1. Structural and electrochemical properties of 20-micron Li(Co1−xLix)O2−δ (x>0) agglomerates with layered structures: Identification of tetravalent cobalt
- Author
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T. Hojo, Chikako Moriyoshi, Yuji Mishima, Akihisa Kajiyama, Yoshihiro Kuroiwa, and T. Nishio
- Subjects
Analytical chemistry ,chemistry.chemical_element ,Mineralogy ,General Chemistry ,Condensed Matter Physics ,Electrochemistry ,chemistry ,Agglomerate ,Vaporization ,Particle ,General Materials Science ,Lithium ,Inductively coupled plasma ,Cobalt ,Solid solution - Abstract
The increasing demand for the high energy density of lithium-ion batteries gives rise to the development of larger particle sizes of the active electrode materials. 20 μm-sized Li(Co 1− x Li x )O 2− δ agglomerates are synthesized via solid-state reactions with different nominal compositions (Li/Co=1.00, 1.02, and 1.05) at 1000 °C for 5 h in ambient air while suppressing the lithium vaporization. Careful inductively coupled plasma and iodometric measurements indicate the existence of tetravalent cobalt in the solid solutions ( x >0). The decreasing ideal capacity with the increasing x value could cause the resulting initial capacities at under a quasi-equilibrium condition. The defect structure is also discussed in terms of the structural parameters calculated from Rietveld refinements of the high-energy synchrotron-radiation powder-diffraction data.
- Published
- 2015
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