Search

To relate fine-scale spatial air-temperature variations in local urban heat islands and urban cool islands—increases and decreases in outside air temperature—within a large urban-climate archipelago to variations in land-use and land-cover properties in the Los Angeles Basin, the research team sought to (a) use fine-resolution meso-urban climate models to identify areas of urban heat and cool islands, select sites for fixed weather monitoring, and choose routes for mobile observations; (b) relate observed intraurban temperature variations to land use and landcover and surface physical properties; and (c) calibrate/validate the climate models. The research team assessed urban temperature variations via simulations and observations, including mobile transects, mesonet, dense networks of personal weather stations, and sparsebut more accurate research-grade monitors. To identify the causative factors of the urban heat and cool islands at the neighborhood scale, the research team collected detailed urban morphometric and land use and land cover datasets, such as 1-meter (3.3 foot) resolution roof albedo (solar reflectance) and tree canopy cover. The research team used the observationvalidated model to finalize the transect routes and site the stationary monitors. This study provides the first observational evidence from analysis of high-spatial-density weather stations that increases in roof albedo at neighborhood scale are associated with reductions in near-surface air temperature. This finding was corroborated with the analysisfrom mobile transect measurements and correlation of observed air temperature with neighborhood-scale albedo and vegetation. This correlation revealed a cooling effect from areawide increase in albedo or canopy cover or both. The calibrated meteorological model accurately identified the localized urban heat and cool islands observed in this study. Interested stakeholders/researchers can use the same models and calibration/validation methodology to characterize within-city microclimate variations elsewhere in California, and can apply them to analyze the benefits from using urban heat island countermeasures.This project report is an extended and more detailed version of a related report prepared for California’s Fourth Climate Change Assessment.

The effects of neighborhood-scale land use and land cover (LULC) properties on observed air temperatures are investigated in two regions within Los Angeles County: Central Los Angeles and the San Fernando Valley (SFV). LULC properties of particular interest in this study are albedo and tree fraction. High spatial density meteorological observations are obtained from 76 personal weather-stations. Observed air temperatures were then related to the spatial mean of each LULC parameter within a 500 m radius "neighborhood" of each weather station, using robust regression for each hour of July 2015. For the neighborhoods under investigation, increases in roof albedo are associated with decreases in air temperature, with the strongest sensitivities occurring in the afternoon. Air temperatures at 14:00-15:00 local daylight time are reduced by 0.31 °C and 0.49 °C per 1 MW increase in daily average solar power reflected from roofs per neighborhood in SFV and Central Los Angeles, respectively. Per 0.10 increase in neighborhood average albedo, daily average air temperatures were reduced by 0.25 °C and 1.84 °C. While roof albedo effects on air temperature seem to exceed tree fraction effects during the day in these two regions, increases in tree fraction are associated with reduced air temperatures at night.

Hybrid aluminum dialkylphosphinates were synthesized from mixed diethyl-, ethylisobutyl-, and diisobutylphosphinates and Al3+ in water. The XRD, DSC, and TGA results of these Al phosphinates established that phosphinate ligands are randomly distributed in the species. The thermal and thermoxidative stabilities of the hybrid phosphinates were easily adjustable by varying the ratio of phosphinate ligands, a desirable feature for efficient flame retardants. The hybrid aluminum dialkylphosphinates with a relatively low ratio of diethylphosphinate demonstrated higher efficiency than Al diethylphosphinate and Al diisobutylphosphinate in flame-retarding polyamide 66. Detailed investigations on the thermal and thermoxidative stabilities of Al dialkylphosphinates and the morphologies of char obtained in UL-94 tests revealed that timely vaporization of degradation products of hybrid dialkylphosphinates at a temperature which closely matches the degradation temperature of polyamides and their ability to promote char formation of polyamides are two key factors which contribute to the excellent performance of hybrid aluminum dialkylphosphinates. [ABSTRACT FROM AUTHOR]

An improved synthetic X- control chart based on hybrid adaptive scheme and run rule scheme is introduced to enhance the statistical performance of traditional synthetic X- control chart on service and management operation. The proposed scientific hybrid adaptive schemes consider both variable sampling interval and variable sample size scheme. The properties of the proposed chart are obtained using Markov chain approach. An extensive set of numerical results is presented to test the effectiveness of the proposed model in detecting small and moderate shifts in the process mean. The results show that the proposed chart is quicker than the standard synthetic X- chart and CUSUM chart in detecting small and moderate shifts in the process of service and management operation. [ABSTRACT FROM AUTHOR]