , Na + , K + , Mg 2+ , and Ca 2+ ) in terms of UV-vis spectral change. Moreover, they also exhibit solid-state IR-spectrometric sensitivity towards F - under ambient conditions. more...

Introduction: Immune checkpoint inhibitors (ICI) have revolutionized the treatment of many malignancies in recent years. However, immune-related adverse events (irAE) are a frequent concern in clinical practice. The safety profile of ICI for the treatment of malignancies in patients diagnosed with autoimmune and cholestatic liver disease (AILD) remains unclear. Due to this uncertainty, these patients were excluded from ICI clinical trials and ICI are withheld from this patient group. In this retrospective multicenter study, we assessed the safety of ICI in patients with AILD., Methods: We contacted tertiary referral hospitals for the identification of AILD patients under ICI treatment in Europe via the European Reference Network on Hepatological Diseases (ERN RARE-LIVER). Fourteen centers contributed data on AILD patients with malignancies being treated with ICI, another three centers did not treat these patients with ICI due to fear of irAEs., Results: In this study, 22 AILD patients under ICI treatment could be identified. Among these patients, 12 had primary biliary cholangitis (PBC), five had primary sclerosing cholangitis (PSC), four had autoimmune hepatitis (AIH), and one patient had an AIH-PSC variant syndrome. Eleven patients had hepatobiliary cancers and the other 11 patients presented with non-hepatic tumors. The applied ICIs were atezolizumab (n=7), durvalumab (n=5), pembrolizumab (n=4), nivolumab (n=4), spartalizumab (n=1), and in one case combined immunotherapy with nivolumab plus ipilimumab. Among eight patients who presented with grade 1 or 2 irAEs, three demonstrated liver irAEs. Cases with grades ≥ 3 irAEs were not reported. No significant changes in liver tests were observed during the first year after the start of ICI., Discussion: This European multicenter study demonstrates that PD-1/PD-L1 inhibitors appear to be safe in patients with AILD. Further studies on the safety of more potent dual immune checkpoint therapy are needed. We conclude that immunotherapy should not categorically be withheld from patients with AILD., Competing Interests: The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest., (Copyright © 2024 Kocheise, Piseddu, Vonderlin, Tjwa, Buescher, Meunier, Goeggelmann, Fianchi, Dumortier, Riveiro Barciela, Gevers, Terziroli Beretta-Piccoli, Londoño, Frankova, Roesner, Joerg, Schmidt, Glaser, Sutter, Fründt, Lohse, Huber, von Felden, Sebode and Schulze.) more...

The lanthanide metal organic framework compounds [Ln(BPTA) 1.5 (Bpy)]·0.5DMF (Ln = Y, Eu, Gd, Tb, Dy; 1a-5a) and [Ln(BPTA) 1.5 (Phen)]·0.5DMF (Ln = Y, Eu, Gd, Tb, Dy; 1b-5b) were prepared by employing 2,5-bis(prop-2-yn-1-yloxy)terephthalic acid (2,5-BPTA) as the primary ligand and 2,2'-bipyridine (1a-5a) and 1,10-phenanthroline (1b-5b) as the secondary ligands. Single-crystal structural studies on [Gd(BPTA) 1.5 (Bpy)]·0.5DMF (3a) and [Dy(BPTA) 1.5 (Phen)]·0.5DMF (5b) indicated that the compounds have a two-dimensional structure. The Y compound exhibits blue emission, and the other compounds exhibit emission in the expected regions ( λ ex = 350 nm). White light emission was achieved by careful mixing of the red (Eu 3+ ) and green (Tb 3+ ) components in the blue emitting Y compound. Thus, Y 0.96 Tb 0.02 Eu 0.02 (bpy) and Y 0.939 Tb 0.06 Eu 0.001 (phen) were found to show white emission when excited using a wavelength of 350 nm. The introduction of N-N-containing ancillary ligands ( i.e. , bpy and phen) increased the overall quantum yield (QY) of white light emission to 31% and 43%, respectively. The high QY observed for the Tb and Eu compounds was found to be sensitive and selective for the fluorometric detection of azinphos-methyl pesticide and trinitrophenol (TNP) in an aqueous medium at the ppb level. The same behaviour was observed when utilising the compounds as onsite paper strip sensors. Their magnetic properties were also studied, revealing for the Tb and Dy derivatives slow relaxation of the magnetisation at low temperature. The present study highlights the usefulness of rigid π-conjugated molecules such as 2,2'-bipyridine and 1,10-phenanthroline in enhancing the many utilities of rare-earth-containing MOFs towards white light emission, the sensing of harmful and dangerous substances and magnetic properties. more...

Large uniaxial magnetic anisotropy, expressed by a negative value of the axial zero-field splitting parameter D , has been achieved in a series of trigonal prismatic Co(II) complexes with the general formula [Co(L)X]Y, where L = 1,5,13,17,22-pentaazatricyclo[15.2.2.17,11]docosa-7,9,11(22)-triene, X = Cl - (1a,b), Br - (2), N 3 - (3), NCO - (4), NCS - (5), NCSe - (6), and Y = Cl - (1), Br - (2), NCS - (4), NCSe - (5), ClO 4 - (3,6). Complexes 1-6 are six-coordinate with the distorted trigonal prismatic geometry imparted by the pentadentate pyridine-/piperazine-based macrocyclic ligand L and by one monovalent coligand X - . Based on magnetic studies, all complexes 1-6 exhibit strong magnetic anisotropy with negative D -values ranging from about -20 to -41 cm -1 . This variation in D ( i.e. the increase of magnetic anisotropy) parallels the trend obtained by theoretical calculations and the lesser distortion of the coordination sphere with respect to the trigonal prismatic reference geometry. AC magnetic susceptibility investigations revealed field-induced single-molecule magnet behaviour for all complexes except Cl - derivative 1. The series investigated represents a rare example of Co(II) complexes with a robust trigonal prismatic geometry. more...

For advanced X-ray sources such as synchrotron radiation facilities and X-ray free electron lasers, a smooth, structure-free beam on the far-field plane is usually strongly desired. The formation of the fine structures in far-field images downstream from imperfect optics must be understood. Although numerous studies have discussed the impacts on focused beams, there are still few quantitative theories for the impacts on beams in the far field. This article is an advance on our previous work, which discussed the uniformity of the intensity distribution in the far field. Here, a new theoretical approach is presented. It not only eases the assumptions needed to relate the fine structures to the wavefront curvature, but it also provides a quantitative estimation of the impacts of optical errors. The theoretical result is also verified by X-ray experiments. more...

The reaction of nitronyl nitroxide biradical NITPhMeImbis [5-(2-methylimidazole)-1,3-bis(1-oxyl-3'-oxido-4',4',5',5'-tetramethyl-4,5-hydro-1H-imidazol-2-yl)-benzene] with Ln(hfac) 3cript>  ⋅ 2H 2 O and Cu(hfac) 2 (hfac=hexafluoroacetylacetonate), led to two series of 2p-3d-4f complexes, namely, nona-spin clusters, [Ln 2 Cu 3 (hfac) 12 (NITPhMeImbis) 2 ] (Ln=Gd 1, Dy 2), or one-dimensional chains [LnCu 2 (hfac) 7 (NITPhMeImbis)] (Ln=Y 3, Dy 4, Tb 5) depending on the temperature of the reaction. All five complexes contain a biradical-Ln unit in which the biradical chelates the Ln III ion by the means of one aminoxyl (i. e. NO) group of each NIT unit. For the discrete complexes, a Cu(hfac) 2 links two biradical-Ln units via one of the remaining NO groups, while for the chain compounds, the two remaining NO groups of the biradical-Ln moiety are each coordinated to a Cu(hfac) 2 unit to form a 1D coordination polymer. Moreover, a terminal Cu(hfac) 2 unit is coordinated to the imidazole-N atom of the NITPhMeImbis ligand. Spin dynamics investigations evidenced the onset of slow relaxation of the magnetization for 2, whereas 4 and 5 exhibit a typical single-chain magnet behavior. This highlights the vital role of the 1D spin correlation in the blocking of the magnetization. These results illustrate that from the same basic building blocks, magnetic relaxation can be carefully modulated by structural adjustments., (© 2022 Wiley-VCH GmbH.) more...

Employing the new nitronyl nitroxide biradical ligand biNIT-3Py-5-Ph (2-(5-phenyl-3-pyridyl)-bis(4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide)), a 16-spin Cu-radical complex, [Cu 8cript> (biNIT-3Py-5-Ph) 4 (hfac) 16 ] 1 , and three 2p-3d-4f chain complexes, {[Ln(hfac) 3 ][Cu(hfac) 2 ] 2 (biNIT-3Py-5-Ph) 2 } n (Ln Ⅲ = Gd 2 , Tb 3 , Dy 4 ; hfac = hexafluoroacetylacetonate), have been prepared and characterized. X-ray crystallographic analysis revealed in all derivatives a common cyclic [Cu-biNIT] 2 secondary building unit in which two bi-NIT-3Py-5-Ph biradical ligands and two Cu II ions are associated via the pyridine N atoms and NO units. For complex 1 , two such units assemble with four additional Cu II ions to form a discrete complex involving 16 S = 1/2 spin centers. For complexes 2 - 4 , the [Cu-biNIT] 2 units are linked by Ln III ions via NO groups in a 1D coordination polymer. Magnetic studies show that the coordination of the aminoxyl groups with Cu or Ln ions results in behaviors combining ferromagnetic and antiferromagnetic interactions. No slow magnetic relaxation behavior was observed for Tb and Dy derivatives. more...

We report the synthesis of [(L)Dy III (Cy 3 PO) 2 ]·[BPh 4 ] (1-Dy) (where H 2 L = 2,6-diacetylpyridine bis-benzoylhydrazone and Cy = cyclohexyl) which crystallized in the triclinic, P 1̄ space group. The local geometry around Dy(III) in 1-Dy was found to be pentagonal bipyramidal (pseudo- D 5h ). The AC magnetic susceptibility measurements performed on 1-Dy and on its diluted 1-Y(Dy) samples showed a typical single-molecule magnet signature revealed by the appearance of AC-frequency dependent out-of-phase susceptibility signals in the absence of a static magnetic field. The out-of-phase AC susceptibility signals were well resolved on the application of a small magnetic field ( H DC = 500 Oe) and yielded an energy barrier for magnetization flipping of U eff / k B = 50 K for the diluted derivative. The magnetic studies on 1-Dy and 1-Y(Dy) and data analysis further confirm that Raman and QTM under-barrier magnetic relaxations play a crucial role in lowering U eff despite the almost axial nature of the Dy(III) ion in 1-Dy. We have rationalized these observations through detailed ab initio calculations performed on the X-ray crystal structure of 1-Dy. more...

A chiral 3D coordination compound, [Gd 2 (L) 2 (ox) 2 (H 2 O) 2 ], arranged around a dinuclear Gd unit has been characterized by X-ray photoemission and X-ray absorption measurements in the context of density functional theory studies. Core level photoemission of the Gd 5p multiplet splittings indicates that spin orbit coupling dominates over j-J coupling evident in the 5p core level spectra of Gd metal. Indications of spin-orbit coupling are consistent with the absence of inversion symmetry due to the ligand field. Density functional theory predicts antiferromagnet alignment of the Gd 2 dimers and a band gap of the compound consistent with optical absorption. more...

Five isostructural microporous supramolecular architectures prepared by H-bonded assembly between the hexa-anionic complex [Zr 2 (Ox) 7 ] 6- (Ox=oxalate, (C 2 O 4 ) 2- ) and tripodal cations (H 3 -TripCH 2 -R) 3+ with R=H, CH 3 , OH and OBn (Bn=CH 2 Ph) are reported. The possibility to obtain the same structure using a mixture of tripodal cations with different R group (R=OH and R=CH 3 ) has also been successfully explored, providing a unique example of three-component H-bonded porous framework. The resulting SPA-1(R) materials feature 1D pores decorated by R groups, with apparent pore diameters ranging from 3.0 to 8.5 Å. Influence of R groups on the sorption properties of these materials is evidenced through CO 2 and H 2 O vapor sorption/desorption experiments, as well as with I 2 capture/release experiments in liquid media. This study is one of the first to demonstrate the possibility of tuning the porosity and exerting precise control over the chemical functionalization of the pores in a given H-bonded structure, without modifying the topology of the reference structure, and thus finely adjusting the sorption characteristics of the material., (© 2022 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.) more...

New lanthanide carboxylate compounds with two- (2D) and three-dimensional (3D) structures have been prepared by employing 2,5-bis(prop-2-yn-1-yloxy)terephthalic acid (2,5-BPTA) as an organic linker. The compounds, [Ln(C 14 H 8 O 6 )(C 7 O 3 H 4 )·2H 2 O]·4(H 2 O), Ln = Y, Pr, Nd, Sm, Eu, Gd, Tb, Dy and [Ln(C 7 O 3 H 4 ) 3 ·(C 3 H 7 ON)·(H 2 O)]·2(H 2 O)(C 3 H 7 NO), Ln = La, Ce, Pr, have two- and three-dimensional structures, respectively. In all compounds, lanthanide ions are connected together, forming a dimer, which is connected by the 2,5-BPTA ligand. In the two-dimensional structure, there are two 2,5-BPTA moieties present, and in the three-dimensional structure, there are three 2,5-BPTA moieties present. The lanthanide centers are nine-coordinated, the 2D structure has a tricapped trigonal prismatic arrangement, and the 3D structure has a monocapped distorted square antiprismatic arrangement. The Pr compound forms in both 2D and 3D structures, whose formation depends on the time of the reaction (2 days─2D and 5-6 days─3D). The ligand emits in the blue region, and using the characteristic emission of Eu 3+ (red) and Tb 3+ (green) ions, we achieve white light emission in the (Y 0.96 Tb 0.02 Eu 0.02 ) compound. The overall quantum yield for the white light emission is 28%. The strong green luminescence of the Tb 3+ -containing compound was employed to selectively sense the Cr 3+ and Fe 3+ ions in aqueous solution with limits of detection (LODs) at 0.41 and 8.6 ppm, respectively. The Tb compound was found to be a good heterogeneous catalyst for the Ullman-type O-arylation reaction between phenol and bromoarene with yields of 95%. Magnetic studies on the Gd-, Tb-, and Dy-containing compounds showed weak exchange interactions within the dimeric Ln 2 units. The present work demonstrates the many utilities of the rare-earth-containing MOFs, especially toward white-light emission, metal-ion sensing, and heterogeneous catalysis. more...

Applications of quantum information science (QIS) generally rely on the generation and manipulation of qubits. Still, there are ways to envision a device with a continuous readout, but without the entangled states. This concise perspective includes a discussion on an alternative to the qubit, namely the solid-state version of the Mach-Zehnder interferometer, in which the local moments and spin polarization replace light polarization. In this context, we provide some insights into the mathematics that dictates the fundamental working principles of quantum information processes that involve molecular systems with large magnetic anisotropy. Transistors based on such systems lead to the possibility of fabricating logic gates that do not require entangled states. Furthermore, some novel approaches, worthy of some consideration, exist to address the issues pertaining to the scalability of quantum devices, but face the challenge of finding the suitable materials for desired functionality that resemble what is sought from QIS devices., (© 2022 IOP Publishing Ltd.) more...

The design of X-ray optics based on diffraction from crystals depends on the accurate calculation of the structure factors of their Bragg reflections over a wide range of temperatures. In general, the temperature dependence of the lattice parameters, the atomic positions and the atomic thermal vibrations is both anisotropic and nonlinear. Implemented here is a software package for precise and flexible calculation of structure factors for dynamical diffraction. α-Quartz is used as an example because it presents the challenges mentioned above and because it is being considered for use in high-resolution X-ray spectroscopy. The package is designed to be extended easily to other crystals by adding new material files, which are kept separate from the package's stable core. Python 3 was chosen as the language to allow the easy integration of this code into existing packages. The importance of a correct anisotropic treatment of the atomic thermal vibrations is demonstrated by comparison with an isotropic Debye model. Discrepancies between the two models can be as much as 5% for strong reflections and considerably larger (even to the level of 100%) for weak reflections. A script for finding Bragg reflections that backscatter X-rays of a given energy within a given temperature range is demonstrated. The package and example scripts are available on request. Also discussed, in detail, are the various conventions related to the proper description of chiral quartz., (© John P. Sutter et al. 2022.) more...

A series of air-stable mononuclear octacoordinate Ln(III) complexes, [(L)Ln(TPPO) 3 ]OTf (Ln = Y ( 1·Y ); Gd ( 1·Gd ); Tb ( 1·Tb ); Dy ( 1·Dy ); Ho ( 1·Ho ); and Er ( 1·Er )) and [(L)Ln(TPPO)(NO 3 )] (Ln = Y ( 2·Y ) and Dy ( 2·Dy )), are synthesized employing a rigid N 3 O 2 -pentadentate chelating ligand as the basis ligand and meridional ancillary ligands (where H 2 L = 2,6-diacetylpyridine bis -benzoylhydrazone, TPPO = triphenylphosphine oxide, and OTf - = trifluoromethanesulfonate). All the complexes are synthesized under aerobic conditions and characterized comprehensively by spectroscopic and X-ray crystallographic techniques. Magnetic property investigation on the polycrystalline solid samples of 1·Ln (Ln = Gd, Tb, Dy, Ho, and Er) and 2·Dy are reported. A field-induced single-molecule magnet behavior was observed for the Dy derivatives. 1·Dy exhibits the highest effective energy barrier of magnetization reversal, U eff / k B = 47 K under H dc = 1 kOe among the complexes presented herein., Competing Interests: The authors declare no competing financial interest., (© 2022 The Authors. Published by American Chemical Society.) more...

Four novel heptanuclear Ln-Cu complexes with the formula [Ln 2 Cu(hfac) 8 (NITPhTzbis) 2 ][LnCu(hfac) 5 (NITPhTzbis)] 2 (LnCu = YCu 1, TbCu 2, DyCu 3 and HoCu 4; hfac = hexafluoroacetylacetonate) were successfully constructed by employing the triazole functionalized nitronyl nitroxide biradical ligand NITPh-Tzbis (NITPh-Tzbis = 5-(1,2,4-triazolyl)-1,3-bis(1'-oxyl-3'-oxido-4',4',5',5'-tetramethyl-4,5-hydro-1 H -imidazol-2-yl)benzene). These hetero-tri-spin complexes are composed of two biradical-bridged dinuclear [(LnCu(hfac) 5 (NITPhTzbis)] units and one trinuclear [Ln 2 Cu(hfac) 8 (NITPhTzbis) 2 ] unit which form a heptanuclear supramolecular structure through π-π interactions. Magnetic susceptibility investigations indicate that ferromagnetic exchange interactions dominate at low temperature for this supramolecular system which can be attributed to the Ln-nitroxide exchange and intramolecular NIT⋯NIT coupling mediated by the m -phenylene moiety. The DyCu derivative was found to exhibit a slow magnetic relaxation behavior. more...

The magnetic anisotropy associated with a pentagonal bipyramidal (PBP) coordination sphere is examined on the basis of experimental and theoretical investigations. The origin and the characteristics of this anisotropy are discussed in relation to the electronic configuration of the metal ions. The effects of crystal field, structural distortion, and a second-coordination sphere on the observed anisotropies for transition meal and lanthanide ions are outlined. For the Ln derivatives, we focus on compounds showing SMM-like behavior ( i.e. slow relaxation of their magnetization) in order to highlight the essential chemical and structural parameters for achieving strong axial anisotropy. The use of PBP complexes to impart controlled magnetic anisotropy in polynuclear species such as SMMs or SCMs is also addressed. This review of the magnetic anisotropies associated with a pentagonal bipyramidal coordination sphere for transition metal and lanthanide ions is intended to highlight some general trends that can guide chemists towards designing a compound with specific properties. more...

Trinuclear systems of formula [{Cr(L N3O2Ph )(CN) 2 } 2 M(H 2 L N3O2R )] (M=Mn II and Fe II , L N3O2R stands for pentadentate ligands) were prepared in order to assess the influence of the bending of the apical M-N≡C linkages on the magnetic anisotropy of the Fe II derivatives and in turn on their Single-Molecule Magnet (SMM) behaviors. The cyanido-bridged [Cr 2 M] derivatives were obtained by assembling trans-dicyanido Cr III complex [Cr(L N3O2Ph )(CN) 2 ] - and divalent pentagonal bipyramid complexes [M II (H 2 L N3O2R )] 2+ with various R substituents (R=NH 2 , cyclohexyl, S,S-mandelic) imparting different steric demand to the central moiety of the complexes. A comparative examination of the structural and magnetic properties showed an obvious effect of the deviation from straightness of the M-N≡C alignment on the slow relaxation of the magnetization exhibited by the [Cr 2 Fe] complexes. Theoretical calculations have highlighted important effects of the bending of the apical C-N-Fe linkages on both the magnetic anisotropy of the Fe II center and the exchange interactions with the Cr III units., (© 2021 Wiley-VCH GmbH.) more...

The preparation, crystal structures, and magnetic properties of a family of hetero-tri-spin 1-D coordination polymers with the formula [Ln(hfac) 3 Cu(hfac) 2ript> (4-NIT-MePyz) 2 ] (Ln = Gd, 1, Tb, 2, Dy, 3; hfac = hexafluoroacetylacetonate; 4-NIT-MePyz = 2-{4-(1-methyl)-pyrazolyl}-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) are reported. In these complexes, the 4-NIT-MePyz radical acts as a linker to bridge the Cu II and Ln III ions through its pyrazole and aminoxyl groups to form a chain structure. Magnetic properties typical of spin-chains are observed for Dy and Tb derivatives but single-chain magnet (SCM) behavior was evidenced only for the Tb compound which is characterized by an energy gap for demagnetization Δ τ / k B of 31 K. more...

Ultra-SAXS can enhance the capabilities of existing synchrotron SAXS/WAXS beamlines. A compact ultra-SAXS module has been developed, which extends the measurable q-range with 0.0015 ≤ q (nm ript>-1 ) ≤ 0.2, allowing structural dimensions in the range 30 ≤ D (nm) ≤ 4000 to be probed in addition to the range covered by a high-end SAXS/WAXS instrument. By shifting the module components in and out on their respective motor stages, SAXS/WAXS measurements can be easily and rapidly interleaved with USAXS measurements. The use of vertical crystal rotation axes (horizontal diffraction) greatly simplifies the construction, at minimal cost to efficiency. In this paper, the design considerations, realization and synchrotron findings are presented. Measurements of silica spheres, an alumina membrane, and a porous carbon catalyst are provided as application examples., (open access.) more...

Beamline I22 at Diamond Light Source is dedicated to the study of soft-matter systems from both biological and materials science. The beamline can operate in the range 3.7 keV to 22 keV for transmission SAXS and 14 keV to 20 keV for microfocus SAXS with beam sizes of 240 µm × 60 µm [full width half-maximum (FWHM) horizontal (H) × vertical (V)] at the sample for the main beamline, and approximately 10 µm × 10 µm for the dedicated microfocusing platform. There is a versatile sample platform for accommodating a range of facilities and user-developed sample environments. The high brilliance of the insertion device source on I22 allows structural investigation of materials under extreme environments (for example, fluid flow at high pressures and temperatures). I22 provides reliable access to millisecond data acquisition timescales, essential to understanding kinetic processes such as protein folding or structural evolution in polymers and colloids., (open access.) more...

Background: SARS-CoV-2 molecular diagnostics is facing material shortages and long turnaround times due to exponential increase of testing demand., Objective: We evaluated the analytic performance and handling of four rapid Antigen Point of Care Tests (AgPOCTs) I-IV (Distributors: (I) Roche, (II) Abbott, (III) MEDsan and (IV) Siemens)., Methods: 100 RT-PCR negative and 84 RT-PCR positive oropharyngeal swabs were prospectively collected and used to determine performance and accuracy of these AgPOCTs. Handling was evaluated by 10 healthcare workers/users through a questionnaire., Results: The median duration from symptom onset to sampling was 6 days (IQR 2-12 days). The overall respective sensitivity were 49.4 % (CI95 %: 38.9-59.9), 44.6 % (CI95 %: 34.3-55.3), 45.8 % (CI95 %: 35.5-56.5) and 54.9 % (CI95 %: 43.4-65.9) for tests I, II, III and IV, respectively. In the high viral load subgroup (containing >10 6 copies of SARS-CoV-2 /swab, n = 26), AgPOCTs reached sensitivities of 92.3 % or more (range 92.3 %-100 %). Specificity was 100 % for tests I, II (CI95 %: 96.3-100 for both tests) and IV (CI95 %: 96.3-100) and 97 % (CI95 %: 91.5-98.9) for test III. Regarding handling, test I obtained the overall highest scores, while test II was considered to have the most convenient components. Of note, users considered all assays, with the exception of test I, to pose a significant risk for contamination by drips or spills., Discussion: Besides some differences in sensitivity and handling, all four AgPOCTs showed acceptable performance in high viral load samples. However, due to the significantly lower sensitivity compared to RT-qPCR, a careful consideration of pro and cons of AgPOCT has to be taken into account before clinical implementation., (Copyright © 2021 Elsevier B.V. All rights reserved.) more...

X-ray beams reflected from a single layer or multilayer coating are widely used for X-ray tomography, holography, and X-ray phase contrast imaging. However, the observed irregular stripe patterns from either unfocused or defocused beams often cause disturbing artifacts and seriously deteriorate the image quality. In this work, we investigate the origin of these irregular fine structures using the wave optics theory. The connection to similar results obtained by the geometric optics theory is also presented. The proposed relation between the second derivative of the wavefront and the irregular structures was then verified by conducting at-wavelength metrology with the speckle-based wavefront sensing technique. This work will not only help to understand the formation of these irregular structures but also provide the basis for manufacturing future 'stripe-free' refection optics. more...

The stuffed tridymite structure Ba(Zn/Co) 1-x Si 1-x M 2x O 4 (M=Al 3+ and Fe <superscript>3+ ) is explored for the possible multiferroic behavior and to develop new inorganic colored materials. The compounds were synthesized by employing conventional solid-state chemistry methods in the temperature range 1100-1175 °C for 24 h. The powder X-ray diffraction (PXRD) and Rietveld refinement studies indicate that the compounds stabilize in the P63 space group (no. 173). The refinement results were also rationalized by employing Raman spectroscopic studies. The compounds were found to be second harmonic generation (SHG) active and show weak ferroelectric behavior. The co-substitution of Co 2+ and Fe 3+ in the structure gives rise to a weak ferromagnetic behavior to the compound, BaCo 0.75 Si 0.75 Fe 0.5 O 4 , making it a multiferroic material. The optical studies on the prepared compounds exhibited blue color (Co 2+ in T d geometry), purple color (Ni 2+ in T d geometry), and simultaneous substitution of Co 2+ and Fe 3+ gives rise to blue-green color owing to metal-to-metal charge transfer (MMCT) effect., (© 2020 Wiley-VCH GmbH.) more...

A water processable cyanido bridged extended chiral heterobimetallic Co(ii)-Fe(iii) network is assembled. The unusual water processability of the coordination polymer originates from dangling hydrophilic substituents. The present approach offers a simple route to impart solution processability to cyanido bridged molecular magnetic materials. more...

Although optical element error analysis is always an important part of beamline design for highly coherent synchrotron radiation or free-electron laser sources, the usual wave optics simulation can be very time-consuming, which limits its application at the early stage of the beamline design. In this work, a new theoretical approach has been proposed for quick evaluations of the optical performance degradation due to optical element error. In this way, time-consuming detailed simulations can be applied only when truly necessary. This approach treats the imperfections as perturbations that convolve with the ideal performance. For simplicity, but not by necessity, the Gaussian Schell-model has been used to show the application of this theoretical approach. The influences of the finite aperture size and height error of a focusing mirror are analysed using the proposed theory. The physical explanation of the performance degradation acquired from the presented approach helps to give a better definition of the critical range of error spatial frequencies that most affect the performance of a mirror. An example comparing two mirror surface errors with identical power spectral density functions is given. These two types of mirror surface errors result in very different intensity profiles. The approach presented in this work could help beamline designers specify the error tolerances on general optical elements more accurately., (open access.) more...

B21 is a small-angle X-ray scattering (SAXS) beamline with a bending magnet source in the 3 GeV storage ring at the Diamond Light Source Ltd synchrotron in the UK. The beamline utilizes a double multi-layer monochromator and a toroidal focusing optic to deliver 2 × 10 12 photons per second to a 34 × 40 µm (FWHM) focal spot at the in-vacuum Eiger 4M (Dectris) detector. A high-performance liquid chromatography system and a liquid-handling robot make it possible to load solution samples into a temperature-controlled in-vacuum sample cell with a high level of automation. Alternatively, a range of viscous or solid materials may be loaded manually using a range of custom sample cells. A default scattering vector range from 0.0026 to 0.34 Å -1 and low instrument background make B21 convenient for measuring a wide range of biological macromolecules. The beamline has run a full user programme since 2013., (open access.) more...

One-dimensional coordination polymers constructed with the 4d metallo-ligand [Mo(NCS) 6 ] 3- associated with Ni II and Co II complexes are reported. The first series consists of anionic NCS-bridged [Mo-M II ] - coordination polymers associated with a discrete paramagnetic complex or a diamagnetic Co III complex acting as cations. The latter takes advantage of the coordination preference of the S-ligand for the soft 3d ions and has led to hetero-trimetallic [Mo III Ni II Co III ] and mixed valence [Mo III Co II Co III ] compounds. A second series concerns neutral chains in which trinuclear [Mo M 2 II ] units are bridged by an additional NCS anion. The soft character of the S atom was also the key to a rare example of a compound involving both high-spin and low-spin Co II centers associated with [Mo(NCS) 6 ]. A [Mo-Ni] derivative obtained with [Mo(NCSe) 6 ] 3- has been considered in order to evaluate the effect of Se versus S on the exchange interaction. The spin distribution for selenocyanate metallo-ligand has been assessed by density functional theory calculations. The crystal structures for all compounds have been characterized, and their magnetic behaviors have been investigated. These ferrimagnetic systems are characterized by antiferromagnetic Mo-M II interactions in the range of -40 to -90 cm -1 (based on H = - J S a S b formalism) operative both with Co II and with Ni II , thus demonstrating the potential of the Mo III -NCS combination for molecular systems in which exchange interactions play an important role. more...

A series of neutral homologous complexes [(L)Ln(Cy 3 PO)Cl] {where Ln = Gd ( 1 ), Tb ( 2 ), Dy ( 3 ), and Er ( 5 )} and [(L)Dy(Ph 3 PO)Cl] ( 4 ) [H script>2 L = 2,6-diacetylpyridine bis -benzoylhydrazone] were isolated. In these complexes, the central lanthanide ion possesses a pentagonal bipyramidal geometry with an overall pseudo D 5 h symmetry. The coordination environment around the lanthanide ion comprises of three nitrogen and two oxygen donors in an equatorial plane. The axial positions are taken up by a phosphine oxide (O donor) and a chloride ion. Among these compounds, the Dy(III) ( 3 and 4 ) analogues were found to be field-induced single-ion magnets. more...

A procedure that enabled rational access to the first example of hybrid material made of NPs grown within a H-bonded framework is reported. To avoid competitive reactions with the framework units, the metal precursor was chemically trapped in the porous structure and subsequently photo-reduced to afford the hybrid material Ag@SPA-2, which consists of Ag NPs of nanometric sizes (<15 nm) homogeneously distributed in the crystals of the host material. In a subsequent step, taking advantage of the porous matrix the silver NPs have been transformed in situ to Ag 2 S NP by simple infiltration of H 2 S. The supramolecular network is shown to play an important role in stabilizing the inorganic nanomaterials and thus in controlling their growth., (© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.) more...

The Diamond Light Source (DLS) beamline I15-1 measures atomic pair distribution functions (PDF) using scattering of 40-80 keV X-rays. A unique focusing element was needed to condense these X-rays from an initial large cross section (11.0 mm H × 4.2 mm V) into a required spot size of FWHM ≈680 μm (H) × 20 μm (V) at a variable position between the sample and the detector. The large numerical aperture is achieved by coating a silicon substrate over 1 m long with three multilayer stripes of Bragg angle 4.2 mrad. One stripe selects X-rays of each energy 40.0, 65.4, and 76.6 keV. Sixteen piezoelectric bimorph actuators attached to the sides of the mirror substrate adjusted the reflecting surface's shape. Focal spots of vertical width < 15 µm were obtained at three positions over a 0.92 m range, with fast, easy switching from one focal position to another. Minimized root mean square slope errors were close to 0.5 µrad after subtraction of a uniform curvature. Reflectivity curves taken along each stripe showed consistent high peaks with generally small angular variation of peak positions. This is the first application of a 1 m long multilayer-coated bimorph mirror at a synchrotron beamline. Data collected with its help on a slice of a lithium ion battery's cathode are presented. more...

A biradical with ferromagnetic intramolecular interaction was found to improve the SCM behavior of a nitronyl nitroxide-Cu-Dy chain, resulting in an energy barrier for magnetization reversal of 40 K. more...

The tangential curvature of actively bent X-ray mirrors at synchrotron radiation and X-ray free-electron laser (XFEL) facilities is typically only changed every few hours or even days. This operation can take tens of minutes for active optics with multiple bending actuators and often requires expert guidance using in situ monitoring devices. Hence, the dynamic performance of active X-ray optics for synchrotron beamlines has historically not been exploited. This is in stark contrast to many other scientific fields. However, many areas of synchrotron radiation and XFEL science, including macromolecular crystallography, could greatly benefit from the ability to change the size and shape of the X-ray beam rapidly and continuously. The advantages of this innovative approach are twofold: a large reduction in the dead time required to change the size of the X-ray beam for different-sized samples and the possibility of making multiple changes to the beam during the measurement of a single sample. In the preceding paper [Part I; Alcock, Nistea, Signorato & Sawhney (2019), J. Synchrotron Rad. 26, 36-44], which accompanies this article, high-speed visible-light Fizeau interferometry was used to identify the factors which influence the dynamic bending behaviour of piezoelectric bimorph deformable X-ray mirrors. Building upon this ex situ metrology study, provided here is the first synchrotron radiation beamline implementation of high-speed adaptive X-ray optics using two bimorphs operating as a Kirkpatrick-Baez pair. With optimized substrates, novel opto-mechanical holders and a next-generation high-voltage power supply, the size of an X-ray beam was rapidly and repeatedly switched in <10 s. Of equal importance, it is also shown that compensation of piezoelectric creep ensures that the X-ray beam size remains stable for more than 1 h after making a major change. The era of high-speed adaptive X-ray optics for synchrotron radiation and XFEL beamlines has begun., (open access.) more...

A multi-dentate nitronyl nitroxide radical Nit-Ph-3,5-bIm (Nit-Ph-3,5-bIm = 2-[3,5-bis(1-imidazole)-phenyl]-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) reacted with Co(hfac)2·2H2O or Cu(hfac)2 to yield two novel 3d-radical complexes {[Co(hfac)2]2(Nit-Ph-3,5-bIm)}n1 and {[Cu(hfac)2]7(Nit-Ph-3,5-bIm)3}n2 (hfac- = hexafluoroacetylacetonate). In both compounds, the Nit-Ph-3,5-bIm radical ligand behaves as a tetradentate ligand to link four M(hfac)2 units in a μ4-η1:η1:η1:η1-coordination mode via its two NO groups and two N atoms of imidazole, generating a unique loop chain for 1 and a three-dimensional framework for 2. The magnetic studies revealed a strong antiferromagnetic Co-ON exchange interaction in 1 while a ferromagnetic Cu-ON interaction is observed in 2. The dc magnetic behaviors of two complexes are analyzed by means of appropriate magnetic models. Furthermore, ac magnetic susceptibilities of the Co complex reveal slow relaxation of magnetization. more...

A description of the technical and design details of a scanning four-bounce crystal monochromator that has recently been commissioned for the Versatile X-ray Absorption Spectroscopy (XAS) beamline at Diamond Light Source is presented. This device consists of two independent rotary axes of unique design which are synchronized using a multiple read-head encoder system. This monochromator is shown to be capable of maintaining the flux throughput of the Bragg axes without the need of any external feedback mechanism from 4 to 20 keV. The monochromator is currently equipped with cryogenically cooled crystals with the upstream axis consisting of two independent Si(111) crystals and a pair of channel-cut crystals in the downstream axis. The possibility of installing an additional Si(311) crystal-set to extend the energy range to 34 keV is incorporated into the preliminary design of the device. Experimental data are presented showing the exceptional mechanical stability and repeatability of the monochromator axes., (open access.) more...

Unprecedented lanthanide (Ln)-radical loop-chain coordination polymers were achieved using multidentate pyridyl- or triazole- substituted nitronyl nitroxide ligands. Their magnetic units consist of ferromagnetic [Ln 2 Radical] moieties, leading for the dysprosium(III) derivatives to slow relaxation of magnetization, which was found to be dependent on the heterocyclic ligands. more...

A cyano-bridged Fe(II)-Cr(III) single-chain magnet designed to ensure a parallel orientation of the axial anisotropy of the building units is reported. This ferromagnetic chain compound consists of a pentagonal bipyramid Fe(II) complex with Ising-type anisotropy and a dicyanide Cr(III) complex interlinked through their apical positions. It is characterized by an energy gap for the magnetization reversal of Δ eff / k B = 113 K and exhibits magnetic hysteresis with a coercive field of 1400 Oe at 2 K which positions this compound among the very few examples of SCMs with spin reversal barriers above 100 K. The quite remarkable performances of this single-strand SCM are attributed to the alignment of the local anisotropy axes, which is supported by ab initio modeling. A discrete Cr 2 Fe complex based on the same building units and behaving as a SMM in zero field is also reported. more...

Two-dimensional hetero-tri-spin 2p-3d-4f coordination polymers involving Co(ii) and Ln(iii) ions assembled with a polydentate paramagnetic nitronyl nitroxide ligand are reported. [Ln(hfac)3{Co(hfac)2}2(NITPhPyrim)2] (LnIII = Gd 1, Tb 2; hfac = hexafluoroacetylacetonate, NITPhPyrim = 2-[4-(5-pyrimidyl)phenyl]-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) consists of a two-dimensional network in which the NITPhPyrim ligand is coordinated to the metal ions by means of its pyrimidine and aminoxyl (NO) groups. In the layer, the Tb center interacts with two NO groups from two different radical ligands, and each pyrimidine connects two Co(hfac)2 units through its two nitrogen atoms to form one-dimensional Co(ii) arrays. The magnetic behavior of the two compounds results from concomitant ferro- and antiferromagnetic interactions between the spin carriers and the spin-orbit effect from Co(ii) as revealed by modeling performed for the Gd(iii) derivative. more...

A pentadentate chelating ligand is employed for the facile synthesis of air-stable pentagonal-bipyramid Ln(III) complexes with a rigid equatorial plane. The Dy(III) analogue exhibits single-ion-magnet behavior with U eff / k B = 70 K under H dc = 500 Oe. more...

Four new copper complexes, viz. [{Cu(2-aminopyridine)(N 3 ) 2 (H 2 O)} 2 ] n (1), [Cu 3 (3-aminopyridine) 2 (N 3 ) 6 ] n (2), [{Cu(3-aminopyridine)(N 3 ) 2 } 2 ] n (3), and [Cu(4-aminopyridine) 2 (N 3 ) 2 ] n (4), have been synthesized with isomeric aminopyridines, viz. 2-aminopyridine (2-ap), 3-aminopyridine (3-ap), and 4-aminopyridine (4-ap), to probe the role of ligand and reactant molar ratios in directing the polynuclear assemblage and the associated magnetic properties. Ligand geometry is quite influential as can be seen through the versatile structures formed, viz. a hydrogen bonded layer of μ-1,1 azide bridged Cu dimers in 1; a network of two different types of dimers (Cu1-Cu2 & Cu3-Cu3') involving μ-1,1; μ-1,3; μ-1,1,3; & μ-1,1,3,3 azide bridges in 2; a ladder structure in which μ-1,1 azide bridges form the rungs and μ-1,3 azide bridges form the rails of the ladder in 3; and a 1-D polymer chain involving μ-1,1 azide bridges in 4. Consistent with the bridge geometry, compounds 1 & 2 display ferromagnetic interactions, while 3 & 4 display antiferromagnetic interactions. The rather unexpected antiferromagnetic interactions in 3, in spite of μ-1,1 azide bridged rungs may be due to the crossover near the bridge angle. The ferromagnetic interactions in 1 and 2 are supported by DFT calculations. more...

Ladder-type and chain 2p-3d-4f complexes based on a bridging nitronyl nitroxide radical, namely, [LnCu(hfac) 5 (NIT-Ph-p-OCH 2 trz)]·0.5C 6subscript> H 14 [Ln = Y (1a), Dy (1b)] and [LnCu(hfac) 5 (NIT-Ph-p-OCH 2 trz)] [Ln = Y (2a), Dy (2b); NIT-Ph-p-OCH 2 trz = 2-[4-[(1H-1,2,4-triazol-1-yl)methoxy]phenyl]-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide; hfac = hexafluoroacetylacetonate) have been successfully achieved through a one-pot reaction of the NIT-Ph-p-OCH 2 trz radical with Cu(hfac) 2 and Ln(hfac) 3 ·2H 2 O. Complexes 1a and 1b feature a ladder-like structure, where the rails are made of Ln(III) and Cu(II) ions alternatively bridged by nitronyl nitroxide and the triazole units while the NIT-Ph-p-OCH 2 trz moieties act as the rungs of the ladder. Complexes 2a and 2b consist of one-dimensional nitronyl nitroxide bridged Ln coordination polymers with dangly Cu(II) units connected to the triazole moieties. All of compounds exhibit ferromagnetic NIT-Dy and/or NIT-Cu interactions. Both Dy derivatives (1b and 2b) show frequency-dependent out-of-phase magnetic susceptibility signals in a zero field indicating slow magnetic relaxation behavior. more...

The shapes of single lens surfaces capable of focusing divergent and collimated beams without aberration have already been calculated. However, nanofocusing compound refractive lenses (CRLs) require many consecutive lens surfaces. Here a theoretical example of an X-ray nanofocusing CRL with 48 consecutive surfaces is studied. The surfaces on the downstream end of this CRL accept X-rays that are already converging toward a focus, and refract them toward a new focal point that is closer to the surface. This case, so far missing from the literature, is treated here. The ideal surface for aberration-free focusing of a convergent incident beam is found by analytical computation and by ray tracing to be one sheet of a Cartesian oval. An `X-ray approximation' of the Cartesian oval is worked out for the case of small change in index of refraction across the lens surface. The paraxial approximation of this surface is described. These results will assist the development of large-aperture CRLs for nanofocusing. more...

A hydrogen-bonded open framework with pores decorated by pyridyl groups was constructed by off-charge-stoichiometry assembly of protonated tetrakis(4-pyridyloxymethyl)methane and [Al(oxalate) ript>3 ] 3- , which are the H-bond donor and acceptor of ionic H-bond interactions, respectively. This supramolecular porous architecture (SPA-2) has 1 nm-large pores interconnected in 3D with large solvent-accessible void (53 %). It demonstrated remarkable affinity for acidic organic molecules in solution, which was investigated by means of various carboxylic acids including larger drug molecules. Competing sorption between acetic acid and its halogenated homologues evidenced good selectivity of the porous material for the halogenated acids. The gathered results, including a series of guest@SPA-2 crystal structures and HRMAS-NMR spectra, suggest that the efficient sorption exhibited by the material relies not only on an acid-base interaction. The facile release of these guest molecules under neutral conditions makes this SPA a carrier of acidic molecules., (© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.) more...

Pentagonal bipyramid Fe II complexes have been investigated to evaluate their potential as Ising-spin building units for the preparation of heteropolynuclear complexes that are likely to behave as single-molecule magnets (SMMs). The considered monometallic complexes were prepared from the association of a divalent metal ion with pentadentate ligands that have a 2,6-diacetylpyridine bis(hydrazone) core (H 2 L N3O2R ). Their magnetic anisotropy was established by magnetometry to reveal their zero-field splitting (ZFS) parameter D, which ranged between -4 and -13 cm -1 and was found to be modulated by the apical ligands (ROH versus Cl). The alteration of the D value by N-bound axial CN ligands, upon association with cyanometallates, was also assessed for heptacoordinated Fe II as well as for related Ni II and Co II derivatives. In all cases, N-coordinated cyanide ligands led to large magnetic anisotropy (i.e., -8 to -18 cm -1 for Fe and Ni, +33 cm -1 for Co). Ab initio calculations were performed on three Fe II complexes, which enabled one to rationalize the role of the ligand on the nature and magnitude of the magnetic anisotropy. Starting from the pre-existing heptacoordinated complexes, a series of pentanuclear compounds were obtained by reactions with paramagnetic [W(CN) 8 ] 3- . Magnetic studies revealed the occurrence of ferromagnetic interactions between the spin carriers in all the heterometallic systems. Field-induced slow magnetic relaxation was observed for mononuclear Fe II complexes (U eff /k B up to 53 K (37 cm -1 ), τ 0 =5×10 -9  s), and SMM behavior was evidenced for a heteronuclear [Fe 3 W 2 ] derivative (U eff /k B =35 K and τ 0 =4.6 10 -10  s), which confirmed that the parent complexes were robust Ising-type building units. High-field EPR spectroscopic investigation of the ZFS parameters for a Ni derivative is also reported., (© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.) more...

The polynuclear compounds containing anisotropic metal ions often exhibit efficient barriers for blocking of magnetization at fairly arbitrary geometries. However, at variance with mononuclear complexes, which usually become single-molecule magnets (SMM) under the sole requirement of a highly axial crystal field at the metal ion, the factors influencing the SMM behavior in polynuclear complexes, especially, with weakly axial magnetic ions, still remain largely unrevealed. As an attempt to clarify these conditions, we present here the synthesis, crystal structures, magnetic behavior, and ab initio calculations for a new series of Ni II -Ln III -W V trimetallics, [(CN) 7 W(CN)Ni(H 2 O)(valpn)Ln(H 2 O) 4 ]·H 2 O (Ln = Y 1, Eu 2, Gd 3, Tb 4, Dy 5, Lu 6). The surprising finding is the absence of the magnetic blockage even for compounds involving strongly anisotropic Dy III and Tb III metal ions. This is well explained by ab initio calculations showing relatively large transversal components of the g-tensor in the ground exchange Kramers doublets of 1 and 4 and large intrinsic tunneling gaps in the ground exchange doublets of 3 and 5. In order to get more insight into this behavior, another series of earlier reported compounds with the same trinuclear [W V Ni II Ln III ] core structure, [(CN) 7 W(CN)Ni(dmf)(valdmpn)Ln(dmf) 4 ]·H 2 O (Ln = Gd III 7, Tb III 8a, Dy III 9, Ho III 10), [(CN) 7 W(CN)Ni(H 2 O)(valdmpn)Tb(dmf) 2.5 (H 2 O) 1.5 ]·H 2 O·0.5dmf 8b, and [(CN) 7 W(CN)Ni(H 2 O)(valdmpn)Er(dmf) 3 (H 2 O) 1 ]·H 2 O·0.5dmf 11, has been also investigated theoretically. In this series, only 8b exhibits SMM behavior which is confirmed by the present ab initio calculations. An important feature for the entire series is the strong ferromagnetic coupling between Ni(II) and W(V), which is due to an almost perfect trigonal dodecahedron geometry of the octacyano wolframate fragment. The reason why only 8b is an SMM is explained by positive zero-field splitting on the nickel site, precluding magnetization blocking in complexes with fewer axial Ln ions. Further analysis has shown that, in the absence of ZFS on Ni ion, all compounds in the two series (except those containing Y and Gd) would be SMMs. The same situation arises for perfectly axial ZFS on Ni(II) with the main anisotropy axis parallel to the main magnetic axis of Ln(III) ions. In all other cases the ZFS on Ni(II) will worsen the SMM properties. The general conclusion is that the design of efficient SMMs on the basis of such complexes should involve isotropic or weekly anisotropic metal ions, such as Mn(II), Fe(III), etc., along with strongly axial lanthanides. more...